• Title/Summary/Keyword: $N_2O/O_2$

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Proposal of Fast Counting Sort (빠른 계수 정렬법의 제안)

  • Lee, Sang-Un
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.15 no.5
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    • pp.61-68
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    • 2015
  • Among comparison sorts, no algorithm excels a current set lower bound of O(nlogn) in operation. Quicksort, the fastest of its kind, has a complexity of O(nlogn) at its best and on average and $O(n^2)$ at worst. This paper thus presents two methods: first is an O(n+k) simple counting sort which operates much more speedily than an O(n+k), (k=maximum value) counting sort, and second is an O(ln) radix counting sort which counts the frequency of numbers in the digit l of a data and saves it in a corresponding virtual bucket in an array, only to virtually divide the array into radix digit numbers. For the 6 experimental data, the proposed algorithm makes O(nlogn) or $O(n^2)$ of Quicksort simple into O(n+k) or O(ln). After all, the proposed sorting algorithm has proved to be much faster than the counting sort and Quicksort.

The Comparison of Property and Visible Light Activity between Bulk and Surface Doped N-TiO2 Prepared by Sol-gel and N2-plasma Treatment

  • Hu, Shaozheng;Li, Fayun;Fan, Zhiping
    • Bulletin of the Korean Chemical Society
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    • v.33 no.1
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    • pp.199-203
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    • 2012
  • A modified sol-gel method and $N_2$-plasma treatment were used to prepare bulk and surface doped N-$TiO_2$, respectively. XRD, TEM, UV-vis spectroscopy, $N_2$ adsorption, Elemental Analyzer, Photoluminescence, and XP spectra were used to characterize the prepared $TiO_2$ samples. The N doping did not change the phase composition and particle sizes of $TiO_2$ samples, but increased the visible light absorption. The photocatalytic activities were tested in the degradation of an aqueous solution of a reactive dyestuff, methylene blue, under visible light. The photocatalytic activity of surface doped N-$TiO_2$ prepared by $N_2$-plasma was much higher than that of bulk doped N-$TiO_2$ prepared by sol-gel method. The possible mechanism for the photocatalysis was proposed.

The effect of $Co_{3}O_{4}$additives on the magnetic Properties of $Ni_{0.8-xZn_{0.2+x}Fe_{2}O_4}$ ($Co_{3}O_{4}$첨가제 변화에 따른 $Ni_{0.8-xZn_{0.2+x}Fe_{2}O_4}$의 자기적 특성)

  • 이선학;오영우;김덕훈;김현식;이해연;송재성
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.331-334
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    • 2001
  • In this study, the magnetic properties for Ni-Zn ferrite were investigated as the function of $Co_3$ $O_4$ additive contents which was predicted to improve the resonance frequency. Toroid specimens with the composition of N $i_{0.8-x}$Z $n_{0.2+x}$F $e_2$ $O_4$(x = 0, 0.05, 0.1, 0.15) ferrites were preparation by conventional ceramic processing technique. The maximum resonance frequency of 19.905 MHz and the permeability of 90.88 in 10 MHz were attained to the N $i_{0.8}$Z $n_{0.2}$F $e_2$ $O_4$with $Co_3$ $O_4$0.3 wt%. Both of the permeability in 10 MHz and the resonance increased to 107.11 and 19.005 MHz respectively for the N $i_{0.8}$Z $n_{0.2}$F $e_2$ $O_4$with $Co_3$ $O_4$wt% than the N $i_{0.8}$Z $n_{0.2}$F $e_2$ $O_4$/ with the free $Co_3$ $O_4$composition.composition.

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Phase Relations and Microstructure of Comounds in the $Si_3N_4-Al_2O_3-SiO_2$ system at $1700^{\cire}C$ ($Si_3N_4-Al_2O_3-SiO_2$계의 1,$700^{\circ}C$에서 생성하는 화합물의 상관계 및 미구조)

  • Lee, Eey-Jong;Kim, Hwan
    • Journal of the Korean Ceramic Society
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    • v.16 no.4
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    • pp.206-212
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    • 1979
  • The phase relations and microstructure appeared at 1700℃ in a system of Si3N4-Al2O3-SiO2 were studied. The samples were pressurelessly sintered at 1700℃ for 1hr and reheated at 1600℃ for 1hr under nitrogen atmosphere. The compounds formed were identified by X-ray diffraction method and the microstrues were observed by SEM. The stable phases appeared in this system were X-phase, Si2ON2, β'-Si3N4 and Mullite. From the results of those experiments, it was concluded that the X-phase has very close composition to that proposed by G, K. Layden, Si3Al6O12N2. SEM photographs showed that Si2ON2 was a plate phase and X-phase was a rectagular plate phase.

