• Title/Summary/Keyword: $NbSe_2$

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In-vitro Hertzian Fatigue Behavior of Zirconia/Alumina Composites (지르코니아/알루미나 복합체의 In-vitro Hertzian 피로거동)

  • Lee, Deuk-Yong;Park, Il-Seok;Kim, Dae-Joon;Lee, Se-Jong
    • Journal of the Korean Ceramic Society
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    • v.41 no.1
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    • pp.69-75
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    • 2004
  • The degree of the indentation damage and strength degradation for 3Y-TZP ceramics and (Y,Nb)-TZP/$Al_2O_3$ dental implant composites was investigated under the Hertzian cyclic fatigue. Fatigue tests were conducted at contact loads of 500 to 3000 N and up to $10^6$ cycles in exact in vitro environments. At 500 N, no strength degradation and crack generation was observed up to $5{\times}10^5$ contact cycles. Fatigue properties of 3Y-TZP ceramics was superior to (Y,Nb)-TZP/ㅍ composites due to stress relief caused by the phase transformation from tettagonal to monoclinic phase. As contact load increased, the drastic reduction in strength was found when the damage transition from ring to radial crack occurred. The extent of strength degradation was more pronounced in vitro environments probably due to chemical corrosion of artificial saliva through cracks introduced during large numbers of contacts.

Research Trend in Solid Lubricant Layered Materials for the High Performance Li-ion Batteries (층상구조 재료의 고체윤활작용을 이용한 고성능 리튬이온 전지 응용 연구동향)

  • Hur, Jaehyun
    • Prospectives of Industrial Chemistry
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    • v.23 no.5
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    • pp.12-20
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    • 2020
  • 최근 층상구조를 가진 전이금속 칼코겐 화합물이 새로운 고성능 리튬이온전지 음극소재로서 주목받고 있다. 층상구조 물질들의 고성능 전극 소재 활용에 있어 박리를 이용한 정확한 층의 개수 조절은 전기화학 반응성을 증가시키고, 전극 필름 내에서의 균일한 거동을 위해서 매우 중요하다. 볼 밀링 공정은 이차전지 전극 소재 제조에 있어서 주로 물질의 분쇄나 고상 화학반응을 유도하여 합금 형태의 전극 소재 개발에 보편적으로 사용되는 공정이나, 층상구조를 가진 전이금속 칼코겐 화합물에 적용하면 층상구조 물질에 고체윤활작용을 일으켜 박리가 촉진된다. 이러한 성질을 이용하여 다양한 종류의 전이금속 칼코겐 화합물(예: MoS2, MoSe2, NbSe2)에 적절한 카본 매트릭스 물질과 복합화를 통해 새로운 전극 소재를 합성하고, 이를 통해 고성능 리튬이온전지 음극 소재를 제조하는 연구 동향에 대해 보고하고자 한다.

Fabrication and Frequency Agile of Microstrip Antennas Using Y-cut $LiNbo_3$, Quartz and FR-4 Substrates. (Y-cut $LiNbo_3$, Quartz, FR-4 기판을 이용한 마이크로스트립 안테나의 제작과 공진주파수 이동에 관한 연구.)

  • Lee, Ki-Se;Lee, Kyu-Il;Kang, Hyun-Il;Song, Joon-Tae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.04b
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    • pp.116-120
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    • 2004
  • In this paper, we proposed a method to shift the resonant frequency by applying the electric field to microstrip patch antenna using piezoelectric substrates. We fabricated microstrip patch antenna using Y-cut LiNbO3, Quartz and FR-4 substrates. We designed and simulated the microstrip antennas by Ensemble V 7.0 of the simulation too1. We observed the resonant frequency by DC applied electric field in a microstrip patch antenna. When the electric field was 300 V/mm, the resonant frequency agile of Y-cut LiNbO3 microstrip patch antennas were 29 MHz. When the electric field was 400 V/mm, the frequency agile of X-cut, Y-cut and Z-cut quartz microstrip patch antennas were 55.2 MHz, 34.2 MHz and 28.0 MHz, respectively. However, when the electric field was 400 V/mm, the resonant frequency of FR-4 microstrip patch antenna does not changed. It was shown that the resonant frequency agile of Y-cut and Z-cut quartz microstrip patch antennas are due to piezoelectric phenomenon not to be permittivity.

