• Title/Summary/Keyword: $SO_3$ 함량

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Sulfur Dioxide, Mineral Contents and Physicochemical Properties Generated during Manufacture of Bamboo Salt (죽염 제조공정에 따른 이산화황, 미네랄 함량 및 이화학적 특성)

  • Kim, Hag-Lyeol;Lee, Seong-Jae;Lee, Jung-Hee;Kim, In-Cheol
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.43 no.8
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    • pp.1248-1256
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    • 2014
  • The purpose of this study was to investigate the mechanisms of behind $SO_2$ formation and elevated cause of reducing power in purple bamboo salt (PBS) along with an analysis of physicochemical properties, content of sulfur compounds, oxidation reduction potential (ORP), mineral contents of salt type (MSS, mudflat solar salt; BS, bamboo salt), and addition of raw bamboo (RB). $SO_2$ content of 630 ppm was detected in PBS. $SO_2$ was not detected in MSS, BS, or RB, whereas $SO_2$ (782 ppm) from $K_2SO_4$ was detected after heating a NaCl, KCl, $MgCl_2$, $MgSO_4$, MgO, $CaCl_2$, $K_2SO_4$, and $FeSO_4$ with RB. $SO_2$ content of BS increased with baking time, and it originated from BSRB1 (13.88 ppm) to BSRB4 (109.13 ppm). $SO_3{^{2-}}$ originated only from MSSRB4 and BSRB2~BSRB4. Sulfate ion content decreased along with increasing $SO_2$ and sulfite ion contents. ORP increased with baking time of MSS and BS, and it was present at higher levels in BSRB4 (-211.40 mV) of BS than MSS. Insoluble content was higher in BS than MSS. Further, Ca, K, and Mg ion contents decreased in MSS and increased in BS with baking time. BSRB4 had 1.4 fold higher levels of Ca, 1.5 fold higher levels of Mg, and 1.8 fold higher levels of K than BS. Li, Al, Mn, Fe, and Sr in MSS as well as Al, Fe, and Ni in BS increased with baking time. Anions (Cl, $NO_3$, and Br) and heavy metals (Pb, Cd, Hg, and As) between MSS and BS were not significantly different. These results suggest that the reducing power of BS was due to $SO_2$ and sulfite ion. To increase the amounts of these compounds and reducing power, higher melting temperature and longer baking time are necessary along with BS, which is created by the addition of RB to roasted salt.

Contents of Cr and Co in Some Fisheries Caught in the West Coast (서해안지역 어패류의 크롬(Cr)과 코발트(Co) 함량)

  • Kim, Ae-Jung;Kim, Sun Yeou;Lee, Won-Chu
    • Analytical Science and Technology
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    • v.11 no.1
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    • pp.29-35
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    • 1998
  • This study was performed to assess the levels of the Cr and Co in fisheries caught from the some areas of west coast in Korea. The samples were 26 kinds of fishes, 19 kindly of Mollusca and 3 kinds of Crustacea. They were ashed with 5 ml $HNO_3$ and then wet-decomposed with 10 ml of a mixture of $HNO_3:H_2SO_4:HClO_4$ (10:1:4). After ashing of samples, the amounts of Cr and Co in the samples were determined by ICP-AES analysis. The moisture content of molluscans was significantly higher than that of crustaceans (p<0.05), but there was no significant difference among fisheries in the Cr content. And the Co content of crustaceans was significantly higher than that of fishes and molluscans (p<0.001). There was no significance between contents of Cr and Co in fisheries. The Cr content of Arkshell was 422.00 ppm, which was the most amount compared with those of the other samples. And the Co in Myong-Ge was 3.78 ppm, which was the most amount. Areliscus honaleus (Cr:2.76 ppm, Co:0.97 ppm), Solen (Cr:6.56 ppm, Co:1.59 ppm) and dried barley shrimp (Cr:1.06 ppm, Co:0.90 ppm) contained great amount of Cr and Co.

