• 제목/요약/키워드: $OH^-$

검색결과 66,821건 처리시간 0.07초

Lard와 Corn oil이 Ethanol로 처리한 Mouse의 혈청 총 Cholesterol함량 및 간 Thiobarbituric acid치에 미치는 영향 (Effect of Lard and Corn oil on Serum total Cholesterol Content and Liver Thiobarbituric acid Value in Mice treated with Ethanol)

  • 백정희
    • 대한가정학회지
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    • 제18권3호
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    • pp.5-11
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    • 1980
  • The study carried out to clarify the effects of lard and corn oil on serum total cholesterol content and liver thiobarbituric acid (TBA) value in ethanol (Et-OH) fed mice. Results obtained from the present study were a follows: 1. serum total cholesterol content was considerably increased by 25% Et-OH administration in mice. In case of 25% Et-OH plus Lard group and Lard group both group were also increased significantly to compare with normal value of mice but 25% Et-OH plus lard group was shown very higher value rather than that of Lard group and Lard group was found similar tendency to compare with the 25% Et-OH plus saline group except to after the 1 day. 2. serum total cholestrol content of 25% Et-OH plus Corn oil group and corn oil group were also increased significantly to compare with normal value, but the 25% Et-Oh plus Corn oil group slightly higher level than that of Corn oil group except to after the 3 days. 3. Lard group was also very similar tendency to compare with the corn oil group except to the 3 days. 4. liver TBA value was increased by 25% Et-OH fed mice. 25% Et-OH plus Lard group and Lard group were also increased significantly to compare with liver TBA value in normal mice, but 25% Et-OH plus Lard group was found higher value rather than that of lard group and 25% Et-OH group (Control). Lard group was similar to that of Control group except to after the 1 day. And 25% Et-OH plus Corn oil group was considerably increased rather than that of Control group, and liver TBA value of the above group was similar to that of 25% Et-OH plus Lard group except to after the 3 days. Corn oil group was shown lower value than that of lard group, but it was no significant.

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희박 예혼합 덤프 연소기에서 OH 자발광을 이용한 열 방출에 관한 실험적 연구 (Experimental Study on Heat Release in a Lean Premixed Dump Combustor using OH Chemiluminescence Images)

  • 문건필;이종호;전충환;장영준
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2004년도 추계학술대회
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    • pp.1146-1151
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    • 2004
  • Measurements of OH chemiluminescence in an atmospheric pressure, laboratory-scale dump combustor at equivalence ratios ranging from 0.63 to 0.89 were reported. The signal from the first electronically excited state of OH to ground state was detected through a band-pass filter with an ICCD. The objectives of this study are two: One is to see the effects of equivalence ratio on global heat release rate and local Rayleigh index distribution. To get the local Rayleigh index distribution, the line-of-sight images were inverted by tomographic method, such as Abel de-convolution. Another aim is to investigate the validity of using OH chemiluminescence acquired with an ICCD as a qualitative measure of local heat release. For constant inlet velocity and temperature, the overall intensities of OH emission acquired at different equivalence ratio showed periodic and higher value at high equivalence ratio. OH intensity averaged over one period of pressure increased exponentially with equivalence ratio. Local Rayleigh index distribution clearly showed the region of amplifying or damping the combustion instability as equivalence ratio increased. It could provide an information/insights on active control such as secondary fuel injection. Finally, local heat release rate derived from reconstructed OH images were presented for typical locations.

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$Cd^{2+}, H^+$ 및 OH-이온이 EDTA를 포함한 Co (Ⅲ) 착물의 킬레이트고리 변화에 미치는 영향 (The Influence for the Change of Chelate Ring of Co (Ⅲ) Complexes Containing EDTA by $Cd^{2+}, H^+, and OH^-$)

  • 김동엽;이동진;오창언;도명기
    • 대한화학회지
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    • 제34권2호
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    • pp.165-170
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    • 1990
  • 광학활성인 $[Co(edta)]^- 착물과 [Co(Hedta)Cl]^- 착물의 반응성과 구조적인 변화를 여러 가지 촉매(H^+, OH^-, 그리고 Cd^{2+})의 존재하에서 연구하였다. Δ-[Co(edta)]- 착물에 촉매로서 H+ 또는 OH-를 각각 작용시키면 착물에 대한 리간드의 G-ring이 열리면서, 광학활성인 [Co(Hedta)OH_2]착물과 라세미-[Co(edta)OH]^{2-} 착물이 생성된다. (-)546-[Co(Hedta)Cl]- 착물에 촉매로서 Cd^{2+}$를 작용시키면, 고리닫힘이 일어나 Δ-[Co(edta)]-착물이 생성되어지고, 이 때 절대배치는 유지되어진다.

