• Title/Summary/Keyword: $O_2$ Sensor

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A study of electronic gasoline engine control technique (전자식 가솔린 엔진의 조절 방법에 관한 연구)

  • 성낙원
    • Journal of the korean Society of Automotive Engineers
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    • v.9 no.5
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    • pp.66-76
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    • 1987
  • The control technique for an electronic engine is studied. For this study an IBM-PC and a throttle body fuel injection system are selected. The computer controls fuel injection, spark timing, exhaust gas recirculation and idle speed. Fuel injection is adjusted either by a feed back signal of a zirconia $O_{2}$ sensor or programmed logic for starting, deceleration, warm ing up and idle modes. When a 3-way catalytic converter is used with the electronic engine control system, CO, THC, and NOx were reduced more than 90% simultaneously.

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A Selective and Sensitive Determination Method of Fe(II) ion using DTPA in Luminol-H2O2 System (Fe(II)-DTPA 착물의 촉매작용을 이용한 루미놀 화학발광 시스템의 선택적 Fe(II) 정량)

  • Lee, Sang Hak;Kim, Kyung Min;Hong, Suk Joo;Kim, Gyu-Man;Jo, Hae Jin;Jang, Taek Gyun;Kim, Young Ho
    • Applied Chemistry
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    • v.15 no.2
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    • pp.113-116
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    • 2011
  • A sensitive and selective determination method of Fe(II) ion by luminol-H2O2 system using a chelating reagent has been presented. A metal ion-chelating ligand complex such as Fe(II)-diethylenetriamine pentaacetic acid (DTPA) produced higher chemiluminescence (CL) intensity as well as longer lifetime in luminol-H2O2 system than metal exist as free ions. Furthermore, the catalytic activity of Cu(II) and Pb (II) complexes with chelating reagents in luminol-H2O2 system was lost since chelating reagents act as a masking agent although free Cu(II) and Pb(II) ions have high catalytic activity. On the optimized conditions, the calibration curve of Fe(II) ion was linear over the range from 1.0×10-7 to 2.0×10-5 M with correlation coefficient of 0.996. The detection limit was calculated to be 4.0×10-8 M.

Characterization of Hydrogen Gas Sensitivity of ZnO Thin Films (고감도 ZnO 박막센서의 수소가스 검출 특성 연구)

  • Kong, Young-Min;Lee, Hak-Min;Huh, Sung-Bo;Kim, Sun-Kwang;You, Yong-Zoo;Kim, Dae-Il
    • Korean Journal of Materials Research
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    • v.20 no.12
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    • pp.636-639
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    • 2010
  • ZnO thin films were prepared on a glass substrate by radio frequency (RF) magnetron sputtering without intentional substrate heating and then surfaces of the ZnO films were irradiated with intense electrons in vacuum condition to investigate the effect of electron bombardment on crystallization, surface roughness, morphology and hydrogen gas sensitivity. In XRD pattern, as deposited ZnO films show a higher ZnO (002) peak intensity. However, the peak intensity for ZnO (002) is decreased with increase of electron bombarding energy. Atomic force microscope images show that surface morphology is also dependent on electron bombarding energy. The surface roughness increases due to intense electron bombardment as high as 2.7 nm. The observed optical transmittance means that the films irradiated with intense electron beams at 900 eV show lower transmittance than the others due to their rough surfaces. In addition, ZnO films irradiated by the electron beam at 900 eV show higher hydrogen gas sensitivity than the films that were electron beam irradiated at 450 eV. From XRD pattern and atomic force microscope observations, it is supposed that intense electron bombardment promotes a rough surface due to the intense bombardments and increased gas sensitivity of ZnO films for hydrogen gas. These results suggest that ZnO films irradiated with intense electron beams are promising for practical high performance hydrogen gas sensors.

Electrical properties of ZnO transparent conducting film fabricated by the sputtering method (스퍼터링법에 의한 ZnO 투명전도막의 제작과 전기적 특성)

  • Jeong, Woon-Jo;Cho, Jae-Cheol;Jeong, Yong-Kun;Yoo, Yong-Tek
    • Journal of Sensor Science and Technology
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    • v.6 no.1
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    • pp.49-55
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    • 1997
  • ZnO thin film had been deposited on the glass by sputtering method, and investigated by optical and electrical properties. When the rf power was 180W and sputtering pressure was $1{\times}10^{-3}$Torr at room temperature, thin lam deposited had strongly oriented c-axis and the lowest resistivity($1{\times}10^{-4}{\Omega}{\cdot}cm$), and then carrier concentration and Hall mobility were $6.27{\times}10^{20}cm^{-3}$ and $22.04cm^{2}/V{\cdot}s$, respectively. Transmittance of ZnO thin film in visible range was above 90%, and this thin film cut of the ultraviolet range below 320nm and the infrared range above 850nm. And after annealing in hydrogen atmosphere, the resistivity of ZnO thin film was somewhat decreased, while obtained as stable state.

