• Journal of Surface Science and Engineering
• /
• v.57 no.2
• /
• pp.86-91
• /
• 2024

In this study, we investigated the effect of Na₂SiO₃ concentration on the Plasma Electrolytic Oxidation(PEO) film formation of Al6061 alloy. The morphology of the PEO films were examined by Optical Microscope(OM) and Scanning Electron Microscope(SEM). PEO film thickness increases as the Na₂SiO₃ concentration increases. The elemental analysis of PEO films was conducted using Dispersive X-ray Spectrometer(EDS). The cross-sectional elemental analysis result shows that the Si concentration tends to increase as the concentration of Na₂SiO₃ increases. X-Ray Diffraction(XRD) analysis was performed to confirm the degree of phase change according to Na₂SiO₃ concentration. In addition, Vickers hardness was measured to confirm the mechanical strength of the PEO film. As the concentration of Na₂SiO₃ increases, the hardness value also tends to increase.

• Korean Journal of Soil Science and Fertilizer
• /
• v.32 no.1
• /
• pp.39-46
• /
• 1999

This study was performed to examine the effect of initial composition ratio and various reaction conditions on CEC and crystallinity of the product in hydrothermal synthesis of zeolitic materials from fly ash. Na-P1 zeolite was formed from the mixture with $SiO_2/Al_2O_3$ ratio above 2.55, however from the mixture with $SiO_2/Al_2O_3$ ratio below 2.25 hydroxy sodalite was formed. The CEC of reaction product(Na-P1 zeolite) treated with 3N-NaOH, $Na_2O/Al_2O_3$ ratio 2.55 and $SiO_2/Al_2O_3$ ratio 2.0 for 12 hours at $103^{\circ}C$ was about $285cmol^+kg^{-1}$, which was higher than those of the products of other reaction condition. The crystallinity of Na-P1 zeolite as high as 45.1% was attained at the optimum reaction condition of 2N-NaOH, $SiO_2/Al_2O_3$ ratio 2.55, $Na_2O/Al_2O_3$ ratio 1.5 for 12 hours at $103^{\circ}C$. The XRD peak of the reaction product could be measured at 7.16, 5.04, 4.12, 3.18, $2.69{\AA}$ and tetragonal pillar shape observed by SEM image be characteristic for Na-P1 zeolite. Judging from the result, it should be considered the optimum synthesis condition for Na-P1 zeolite from fly ash was 2~3N NaOH, $SiO_2/Al_2O_3$ ratio 2.55 and $Na_2O/Al_2O_3$ ratio 1.5~2.0 for 12 hours at $80{\sim}103^{\circ}C$.

• Journal of the Korean Ceramic Society
• /
• v.19 no.1
• /
• pp.13-18
• /
• 1982

The crystallization of metastable "orthorhombic" phase from the glass in the system of Na $AlSi_3O_8-CaAl_2Si_2O_8$ is studied. These crystals are crystallized in the range of composition from $Ab_80An_20$ to An100. The symmetry of these crystals show orthorhombic as a possible space group P22121. Two probable twin models are proposed. proposed.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.32 no.1
• /
• pp.12-15
• /
• 2022

The effect of SiO₂, Na₂O and CaO on isokom temperatures in soda-lime glass is estimated by comparing calculated isokom temperatures using viscosity model proposed by Lakatos. The isokom temperatures at the viscosity of log η = 12.3, 10, 6.6 and 1 (Pa·s) are lowered by 6, 7, 10 and 24℃, respectively, by the substitution of SiO₂ with Na₂O by 1 mol%. Meanwhile, replacing 1 mol% of SiO₂ with CaO raises the isokom temperatures by 3~4 and 2℃ at the viscosity of log η = 12.3 and 10 (Pa·s), respectively, but lowers the temperatures by 1 and 21℃ at the viscosity of log η = 6.6 and 1(Pa·s), respectively.

• Journal of the Korean Ceramic Society
• /
• v.30 no.2
• /
• pp.85-92
• /
• 1993

Oxynitride glasses in Na-Ca-Si-O-N system were prepared by melting at 135$0^{\circ}C$ for 2 hours in N2 gas. The effects of Si/Na mole ratio and the various Si3N4 contents were investigated. Stable oxynitride glasses can be obtained up to 9wt.% Si3N4 content in case the Si/Na mole ratio was 2.12 and 1.62, but $\beta$-Si3N4 was precipitated at 9wt.% Si3N4 content in case the Si/Na mole rtio was 1.12. Density (p), chemical durability, hardness (Hv), and fracture toughness (KIC) increased with increasing Si3N4 content. In cae the Si/Na mole ratio was 1.12, the increment of properties was remarkable but hardness and fracture toughness did not increase no longer owing to precipitation of $\beta$-Si3N4.

