• Title/Summary/Keyword: $NO_x$Concentration

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Effects of tree-spray of organic calcium agent on the mineral nutrition concentration of petiole, fruit skin and fruit quality at harvest in 'Campbell Early' grapevine (포도 '캠벨얼리'에서 유기칼슘제 수관살포에 의한 엽병과 과피의 무기성분 농도 및 과실품질)

  • Moon, B.W.;Lee, Y.C.;Nam, K.W.;Koo, J.J.;Jung, H.W.
    • Journal of Practical Agriculture & Fisheries Research
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    • v.13 no.1
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    • pp.35-46
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    • 2011
  • The effects of organic calcium agent(ECa) tree-spray on the mineral nutrition concentration of petiole and fruit skin and quality in grapevines were studied. The calcium concentration of petiole and fruit skin at harvest in 'Campbell Early' by tree-spray after flowering 14days of calcium agent were increased significantly in calcium chloride 0.4%, ECa 250X and MCa 500X compared to control. The calcium concentration of petiole and fruit skin at harvest by ECa tree-spray after 7 days and 14 days flowering were increased significantly compared to control and 21 days after flowering treatment. Also, The calcium concentration of petiole and fruit skin at harvest by tree-spray of ECa 250X and 125X after flowering were increased significantly compared to control and 500X treatment. Fruit quality, fruit cluster weight, cracking fruit and Bitter rot occurrence by ECa tree-spray of treatment time and concentration different showed no difference between control. Phytotoxicity by tree-spray of ECa concentration different not occur to leaf and fruit.

A Study on Measurement of NO Concentrations in Laminar Nonpremixed $H_2/N_2$ Flame by LIF (레이저 유도 형광법(LIF)을 이용한 층류 비예혼합 $H_2/N_2$화염에서의 NO 농도측정에 관한 연구)

  • Kim, Sun-Wook;Jin, Seong-Ho;Kim, Gyung-Soo;Park, Kyoung-Suk
    • 한국연소학회:학술대회논문집
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    • 2001.06a
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    • pp.133-138
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    • 2001
  • In this study, quantitative nitric oxide concentration distributions are investigated in the laminar nonpremixed $H_2/N_2$ flames by laser-induced fluorescence (LIF). The measurements are taken in flames for different $N_2$ dilution ratios varying from 20${\sim}$80%, and fuel now rate is fixed as lslpm. The NO A-X (0,0) vibrational band around 226 nm is excited using a XeCl excimer-pumped dye laser. We applied same excitation line used in $CH_4$ premixed flame. Overall, NO concentration was rapidly decreased with $N_2$ addition and we could not measure the concentration any longer for $N_2$ dilution above 80%.

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Evaluation of On-Road NOx Emission from a Light Duty Diesel Vehicle using a Portable Emissions Measurement System (이동식 배출가스 측정장비를 이용한 소형 경유 자동차의 실도로 질소산화물 배출특성 분석)

  • Lee, Tae-Woo;Lee, Jong-Tae;Kim, Jeong-Soo
    • Journal of Korean Society for Atmospheric Environment
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    • v.28 no.1
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    • pp.94-104
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    • 2012
  • The purpose of this research is to quantify the compliance of on-road emission from a light duty diesel vehicle, based on a comparison to emission regulation standard. $NO_x$, CO and THC emissions were measured using a portable device on a selected real-world driving route with a length of approximately 22 km. On-road measurements were repeated by 10 times on a same route to reflect variability in traffic conditions. A test route was divided into 22 road links with length of 1 km to analyze emission results with higher spatial resolution. The average emissions of $NO_x$, CO and THC over total travel distance, which is approximately 220 km, were quantified to be in compliance with emission regulation standards. Under higher spatial resolution, $NO_x$ concentration exceeded a standard in 92 links out of 220 links. The extended time in stop period and the stop-and-go driving cycle were identified as two important reasons for increased $NO_x$ emissions in observed cases. Heavy traffics showed higher $NO_x$ emissions than free flow. These results indicate that the real-world vehicle emissions might exceed the compliance level associate with traffic conditions. Another interesting observation of this research is that the on-road emission characteristics can be independent to the average speed of road links with higher spatial resolution. Variability in on-road emission might not be fully described by solely relying on an average speed, because variability in traffic conditions and road conditions can influence on real-world vehicle emissions.

