• Title/Summary/Keyword: $O_2$ Consumption

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Enzyme Kinetics Based Modeling of Respiration Rate for 'Fuyu' Persimmon (Diospyros kaki) Fruits (효소반응속도론에 기초한 단감의 호흡 모델에 관한 연구)

  • Ahn, Gwang-Hwan;Lee, Dong-Sun
    • Korean Journal of Food Science and Technology
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    • v.36 no.4
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    • pp.580-585
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    • 2004
  • Respiration of 'Fuyu' persimmon (Diospyros kaki) fruits were measured in terms of oxygen consumption rate and carbon dioxide evolution by closed system experiments at 0, 5, and $20^{\circ}C$. Enzyme kinetics-based respiration model was used to describe respiration rate as function of $O_2\;and\;CO_2$ gas concentrations $(R=V_m[O_2]/K_m+(1+[CO_2]/K_i)[O_2])$, and Arrhenius equation was applied to analyze temperature effect. $V_m\;and\;K_m$ increased, while $K_i$ decreased, with increasing temperature. $K_m\;of\;O_2$ consumption was greater than that of $CO_2$ evolution at equal temperature. Inhibitory effect of reduced $O_2$ level on $O_2$ consumption was more prominent than that on $CO_2$ evolution. Activation energy of respiration decreased with reduced $O_2$ and elevated $CO_2$ concentrations. Activation energy of $CO_2$ evolution was greater than that of $O_2$ consumption. Permeable package experiments verified respiration model parameters by showing good agreement between predicted and experimental gas concentrations in package.

Role of Blood Flow vs. $O_{2}$ Consumption in Nicotinamide-induced Increase $pO_{2}$ in a Murine Tumor (Nicotinamide에 의한 종양내 산소 분압의 증가에 있어서 혈류 또는 산소 소모의 역할)

  • Lee Intae;Demhartner Thomas J.;Cho Moon-June
    • Radiation Oncology Journal
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    • v.12 no.1
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    • pp.17-25
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    • 1994
  • We evaluated the effect of nicotinamide on cellular $O_{2}$ consumption and metabolic status i.e., adenylate phosphates and $NAD^{+}$in-vitro, and changes in blood flow in-vivo, to determine whether changes in cellular metabolism or increased oxygen availability, was responsible for increased tumor oxygenation. Thirty min, pre-incubation of cells with$\∼$4mM (= 500mg/kg) nicotinamide resulted in no change in cellular $O_{2}$ consumption. Similarly neither the adenylate Phosphates nor the cellular $NAD^{+}$levels were altered in the presence of $\∼$4mM nicontinamide. In-vivo, nicotinamide (500mg/kg) increased $O_{2}$ availability as estimated by changes in relative tumor blood flow (RBC flux). The changes in RBC flux measured by the laser Doppler method, were tumor volume dependent and increased from$\∼$35$ \% $ in$\∼$ 150$mm_{3}$tumors to$\∼$~75$ \% $ in$\∼$500$mm^{3}$ tumors. In conclusion, these observations indicate a reduction in local tissue $O_{2}$ consumption is not a mechanism of improved tumor oxygenation by nicotinamide in FSa II murine tumor model. The primary mechanism of increased $pO_{2}$ appears to be an increased local tumor blood flow.

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The Effect of Co-culture and Oxygen Concentration on In Virto Fertilization of Follicular Oocytes in Korean Native Cattle (공배양 및 산소농도가 한우 난포란의 체외발생에 미치는 영향)

  • 이재관;윤준진;황성수;윤종택;김창근;정영채
    • Korean Journal of Animal Reproduction
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    • v.22 no.1
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    • pp.43-50
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    • 1998
  • The effect of oxygen tension on embryonic development in co-culture was evaluated from the standpoint of the reduction of dissolved oxygen concentration by the oxygen consumption of feeder cells. Three co-culture systems using bovine oviductal epitherial cells (BOEC), African green monkey kidney cells (Vero cells) or buffalo rat liver cells (BRLC) have been compared in terms of development of bovine embryos derived from oocytes matured and fertilized in vitro. Among the co-cultured embryo, Vero cells su, pp.rted the highest developmental rate (29%) and the other two showed the similar rates. When the co-cultures were incubated in three different oxygen tension such as 5, 10, 20% oxygen atmosphere, embryos co-cultured with Vero cells at 10%-O2 resulted in the highest percentage of development. From the measurement of oxygen consumption of feeder cells, BRLC consumed 1.38 10-10 mg-O2/min/cell which was higher than 0.94 10-10 and 0.26 10-10mg-O2/min/cell for Vero cells and BOEC, respectively. Based on the oxygen consumption data, the phenomena of optimum oxygen tension required in embryo development in vitro has been analyzed, and we suggested that gas phase oxygen concentration, oxygen consumption rate of feeder cells and the number of feeder cells should be considered for the design of optimal co-culture system for effective fertilization of embryos in vitro.