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중국의 유황시비 및 유환연구 개관

  • Cao Zhihong;Hu Zhengyi
    • Proceedings of the Mineralogical Society of Korea Conference
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    • 1996.10a
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    • pp.61-72
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    • 1996
  • 중국 토양표토의 유황함량은 27에서 967mg S/kg(평균 233.2mg S/kg, n=632)범위에 있다. 이중 홍토(Haplic Acrisols)와 황갈색토(Eutric Cambisols)는 양쯔 및 Huaihe강 사이에 중국 중앙에 분포하고 유황함량은 각각 146과 159mg S/kg이다. 황색 목장토(Gleyic Cambisols)와 회색 목장토(Umbric Fluvisols)는 가장 높은 전 유황함량과 가장 높은 유황공급력을 가지고 있으나 제일 인산석회 침출 유황함량(현지유효 유황함량으로 평가)은 가장낮다. 그러나 황갈색 및 홍토는 이와는 반대 특성을 지니고 있다. Shajiang 흑토(Calcic Vertisols)와 논토양(Mollic/Eutric Fluvisols과 Anthraquic 상)은 총 유황함량, 인산 침출 유황함량과 잠재 유황 공급력에서는 중간에 속하고 남부 Huaihe강에 걸쳐있는 논토양에서 유황함량은 재배기간중 균형 상태에 있으나 전(前)작물에서 특히 밀과 유채에서는 부족한 상태이다. 황산염($SO_4^{2-}$)은 토양중 상하로 이동 되면서 균형을 유지하여 토양 수분함량과 밀접한 관계가 있다. 따라서 제일인산칼슘 용액침출 유황 함량을 가지고 표토에서 유황의 과부족을 진단하기는 그리 쉬운 일이 아니다 중국에서 수행된 유황시비 시험에서 20개 작목에서 평균 $4.3-40\%$의 수량증수를 기록하였으며 유황시비는 증수뿐만 아니라 작물의 질을 개선하나 담배잎의 연소성은 유황함량과 부의 상관이 있다.

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The Analysis of Cordycepin and Alcohol Content in accordance with The Various Manufacturing Process of The Liqueur Containing The Cordyceps Extract (동충하초 추출물을 함유한 리큐르의 제조공정에 따른 Cordycepin 및 Alcohol 함량 분석)

  • Choi, Seon-Hyo;Kwon, Sang-Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.12
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    • pp.8292-8296
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    • 2015
  • We manufactured a liqueur containing Cordyceps extract. 21 kinds of the liqueur were manufactured and analyzed the cordycepin content, cordycepin stability and alcohol content. Cordycepin content was detected up to $58{\mu}g/mL$ in DL-3(adding Cordyceps militaris and leached for 3 months). Results of Alcohol content analysis, Methanol was not detected in all samples. Ethanol contents showed at 31.4% from the Leaching process for 3 months after distillation, and at 17.2% from the rice wine adding Cordyceps militaris 8 g. In the results of the Cordycepin content stability analysis, the Cordycepin content decreased during storage period little by little, so our considered opinion is that the cordycepin content should be increased slightly when producing as products.

Influences of Phosphorus Content and Phytase Activity from the Vermicomposting Environment (Vermicomposting 조건에서 분리한 Phytase의 활성화의 인 함량에 미치는 영향)

  • 이주삼
    • Journal of Animal Environmental Science
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    • v.6 no.1
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    • pp.45-52
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    • 2000
  • The effect of earthworm on the recycling or control of organic P in environment has been investigated. The activity of phytase(myo-inositol hexaposphate phosphohydrolase, EC 3.1.3.8) produced by isolated microoganisms from vermicomposted cow manure was usually higher than that of phytase produced by isolated microorganisms from composted cow manure. However the activity of phytase excreted by seperated earthworm(Eisenia foetida) was not detected. The concentration of total P and available P was revealed 2.88%, 0.22% in composted cow manure and 1.70% 0.14% in vermicomposted cow manure.