The Detection Characterization of NOX Gas Using the MWCNT/ZnO Composite Film Gas Sensors by Heat Treatment (열처리에 따른 MWCNT/ZnO 복합체 필름 가스센서의 NOX 가스 검출 특성)

  • Kim, Hyun-Soo;Jang, Kyung-Uk
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.31 no.7
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    • pp.521-526
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    • 2018
  • In particular, gas sensors require characteristics such as high speed, sensitivity, and selectivity. In this study, we fabricated a $NO_X$ gas sensor by using a multi-walled carbon nanotube (MWCNT)/zinc oxide (ZnO) composite film. The fabricated MWCNT/ZnO gas sensor was then treated by a $450^{\circ}C$ temperature process to increase its detection sensitivity for NOx gas. We compared the detection characteristics of a ZnO film gas sensor, MWCNT film gas sensor, and the MWCNT/ZnO composited film gas sensor with and without the heat-treatment process. The fabricated gas sensors were used to detect $NO_X$ gas at different concentrations. The gas sensor absorbed $NO_X$ gas molecules, exhibiting increased sensitivity. The sensitivity of the gas sensor was increased by increasing the gas concentration. Additionally, while changing the temperature inside the chamber for the MWCNT/ZnO composite film gas sensor, we obtained its sensitivity for detecting $NO_X$ gas. Compared with ZnO, the MWCNT film gas sensor is excellent for detecting $NO_X$ gas. From the experimental results, we confirmed the enhanced gas sensor sensing mechanism. The increased effect by electronic interaction between the MWCNT and ZnO films contributes to the improved sensor performance.

Distributions and Behaviors of H2O2 Above the Yellow Sea in the Years Between 2002 and 2004 (2002년에서 2004년 동안 서해상공에서 관측된 과산화수소의 농도분포 및 거동)

  • Kim Y.M.;Shin S.A.;Han J.S.;Lee M.H.;Kim J.A.
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.6
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    • pp.689-697
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    • 2005
  • Hydrogen peroxide is a reservoir of OH radical which is the powerful oxidant in the atmosphere. Therefore, the status of the oxidizing atmosphere could be reflected on the concentration of $H_{2}O_{2}$. In this study, the distribution of $H_{2}O_{2}$ was determined during the intensive aircraft measurements over the Yellow sea in March, December 2002, April, November 2003 and March, October 2004. Flights covered from $124^{circ}E\;to\;129^{circ}E\;and\;35^{circ}N\;to\;37^{circ}N$, and extending to 3,000 m. The flight patterns were set properly to assess the altitudinal and longitudinal distribution for $H_{2}O_{2}$. $H_{2}O_{2}$ was extracted onto aqueous solution using a continuously flowing glass coil and analyzed by a high performance liquid chromatography (HPLC) accompanied with a fluorescence detector using postcolumn enzyme derivatization. Mixing ratios of $O_{3},\;NO_{x}\;and\;SO_{2}$ were measured in real time by commercial analysis instruments. Along the heights, the maximum concentration of $H_{2}O_{2}$ appeared around 1,500 m then gradually decreased with increasing altitude. The vertical behavior of ozone showed the similar trend to $H_{2}O_{2}$. The mean mixing ratio of $NO_{x}$ was about 2 ppbv and not showed clear vertical distribution patterns. The mean value of was the same as $NO_{x}$ however $SO_{2}$ appeared extreme concentration in low altitude. $H_{2}O_{2}\;and\;O_{3}$ showed even longitudinal distribution however $NO_{x}$ mixing ratio in land ($127^{circ}E$) was much higher than over the sea. $SO_{2}$ rather decreased with increasing longitude. $H_{2}O_{2}$ was in inverse proportion to $NO_{x}$ in spring and summer and $SO_{2}$ in spring, which indicated its significant role to NO and $SO_{2}$ oxidation pathways.