• Journal of Korean Ophthalmic Optics Society
• /
• v.8 no.1
• /
• pp.1-5
• /
• 2003

Quarternary $Na_2O-B_2O_3-Al_2O_3-SiO_2$ glasses were fabricated by the function of $R({\equiv}Na_2O\;mole%/B_2O_3\;mole%)$ and $K({\equiv}(Al_2O_3\;mole%+SiO_2\;mole%)/B_2O_3mole%)$. The structures of these glasses were investigated through refractive index and vicker's hardness. The refractive index increased as the increase of the polarizability in the glass network. In the region of low $Na_2O$ content, the refractive index increased due to the increase of the polarizability in the glass network, but in the region of high $Na_2O$ content, the rate of increase of the refractive index decreased due to the increase of the molar volume caused by the formation of $BO_3{^-}$ units with relatively high molar volume. And, the refractive index decreased as the increase of $Al_2O_3+SiO_2$ content with the molar volume in the glass network. The increase and decrease of vicker's hardness values for those glasses depended on the fraction of tetrahedral $BO_4$ units and it of triangle $BO_3{^-}$ units with non-bridging oxygen, respectively.

• Journal of the Mineralogical Society of Korea
• /
• v.19 no.4 s.50
• /
• pp.347-353
• /
• 2006

The atomic-nano scale structures of multi-component aluminosilicate glasses have not been well understood in spite of its implications fur dynamics and generation of magma in the natural system due to lack of suitable spectroscopic and scattering experiments. Here, we report O-17 MAS and isotropic projection of 3QMAS NMR spectra for quaternary Na-Ca silicate glasses $[(CaO)_x(Na_2O)_{1-x}]\;(A1_2O_3)_{0.5}(SiO_2)_6,\;CNAS)$ at 14.1 Tesla where atomic configurations around bridging oxygen (Si-O-Si, Si-O-Al) and non bridging oxygen (Na-O-Si, Ca-O-Si, (Na, Ca)-O-Si) are partially resolved. With increasing Na content, the fraction of Na-O-Si increases while those for bridging oxygens remain constant. The Na/Ca ratio apparently affects the peak widths of bridging oxygen peaks (e.g., Si-O-Si)) and thus the topological entropy as well as chemical shifts of the bridging oxygen peaks, implying that both BOs and NBOs are strongly interacting with network modifying cations The effect of cation field strength on the degree of Al-avoidance was also discussed.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.21 no.5
• /
• pp.12-20
• /
• 2017

This report presents the results of an investigation on the fundamental properties of mortars high fluidity high volume slag cement(HVSC) activated with sodium silicate($Na_2SiO_3$). The ordinary Portland cement(OPC) was replaced by ground granulated blast furnace slag(GGBFS) from 40% to 80% and calcium sulfoaluminate(CSA) was 2.5% or 5.0% mass. The $Na_2SiO_3$ was added at 2% and 4% by total binder(OPC+GGBFS+CSA) weight. A constant water-to-binder ratio(w/b)=0.35 was used for all mixtures. The research carried out the mini slump, V-funnel, setting time, compressive strength and drying shrinkage. The experimental results showed that the contents of superplasticizer, V-funnel, setting time and drying shrinkage increased as the contents of CSA and $Na_2SiO_3$ increase. The compressive strength increases with and an increase in CSA and $Na_2SiO_3$. One of the major reason for these results is the accelerated reactivity of GGBFS with CSA and $Na_2SiO_3$. The maximum performance was CSA 5.0% + $Na_2SiO_3$ 4% specimens.

• Journal of the Korean Ceramic Society
• /
• v.25 no.1
• /
• pp.27-34
• /
• 1988

In order to investigate the reason of changes in the physical properties of glasses near the region for which R(Ga/Na)=1, spectroscopic studies using FT-IR and Raman spectroscopy have been carried out on Na2O.2SiO2 glass with addition of Ga2O3 from 0 to 35 mole %, i.e., from R=0 to 1.61. The main purpose of this work is to investigate the coordination number of Ga3+ in glass with variation of glass composition and to determine the existence of tricluster in the Ga-rich region for which R>1.0 in Na2O-Ga2O3-SiO2 system.

• Journal of the Korean Ceramic Society
• /
• v.36 no.10
• /
• pp.1087-1093
• /
• 1999

Bioglass which is one of the surface active bionmaterials has a good biocompatibility but a poor mechanical strength, In the present work therefore two types of fluoride-containing bioglasses were coated on an alumina to improve mechanical strength. Crystallization of the coating layer and the hydroxyapatite formation on the bioactive glass coatings in tris-buffer solution were studied. When bioactive glass coated alumina was heat-treated Na2CaSi3O8 crystal was formed on the layer at lower temperature while wollastonite(CaSIO3) was obtained at higher temperature. Hydroxyapatite forming rate on the coating layer with Na2CaSi3O8 crystal was delayed with SiO2 contents in glass composition. However the hydroxyapatite was developed in 20minutes regardless SiO2 contents when the coating layer crystallized into wollastonite. More amount of P3+ ions were leached out of the coating layer with wollastonite than that with Na2CaSi3O8 crystal while Na+ and Ca2+ ions were leached out more easily from the Na2CaSi3O8 crystal containing coating layer.