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Effects of Low Salinity acclimation on Oxygen Consumption in Giant Grouper, Epinephelus lanceolatus (염분변화가 대왕바리, Epinephelus lanceolatus의 산소소비에 미치는 영향)

  • Kim, Moon-Jin;Lim, Han-Kyu;Jeong, Min-Hwan
    • Journal of Fisheries and Marine Sciences Education
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    • v.27 no.2
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    • pp.526-536
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    • 2015
  • Changes of oxygen consumption in juvenile giant grouper, Epinephelus lanceolatus were investigated in order to find out the physiological responses associated with freshwater and low salinities acclimation. Salinity changes in this experiment were set as follows; 35 psu (Exp. I) as control, decrease in the manners of $35{\rightarrow}20{\rightarrow}10{\rightarrow}0$ psu (Exp. II), $35{\rightarrow}10{\rightarrow}0$ psu (Exp. III) and $35{\rightarrow}0$ psu (Exp. IV). The average oxygen consumption at $27^{\circ}C$ in Exp. I (control) was $106.9{\pm}0.7mg$ $O_2/kg/h$. In Exp. II, according to the changes of $35{\rightarrow}20{\rightarrow}10{\rightarrow}0$ psu in freshwater acclimation, fish showed the gradual decrease in oxygen consumption as $108.1{\pm}2.1$, $99.6{\pm}2.9$, $74.6{\pm}0.9$ and $62.7{\pm}1.0mg$ $O_2/kg/h$, respectively. The fish in Exp. III also revealed the same tendency as $106.5{\pm}1.3$, $77.0{\pm}1.2$ and $64.7{\pm}1.2mg$ $O_2/kg/h$, respectively. In Exp. IV, fish showed the decreased oxygen consumption from $109.0{\pm}0.9mg$ $O_2/kg/h$ of 35 psu to $71.6{\pm}2.0mg$ $O_2/kg/h$ of 0 psu. Giant grouper is thought to be a diurnal fish species, because the level of oxygen consumption during light period was higher than that during dark period.

Performance Analysis of an Oxy-fuel Combustion Power Generation System Based on Waste Heat Recovery: Influence of CO2 Capture (배열회수형 순산소연소 발전시스템의 성능해석: CO2 포집의 영향)

  • Tak, Sang-Hyun;Park, Sung-Ku;Kim, Tong-Seop;Sohn, Jeong-Lak;Lee, Young-Duk
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.12
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    • pp.968-976
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    • 2009
  • As the global warming becomes a serious environmental problem, studies of reducing $CO_2$ emission in power generation area are in progress all over the world. One of the carbon capture and storage(CCS) technologies is known as oxy-fuel combustion power generation system. In the oxy-fuel combustion system, the exhaust gas is mainly composed of $CO_2$ and $H_2O$. Thus, high-purity $CO_2$ can be obtained after a proper $H_2O$ removal process. In this paper, an oxy-fuel combustion cycle that recovers the waste heat of a high-temperature fuel cell is analyzed thermodynamically. Variations of characteristics of $CO_2$ and $H_2O$ mixture which is extracted from the condenser and power consumption required to obtain highly-pure $CO_2$ gas were examined according to the variation of the condensing pressure. The influence of the number of compression stages on the power consumption of the $CO_2$ capture process was analyzed, and the overall system performance was also investigated.

The Effects of Alkali Sulfate on the Hydration of a C3A−CaSO4⋅2H2O System

  • Lee, Jong-Kyu;Chu, Yong-Sik;Kwon, Choon-Woo
    • Journal of the Korean Ceramic Society
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    • v.44 no.9
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    • pp.471-476
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    • 2007
  • The hydration mechanism of the $3CaO{\cdot}Al_2O_3-CaSO_4{\cdot}2H_2O$ system in the presence of alkali sulfates has been investigated. The early hydration rate of $3CaO{\cdot}Al_2O_3$ was accelerated by the addition of $Na_2SO_4$ and $K_2SO_4$. This is closely related to the formation of syngenite $(CaSO_4{\cdot}K_2SO_4{\cdot}H_2O)$, and the U-phase added $K_2SO_4$ and $Na_SO_4$ in the $3CaO{\cdot}Al_2O_3-CaSO_4{\cdot}2H_2O$ system, respectively. The formation of the rigid syngenite and U-phase structure led to rapid setting and decreases the sulfate content in the liquid phase of the hydrating cement to the extent that it cannot adequately retard the hydration of $3CaO{\cdot}Al_2O_3$. In case of the alkali sulfate not added to the $3CaO{\cdot}Al_2O_3-CaSO_4{\cdot}2H_2O$ system, the ettringite was transformed to monosulfoaluminate immediately after the consumption of gypsum. However, when the alkali sulfates were added to this system, the ettringite did not transform to monosulfoaluminate immediately even though the gypsum was completely consumed. There was a stagnation period to transform to the monosufoaluminate after the consumption of gypsum because the syngenite and U-phase remained as the sulfate source.