Electrical properties of n-type $WO_{3}$ based gas sensors (N-형 $WO_{3}$계 가스센서의 전기적 특성)

  • Yang, Jong-In;Kim, Il-Jin;Lim, Han-Jo;Han, Sang-Do;Chung, Kwan-Soo
    • Journal of Sensor Science and Technology
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    • v.7 no.3
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    • pp.188-196
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    • 1998
  • The sensing and electrical characteristics of $WO_{3}$-based n-type semiconductor gas sensors are investigated. In normal air condition, $TiO_{2}$(4 wt. %)-doped $WO_{3}$-based sensor fabricated without any binder shows the grain boundary ( GB ) potential barrier height of 0.26 V. Sensors fabricated with alumina, PVA and silica sol binders show 0.17, 0.22 and 0.26 V of GB potential barrier height, respectively. In the ambience of 120 ppm $NO_{x}$ concentration, the GB potential barrier height of the sensor fablicated without binder is increased to 0.59 V. The sensors were fabricated with alumina, PVA, silica sol binders show 0.43, 0.66 and 0.52 V of potential barrier, respectively. Thus the variation of the potential barrier at GB is largest in the sensor fabricated with the PVA binder. This is found to be the main reason why the sensor fabricated with the PVA binder shows the best sensitivity. It is also found that the decrease of sensitivity at a temperature higher than the optimum operation temperature is due to the temperature dependence of the sensor resistance in normal air condition rather than the desorption of the adsorbed $NO_{x}$ gas particles. In the ambience of 250 ppm CO concentration, the GB potential barrier heights of the sensors fabricated without binder and with PVA binder are about 0.2 V showing negligible change compared to the case of normal air ambience. This fact indicates that these sensors are good candidates for the selective detection of $NO_{x}$ gas in the mixture of CO and $NO_{x}$ gases.

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Growth and Nutrient Uptake of 'Seolhyang' Strawberry (Fragaria × ananassa Duch) Responded to Elevated Nitrogen Concentrations in Nutrient Solution (질소 시비농도가 '설향' 딸기(Fragaria × ananassa Duch)의 생장과 무기원소 흡수에 미치는 영향)

  • Choi, Jong-Myung;Latigui, Ahmed;Yoon, Moo-Kyung
    • Horticultural Science & Technology
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    • v.28 no.5
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    • pp.777-782
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    • 2010
  • This research tested five modified Hoagland solutions for proper fertility management of nitrogen in 'Seolhyang' strawberry cultivations. The changes of nutrient solutions were in total nitrogen concentrations ($meq{\cdot}L^{-1}$) such as 0 (${NO^-}_3$), 2.5 (${NO_3}^-$), 5 (${NO_3}^-$), 10 ($7.5{NO_3}^-$ + $2.5{NH_4}^+$) and 15 ($10{NO_3}^-$ + $5{NH_4}^+$). The fresh weight and $NO_3$-N concentrations in petiole sap responded to the elevated nitrogen concentrations in fertilizer solution in quadratic (y=7.10+2.668x-$0.115x^2$, $R^2=0.7983^{***}$) and linear (y=26.14+5.245x, $R^2=0.6083^{***}$), respectively. The dry weight and N content of the above ground plant tissue responded to the elevated nitrogen in quadratic (y=2.140+0.492x-$0.022x^2$, $R^2=0.6110^{***}$) and linear (y=0.569+0.033x, $R^2=0.6952^{***}$), respectively. In our experiment the solution with $5meq{\cdot}L^{-1}$ of ${NO_3}^-$ showed positive results in both dry and fresh weight productions. However, a future research about modification of this solution and growth and nutrient uptake response is necessary to achieve better growth of 'Seolhyang' strawberry.

Effect of Removal of Power Plant Emissions on the characteristics of Ozone Concentration Changes in Summer (화력발전소 배출량 제거에 따른 여름철 O3 농도의 변화 특성)