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우수한 광투과도를 갖는 ZnO 기반의 투명박막트랜지스터 제작 및 특성 분석

  • Lee, Yeong-Min;Lee, Se-Jun;Lee, Jin-Yong;Kim, Hyeong-Jun;Ryu, Han-Tae;Kim, Deuk-Yeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.204-204
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    • 2010
  • 본 연구에서는 Glass 기판 위에 우수한 광 투과도를 갖는 ZnO 기반의 Thin Film Transistor (TFT)를 제작하였으며, 이에 대한 전기적 및 광학적 특성을 분석하였다. 소자 구조의 제작은 Maskless Aligner를 이용한 Optical lithograph법을 이용하였다. 채널층은 ZnO로 하였고 Source/Drain 영역은 GaZnO로 하여 전체구조가 ZnO 기반의 homogeneity를 유지하게 하였다. 이때 Gate 절연막은 Bi1.5Zn1Nb1.5O7와 SiO2 두가지 종류로 하여 각각의 특성을 비교하였다. 본연구에서 TFT구조의 각 층은 모두 r. f. 마그네트론 스퍼터법으로 증착하였다. 제작된 TFT들은 채널층 및 절연막 형성 등에 관여된 세부적 실험변수의 변화에 관계없이 약 75% 이상의 우수한 광투과도 특성을 보였다. 전기적 특성 평가에서, 제작된 TFT들은 전반적으로 비교적 낮은 문턱전압과 높은 이동도를 보였다. 하지만, 트랜지스터의 전기적 전송 특성의 주요 인자들인 채널-이동도, 스위칭, 누설 및 이력 등은 ZnO 채널층 혹은 Bi1.5Zn1Nb1.5O7 절연막 형성 시 주입되는 O2 가스의 분압에 의존하는 것이 관측되었다. 이를 통하여 트랜지스터의 각 세부 영역의 구조 및 형성 조건이 트랜지스터의 전기적 특성에 미치는 영향과 상관관계에 대하여 논의한다.

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Dpp Represses eagle Expression at Short-Range, but Can Repress Its Expression at a Long-Range via EGFR Signal Repression

  • Kim, Se Young;Jung, Keuk Il;Kim, Sang Hee;Jeon, Sang-Hak
    • Molecules and Cells
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    • v.26 no.6
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    • pp.576-582
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    • 2008
  • Nervous system development takes place after positional information has been established along the dorsal-ventral (D/V) axis. The initial subdivision provided by a gradient of nuclear dorsal protein is maintained by the zygotic genes expressed along the D/V axis. In this study, an investigation was conducted to determine the range of Dpp function in repressing the expression of eagle (eg) that is present in intermediate neuroblasts defective (ind) and muscle specific homeobox (msh) gene domain. eg is expressed in neuroblast (NB) 2-4, 3-3 and 6-4 of the msh domain, and NB7-3 of the ind domain at the embryonic stage 11. In decapentaplegic (dpp) loss-of-function mutant embryos, eg was ectopically expressed in the dorsal region, while in dpp gain-of-function mutants produced by sog or sca-GAL4/UAS-dpp, eg was repressed by Dpp. It is worthy of note that Dpp produced from sim;;dpp embryos showed that Dpp could function at long range. However, Dpp produced from en-GAL4/UAS-dpp or wg-GAL4/UAS-dpp primarily acted at short-range. This result demonstrated that this discrepancy seems to be due to the repression of Dpp to EGFR signaling in sim;;dpp embryos. Taken together, these results suggest that Dpp signaling works at short-range, but can function indirectly at long-range by way of repression of EGFR signaling during embryonic neurogenesis.