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Temporal and Spatial Variability of Precipitation and Evaporation over the Tropical Ocean

  • Yoo, Jung-Moon;Lee, Hyun-A
    • Journal of the Korean earth science society
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    • v.24 no.1
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    • pp.22-29
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    • 2003
  • Temporal and spatial variability of precipitation (P), evaporation (E), and moisture balance (P-E; precipitation minus evaporation) has been investigated over the tropical ocean during the period from January 1998 to July 2001. Our data were analyzed by the EOF method using the satellite P and E observations made by the Tropical Rainfall Measuring Mission (TRMM) Precipitation Radar (PR) and the Special Sensor Microwave/Imager (SSM/I). This analysis has been performed for two three-year periods as follow; The first period which includes the El Ni${\tilde{n}}$o in early 1998 ranges from January 1998 to December 2000, and the second period which includes the La Ni${\tilde{n}}$o events in the early 1999 and 2000 (without El Ni${\tilde{n}}$o) ranges from August 1998 to July 2001. The areas of maxima and high variability in the precipitation and in the P-E were displaced from the tropical western Pacific and the ITCZ during the La Ni${\tilde{n}}$o to the tropical middle Pacific during the El Ni${\tilde{n}}$o, consistent with those in previous P studies. Their variations near the Korean Peninsula seem to exhibit a weakly positive correlation with that in the tropical Pacific during the El Ni${\tilde{n}}$o. The evaporation, out of phase with the precipitation, was reduced in the tropical western Pacific due to humid condition in boreal summer, but intensified in the Kuroshio and Gulf currents due to windy condition in winter. The P-E variability was determined mainly by the precipitation of which the variability was more localized but higher by 2-3 times than that of evaporation. Except for the ITCZ (0-10$^{\circ}$N), evaporation was found to dominate precipitation by ${\sim}$2 mm/day over the tropical Pacific. Annual and seasonal variations of P, E, and P-E were discussed.

Gas sensing properties of $LaFeO_3$ thin films fabricated by RF magnetron sputtering method (RF Magnetron Sputtering 법으로 제조된 $LaFeO_3$ 박막의 가스감지 특성)

  • Jang, Jae-Young;Ma, Dae-Young;Park, Ki-Cheol;Kim, Jeong-Gyoo
    • Journal of Sensor Science and Technology
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    • v.9 no.5
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    • pp.357-364
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    • 2000
  • The structural, electrical and gas sensing characteristics of $LaFeO_3$ thin films fabricated by r.f. magnetron sputtering method on $Al_2O_3$ substrates were investigated. (121) domonant crystalline plane was observed for the films heat-treated at above $600^{\circ}C$ and gas sensing properties showed p-type semiconductor behaviors. Gas sensing characteristics of the $LaFeO_3$ thin films was studied as a function of film thicknesses and heat treatment temperatures. While the variation of the film thickness showed a little effect on the sensitivity, the heat treatment temperature was critical to the sensitivity. The thin films with thickness of 400 nm heat-treated at $800^{\circ}C$ showed the sensitivity of 400% for 5000ppm CO and 60% for 350ppm $NH_3$ at the working temperature of $300^{\circ}C$.

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Study on Porous Silicon Sensors to Measure Low Alcohol Concentration (저농도 알코올 측정을 위한 다공질 실리콘 센서에 관한 연구)

  • Kim Seong-Jeen
    • Journal of the Korean Electrochemical Society
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    • v.2 no.3
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    • pp.130-133
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    • 1999
  • In this work, a capacitance-type alcohol gas sensor using porous silicon layer is developed to apply for breath alcohol measurement and its characteristics are estimated at room temperature. Current alcohol sensors using metal oxides such as tin-oxide are not only difficult to measure low alcohol concentration, but also should heat at $200\;to\;400^{\circ}C$ to improve the sensitivity. But the sensor using porous silicon layer has good sensitivity even at room temperature by very large effective surface area and suitable structure to fabricate integrated micro sensors. In the experiment, the capacitance was measured for the range of 0 to $0.5\%$ alcohol concentration with the interval of $0.05\%$, in which alcohol solution was kept at 25, 36, and $45^{\circ}C$ by a heater. As the result, good linearity was observed and the capacitance increased about 1.1, 2.6 and $4.6\%$ per the increment of $0.1\%$ alcohol concentration each temperature, respectively, at the frequency of 120 Hz.