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Synthesis of TiO2 Fine Powder by Sol-Gel Process and Reaction Mechanism(II) : Hydrolysis of Titanium n-Propoxide (졸-겔법에 의한 TiO2미분말 합성과 반응메카니즘(II): Titanium n-propoxide의 가수분해)

  • Myung, Jung-Jae;Park, Jin-koo;Chung, Yong-Sun;Kyong, Jin-Bum;Kim, Ho-Kun
    • Applied Chemistry for Engineering
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    • v.8 no.5
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    • pp.777-783
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    • 1997
  • $TiO_2$ powders were synthesized via hydrolysis reaction of titanium n-propoxide in n-propanol solvent and the reaction rates were studied by use of UV-vis spectroscopic method. Concentration of water, reaction temperature, reaction time and acid-base effects of the solution were investigated to determine the optimum conditions for $TiO_2$ powder synthesis. The reaction were controlled to proceed to pseudo-first orders reaction in the presence of excess water in n-propanol solvent. The rate constants which varied with temperature and concentration of water were calculated by Guggenheim method. Reaction using $D_2O$ was also carried out to determine the catalytic character of water. $TiO_2$ powders were synthesized only in the neutral and basic solution and those were almost spheric forms having average particle size of $0.4-0.7{\mu}m$ diameter. Particle size decreased with increasing concentration of water and reaction temperature, however, increased with increasing reaction time. Associative $S_N2$ mechanism for the hydrolysis was proposed from the data of n-value in the transition state and thermodynamic parameter. $D_2O$ solvent isotope effect showed that $H_2O$ molecules reacted as nucleophilic catalysis.

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Evaluation of N2O Emissions by Nutrient Source in Soybean and Pepper Fields (콩과 고추재배지에서 양분 공급원별 N2O 배출량 평가)

  • Kim, Gun-Yeob;Lee, Sun-Il;Lee, Jong-Sik;Jeong, Hyun-Cheol;Choi, Eun-Jung
    • Korean Journal of Environmental Biology
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    • v.36 no.4
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    • pp.680-686
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    • 2018
  • Nitrogen fertilizers, hairy vetch, and slow-release complex fertilizers were applied to the soil during the cultivation of crops. The impact of these factors on $N_2O$ emission was quantitatively assessed and the GHGs reduction effect comprehensively evaluated. Among the three factors, the significant factors affecting $N_2O$ emission were mineral nitrogen>soil moisture>temperature. Yield and fertilizer utilization efficiency were highest in the slow-release complex fertilizer treatment. There was no significant difference in $N_2O$ emissions between the slow-release complex fertilizer treatments and the NPK+hairy vetch treatments. Comprehensive results showed that slow-release complex fertilizers treatment has high yield and fertilizer utilization efficiency but low $N_2O$ emission.

Greenhouse gases emission from aerobic methanotrophic denitrification (AeOM-D) in sequencing batch reactor

  • Lee, Kwanhyoung;Choi, Oh Kyung;Lee, Jae Woo
    • Membrane and Water Treatment
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    • v.8 no.2
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    • pp.171-184
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    • 2017
  • This study presents the effect of hydraulic retention time (HRT) on the characteristics of emission of three major greenhouse gases (GHGs) including $CH_4$, $CO_2$ and $N_2O$ during operation of a sequencing batch reactor for aerobic oxidation of methane with denitrification (AeOM-D SBR). Dissolved $N_2O$ concentration increased, leveled-off and slightly decreased as the HRT increased from 0.25 to 1d. Concentration of the dissolved $N_2O$ was higher at the shorter HRT, which was highly associated with the lowered C/N ratio. A longer HRT resulted in a higher C/N ratio with a sufficient carbon source produced by methanotrophs via methane oxidation, which provided a favorable condition for reducing $N_2O$ formation. With a less formation of the dissolved $N_2O$, $N_2O$ emission rate was lower at a longer HRT condition due to the lower C/N ratio. Opposite to the $N_2O$ emission, emission rates of $CH_4$ and $CO_2$ were higher at a longer HRT. Longer HRT resulted in the greater total GHGs emission as $CO_2$ equivalent which was doubled when the HRT increased from 0.5d to 1.0 d. Contribution of $CH_4$ onto the total GHGs emission was most dominant accounting for 98 - 99% compared to that of $N_2O$ (< 2%).

Sintering Behavior and Thermal Conductivity of Aluminum Nitride Ceramics with MgO-CaO-Al2O3-SiO2 Nano-glass Additive (나노 MgO-CaO-Al2O3-SiO2 glass 첨가제를 가진 AlN의 소결거동 및 열전도도)

  • Baik, Su-Hyun;Kim, Kyung Min;Ryu, Sung-Soo
    • Journal of Powder Materials
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    • v.25 no.5
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    • pp.426-434
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    • 2018
  • In this study, $MgO-CaO-Al_2O_3-SiO_2$ (MCAS) nanocomposite glass powder having a mean particle size of 50 nm and a specific surface area of $40m^2/g$ is used as a sintering additive for AlN ceramics. Densification behaviors and thermal properties of AlN with 5 wt% MCAS nano-glass additive are investigated. Dilatometric analysis and isothermal sintering of AlN-5wt% MCAS compact demonstrates that the shrinkage of the AlN specimen increases significantly above $1,300^{\circ}C$ via liquid phase sintering of MCAS additive, and complete densification could be achieved after sintering at $1,600^{\circ}C$, which is a reduction in sintering temperature by $200^{\circ}C$ compared to conventional $AlN-Y_2O_3$ systems. The MCAS glass phase is satisfactorily distributed between AlN particles after sintering at $1,600^{\circ}C$, existing as an amorphous secondary phase. The AlN specimen attained a thermal conductivity of $82.6W/m{\cdot}K$ at $1,600^{\circ}C$.

