• Title/Summary/Keyword: $SF_6/CO_2$

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A Study on Greenhouse Gas Inventories for Regional Governments (A Case Study of Jeonbuk Province) (지자체 온실가스 인벤토리 구축연구 - 전라북도 사례)

  • Jang, Nam-Jung
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.7
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    • pp.565-572
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    • 2009
  • Greenhouse gas(GHG) inventories and basic strategies for Jeonbuk regional government were established to reduce greenhouse gas emissions. The method to construct GHG inventories of Jeonbuk followed the 'Revised IPCC 1996 Guidelines'which was used for the 'Third National Communication of the Republic of Korea under UNFCCC'. Korean government could use primary energy consumption for the energy industries section in the national GHG inventories. However, regional governments should use secondary energy consumption (included electricity consumption) for the energy industries section for their GHG inventories because they could not control the emission of energy transformation section. In the result of Jeonbuk GHG inventories in 2006, carbon dioxide($CO_2$) emissions from fuel combustion covered 87.1% of total emissions. Methane($CH_4$), carbon dioxide($CO_2$) from other sections, nitrous oxide($N_2O$) and F-gas(HFCs, PFCs, $SF_6$) accounted for 8.1, 2.2, 1.6 and 1.0% of total emissions, respectively. The sectional emission decreased in the order of the energy(88.0%), agriculture(7.6%), waste(2.3%) and industrial processes(2.1%) section. The energy industries section that contained electricity consumption was the most dominant emission source in the energy section. F-gas consumption, rice cultivation and waste incineration were main emission sources in the industrial processes, agriculture and waste section, respectively. In this study, basic directions of each section were established by the results of Jeonbuk GHG inventories in 2006.

A study for breakdown characteristics of dry-air, $N_2/O_2$ and $N_2$ gas with AC voltage (AC 전압하에 Dry-air, $N_2/O_2$ 합성 가스, $N_2$ 가스의 절연특성 비교 분석)

  • Lee, Y.J.;Koo, J.Y.;Chang, Y.M.;Jung, S.Y.;Park, J.H.;Son, U.K.;Lee, S.K.
    • Proceedings of the KIEE Conference
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    • 2007.11a
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    • pp.180-181
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    • 2007
  • 현재 초고압 송변전기기에 적용되고 있는 $SF_6$가스는 절연 및 소호성능이 우수하며 회복특성이 뛰어나기 때문에 초고압 기기의 절연매체로서 널리 사용되고 있으나 가격이 비싸고 저온 및 높은 압력에서 액화되기 쉬우며 대기 중으로 방출될 경우에는 온실효과를 야기 시키는 단점을 가지고 있다. 최근 환경에 대한 관심과 규제가 높아지면서 온실가스에 대한 규제로서 교토 의정서가 정식 발효됨에 따라 $SF_6$가스는 금후 총량 제한에 의해 사용량이 규제 받을 가능성이 대단히 높다. 따라서 $SF_6$ 가스와 Air, N2, CO2, N2/O2 합성가스, He 등과 혼합된 절연매체들이 하나의 대안으로 연구되었다. 본 연구에서는 대체 절연가스로 주목받고 있는 Dry-air(공기 중에서 수분과 각종 불순물을 제거한 공기), N2/O2 합성가스, N2 가스를 4mm 간격의 준평등(구대구전극) 전계에서 0.5atm에서 9atm까지 변화시켰을 때 절연내력을 비교하였다. 또한, 보다 평등전계에 가까운 10mm의 간격에서도 0atm에서 4atm까지 동일한 전압을 인가하여 절연내력을 비교 분석하였다.

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Gas Exchange Rates Measured Using a Dual-Tracer ($SF_6$ and $^3He$) Method in the Coastal Waters of Korea

  • Lee, Hyun-Woo;Lee, Ki-Tack;Kaown, Duk-In
    • Ocean Science Journal
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    • v.43 no.1
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    • pp.17-24
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    • 2008
  • Over a period of 5 days between August 12 and 17, 2005, we performed a gas exchange experiment using the dual tracer method in a tidal coastal ocean located off the southern coast of Korea. The gas exchange rate was determined from temporal changes in the ratio of $^3He$ to $SF_6$ measured daily in the surface mixed layer. The measured gas exchange rate($k_{CO_2}$), normalized to a Schmidt number of 600 for $CO_2$ in fresh water at $20^{\circ}C$, was approximately $5.0\;cm\;h^{-1}$ at a mean wind speed of $3.9\;ms^{-1}$ during the study period. This value is significantly less than those obtained from floating chamber-based experiments performed previously in estuarine environments, but is similar in magnitude to values obtained using the dual tracer method in river and tidal coastal waters and values predicted on the basis of the relationship between the gas exchange rate and wind speed (Wanninkhof 1992), which is generally applicable to the open ocean. Our result is also consistent with the relationship of Raymond and Cole (2001), which was derived from experiments carried out in estuarine environments using $^{222}Rn$ and chlorofluorocarbons along with measurements undertaken in the Hudson River, Canada, using $SF_6$ and $^3He$. Our results indicate that tidal action in a microtidal region did not discernibly enhance the measured $k_{CO_2}$ value.

