• Title/Summary/Keyword: $PO{_4}^{3-}-P$

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Investigation of Nutrient Release from the Sediments Near Weir in the Namhan River (남한강 보 구간 퇴적물의 영양염류 용출에 관한 연구)

  • Kim, Hye Yeon;Huh, In Ae;Choi, Jung Hyun
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.8
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    • pp.554-563
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    • 2013
  • The purpose of this study is to evaluate the possibility of nutrient release at up and downstream of Kangchun weir, upstream of Yuju and Ipo weir in Namhan River. For this survey, we measured basic characteristics of the sediments (water content, ignition loss, TOC, TP, SRP, TN, phosphorus fractionation) and conducted nutrients release experiments under both aerobic and anaerobic condition. The overlying water from the sediment-water column was analyzed for nutrients (i.e. TP, $PO_4$-P, TN, $NO_3$-N, $NH_3$-N) everyday for 18days. Result of soil texture experiment showed that sediments are Sand. SRP concentration before the release experiment was different with the value after the release experiment. According to this result, we can find that there were more activated release processes in anaerobic condition. $PO_4$-P increased from 1 to 8 days and remained at the maximum value (7~8 days) afterward. The rapidly increase of $PO_4$-P was observed from 1 to 2~3 days whereas the TP continuously increase from 1 to 18 days. The $PO_4$-P release rate calculated by up to 7~8 days data highly correlated with initial SRP concentration with $R^2$=0.8502. $NO_3$-N release rate appears constantly decreasing trend as -5.7~-3.08 $mg/m^2{\cdot}day$, otherwise the $NH_3$-N release rate, by-product of a organic matter decomposition using nitrate as electron acceptor, was 0.57~2.41 $mg/m^2{\cdot}day$. Substantial portion in TN can be induced by organic nitrogen which originated from the tributary passing through non-point pollutant source. Compared with other similar researches, phosphorus and nitrogen release rates obtained in this study can be considered as relatively low values. Since this study targeted the sediments accumulated by one time of flooding season, there are limitation to generalize theses results. Therefore, it is necessary to consistently monitor and investigate the accumulation of nutrients in the sediment for understanding the effect of weir construction on the overlying water quality.

Variations of pH, EC and anion of stemflow and throughfall in Quercus mongolica and Q. variabilis (신갈나무와 굴참나무 수간류, 임내우의 pH, 전기전도도 및 음이온 변화)

  • Kim, Min-Sik;Seomun, Won;EZAKI, Tsugio;Chun, Kun-Woo
    • Journal of Forest and Environmental Science
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    • v.16 no.1
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    • pp.82-92
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    • 2000
  • The pH, EC and anion of stemflow in Quercus mongolica and Q. variabilis were surveyed and analyzed in order to examine the relationship between watershed conservation function and flood control function of forest in quality and quantity in the Experiment Forests. College of Forest Sciences, Kangwon National University. The results were as follows: 1. pH values of rainfall ranged from 4.47 to 6.55(average: 5.39), and pH values of throughfall ranged from 4.07 to 6.25(average 5.45) for Q. mongolica and from 4.34 to 6.57(average : 5.62) for Q. variabilis, and thus pH values were not different between these two species. Also, pH values of stemflow from Q. mongolica ranged from 4.08 to 6.13(average 5.17) and those of stemflow from Q. variabilis ranged from 3.62 to 6.11(average : 4.68), and pH values of rainfall gave little influence on pH values of stemflow. But, pH values of stemflow in Q. mongolica and Q. variabilis appeard significantly lower in spring and than those in summer and autumn. 2. EC of rainfall was $3.0{\sim}62.6{\mu}s/cm$(average: $18.8{\mu}s/cm$), and EC of throughfall was $5.4{\sim}85.0{\mu}s/cm$(average : $25.1{\mu}s/cm$) for Q. mongolica and $5.0{\sim}253.0{\mu}s/cm$(average : $31.2{\mu}s/cm$) for Q. variabilis. Also, EC of stemflow from Q. mongolica ranged from 9.5 to $500.0{\mu}s/cm$(average : $81.8{\mu}s/cm$) and that of stemflow from Q. variabilis ranged from 11.5 to $534.5{\mu}s/cm$(average : $80.2{\mu}s/cm$). Seasonal EC of rainfall had little variation in the range of 20 to $30{\mu}s/cm$: EC of stemflow showed more than $100{\mu}s/cm$ from March to April and about $30{\mu}s/cm$ in summer period. Seasonal EC of stemflow varied so much and appeared high again from October to November. 3. $Cl^-$, $NO_3{^-}$ and $SO_4{^{2- }}$ concentrations of rainfall and throughfall were from 1 to 15ppm. and $PO_4{^{2- }}$ concentrations showed 0.57ppm and 0.23ppm in rainfall, 0.08ppm in Q. mongolica and 0.14ppm, 0.12ppm and 1.19ppm in Q. variabilis. Also, $Cl^-$, $NO_3{^-}$ and $SO_4{^{2-}}$ concentrations of stemflow were relatively higher than rainfall, and showed differences among seasons. $PO_4{^{2-}}$ concentration of rainfall and throughfall were not possible to observe, but $PO_4{^{2-}}$ concentrations of stemflow ranged from 0.08 to 31.99ppm(average : 3.22ppm) for Q. mongolica and that of stemflow ranged from 0.06 to 12.28ppm(average : 1.93ppm) for Q. variabilis.

