• E2M - 전기 전자와 첨단 소재
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• 제9권4호
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• pp.351-356
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• 1996

The quartemary system ceramics 0.5[xPb(Zn$_{1}$3/Nb$_{2}$3/)O$_{3}$-(1-x)Pb(Ni$_{1}$3/Nb$_{2}$3/)O$_{3}$]-0.5[yPbTiO$_{3}$-(1-y) PbZrO$_{3}$ for piezoelectric actuators were prepared bv the were added to the raw materials up to 5 mole. Sintering temperature was varied form 1000.deg. C to 1200.deg. C. Sintering characteristrics, dielectric and piezoelectric properties were then investigated. Piezoelectric properties of sample prepared by the molten salt method were improved compared to those prepared by the conventional method. Addition of PZN shifted morphotropic phase boundary to more Zr-rich composition and decreased the piezoelectric properties.

• 센서학회지
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• 제13권2호
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• pp.152-156
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• 2004

The dielectric and piezoelectric properties of 0.36Pb($Sc_{1/2}Nb_{1/2}$)$O_{3}$-0.25Pb($Ni_{1/3}Nb_{2/3}$)$O_{3}$-0.39Pb$TiO_{3}$ (hereafter PSNNT) at the morphotropic phase boundary (MPB) composition were investigated with $0{\sim}2.5$ mot% $MnO_{2}$ doping. Bulk density, dielectric loss and tetragonality of crystal structure were all improved with increasing $MnO_{2}$ additive content. With increasing $MnO_{2}$ additive content, the electromechanical coupling factor and quality factor were also increased: Electromechanical coupling $k_{p}$ and quality factor $Q_{m}$ at 2.0 mol% $MnO_{2}$ doping with were showed highest values of 55.6 % and 252, respectively.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2005년도 춘계학술발표대회 및 제8회 신소재 심포지엄 논문개요집
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• pp.64-64
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• 2005

• 한국재료학회:학술대회논문집
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• 한국재료학회 2012년도 춘계학술발표대회
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• pp.94.2-94.2
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• 2012

에너지 하베스터에 적용 가능한 $0.72Pb(Zr_{0.47}Ti_{0.53})O_3-0.28Pb((Ni_{0.55}Zn_{0.45})_{1/3}Nb_{2/3})O_3$ (PPZNN) 후막세라믹의 구조적 압전 특성을 조사하였다. $850^{\circ}C$에서 하소를 마친 파우더를 72시간 볼 밀링 처리한 후, 테잎 캐스팅 공정을 이용하여 0.3mm의 두께로 PPZNN 압전 세라믹을 제조하였다. $900^{\circ}C$에서 $1200^{\circ}C$까지 다양한 온도에 소결하여 온도가 증가될수록 정방형 구조로 상전이 거동하는 모습을 보였으며, 특히 $1050^{\circ}C$에서 소결된 PPZNN후막 세라믹은 이차상이 없는 고밀도의 미세구조가 관찰되었다. $d_{33}$=440 pC/N 그리고 kp = 0.46의 우수한 압전 특성을 보였으며, 에너지 변환 성능을 나타내는 $d33{\cdot}g33$ 값은 약 $20439{\times}10^{-15}\;m^2/N$ 로 매우 우수하였다. PPZNN후막 세라믹을 유니몰프 켄틸레버 형태로 제작하여 발전 평가하였을 때 저항이 470 $k{\Omega}$에서 969 ${\mu}W$ (4930 ${\mu}W/cm^3$)로 관찰되었다. PPZNN 후막 압전 세라믹은 향후 압전에너지 하베스터 소재로 다양한 응용분야에 사용될 것으로 예상된다.

• 한국전기전자재료학회논문지
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• 제19권3호
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• pp.222-227
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• 2006

RAINBOW(Reduced And Internally Biased Oxide Wafers) are a new class of high-displacement, piezoelectric actuator produced by selectively removing oxygen from one surface of ceramic using a high-temperature chemical reduction process. In this paper, RAINBOW actuator materials of $0.4Pb(Ni_{1/3}Nb_{2/3})O_3-0.6Pb(Zr_{x}Ti_{1-x})O_3$ ceramics were prepared. Its dielectric and piezoelectric properties were investigated in the vicinity of MPB. The piezoelectric properties showed the maximum value of ${\epsilon}r$ = 4871, $d_{33}$ = 610 ($10^{-12}$ m/V), $d_{31}$ = -299 ($10^{-12}$ m/V), $k_{33}$ = $71\%$, Qm = 70, in $0.4Pb(Ni_{1/3}Nb_{2/3})O_{3}-0.6Pb(Zr_{405}Ti_{595})O_3$ composition sintered at $1250^{\circ}C$. The strain - electric field characteristics of RAINBOW actuator were significantly improved comparison with the conventional bulk actuator. The prepared RAINBOW actuator showed about $390\;{\mu}m/100\;V$ displacement.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2007년도 제38회 하계학술대회
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• pp.1337-1338
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• 2007