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다고리 방향족 탄화수소의 반응 경로에 대한 DFT 연구 I: 2개의 OH 라디칼에 의한 페난트렌의 분해 반응 (A DFT Study for the Reaction Pathway(s) of Polycyclic Aromatic Hydrocarbons I: Phenanthrene Degradation with two OH Radicals)

  • 이민주;이병대
    • 대한화학회지
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    • 제65권1호
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    • pp.9-14
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    • 2021
  • 이 연구에서는 1기압 298 K 기체 상태에서 페난트렌에 두 개의 OH 라디칼이 연쇄적으로 작용하여 페난트렌이 분해되는 반응 과정을 B3LYP/6-31G(d,p) 기저함수를 사용하여 DFT 계산을 수행하였다. 계산 결과 두 개의 OH 라디칼이 연쇄적으로 페난트렌에 작용하는 경우에도 phenanthren-9-ol 생성 반응이 phenanthren-1-ol 생성 반응보다 유리할 것으로 예측된다. 한편 OH 첨가와 H 추출 과정에 대한 우선성은 상온에서 OH 첨가 과정이 유리할 것으로 예측되었다.

천연 Brucite의 물성분석 및 이산화황 흡수제로의 응용 (Property Analysis of Natural Brucite and Its Application as Sulfur Dioxide Absorbent)

  • 강성구;김명환;김진배
    • 청정기술
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    • 제15권4호
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    • pp.239-244
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    • 2009
  • 중국 Liaoning에서 산출된 천연 brucite를 원료로 $Mg(OH)_2$ slurry를 제조하고, 그 탈황 성능을 magnesite를 원료로 열분해 및 수화반응으로 제조된, $Mg(OH)_2$ slurry와 비교하였다. Brucite와 magnesite를 원료로 제조된 $Mg(OH)_2$ 분말의 물리/화학적 특성은 유사했지만, brucite를 원료로 제조된 $Mg(OH)_2$ 결정입자의 판상구조가 보다 안정적으로 발달되어 있었다. Brucite와 magnesite를 원료로 제조된 $Mg(OH)_2$ slurry의 탈황효율은 brucite가 조금 높았다. Brucite를 배연탈황용 흡수제로 충분히 적용할 수 있을 것으로 기대된다.

PROPERTIES OF OH/IR STARS WITH THE IRAS LRS SPECTRA

  • CHEN P. S.;KWOK S.
    • 천문학회지
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    • 제29권spc1호
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    • pp.257-258
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    • 1996
  • 1607 OH/IR stars associated with IRAS sources are assembled and the IRAS LRS spectra of 980 OH/IR stars are examined in this paper. The nature of the circumstellar dust for these sources is classified. The distributions of these subgroups of OH/IR stars in the IRAS color-color diagram and the period-color diagram are interpreted with their evolutionary status. The Galactic and the velocity distributions of these subgroups of OH/IR stars are also presented. The correlations among the expanding velocities of the envelopes, colors, periods and the pumping efficiencies for subgroups of OH/IR stars are investigated to outline the evolutionary status of OH/IR stars.