Localized Corrosion Resistance and Microstructural Changes in UNS N07718 Alloy After Solution Heat Treatment

  • Yoon-Hwa Lee;Jun-Seob Lee;Soon il Kwon;Jungho Shin;Je-Hyun Lee
    • Corrosion Science and Technology
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    • v.23 no.2
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    • pp.166-178
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    • 2024
  • The localized corrosion resistance of UNS N07718 alloy was investigated after solution heat treatment. When the alloy was heat-treated at 1050 ℃ for 2.5 hours, it experienced an increase in average grain diameter, a reduction in grain boundary area, and the dissolution of delta phases along grain boundaries. Additionally, primary metallic nitrides (MN) and metallic carbides (MC), enriched with either Ti or Nb, were identified and exhibited a random distribution within the microstructures. Despite the solution heat treatment, the composition, diameter, and abundance of MNs and MCs remained relatively consistent. The critical pitting temperature (CPT), as determined by the ASTM G48-C immersion test, revealed similar values of 45 ℃ for both treated and untreated alloys. However, a decrease in maximum pit depth and corrosion rate was observed after the solution heat treatment. The microstructural changes that occurred during the heat treatment and their potential implications were discussed to understand the influence of the solution heat treatment.

Localized Corrosion Behavior of Inconel 718 in a Chloride-Containing Aqueous Solution (염수 환경에서 Inconel 718의 국부 부식 거동)

  • Lee, Jun-Seob;Lee, Yejin;Kwon, Soon il;Shin, Jungho;Lee, Je-Hyun
    • Corrosion Science and Technology
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    • v.20 no.6
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    • pp.361-366
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    • 2021
  • Localized corrosion behavior of Ni-based Inconel 718 alloy was investigated by electrochemical anodic polarization techniques in NACE TM 0177 A solution of 5 wt% NaCl + 0.5 wt% acetic acid at room temperature. After the solution heat treated at 1080 ℃ for 2.5 h, Inconel 718 was age-hardened at 780 ℃ for 8 h. The microstructure of the alloy surface was investigated by optical microscopic or scanning electron microscopic technique. The austenitic phase with the presence of metal carbides was observed on the surface of Inconel 718. Metal-carbides such as Nb-Mo and Ti-carbide with diameters of approximately 10 and 3 ㎛, respectively, were formed in Inconel 718. Anodic polarization results revealed that localized corrosion was observed at the interface between austenitic phase of a substrate and metal carbides. Difference in electrochemical property between a metal carbide and an austenitic substrate could provide an initiation site for localized corrosion of Inconel 718 surface.

Effect of Solution Annealing Heat Treatment on the Localized Corrosion Resistance of Inconel 718 (Inconel 718의 국부 부식 저항성에 미치는 용체화 열처리의 영향)

  • Yoonhwa Lee;Jun-Seob Lee;Soon Il Kwon;Jungho Shin;Je-hyun Lee
    • Corrosion Science and Technology
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    • v.22 no.5
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    • pp.359-367
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    • 2023
  • The localized corrosion resistance of the Ni-based Inconel 718 alloy after solution heat treatment was evaluated using electrochemical techniques in a solution of 25 wt% NaCl and 0.5 wt% acetic acid. Solution heat treatment at 1050 ℃ for 2.5 hours resulted in an increased average grain diameter. Both Ti carbides (10 ㎛ diameter) and Nb-Mo carbides (1 - 9 ㎛ diameter) were distributed throughout the material. Despite heat treatment, the shape and composition of these carbides remained consistent. An increase in solution temperature led to a decrease in pitting potential value. However, the pitting potential value of solution heat-treated Inconel 718 was consistently higher than that of as-received Inconel 718 at all tested temperatures. Localized corrosion initiation occurred at 0.4 VSSE in a temperature environment of 80 ℃ for both as-received and solution heat-treated Inconel 718 alloys. X-ray photoelectron spectroscopic analysis indicated that the composition of the passive film formed on specimen surfaces remained largely unchanged after solution heat treatment, with O1s, Cr2p3/2, Fe2p3/2, and Ni2p3/2 present. The difference in localized corrosion resistance between as-received and solution heat-treated Inconel 718 alloys was attributable to microstructural changes induced by the heat treatment process.

