• Korean Journal of Materials Research
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• v.3 no.1
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• pp.28-32
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• 1993

Abstract The hot wire anemometer-type flow sensor, which consisted of Ni thin film resistors evaporated on Si substrates, was fabricated and characterized. It was known that the temperature coefficients of Ni resistors were decreased as the film thickness was thinned and the operating characteristics of the fabricated flow sensor were determined as a sensitivity of 111.3${\mu}$W/(${\ell}$ pm$)^{1/2}$ and a dynamic response time of several 10 seconds.

• Journal of Powder Materials
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• v.21 no.6
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• pp.429-433
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• 2014

This study investigated the magnetic properties and frequency dispersion of complex permeability of Ni-Zn-Co ferrites used for magnetic shielding in near field communication (NFC) system. The sintered specimens of $(Ni_{0.7}Zn_{0.3})_{1-x}Co_xFe_2O_4$ composition were prepared by the conventional ceramic processing. The coercive force and saturation magnetization were measured by vibrating sample magnetometer. The complex permeability was measured by RF impedance analyzer in the range of 1 MHz~1.8 GHz. The coercive force increased and saturation magnetization decreased with increasing the Co substitution. The real and imaginary parts of complex permeability decreased and the resonance frequency increased with Co substitution, which was attributed to the increase in crystal anisotropy field and reduction in saturation magnetization. The effect of Co substitution could be found in reducing the magnetic loss to nearly zero at the operating frequency of NFC (13.56 MHz).

• Metals and materials international
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• v.24 no.6
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• pp.1285-1292
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• 2018

Microstructural properties of as-grown and annealed CoCrFeMnNi high entropy alloy (HEA) oxynitride thin films were investigated. The CoCrFeMnNi HEA oxynitride thin film was grown by magnetron sputtering method using an air gas, and annealed under the argon plus air flow for 5 h at $800^{\circ}C$. The as-grown film was homogeneous and uniform composed of nanometer-sized crystalline regions mixed with amorphous-like phase. The crystalline phase in the as-grown film was face centered cubic structure with the lattice constant of 0.4242 nm. Significant microstructural changes were observed after the annealing process. First, it was fully recrystallized and grain growth happened. Second, Ni-rich region was observed in nanometer-scale range. Third, phase change happened and it was determined to be $Fe_3O_4$ spinel structure with the lattice constant of 0.8326 nm. Hardness and Young's modulus of the as-grown film were 4.1 and 150.5 GPa, while those were 9.4 and 156.4 GPa for the annealed film, respectively.

• Progress in Superconductivity and Cryogenics
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• v.8 no.3
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• pp.32-36
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• 2006

Simplification of the buffer architecture in the fabrication of coated conductors is required because the deposition of multi-layers leads to a longer production time and a higher cost of coated conductors. In this study, a single layered buffer deposition of $CeO_2$ for low cost coated conductors has been tried using thermal evaporation technique. l00nm-thick $CeO_2$ layers deposited by thermal evaporation were found to act as a diffusion layer. $0.4{\mu}m$-thick SmBCO superconducting layers were deposited by thermal co-evaporation on the $CeO_2$ buffered Ni-W substrate. Critical current of $55.4 A/cm^2$ was obtained for the SmBCO coated conductors.

• Bulletin of the Korean Chemical Society
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• v.20 no.3
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• pp.297-300
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• 1999

The protonation constants of the macrocyclic ligands, 1,4-dioxa-7,10,13,16-tetraaza-cyclooctadecane-N,N',N",N"'-tetra(acetic acid) [N-ac4[18]aneN402] and 1,4-dioxa-7,10,13,16-tetraazacyclooctadecane-1,4-dioxa-7,10,13,16-N,N',N",N"'-tetra(methylacetic acid) [N-meac4[18]aneN4O2] have been determined by using potentiometric method. The protonation constants of the N-ac4[18]aneN4O2 were 9.31 for logK1H, 8.94 for logK2H, 7.82 for logK3H, 4.48 for logK4H and 2.94 for logK5H. And the protonation constants of the N-meac4[18]aneN4O2 were 9.34 for logK1H, 9.13 for logK2H, 8.05 for logK3H, 5.86 for logK4H, and 3.55 for logK5H. The stability constants of complexes on the divalent transition ions (Co2+, Ni2+, Cu2+, and Zn2+) and tiivalent metal ions (Ce3+, Eu3+, Gd3+, and Yb3+) with ligands N-ac4[18]-aneN4O2 and N-meac4[18]aneN4O2 have been obtained from the potentiometric data with the aid of the BEST program. The three higher values of the protonation constants for synthesized macrocyclic ligands correspond to the protonation of nitrogen atoms, and the fourth and fifth values correspond to the protonation of the carboxylate groups for the N-ac4[18]aneN4O2 and N-meac4[18]aneN4O2. The meatal ion affinities of the two tetra-azamacrocyclic ligands with four pendant acetate donor groups or methylacetate donor groups are compared. The effects of the metal ions on the stabilities are discussed, and the trends in stability constants resulting from changing the macrocyclic ring with pendant donor groups and acidity of the metal ions.

