• 제목/요약/키워드: $NO_x$ gas

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가솔린엔진용 대체연료의 화염거동에 관한 연구 (A Study on the Flame Behavior of Substitute Fuel of Gasoline Engine)

  • 양정규;류정인
    • 수산해양기술연구
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    • 제21권2호
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    • pp.157-166
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    • 1985
  • 가변 압축비 기관(C. F. R.)에 ionization gap probe를 피스톤 및 실린터 헤드 sleeve에 설치하여 화염거동에 대하여 실험한 결과는 다음과 같다. 1) 혼합연료에서 화염전파속도는 메타놀 함량에 따라 증가한다. 2) 혼합연료에서 메타놀 percent가 증가하면 에너지 소모비 (Btu/HP-hr)가 감소하여 열효율은 증가한다. 3) 당량비가 일정하면 평균유효압력은 메타놀 량이 증가할수록 감소한다. 4) 순수한 가솔린 및 혼합연료는 점화진각이 클수록 NO 하(X) 방출량은 증가하고 희박 혼합기 영역에서 NO 하(X) 방출량은 최대가 된다. 또 RG50/M40/THF10/W1의 연료에서는 당량비가 0.95이하에서는 당양비가 낮을수록, 점화진각이 높을수록 NO 하(X) 방출량은 증가하고, 0.95 이상에서는 당량비와 점화진각이 클수록 방출량은 감소한다. 5) CO, HC의 최소값은 메타놀 함유량이 높을수록 감소한다.

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SnO2 나노와이어를 이용한 저온동작 고감도 고선택성 NO2 가스센서 (Highly sensitive and selective NO2 gas sensor at low temperature based on SnO2 nanowire network)

  • 김유종;박소영;이정석;이세형;우경완;이상현;이문석
    • 센서학회지
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    • 제30권3호
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    • pp.175-180
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    • 2021
  • In this paper, methods for improving the sensitivity of gas sensors to NO2 gas are presented. A gas sensor was fabricated based on an SnO2 nanowire network using the vapor-phase-growth method. In the gas sensor, the Au electrode was replaced with a fluorinedoped tin oxide (FTO) electrode, to achieve high sensitivity at low temperatures and concentrations. The gas sensor with the FTO electrode was more sensitive to NO2 gas than the sensor with the Au electrode: notably, both sensors were based on typical SnO2 nanowire network. When the Au electrode was replaced by the FTO electrode, the sensitivity improved, as the contact resistance decreased and the surface-to-volume ratio increased. The morphological features of the fabricated gas sensor were characterized in detail via field-emission scanning electron microscopy and X-ray diffraction analysis.

배기가스 재순환을 적용한 하이브리드 연소시스템에 대한 기초 연구 (A Fundamental Study of Hybrid Combustion System Applying Exhaust Gas Recirculation)

  • 오휘성;유병훈;박태준;이창언
    • 에너지공학
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    • 제25권1호
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    • pp.100-107
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    • 2016
  • 본 연구에서는 예혼합 화염과 비예혼합 화염을 동시에 구현하는 하이브리드 연소시스템에 배기가스 재순환 방법(FI-EGR and FPI-EGR)을 적용하여 공해물질 저감 효과를 확인하였다. 그 결과, 배기가스 재순환을 적용한 경우 상당량의 NOx 배출지수가 감소하는 것을 확인 할 수 있었으며, 추가적으로 배기가스 재순환을 적용한 하이브리드 연소시스템의 배출성능이 동일한 배기가스 재순환율을 가지는 비예혼합 화염의 배출성능보다 우수함을 확인하였다. 특히, 비예혼합 화염과 예혼합 화염의 비율이 50: 50인 하이브리드 연소시스템의 연료 측에 25% 까지 배기가스를 재순환 시킬 경우(FI-EGR), 배기가스 재순환을 적용하지 않은 비예혼합 화염에 비해 NOx 배출지수가 59% 저감되는 것을 확인하였으며, 혼합비율이 70:30인 하이브리드 연소시스템의 예혼합기와 연료측에 15%까지 배기가스를 재순환 시킬 경우(FPI-EGR), 배기가스를 재순환하지 않은 하이브리드 화염에 비해 NOx 배출지수가 48% 저감되는 것을 확인하였다.

초희박 LPG 직접분사식 엔진에서 질소산화물 저감을 위한 배기재순환 적용성 평가 (Evaluation of EGR applicability for NOx reduction in lean-burn LPG direct injection engine)

  • 박철웅;조시현;김태영;조규백;이장희
    • 한국가스학회지
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    • 제19권4호
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    • pp.22-28
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    • 2015
  • LPG가 수송용 연료로서 경쟁력을 유지하기 위해서는 지속적인 기술개발을 통해 휘발유와의 연비격차를 감소시키고 후처리시스템 등에 의한 가격 부담을 낮추어야 한다. 이에 본 연구에서는 안정적인 희박연소 구현을 통한 연비개선을 얻기 위해 실린더 중앙에 점화플러그와 연료분사기가 인접해 있고, 연료가 분사된 후 바로 점화가 이루어지도록 하는 분무유도방식의 LPG 직접분사엔진을 개발의 일환으로 연소제어인자의 변화에 따른 연소 특성을 분석하였다. 안정적인 연소를 위해 국부적으로 농후한 혼합기를 형성하는 성층희박연소의 특성상 일정 수준이상의 질소산화물이 배출되는 문제점을 갖고 있다. 질소산화물 저감을 위해 EGR을 적용한 결과 연료소비율과 THC의 배출은 약간 증가하지만 $NO_x$배출은 약 15% 저감되었다. EGR 적용에 의한 연소속도의 감소는 초기 화염발달 시기에 집중되어 나타났으며 흡입공기의 희석효과에 의해 EGR율이 증가할수록 최대 열방출율 및 열방출율 증가 기울기가 감소하였다.