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농도제어장치를 이용하여 면직물 전처리 공정에서 발생하는 가성소다 폐액의 재활용에 관한 연구 - 재활용 가성소다에 의한 면직물의 정련성 - (A Study on Recycling NaOH from Pre-treatment Process with Concentration Control System - Scouring Ability of Cotton Fabric Treated with Recycled NaOH -)

  • 이언필
    • 한국의류산업학회지
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    • 제6권3호
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    • pp.393-398
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    • 2004
  • This research offers recycling method of NaOH from mercerizing process of cotton fabric. The measuring system of NaOH concentration was designed for the mercerizing process and tested for various conditions which can be occurred in factory. The accuracy of the system was varied as the testing condition was changed. As the concentration of sulfuric acid used for titrating NaOH decreased, the accuracy of measuring system increased. The concentration of NaOH for waste water collected from mercerizing process was measured by 5.2%. As the ratio of newly mixed NaOH increased, moisture regain. water absorbency and whiteness of the specimen increased. The bending rigidity(B) and shear rigidity(G) decreased, as the ratio of newly mixed NaOH increased.

Enhancing Effect of Organic Substances on Hydroxyl Radical Generation During Ozonation of Water: Stopped-Flow ESR Technique

  • Han, Sang-Kuk
    • Bulletin of the Korean Chemical Society
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    • 제25권12호
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    • pp.1907-1910
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    • 2004
  • Generation of hydroxyl radical, one of their major active species in ozonation of water was directly observed with spin-trapping/electron spin resonance (ESR) technique using 5,5-dimethyl-pyrrolidine-1-oxyl (DMPO) as a spin-trapping reagent. Hydroxyl radical was trapped with DMPO as a stable radical, DMPO-OH. 80 mM of ozone produced $1.08{\times}10^{-6}$M of DMPO-OH, indicating that 1.4% of ${\cdot}$OH is trapped with DMPO if ${\cdot}$OH is produced stoichiometrically from ozone. Humic acid suppressed DMPO-OH generation in a dose-dependent manner. Generation rate of DMPO-OH was determined with ESR/stopped-flow measurement. Phenol derivatives increased the amount and generation rate of DMPO-OH, indicating that phenol derivatives enhance·OH generation during ozonation of water.

Rapid Energy Transfer Mechanism of F Electronic Excitation to the Vibration of Randomly Distributed $OH^- in KCI

  • 장두전;아철승
    • Bulletin of the Korean Chemical Society
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    • 제19권10호
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    • pp.1063-1068
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    • 1998
  • The nature of F electronic excitation energy transfer to OH- vibrational levels in KCl crystals is the exchange interaction, although the transfer process exhibits three temporally distinguishable components depending on the distance between excited F center and OH-. The critical distance as well as rate of the major energy transfer process in randomly distributed samples increases rapidly as OH- librational motions become active with temperature rise. The excited state character introduced into the OH- ground electronic state by perturbation is essential for the exchange interaction. The perturbation is brought about by the expanded electron cloud of excited F center for OH- associated to F center, whereas by librations and lattice vibrations perpendicular to the bond axis for isolated OH- . F excitation quenching efficiency by OH- is dependent on the variation of the critical distance rather than the rate as the rate is much faster than the normal F bleach recovery rate.

Determination of Relative Reactivities of Free Hydroxyl Groups in β-Cyclodextrin, Amylose, and Cellulose by Reductive-Cleavage Method

  • 이창규;김은주;전중호
    • Bulletin of the Korean Chemical Society
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    • 제20권10호
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    • pp.1153-1158
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    • 1999
  • β-Cyclodextrin, amylose, and cellulose were partially methylated and acetylated in order to examine the relative reactivities of 2-, 3-, and 6-OH groups to alkylation and acylation. The partially methylated samples of the polysaccharides were treated with excess of ethyl iodide and sodium hydroxide in dimethyl sulfoxide to convert all of the free hydroxyl groups to ethyl ether groups. The partially O-ethylated and O-methylated polysaccharides were reductively cleaved with triethylsilane in the presence of trimethylsilyl methanesulfonate and borontrifluoride etherate (5 : 1 by mole) and the resulting 4-OH group was acetylated and benzoylated to form mixtures of eight 4-O-acyl-1,5-anhydroalditols. The relative ratio of the alditol esters were analyzed by gas chromatography to determine the degree of substitution at each position. A similar sequence of reactions was carried out with partially acetylated polysaccharides. The results indicated that the order of relative reactivities for methylation are 2-OH > 6-OH > 3-OH and for acylation are 6-OH > 2-OH > 3-OH regardless of the anomeric configuration.