• Bulletin of the Korean Chemical Society
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• v.24 no.11
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• pp.1623-1626
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• 2003

The dependency of the rate of $CO_2$ reforming of methane on the catalyst loading and the reactor size was examined at a fixed temperature of $750\;^{\circ}C$ and a fixed GHSV of 18000 mL(STP)/$g_{cat}.h$. The conversion of methane in $CO_2$reforming decreased with increase in the reactor size. The catalyst was severely deactivated with increase in the catalyst amount. The amount of carbonaceous species combustible below $550\;^{\circ}C$, determined by TPO experiments with the used catalyst samples increased with increase in the catalyst amount, which was again confirmed by XRD and TEM experiments. The increase of the carbonaceous species combustible below $550\;^{\circ}C$ may be due to the suppression of the reverse Boudouard reaction, since the $CO_2$ reforming of methane, a highly endothermic reaction, resulted in lowering the reaction temperature.

• Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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• 2003.10a
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• pp.153-156
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• 2003

The multi-layer oxide buffer layer for the coated conductor was deposited on biaxially textured Ni substrates using pulsed laser deposition. Oxygen partial pressure, 4％$H_2$/Ar partial pressure, and deposition temperature were deposition variables investigated to find the optimum deposition conditions. $Y_2$O$_3$seed layer was deposited epitaxially on metal substrate. The full buffer architecture of $Y_2$O$_3$/YSZ/CeO$_2$was successfully prepared on metal substrate.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2000.07a
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• pp.423-426
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• 2000

The 3-D $31.5$\times$31.5$\times$2.5mm$^3$model of contour vibration mode piezoelectric transformer with Pb($Ni_{1/2}$$W_{1/2}$)$O_3$-Pb(Zr,Ti)$O_3$ ceramics was simulated by ANSYS according to the dot size 17, 18, 19, 20, 21 $mm\phi$ and analyzed the results. The mechanical quality factor of the 3-D model was decreased with the dot size and increased as 2605 at 20 $mm\phi$ and after then decreased again. The output voltage of that sample was 74123 [V] and the maximum stress of the dot electrode at that sample was 288[$10^7$N/$m^2$] and the maximum displacement of the ring electrode at that sample was 128 [$\mu\textrm{m}$].

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.181.1-181.1
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• 2014

Supercapacitor is attracting growing attention for a promising energy conversion and storage device because of its desirable electrochemical properties such as rapid charge-discharge rate, high power density and long cycle life. Three-dimensional (3D) metal nanostructure has been widely studied since it can provide efficient charge transport along the 3D network in many device applications. In this work, we fabricated well-ordered 3D nickel (Ni) nanostructures using 3D-arrayed polystyrene nano-opal substrates. We also fabricated half-cell supercapacitors by electrodepositing $RuO_2$ onto these nanostructured Ni current collectors and investigated their morphological and electrochemical properties.

• Progress in Superconductivity and Cryogenics
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• v.8 no.3
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• pp.9-12
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• 2006

Batch type co-evaporation EDDC (Evaporation using Drum in Dual Chambers) system was recently manufactured to fabricate 100m - long SmBCO superconducting coated conductor. As a preliminary study before the fabrication of long tape. short CC samples have been fabricated using the EDDC system and their crystal texture and $I_c$ properties were investigated. $1.2 {\mu}m$-thick SmBCO layers were deposited on $CeO_2/YSZ/CeO_2$ buffered Ni-W tapes. $I_c$ of 128A/cm-w and corresponding $J_c$ of $1.1 MA/cm^2$ at 77K in self-field were obtained for SmBCO CC tape. In-field property of SmBCO CC was confirmed to be better than that of YBCO deposited by PLD.