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Effect of Vanadium Loading Amount on Pt/V/TiO2 Catalyst on NH3-SCO Reaction (NH3-SCO 반응에서 Vanadium 담지함량이 Pt/V/TiO2 촉매에 미치는 영향)

  • Kim, Min Su;Kim, Ki Wang;Hong, Sung Chang
    • Applied Chemistry for Engineering
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    • v.33 no.6
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    • pp.594-599
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    • 2022
  • In the study, NH3-SCO (selective catalytic oxidation) reaction activity accodrding to vanadium loading amount were compared when preparing Pt/V/TiO2. Considering both NH3 conversion rate and N2 selectivity, V 2 wt% loading of the catalyst showed the best activity. When the correlation between physical/chemical characteristics and reaction activity was confirmed, it was confirmed that the increase in lattice oxygen and (V3+ + V4+) ratios were active factor. In addition, when the SO2 durability experiment was conducted using the best catalyst, it was confirmed that the influence was insignificant even if the high concentration of SO2 was injected.

Preperation and Flavor Characteristics of Seasoning Oil for Chinese Dish (중화요리용 향미유의 제조 및 향미특성)

  • Koo, Bon-Soon
    • Journal of the Korean Society of Food Culture
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    • v.20 no.2
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    • pp.214-220
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    • 2005
  • Seasoning oil (SO) for Chinese dish was manufactured from the combination of Maillard reaction for methionine and xylose with autoclaving method. Volatile compounds were determined by GC, GC-MSD for this SO and 3 kinds of seasoning jajang samples which was obtained from restaurant. From this SO 61 kinds-404.92ppm volatile compounds were separated and identified. And from 3 samples of restaurant, 39 kinds-333.52ppm, 42 kinds-330.01ppm, 42 kinds-393.18ppm obtained respectively. Major volatile components of SO were diallyl disulfide, pentane, diallyl trisulfide, t,t-2,4-decadienal and zinngiberene. Those contents were 40.15ppm, 32.32ppm, 19.57ppm, 15.06ppm and 13.23ppm, respectively. Major volatile components in 3 kinds samples were pentane, propenal, hexanal, t-2-heptanal, 2,4-heptadienal, t,t-2,4-decadienal and unknown components. The volatile components of SO were very similar to 3 samples,

Soil Texture, Electrical Conductivity and Chemical Components of Soils under the Plastic Film House Cultivation in Northern Central Areas of Korea (중북부지역(中北部地域) 시설원예지(施設園藝地) 토양(土壤)의 토성(土性), 염농도(鹽濃度) 및 화학성분(化學成分)의 조성(組成))

  • Jung, Goo-Bok;Ryu, In-Soo;Kim, Bok-Young
    • Korean Journal of Soil Science and Fertilizer
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    • v.27 no.1
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    • pp.33-39
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    • 1994
  • This survey was conducted to investigate the factors affecting on salt accumulation and chemical components of soils cultivated with horticulture crops in plastic film houses. The soil samples were taken from 40 sites in the northern central areas of Korea and were analyzed for the chemical properties and soil separates. The data were evaluated with soil texture and years of cultivation as major factors. The results are summarized as follows : 1. The chemical properties of surface soils in plastic film house were pH 5.80, EC $3.59mScm^{-1}$, O.M. 4.20%, Av. $P_2O_5$ 1,178ppm, $NO_3-N$ 180ppm, Av. $SO_4{^{2-}}$ 353ppm, $Cl^-$ 240ppm, Ex. Na 0.40me/100g. 2. Compared to the outside soil of plastic film house, the inside soil had 2.5~3 times higher contents of $NO_3-N$, Av. $SO_4{^{2-}}$ and $Cl^-$, 1.2~1.8 times higher exchangeable base elements, and 2.8 times higher electrical conductivity. But pH value of the inside soil was lower than the outside soil by 0.3 pH unit. 3. Soil texture classification showed that sandy loam, loam and silt loam were 32.5 %, 37.5 %, and 30.0 %, respectively. The contents of $NO_3-N$, Av. $SO_4{^{2-}}$, $NH_4-N$ and EC value were very high in silt loam soils. Av. $P_2O_5$ content and pH value of sandy loam soils were higher than those of silt loam and loam soils. 4. The contents of O.M. and Av. $P_2O_5$ were higher in long term cultivation, but the contents of $NO_3-N$, Av. $SO_4{^{2-}}$, $Cl^-$, Ex. Mg and Ex. Na including EC of the soil with 2~4 years cultivation were higher than those of the soil with above 5 years cultivation. 5. Multiple linear regression analysis showed that contribution degree of soil chemical properties to the EC was high in the order of $NO_3-N$ > Av. $SO_4{^{2-}}$ > Ex. Na > $Cl^-$ > Av. $P_2O_5$ > $NH_4-N$ > Ex. Mg>Ex. Ca. Among the soil chemical properties the contribution of anions was remarkably high. 6. EC value correlated with ${\sum}A$(total content of anions)as $r=0.932^{**}$ and with ${\sum}C$(total content of cations) as $r=0.452^{**}$.