  • Kim, Dongjin;Jeon, Wonbae;Park, Jaehyeong;Mun, Jeonghyeok
    • Journal of the Korean earth science society
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    • v.42 no.2
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    • pp.149-163
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    • 2021
  • In this study, the changes in ozone (O3) concentrations due to the removal of power plant emissions were analyzed using a community multi-scale air quality (CMAQ) model. Two different CMAQ model simulations, one considering the emissions from the Hadong power plant and one without considering the emissions, were conducted to investigate the effect of the emissions on the changes in the O3 concentrations in the surrounding areas. Subsequently, the CMAQ simulations exhibited an increase in the O3 concentration (25.24%) despite a decrease in the NOx (-18.87%) and volatile organic carbon (VOC, -11.27%) concentrations, which are major O3 precursors. The changes in the NO and O3 concentrations due to the removal of power plant emissions presented a strong negative correlation (r= -0.72). This indicated that the increase in the O3 concentration was mainly attributed to the significantly decreased NO concentration, thus, mitigating the O3 titration reaction (NO+O3→NO2+O2). Additionally, due to the VOC-limited (i.e., NOx-saturated) conditions in the study region, NO affected the O3 concentration, indicating that the O3 concentrations in a particular region are not only proportional to the increase or decrease in emissions. Therefore, an in-depth understanding of the chemical O3 production and loss in a particular region is necessary to accurately evaluate the effect of emission control on the changes in the O3 concentration.

Mixed Structure Effect of Fuel and Air on Rotary Kiln Burner Flame (연료 및 공기의 혼합구조가 로타리 킬른 용 버너 화염에 미치는 영향)

  • Kim, Youngho;Lee, Cheolwoo;Kim, Insu;Lim, Youngbin
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.339-342
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    • 2014
  • Rotary kiln produces lime from limestone through thermal decomposition. Ring formation in kiln internal wall is known issue that decreases productivity. The cause of ring formation is temperature imbalance as flame leans toward upper wall. Therefore, burner nozzle geometry was changed to improve air-fuel mixing state which leads to prevention of ring formation. CFD simulation and experimental test were performed in this study to investigate the effect of air-fuel mixing on flame structure, temperature and $NO_X$ concentration. It is shown that combustion efficiency has been enhanced and $NO_X$ concentration has been decreased by using swirl flow for secondary combustion air. It's also shown that flame has been straightened by using straight flow for secondary combustion air.

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Effects of Reactive Oxygen Species on Motility in Human Spermatozoa (반응성 산소족이 사람 정자의 운동성에 미치는 영향)

  • Kang, Hee-Gyoo;Kim, Dong-Hoon;Han, Sung-Won;Kim, Myo-Kyung;Kwon, Hyuck-Chan;Lee, Ho-Joon;Kim, Moon-Kyoo
    • Clinical and Experimental Reproductive Medicine
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    • v.27 no.4
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    • pp.393-403
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    • 2000
  • Objective: To investigate the effects of ROS on kinematic parameters in human spermatozoa. To verify the changes in above parameters, human spermatozoa were incubated with xanthine-xanthine oxidase (X-XO), $H_2O_2$, sodium nitroprusside (SNP) or lymphocyte. Otherwise, spemlatozoa were incubated under low $O_2 (5%) condition. Methods: CASA was employed to analyze sperm motion parameters. Results: Under $H_2O_2 treatment, all kinematic parameters of spermatozoa were dramatically increased during 30 min, but gradually decreased thereafter. Under the low concentration of $H_2O_2 (125 ${\mu}M$ and 250 ${\mu}M$), the movement velocity (VAP, VCL, VSL) decreased, but forward movement increased. Under the 1mM $H_2O_2, sperm showed reduced kinematic parameters except during first 30 min of incubation. In the cases of X-XO and SNP treatment, the movement velocity increased but the forward movement reduced. After incubation for 3 hr treatment, the kinematic parameters gradually decreased in high concentration of X-XO. However these parameters maintained or increased in low concentration of X-XO. There was no obvious changes in the above parameters in the high concentration of SNP. In the presence of high concentration of lymphocytes, all parameters decreased. Under the 5% $O_2 condition, the parameters of the movement velocity and movement pattern increased, but forward movement decreased. Taken togethers, it suggested that ROS increased the movement velocity but decreased the forward movement and lateral head replacement. $H_2O_2, X-XO, SNP and lymphocyte treatment significantly increased capacitated spermatozoa within I h of incubation. There was no significant difference in capacitation between low- and high $O_2 group. Conclusion: The early onset of capacitation in the presence of ROS suggest that ROS might be a positive regulator of sperm capacitation and hyperactivation. These results demonstrate that low concentration ROS facilitates the movement velocity but high concentration ROS was inhibitory.

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