Study on the distribution of marine bacteria and the consumption of oxygen in Wonmun bay (원문만의 해양세균분포와 산소소모량에 관한 연구)

  • PARK Young-Tae;LEE Won-Jae;PARK Joo-Suck;LEE Pil_Yong;KIM Hak-Gyoon
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.24 no.5
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    • pp.303-314
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    • 1991
  • Hypoxic bottom $(\leq2.0ml/l),\;40\%\;oxygen\;saturation)$ is formed in the semi-closed Wonmun bay during summer and autumn early. This study was carried out to know seasonal distribution of marine bacteria and the role of marine bacteria for forming the hypoxic bottom at Wonmun bay during summer and autumn early, 1990. During the study periods, 170 bacterial strains were isolated from sea water and sediment. Viable cell counts were ranged between $10^5-10^7\;cells/ml$. The dominant species were Acinetobacter spp. in spring, Flavobacerium spp. in summer, Pseudomonas spp. in autumn, Serratia spp. in winter. Because ETSA(Electron Transport System Activity) reveals potential consumption of oxygen in the aquatic microorganisms, the ETSA was used as potential consumption of oxygen in this study. The potential consumption of oxygen was in the range of $232.4-637.5{\mu}l/O_2/l/day$ by marine organism and $142.6-432.4{\mu}l/O_2/l/day$ by marine bacteria during the study periods. The ratio of potential oxygen consumption of marine bacteria to total marine microorganism was 0.54. The potential consumption of oxygen by marine bacteria closely related with the number of viable cells. Consequently, bacteria play an important role to form Hypoxic bottom at marine environment.

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Degradation of Humic Acids by Ozone/high pH, Ozone/Hydrogen Peroxide and Ozone/Hydrogen Carbonate System ($O_3$/high pH, $O_3/H_2O_2$$O_3/{HCO_3}^-$ 시스템에서의 부식산의 분해 반응 특성)

  • Shin, Hyun Sang;Kim, Kei Woul;Rhee, Dong Seok
    • Analytical Science and Technology
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    • v.13 no.5
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    • pp.652-658
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    • 2000
  • Chemical degradation of aqueous humic acid by ozonation was studied with respect to the direct reactions of ozone and the indirect reactions due to its preliminary decomposition to secondary oxidant, OH radical. This was characterized by analyzing TOC, $UV_{254}$ and ozone consumption measured in different experimental conditions in which ozone reacted in the presence of various concentrations of $H_2O_2$ and $HCO_3{^-}$ concentrations ranging from 20 to 100 mg/L. and different pH (5-9). The results suggest that the TOC removal is mainly dependent on indirect reactions of OH radical whereas $UV_{254}$ reduction is mainly dependent on direct reactions of ozone with humic acid molecules. It has been also found that ozone consumption was most likely to be affected by pH and alkalinity in the solution.

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Micromachined MoO3 Gas Sensor with Low Power Consumption of 0.5 Watt

  • Jang, Gun-Eik;Wu Q.H.;Liu C.C.
    • Transactions on Electrical and Electronic Materials
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    • v.6 no.4
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    • pp.173-176
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    • 2005
  • A new $MoO_3$ based microsensor with low power consumption was presented. Typical size of sensor was 5mm in width and 8mm in length. As a sensitive electrode, $MoO_3$ was successfully fabricated by IC technology on pyrex glass of $250{\mu}m$ in thickness. After annealing at $550^{\circ}C$ for 3hrs, the film was fully crystallized and demonstrated as pure $MoO_3$ structure. The grain size of $MoO_3$ was plat like and typical size was about $1{\mu}m$. Based on the results of sensitivity measurement, $MoO_3$ microsensor shows especially high selectivity to $H_2$ reducing gas atmosphere. The applied heater power was lower than 0.5 Watt.

Effect of Physico-chemical Properties of Pt/TiO2 Catalyst on CO Oxidation at Room Temperature (Pt/TiO2 촉매의 물리화학적 특성이 CO 상온산화 반응에 미치는 영향 연구)

  • Kim, Sung Chul;Kim, Geo Jong;Hong, Sung Chang
    • Applied Chemistry for Engineering
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    • v.29 no.6
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    • pp.657-662
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    • 2018
  • In this study, the effect of $Pt/TiO_2$ catalysts on the CO oxidation reaction at room temperature was investigated using various $TiO_2$ supports with different physical properties to compare and evaluate $Pt/TiO_2$ catalysts. Physicochemical properties of the catalyst were alanyzed using XPS, CO-chemisorption, BET, and CO-TPD. As a result, when the active particle diameter was smaller, while the metal dispersion and surface area were larger, the CO room temperature oxidation reaction was better. These physical properties increased the number of active sites, causing the target material to increase the adsorption amount of CO. In addition, when the $O_2$-consumption increased, the CO-room temperature oxidation reaction activity increased due to the excellent oxygen-transferring ability.