Design of Marine IoT Wireless Network for Building Fishing Gear Monitoring System (어구 모니터링 시스템 구축을 위한 해상 IoT 무선망 설계)

  • Kwak, Jae-Min;Kim, Se-Hoon;Lee, Seong-Real
    • Journal of Advanced Navigation Technology
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    • v.22 no.2
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    • pp.76-83
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    • 2018
  • In order to prevent overusing the fishing gear and to reduce discarded fishing gear, there is a need for a technique that can efficiently transmit the information including the type and location of the fishing gear and the user's real name to the fishing boat and the control center using IoT-based communication. In order to do this, it is necessary to be able to confirm the position information of a plurality of buoys that can be identified by the base stations on the land. In this paper, in order to service the maritime IoT communication system, we calculate the link budget between the land base station and the targets on the sea to derive the service coverage. To design a marine IoT radio network for building a fishing gear monitoring system, we calculate link budget for wireless service optimization at sea for NB-IoT using 1.8 GHz frequency band and LoRa service using 900 MHz frequency band. In addition, the link budget between the land base station and buoy, the link budget between the land base station and fishing boat are calculated and the results are analyzed.

Study on the Metallogenic Classification Relating to Igneous Activity in the Ogcheon Geosynclinal Zone, Korea (옥천지향사대(沃川地向斜帶)의 화성활동(火成活動)에 의한 광화작용(鑛化作用)의 유형(類型)에 관(關)한 연구(硏究))

  • Lee, Dai Sung;Chi, Jeong Mann;Lee, Dai Woon
    • Economic and Environmental Geology
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    • v.13 no.3
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    • pp.167-184
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    • 1980
  • The granitic plutons associated with Ogcheon geosynclinal zone can be grouped into three different subzones; SE-Subzone for the migmatitic and schistose granites of the southeast margin, 101-181m.y. old; NW-Subzone for those of the northwest margin, 112-163m. y. old; and C-Subzone for those of central part of the zone, 63-183m.y. old. The intrusives in C-Subzone are further subdivided into the older, adamellite to granodiorite (148-183m.y. old) and the younger, perthitic granites (63-106m,y. old). The metallogenic distribution of South Korea suggests that, in the Ogcheon Zone, it is possible to delineate an elongated polymetallogenic province in the general orientation of the zone intimately related with the migmatite and plutonic zones mentioned. Moreover, the mineralization in the province was basically controlled by the patterns of local geology involving country rocks and related igneous bodies, that permit subdivision of the province into the following three parts: Northeast (NE) Province consists dominantly of thick Paleozoic calcareous sediments; Middle (M) Province is characterized by predominant argillaceous and partly calcareous sediments of Precambrian to Late Paleozoic age; and Southwest (SW) Province consisting mainly of volcanic and arenaceous sediments of Mesozoic age. The three different plutonic zones with three different country rock provinces above mentioned make a combination which consists of nine classes. Each class can be assumed to be characterized by specific mineralization type. In order to classify the mineralization types, the present study sampled twenty six ore deposits and mineralized areas in Ogcheon zone as shown figure 2; eight ore deposits from plutonic SE-Subzone, ten from the plutonic NE-Subzone and eight from the plutonic C-Subzone. The characteristics of the classes are as follows: NE-SE is predominant in Au-Ag vein and Sn-migmatite of katazonal occurrence; NE-C is most productive in Pb-Zn and remarkable in Fe contact deposit in mesozone and partly Pb-Zn-Cu skarn in limestone and subordinate in mesozone and partly Pb-Zn pipes; M-SE is considerable in Au-Ag vein and rare elements (Nb, Ta, etc.) of pegmatite; M-C is predominant in F-veins in epizone and Mo-W, Fe, Cu veins occur in replacement type; M-NW is productive in Fe metamorphic and skarn types, partly remarkable in Cu, Pb-Zn contact; SW-SE is barren in mineralization related to Jurassic igneous rocks; SW-C is predominant in alunite and pyrophyllite in tuffs; and SW-NW is scarece in Pb-Zn, Cu, As and Au-Ag veins.

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