Development of Small-sized SQUID and Direct-coupled Electronics for High-$T_c$ Scanning SQUID Microscope (소형 SQUID, 직접 되먹임 방식 전자회로, 고온초전도 SQUID 주사현미경의 개량)

  • Baek, B.;Lee, S. M;Yun, J. H.;Khim, Z. G.
    • Progress in Superconductivity
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    • v.3 no.1
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    • pp.78-82
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    • 2001
  • The spatial resolution of $high-T_{c}$ scanning SQUID microscope is limited by the washer size of SQUID and the gap distance between SQUID sensor and the sample. In this work, we tried to improve the spatial resolution of scanning SQUID microscope by reducing the size of SQUID sensor fabricated with $YBa_2$$Cu_3$$O_{7}$ thin film. Outer dimensions of the SQUiDs we tested are 24 $\mu\textrm{m}$ $\times$ $ 28\mu\textrm{m}$, $12 \mu\textrm{m}$ $\times$ $16\mu\textrm{m}$, $12\mu\textrm{m}$ x $12\mu\textrm{m}$, $10 \mu\textrm{m}$ $\times$ $10 \mu\textrm{m}$ each. To operate them in the flux-locked loop scheme, we used a direct-coupled electronics instead of using conventional electronics involving a modulation scheme. Since the direct-coupled feedback scheme does not require modulation current adjustment that poses as a practical difficulty in the SQUID operation in modulation-scheme, the direct feedback operation is rather simpler than the conventional modulation method. The resulting noise features were dominated by the noise of preamp in FLL electronics except that of the largest SQUID. The noise levels of SQUIDs are expected below 1$\times$$10^{-5}$ $\Phi_{0}$H $z^{1}$2/ (at 300 Hz), that is a typical noise level for SQUID made of $YBa_2$C $u_3$$O_{7}$ thin film. The data acquisition and motion-controlling parts were also improved, resulting in faster data acquisition rate and less vibration of the system.m.

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Electrochemical Detection of Hydrogen Peroxide based on Hemoglobin-DNA/pyterpy Modified Gold Electrode (Hemoglobin-DNA/pyterpy 박막을 이용한 과산화수소의 전기화학적 검출)

  • Lee, Dong-Yun;Choi, Won-Suk;Park, Sang-Hyun;Kwon, Young-Soo
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.1295-1296
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    • 2008
  • Hydrogen peroxide ($H_2O_2$) biosensor is one of the most developing sensors because this kind of sensors is highly selective and responds quickly to the specific substrate. Hemoglobin (Hb) has been used as ideal biomolecules to construct hydrogen peroxide biosensors because of their high selectivity to $H_2O_2$. The direct electron transfer of Hb has widely investigated for application in the determination of $H_2O_2$ because of its simplicity, high selectivity and intrinsic sensitivity. An electrochemical detection for hydrogen peroxide was investigated based on immobilization of hemoglobin on DNA/Fe(pyterpy)$^{2+}$ modified gold electrode. The pyterpy monolayers were firstly an electron deposition onto the gold electrode surface of the quartz crystal microbalance (QCM). It is offered a template to attach negatively charged DNA. The fabrication process of the electrode was verified by quartz crystal analyzer (QCA). The experimental parameters such as pH, applied potential and amperometric response were evaluated and optimized. Under the optimized conditions, this sensor shows the linear response within the range between $3.0{\times}10^{-6}$ to $9.0{|times}10^{-4}$ M concentrations of $H_2O_2$. The detection limit was determined to be $9{\times}10^{-7}$ M (based on the S/N=3).

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Characterization to flammable gas $\alpha$-$Fa_{2}O_{3}/SnO_{2}$ system thin film fabricated by APCVD (APCVD법에 위해 제조된 $\alpha$-$Fa_{2}O_{3}/SnO_{2}$계 박막의 가연성 가스 감지 특성 평가)

  • 심성은;이세훈;최성철
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.2
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    • pp.105-110
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    • 2000
  • The $\alpha$-$Fa_{2}O_{3}/SnO_{2}$ thin film gas sensor was fabricated by APCVD and heat treated. The gas sensitivity to flammable gases ($CH_4$, $H_2$, LPG) was measured. This device was to heat treatment at $400^{\circ}C$, $450^{\circ}C$, $500^{\circ}C$, $550^{\circ}C$, $600^{\circ}C$ for 2 h to enhance the gas sensitivity. The heat treated device at $500^{\circ}C$ for 2 h had the best properties and especially it shows high sensitivity to H2 gas. The sensitivity to gases was studied in the temperature range from lOoC to $300^{\circ}C$ in order to find the optimum detection temperature. In the range of detection from 500 ppm to 10,000 ppm at $175^{\circ}C$ the fabricated device showed that the gas sensitivity to $H_2$ was from 62%~76% and to $CH_4$ was from 16 %~58% and to LPG was from 8%~37 %. The sensitivity difference between heat treated device and as fabricated one was about 10 8 The long-term stability to LPG at 1,000 ppm was converged to sensitivity of 30 %.

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