Comparison on the Energy Consumption of the Vacuum Evaporation and Hydrated-Based Technologies for Concentrating Dissolved Ions (용존 이온 농축을 위한 진공 증발 기술과 하이드레이트 기반 기술의 소모 에너지 비교)

  • Han, Kunwoo;Rhee, Chang Houn;Ahn, Chi Kyu;Lee, Man Su
    • Korean Chemical Engineering Research
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    • v.57 no.3
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    • pp.378-386
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    • 2019
  • In the present paper we report the calculation results of operation energy consumption for dissolved ions concentration technologies using vacuum evaporation (VE) and hydrate formation. Calculations were conducted assuming the tenfold concentration of saline water (0.35 wt% NaCl solution) of 1 mol/s at room temperature and atmospheric pressure employing vacuum evaporation at $69^{\circ}C$ and 30 kPa and hydrate-based concentration using $CH_4$, $CO_2$ and $SF_6$ as guest molecules. Operation energy consumption of VE-based concentration resulted in 47 kJ/mol, whereas those of hydrate-based concentration were 43, 32, and 28 kJ/mol for $CH_4$, $CO_2$ and $SF_6$ hydrates, respectively. We observe that hydrate-based concentration can a competitive option for dissolved ions recovery from energy consumption standpoint. However, the selection of guest gas is very critical, since it accordingly determines the hydration number, the hydrate formation energy, gas compression energy, etc. The selection of guest gas, separation of concentrated brine and water phases, and the enhancement of hydrate formation rate are the key factors for the commercialization of hydrated-based technology for concentrating dissolved ions.

Nanophase Iron Clusters Produced by CO₂Laser Multiphoton-Decomposition of $Fe(CO)_5$ : Their Generation and Characterization

  • Lee, G. H.;Huh, S. H.;Jung, H. I.
    • Bulletin of the Korean Chemical Society
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    • v.17 no.8
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    • pp.686-688
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    • 1996
  • We have produced nanophase iron clusters inside a gas cell by decomposing iron pentacarbonyls from the mixture of ~20 Torr Fe(CO)5/~3 Torr SF6 with a pulsed CO2 laser. The product displayed a black tint. Its composition was identified to be mostly iron from an inductively coupled plasma (ICP) atomic emission spectrum. The X-ray diffraction (XRD) pattern indicates a body-centered cubic structure for the cluster. A transmission electron micrograph proves that their diameter ranges between 50 and 70 Å and their average diameter is 60 Å.

A Study of Manufacturing AZ91D Mg Alley Wheel (마그네슘 합금제 휠 제조에 관한 연구)

  • Kim, Jung-Gu;Shin, Il-Seong;Kum, Dong-Hwa
    • Korean Journal of Materials Research
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    • v.9 no.7
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    • pp.715-723
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    • 1999
  • Magnesium has been used as wheel materials in the automotive industry for more than 20 years. The magnesium wheels, which are lighter by 25% than aluminum wheels, provide easy controllability providing excellent road holding by the reduction of weight. The purpose of this work is to develop cast AZ91D alloy wheel by sand cast and permanent mold cast. The fluxless melting with the protective gas $(SF_6+CO_2)$ was Performed to eliminate oxidation of melt and impurity. The transfer of molten magnesium to the mold was done by using gas-pressurized Pump system through the heated pipe. The mechanical properites of AZ91D alloy wheel were investigated as a function of heat treatment, ingot composition.