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Pollutants Release from Sediments in Estuarine Reservoir (간척담수호 저층퇴적물의 오염물질 용출특성)

  • Jung, Kwang Wook;Yoon, Chun Gyeong;Lee, In Ho;Lee, Seung Il;Kang, Su Man;Ham, Jong Hwa
    • Journal of The Korean Society of Agricultural Engineers
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    • v.56 no.1
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    • pp.1-9
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    • 2014
  • Sediment pollutants have been considered an important source for the eutrophication of estuarine reservoir. In this study, the effects of pollutants released from bottom sediment to water column were investigated. Sediment samples were collected each two station from Namyang and Sukmoon estuarine reservoirs in August 2013. The fractionation result of sediment phosphorus indicated that Adsorbed-P ($36.7{\pm}8.84%$) and Nonapatite-P ($29.3{\pm}12.50%$) are the two dominant phosphorus groups in the sediments. For sediment release test, eight sets of acrylic chamber (0.3 m $diameter{\times}1m$ high, with 0.15 m sediment depth) were used with aerobic and anaerobic environment. Under anaerobic conditions, rates of $NH_4-N$ release from the sediments were highly variable, with final concentrations of $NH_4-N$ in the overlying water varying from between about 0.69~1.04 in Namyang and 2.58~4.23 mg/L in Sukmoon reservoir. The $NH_4-N$ release was active at the upstream around the confluence of tributary compared to downstream near the embankment. The $PO_4-P$ release was more obvious than $NH_4-N$ in anaerobic condition. The final $PO_4-P$ concentrations were approximately from two-fold to eight-fold higher than initial concentration. In terms of reservoir water quality management, not only tributary pollutants but also sediment nutrient loading is necessary to consider the water quality contribution.

Molecular Cloning, Expression Analysis and Enzymatic Characterization of Elastase-like Serine Protease from the Olive Flounder (Paralichthys olivaceus) (넙치로부터의 Serine Protease의 분자생물학적 클로닝, 발현, 특성분석)

  • Han, Jin-Wook;Seo, Jung-Soo;Ahn, Sang-Jung;Lee, Jin-Young;Park, Ju-Hyeon;Kim, Na-Young;Kim, Moo-Sang;Hwang, Jee-Youn;Chung, Joon-Ki;Lee, Hyung-Ho
    • Journal of Fisheries and Marine Sciences Education
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    • v.26 no.4
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    • pp.808-822
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    • 2014
  • 넙치 (Paralichthys olivaceus)로부터 elastase-like serine protease (PoElSp)를 암호화하는 cDNA를 클로닝하여 그 서열을 분석한 결과, PoElSp 유전자는 269 아미노산을 암호화하는 978염기쌍으로 구성되었다. PoElSp 유전자의 조직 특이적 발현 양상을 RT-PCR법으로 조사한 결과, 간, 비장 및 소장에서 그 발현이 크게 나타났다. lipopolysaccharide (LPS)로 인위적 세균감염을 유도한 후, 1시간째에 콩팥에서, 3시간째에는 근육에서, PoElSp 유전자의 발현이 크게 증가하였다. 또한, 이 유전자의 발현은 비장에서 LPS 주입 후 1-24시간동안 점차로 증가하였다. pro-mature PoElSp (proPoElSp)에 해당하는 cDNA를 pET32a 벡터 시스템을 이용하여 대장균에서 발현시켰다. 이 재조합 proPoElSp 단백질의 활성은 gelatin zymography 방법과 합성형광 Z-Phe-Arg-AMC의 분해법을 이용하여 측정하였다. 단백질 분해효소 활성을 위한 최적 pH는 7.5였다. 실험결과들을 종합하면, PoElSp 단백질은 면역 반응에서 중추적 역할을 하리라 판단된다.