In this study, in order to develop low temperature sintering ceramics for multilayer piezoelectric actuator, 0.07Pb$(Mn_{1/3}Nb_{2/3})O_{3}-xPb(Ni_{1/3}Nb_{2/3})O_{3}-(0.93-x)Pb(Zr,Ti)O_{3}$ ceramics system were fabricated using $Li_{2}CO_{3}-Bi_{2}O_{3}$-CuO sintering aids and the specimens were sintered at $930^{\circ}C$. Thereafter their piezoelectric and dielectric characteristics were investigated with the amount of PNN substitution. At 9[mol%] PNN substitution, electromechanical coupling factor (kp), mechanical quality factor (Qm) and piezoelectric constant ($d_{33}$) showed the optimum value of 0.60, 1323 and 387pC/N, respectively.

• 한국재료학회지
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• 제3권3호
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• pp.261-271
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• 1993

4.5 Pb($Zn_{1/3}Nb_{2/3})O_3-40.5Pb(Ni_{1/3}Nb_{2/3})O_3$-55PZT와 PLZT(10/70/30, 11/60/40)를 경사조성으로 하여 경사기능 재료를 제조하였으며, 그 유전 특성과 압전 변형율 특성을 조사하였다. 경사기능재료는 A/B/A의 세층으로 성형하고 소결한 후 한 층을 연마해내어 제작하였다. 닥터블레이드용 슬립에는 acrylic계 유기 결합제가 34-36wt% 혼합되었으며, 건조 후 균열이 없는 양호한 thick film을 제조하였다. $1250^{\circ}C$, 2시간의 소성에 의해 경사기능화된 시편은 Nb와 La등의 조성 차이에 의한 구배를 이루었으며, 구배영역은 약 30${\mu}$m 정도였다. 경사기능재료에서 유전상수나 큐리온도롸 같은 유전특성은 조합한 조성층의 특성들사이의 값을 나타내었다. 인가 전압에 따른 변형율 특성은 단일 조성의 시편보다 현저하게 증가하였다. 실제로 경사기능 압전엑튜에이터를 제조한 결과 약 3${\mu}$m/100V 정도의 변위향을 나타내었다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1995년도 하계학술대회 논문집 C
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• pp.1028-1030
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• 1995

In the fields of the optics, precise machine, semiconducting processing, the micro-positioning actuators are required for the control of position in the submicron range. In this study, $Pb(Ni_{1/3}Nb_{2/3})O_3-Pb({Zn}_{1/3}Nb_{2/3})O_3-Pb({Zr}_{1/2}Ti_{1/2})O_3$ ceramics were fabricated by solid state reaction. The structural, dielectric and electric properties were investigated for sintering condition. The specimen sintered at $1,150(^\circ}C)$ for 1hr, had the highest density and dielectric contant. The resistivity, dielectric and density were increased with increasing PZN contents.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1997년도 하계학술대회 논문집 C
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• pp.1326-1329
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• 1997

In this paper, PNN-PZN-PZT ceramics were fabricated with various mole ratio of the PZT[$Pb(Zr_{1/2}Tid_{1/2})O_3$]. PNN [$Pb(Ni_{1/3}Nb_{2/3})O_3$] and PZN[$Pb(Ni_{1/3}Nb_{2/3})O_3$ powders prepared by double calcination and PZT powders prepared by molten-salt synthesis method. The formation rate of perovskite phase in PNN-PZN-PZT ceramics could be obtained about 92% at PZT 0.3 mole ratio. The relative permittivity of specimen with PZT 0.3 mole ratio was shown 5,320 and appeared the relaxor ferroelectric feature. The maximum piezoelectric coefficient $d_{31}$ to be used for evaluation the displacement of piezoceramics in PNN-PZN-PZT ceramics was $324{\times}10^{-12}$(C/V) at the vicinity of morphotropic phase boundary and was larger than that of solid PZT ceramics($120{\times}10^{-12}C/V$).

• 대한전기학회:학술대회논문집
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• 대한전기학회 1997년도 하계학술대회 논문집 C
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• pp.1330-1332
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• 1997

In this paper, PNN-PZN-PZT ceramics were fabricated with various mole ratio of the PZT[$Pb(Zr_{1/2}Tid_{1/2})O_3$]. PNN [$Pb(Ni_{1/3}Nb_{2/3})O_3$] and PZN[$Pb(Ni_{1/3}Nb_{2/3})O_3$ powders prepared by double calcination and PZT powders prepared by molten-salt synthesis method. The formation rate of perovskite phase in PNN-PZN-PZT ceramics could be obtained about 92% at PZT 0.3 mole ratio. The relative permittivity of specimen with PZT 0.3 mole ratio was shown 5,320 and appeared the relaxor ferroelectric feature. The maximum piezoelectric coefficient $d_{31}$ to be used for evaluation the displacement of piezoceramics in PNN-PZN-PZT ceramics was $324{\times}10^{-12}$(C/V) at the vicinity of morphotropic phase boundary and was larger than that of solid PZT ceramics($120{\times}10^{-12}C/V$).