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Mineralogy of Alunite from the Sungsan Mine (성산광산(聲山鑛山) 명반석(明礬石)의 광물학적(鑛物學的) 특성(特性))

  • Cho, Hyen Goo;Kim, Soo Jin
    • Journal of the Mineralogical Society of Korea
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    • v.2 no.2
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    • pp.81-89
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    • 1989
  • Alunite occurs as massive, cavity-filling and veinlets in the Cretaceous Hwangsan Formation in the Sungsan mine, Korea. It is a hydrothermal alteration product of rhyolitic tuffs, and associated with dickite, quartz and barite. The average chemical formula of alunite in the mine is $(K_{0.93}Na_{0.07})_{1.00}Al_{3.00}(SO_4)_{2.00}(OH)_6$. Atomic percentage of Na substituting for K in A site of the alunite structure varies from 5.9 to 9.2. Unit-cell volume and c dimension decrease with increasing Na atomic percentage. On the basis of thermal and high temperature XRD analyses, the decomposition of alunite into $KAl(SO_4)_2$ and $NaAl(SO_4)_2$ concomitant with the liberation of structural water (12.86%) occurs at about $550^{\circ}C$. The reconstruction of $KAl(SO_4)_2$ and $NaAl(SO_4)_2$ to $Al_2(SO_4)_3$, arcanite and thenardite, and the crystallization of ${\gamma}-Al_2O_3$ take place at about $720^{\circ}C$. The destruction of $Al_2(SO_4)_3$ structure takes place at about $760^{\circ}C$ removing 3/4 of total $SO_3$ (27.32%).

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Geochemical and Environmental Isotope Study on the Groundwater from the Youngcheon Area, Gyeongbuk Province (경북 영천지역 지하수의 지구화학 및 환경동위원소 연구)

  • Kim, Geon-Young;Koh, Yong-Kwon;Bae, Dae-Seok;Won, Chong-Ho;Jung, Do-Hwan;Choi, Byoung-Young
    • Journal of Soil and Groundwater Environment
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    • v.12 no.4
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    • pp.35-53
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    • 2007
  • Geochemical and isotope studies on the groundwater system of the Youngcheon area were carried out. Most groundwaters belong to Ca-$HCO_3$ and Ca-$SO_4$ types and some groundwaters belong to Na-$HCO_3$ type. Geochemical characteristics of these groundwaters were mainly affected by their basement rocks around the boreholes. High $SO_4$ content of groundwater is the result of reaction with sulfate or sulfide minerals in the host rock. Ca was originated from the carbonate minerals in the sedimentary rock. After the groundwater was saturated with calcite, the Na-$HCO_3$ type groundwaters were evolved by the reaction with plagioclase for a relatively long residence time. This explanation was supported by low tritium contents of Na-$HCO_3$ type groundwaters. ${\delt}a^{18}O$ and ${\delta}D$ data indicate that the groundwaters are of meteoric water origin and there was no difference between the various types of waters. Grondwaters from the boreholes BH-1, BH-9 and BH-12 showed the geochemical and isotopic characteristics of deep groundwater. Most borehole groundwaters except them did not show the systematic geochemical variations with sampling depth indicating that the shallow and deep groundwaters were mixed with each other throughout the study area. The results of water quality analysis indicate that the study area is highly contaminated by the introduction of agricultural sewage.