Cultural Condition of Pseudomonas mendocina for Polysaccharide Production (Pseudomonas mendocina 에 의한 Polysaccharide 생산)

  • Yoo, Jin-Young;Chung, Dong-Hyo
    • Korean Journal of Food Science and Technology
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    • v.21 no.5
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    • pp.619-623
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    • 1989
  • The cultural condition of Pseudomonas mendocina for polysaccharide production was examined. The optimal medium contains following composition per liter of distilled water: Sucrose 23.75g, $(NH_4)_2SO_4$ 1.57g, Yeast extract 0.5g, $KH_2PO_4\;2.9g,\;MgSO_4.\;7H_2O\;1.0g,\;CaCO_3$ 2.5g. The optimum temperature and pH were $30^{\circ}C$ and 6.5. At the condition. Ps mendocina produced 5.98g/l of polysaccharide. The culture viscosity after 3 days was 191mPa.s at $70sec^{-1}$. The product yield $(Y_{p/s})$ and specific productivity $(Q_p)$ were 25.18% and 32.83mg/g-cell/h.

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A Study on the Removal of Nitrogen and Phosphorus of Municipal Wastewater with Biological Coated Media (미생물 코팅 담체를 이용한 하수의 질소$\cdot$인 제거에 관한 연구)

  • Kim Young-Gyu;Cho Il-Hyoung
    • Journal of Environmental Health Sciences
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    • v.32 no.1 s.88
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    • pp.27-35
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    • 2006
  • This study was carried out to investigate the removal of nitrogen and phosphorus in municipal sewage depending on existence of biological coated media in BCM reactor. The reactor with biological coated media is the process combining $A_2/O$ process. The removal efficiencies for $COD_{Mn},\; BOD_5,\;SS$, T-N and T-P were $78\%,\;90.5\%,\;92.3\%,\;61.9\%,\;60.2\%$, respectively. The specific nitrification rate$(mgNO_3-N/gMLSS{\cdot}d)$ of Contact aeration basin was 52.2 and the specific denitrification rate$(mgNO_3N/gMLSS{\cdot}d)$ in anoxic basin was 95.1. Also, phosphorus release$(mgPO_4-P/gMLSS{\cdot}d)$ in Anaerobic basin was 71.8 and Phosphorus uptake$(mgPO_4-P/gMLSS{\cdot}d)$ in contact aeration was 27.1.

Application of major plant nutrient releasing model and N2O emissions to the leachate from the mixtures of rice hull biochar and organic fertilizer materials (왕겨 바이오차와 유기농자재 혼합에 따른 주요 양분 용출 모델 적용 및 N2O 배출량 산정)

  • DongKeon Lee;JaeLee Choi;ChangKi Shim;JooHee Nam;SeokIn Youn;JeongSeok Song;Dogyun Park;JoungDu Shin
    • Journal of the Korea Organic Resources Recycling Association
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    • v.31 no.3
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    • pp.43-53
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    • 2023
  • This batch experiment evaluated the impacts of major plant nutrient releases by applying the modified Hyperbola model on the leachates and N2O emissions from incorporated rice hull biochar with organic fertilizer materials. The treatments consisted of the control as incorporated with organic fertilizer materials, the incorporated rice hull biochar with organic fertilizer materials, and the incorporated plasma-activated rice hull biochar with organic fertilizer materials under redox conditions. The results indicated that the maximum release amount of NH4-N was 3486.3 mg L-1 in the control, and their reduction rates of NH4-N, NO3-N, PO4-P, and K were 8.0%, 17.5% 44.3.0% and 8.7%, respectively, relative to the control. In the control, the highest soluble amount of PO4-P was 681.0 mg L-1. The estimations for accumulated NH4-N, NO3-N, PO4-P, and K-releases in all the treatments were significantly (p<0.01) fitted with a modified Hyperbola model. For greenhouse gas emissions, the lowest cumulative N2O was 340.4 mg kg-1 in the soil incorporated with plasma-activated rice hull biochar, and the reduction rates were 27.8% and 86.4% in the rice hull biochar and plasma-activated rice hull biochar treatments, respectively, compared to the control. Therefore, it concluded that the incorporated rice hull biochar can be especially useful for controlling PO4-P release and N2O emissions for bio-fertilizer applications.