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Enhancement of Anti-Inflammatory Activity of PEP-1-FK506 Binding Protein by Silk Fibroin Peptide

  • Kim, Dae-Won;Hwang, Hyun-Sook;Kim, Duk-Soo;Sheen, Seung-Hoon;Heo, Dong-Hwa;Hwang, Gyo-Jun;Kang, Suk-Hyung;Kweon, Hae-Yong;Jo, You-Young;Kang, Seok-Woo;Lee, Kwang-Gill;Park, Jin-Seu;Eum, Won-Sik;Cho, Yong-Jun;Choi, Soo-Young
    • Journal of Microbiology and Biotechnology
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    • v.22 no.4
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    • pp.494-500
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    • 2012
  • Silk fibroin (SF) peptide has been traditionally used as a treatment for flatulence, spasms, and phlegm. In this study, we examined whether SF peptide enhanced the anti-inflammatory effect of PEP-1-FK506 binding protein (PEP-1-FK506BP) through comparing the anti-inflammatory activities of SF peptide and/or PEP-1-FK506BP. In the presence or absence of SF peptide, transduction levels of PEP-1-FK506BP into HaCaT cells and mice skin and anti-inflammatory activities of PEP-1-FK506BP were identified by Western blot and histological analyses. SF peptide alone effectively reduced both mice ear edema and the elevated levels of cyclooxygenase-2, interleukin-6 and $-1{\beta}$, and tumor necrosis factor-${\alpha}$, showing similar anti-inflammatory effect to that of PEP-1-FK506BP. Furthermore, co-treatment with SF peptide and PEP-1-FK506BP exhibited more enhanced anti-inflammatory effects than the samples treated with SF peptides or PEP-1-FK506BP alone, suggesting the possibility that SF peptide and PEP-1-FK506BP might interact with each other. Moreover, the transduction data demonstrated that SF peptide did not affect the transduction of PEP-1-FK506BP into HaCaT cells and mice skin, indicating that the improvement of anti-inflammatory effect of PEP-1-FK506BP was not caused by enhanced transduction of PEP-1-FK506BP. Thus, these results suggest the possibility that co-treatment with SF peptide and PEP-1-FK506BP may be exploited as a useful therapy for various inflammation-related diseases.

A Study on the Greenhouse Gas Emission and Reduction Measures of Domestic Magnesium Production Process (국내 마그네슘 생산공정의 온실가스 배출량 산정 및 감축방안 연구)

  • Kim, Kyung-Nam;Im, Jin-Ah;Yoo, Kyung-Seun
    • Journal of Climate Change Research
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    • v.5 no.3
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    • pp.219-230
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    • 2014
  • In this study, greenhouse gas emission of magnesium industry was estimated and the reduction potential of the greenhouse gas emission was evaluated with reduction technologies. Default value of IPCC guideline was used to calculate the greenhouse gas emission and $SF_6$ alternatives were considered in reduction potential. Import of magnesium ingot was 22,806 ton in 2013, which will be expected to increase to 81,700 ton with 20% rate in 2020. Magnesium ingot was consumed to produce magnesium alloy in diecasting process. Recently, commercial production of crown magnesium and magensium plate began. Based on ingot consumption, $CO_2$ emission of domestic magnesium industry was estimated to 504,000 ton, which is about 0.79% of domestic industrial emissions. Reduction potential of diecasting process was estimated to 489,320 ton by changing SF6 to alternative gases such as HFC-134a, Novec-612. Emission factor of Tier 3 level should be developed to enhance the accuracy of greeenhouse gas emission of magnesium industry.

Process Optimization for Cookies with Low-marketable Israeli Carp Cyprinus carpio Using Response Surface Methodology (RSM) (반응표면분석법을 활용한 저상품성 향어(Cyprinus carpio) 쿠키 제조 공정 최적화)

  • Ye Youl Kim;Sang In Kang;Jin-Soo Kim
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.56 no.3
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    • pp.284-292
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    • 2023
  • This study was conducted to optimize the cookie preparation using Israeli crap Cyprinus carpio paste (C-ICP). The results of response surface methodology suggested the selection of other supplementary materials/[soft flour (SF) + ICP] (X1) and SF/ICP (X2) as independent variables, and hardness (Y1), yellowness (Y2), amino acid nitrogen (Y3), and overall sensory acceptance (Y4) as dependent variables. The optimal conditions of OS, SF, and ICP were 35.0%, 40.3% and 24.7%, respectively, and the predicted values of the multiple response optimal conditions Y1, Y2, Y3, and Y4 were 2,006.2 N/m2, 21.1, 30.0 mg/100 g, and a score of 6.6, respectively. Under the optimum conditions, experimental values of Y1, Y2, Y3, and Y4 were 2,010.5 ± 22.3 N/m2, 21.6 ± 0.5, 29.6 ± 0.7 mg/100 g, and a score of 6.9 ± 0.3, respectively, which were not significantly different from the predicted values (P < 0.05). The results on hardness, moisture, VCI yellowness, and lightness suggested that the optimum heating period was 20 min. C-ICP prepared under the optimum conditions was superior in sensory evaluation to cookies without the Israeli carp paste.