Paper-Electrophoretic Separation of Ruthenium Chloro-Complexes (전기영동에 의한 루테늄 염화착물의 분리)

  • Byung-Hun Lee;Cheon-Hwey Cho
    • Nuclear Engineering and Technology
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    • v.16 no.2
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    • pp.58-63
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    • 1984
  • Paper electrophoretic separation of octahedrally bonded (Ruc $l_{6}$ )$^{3-}$ has been carried out by using the specially designed migration apparatus. The supporting electrolyte solutions are as follows: 0.1M-HCl $O_4$, 0.05 M-HCl+0.09M-KCl, 0.1M-HCl, 5$\times$10$^{-3}$ M-NTA, 0.01M-HCl, 0.01M-HCl $O_4$, 0.01M-citric acid, 0.01M-K $H_2$P $O_4$+0.01M-N $a_2$HP $O_4$, 0.05M-borax, 0.025M-N $a_2$C $O_3$+0.025M-NaHC $O_3$, 0.01M-N $a_3$P $O_4$, 0.01M-NaOH and 0.1 M-NaOH. The (Ruc $l_{6}$ )$^{3-}$ appears in 2 to 4 peaks and is found in several chemical species such as (RuCl ($H_2O$)$_{5}$ )$^{2+}$, cis and trans (RuC $l_2$($H_2O$)$_4$)$^{1+}$, (RuC $l_3$($H_2O$)$_3$)$^{0}$ , (RuC $l_4$($H_2O$)$_2$)$^{1-}$, (RuC $l_{5}$ ($H_2O$))$^{2-}$ and (RuC $l_{6}$ )$^{3-}$. The retention value has been found to be highest in the 0.025M-N $a_2$C $O_3$+0.025M-NaHC $O_3$ electrolyte solution.n.

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Effects of Sintering Additives and Atmospheres on the Piezoelectric and Sintering Properties of $Pb_{0.98}Cd_{0.02}Zr_{0.36}Ti_{0.39}Ni_{0.083}Nb_{0.167}O_3$ (소결첨가제와 분위기가 $Pb_{0.98}Cd_{0.02}Zr_{0.36}Ti_{0.39}Ni_{0.083}Nb_{0.167}O_3$의 소결 및 압전 특성에 미치는 영향)

  • 문종하;박진성;박현수
    • Journal of the Korean Ceramic Society
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    • v.33 no.11
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    • pp.1260-1266
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    • 1996
  • The effects of SiO2 MnO2 and sintering atmospheres (O2, N2) on the piezoelectric properties and densification behaviors of Pb0.98Cd0.02Zr0.36Ti0.39Ni0.083Nb0.167O3 were investigated. The addition of SiO2 to the system enhanced the rate of densification but supressed the rate of grain growth. On the other hand the addition of MnO2 to the system did not nearly affect the rate of densification but increased slightly the rate of grain growth The densification of Pb0.98Cd0.02Zr0.36Ti0.39Ni0.083Nb0.167O3 containing of SiO2 or MnO2 was promoted with increasing the partial pressure of O2. The relative dielectric constant ($\varepsilon$r) and piezoelectric constant (d33) of Pb0.98Cd0.02Zr0.36Ti0.39Ni0.083Nb0.167O3 containing of SiO2 or MnO2 sintered under O2 atmosphere were higher than under N2 atmosphere. Whereas the mechanical quality factor (Qm) of specimens sintered under O2 atmosphere were lower than under N2 atmosphere. Thus the sintering atmosphere of O2 and N2 in Pb0.98Cd0.02Zr0.36Ti0.39Ni0.083Nb0.167O3 containing of SiO2 or MnO2 acted as donor and acceptor respectively. As the amount of SiO2 increased the relative dielectric constant ($\varepsilon$r) and piezoelectric constant (d33) of Pb0.98Cd0.02Zr0.36Ti0.39Ni0.083Nb0.167O3 but the mechanical quality factor (Qm) did not nearly change, In the case of the addition of MnO2 to the system the relative dielectric constant ($\varepsilon$r) and piezoelectric constant (d33) of Pb0.98Cd0.02Zr0.36Ti0.39Ni0.083Nb0.167O3 sintered under O2 atmosphere decreased rapidly with increasing the amount of MnO2 but they were unchanged with increasing the amount of MnO2 under N2 sintering atmosphere. Therefore the differences of the relative dielect-ric constant ($\varepsilon$r) and piezoelectric constant (d33) due to sintering atmosphere were diminished as the amount of MnO2 increased.

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