Characteristics of Wastewater Treatment in Applying RBC Modified Dephanox Process (회전원판법을 적용한 Modified Dephanox 공정의 하수처리특성)

  • Kang, Min-Koo;Kim, Keum-Yong;Ryu, Hong-Duck;Lee, Sang-Ill
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.5
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    • pp.477-486
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    • 2010
  • This study was performed with the object in which it improves the nitrification by using RBC, that is one of the biological waste water treatment process. By applying the Modified Dephanox process to RBC in this research in order to evaluate the improvement of the nitrification by RBC a research was conducted. There is the most conspicuous feature of the process of using RBC. it is that the nitrification can be smoothly performed even if the suspended solid of the high concentration as the interference factor in the nitrification tank is flowed in. Moreover, as a result of experiment, TCOD removal efficiency of the process showed up more than about 90%. when influent TCOD loading rate was 0.04~0.1 kg / $day{\cdot}m^3$. and T-N removal efficiency is high at about 75% in spite of the process operating of the laboratory scale was observed. Also, As increasing influent ${PO_4}^{3-}$-P, T-P loading rate, ${PO_4}^{3-}$-P, T-P removal efficiency was increased. Finally, it was elucidated that the utilization of RBC in external nitrification system resulted in not only high nitrification performance but also stable system operation by minimizing inhibitory effect of overflowed suspended solid (SS).

Defect Chemistry of BaTiO_3$ Codoped with Mn and Nb

  • Han, Young-Ho;Shin, Dong-Jin
    • The Korean Journal of Ceramics
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    • v.4 no.2
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    • pp.68-71
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    • 1998
  • The effect of Mn and Nb additions on the electrical properties of BaTiO$_3$ has been studied by means of equilibrium electrical conductivity as a function of temperature, oxygen partial pressure(Po$_2$) and composition. If the manganese ion is added to the normal Ti site, i.e. BaTi$_{1-x}Mn_xO_{\delta-6}$, the equilibrium conductivity shows strong evidence of acceptor-doped behavior. The conductivity minimum, corresponding to the transition from oxygen excess, p-type behavior to oxygen deficient, n-type behavior with decreasing Po$_2$, is displaced to lower Po$_2$ and is broadened and flattened. The partial replacement of Mn ion with Nb decreases the acceptor-doped effect and the total replacement exhibits a typical donor-doped behavior. It was confirmed that unlike undoped or other acceptor-doped behavior. It was confirmed that unlike undoped or other acceptor-doped samples, for the p-type region, the electrical conductivity follows the 1/6th power dependence of oxygen partial pressure.

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Effect of pH and Initial Phosphorus Concentration on Phosphorus Removal by Aluminum Salts (알루미늄염에 의한 인 제거 시 pH와 초기 인 농도의 영향)

  • Park, Jeongwon;Kwak, Hyoeun;Min, Sojin;Chung, Hyung-Keun;Park, Pyung-Kyu
    • Journal of Korean Society of Water and Wastewater
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    • v.30 no.2
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    • pp.123-130
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    • 2016
  • Phosphorus (P) removal by aluminum sulfate solution was investigated with varying pH and initial P concentrations. P removal was the highest at around pH 6. The pH range where P removal occurred was slightly wider at higher initial P concentrations. Compared to theoretical calculations, it was confirmed that $AlPO_4$ precipitation was the main reason for P removal at low pH. At high pH, where there should be no $AlPO_4$ precipitates, the P removal by adsorption of amorphous $Al(OH)_3$ precipitates was experimentally observed. The P removal by adding amorphous $Al(OH)_3$ precipitates prepared before the adsorption experiments, however, was lower than that by injecting aluminum sulfate solution because the prepared precipitates became larger, leading to less specific surface area available for adsorption. Ions other than sulfate had little influence on P removal.