LaMnO3형 페롭스카이트 산화물에서 입자상물질의 촉매연소반응 (Catalytic Combustion of Carbon Particulate over LaMnO3 Perovskite-Type Oxides)

  • 이용화;이근대;박성수;홍성수
    • 한국환경과학회지
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    • 제13권7호
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    • pp.619-626
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    • 2004
  • We have studied the catalytic combustion of soot particulates over perovskite-type oxides prepared by malic acid method, The catalysts were modified to enhance the activity by substitution of metal into A or B site of perovskite oxide. In addition, the reaction conditions such as temperature and $O_2$ concentration were investigated. The partial substitution of alkali metals into A site in the $LaMnO_3$ catalyst, enhanced the catalytic activity in the combustion of carbon particulate and the activity was shown in the order: Cs > K > Na. For the $La_{1-x}Cs_{x}MnO_{3}$ catalysts, the catalytic activity showed the maximum value with x=0.3 but no more increase on the catalytic activity was shown with x > 0.3. For the $La_{0.8}Cs_{0.2}MnO_{3}$ catalyst, the substitution of Fe or Ni increased the ignition temperature. The ignition temperature decreased with an increase of $O_2$ concentration, however, no more increase in the catalytic activity was shown with $O_2$ concentration > 0.2. The introduction of NO into reactants showed no effect on the catalytic activity.

단기통 엔진에서 대유량 EGR을 통한 저온 연소 특성 (Characteristics of Low Temperature Combustion in Single Cylinder Engine by High EGR Rate)

  • 조상현;오광철;이춘범
    • 한국자동차공학회논문집
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    • 제17권4호
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    • pp.79-85
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    • 2009
  • Low temperature combustion regime for the simultaneous reduction of nitrogen oxides ($NO_x$) and paticulate matter (PM) is demonstrated in single cylinder engine at various operating parameters, such as EGR rate, injection timing, EGR temperature, amount of fuel and swirl rate. Low temperature combustion is accomplished by high exhaust gas recirculation (EGR) rate in this study. Generally, the emission of $NO_x$ almost completely disappears and PM significantly increases in the first decreasing regime of oxygen concentration but after peaking about 10~12% oxygen concentration, PM then decreases regardless of fuel injection quantity. Low temperature combustion regime was extended by low EGR temperature, high injection pressure and low amount of fuel.

가스 스월버너의 공연비 제어에 관한 연구 (Study on the control of fuel-air ratio ofgas swirl burner)

  • 김인규;김영수;김양호;김경수;김지원
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 1999년도 제19회 KOSCO SYMPOSIUM 논문집
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    • pp.129-138
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    • 1999
  • In this paper, our main issue is that establishing the control procedure of continuous gas flow rate according to combustion fan RPM. For this, first, we decide the optimum operating condition of gas swirl burner through analysis of combustion characteristics - thermal efficiency, combustion efficiency and exhaust gases such as CO, $CO_{2}$, $O_{2}$, $NO_{x}$ and THC. Second, fuel gas flow rate of gas valve is decided with considering excess air ratio and combustion fan RPM is decided by the target of combustion air flow rate. Finally, experimental operating equation is acquired by regression for gas valve and combustion fan. This equation is the control equation of continuous gas flow rate and always gas flow rate is decided by combustion fan operating RPM.

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배기가스 플라즈마에서의 레이저유기형광법(LIF)에 의한 $NO_x$ 계측 ($NO_x$ Measurement of Exhaust Gas plasma by Laser Induced Fluorescence Spectroscopy)

  • 전용우;하장호;박원주;이광식;최상태;윤영대
    • 한국조명전기설비학회:학술대회논문집
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    • 한국조명전기설비학회 1999년도 학술대회논문집-국제 전기방전 및 플라즈마 심포지엄 Proceedings of 1999 KIIEE Annual Conference-International Symposium of Electrical Discharge and Plasma
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    • pp.95-98
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    • 1999
  • This paper describes preliminary discussions on spatial distribution of NO density, which is mostly contained in simulated NOX exhaust, between a wire-cylinder geometry discharge gaps by using Laser Induced Fluorescence(LIF) Spectroscopy. Spatial distribution of NO density will be measured with varying NO concentrations from 166 to 644[ppm] and diameters of central electrode from 6 to 10mm. Pulsed Nd:YAG laser, Optical Parametric Oscillator(OPO), and Frequency Doubler are used to excite NO molecules to their excited state.

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대향류 확산화염의 고온공기 연소특성에 관한 수치해석 (A Numerical Analysis of the Characteristics with High Temperature Air Combustion in Counterflow Diffusion Flame)

  • 조은성;히데아키 코바야시;정석호
    • 한국연소학회지
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    • 제8권4호
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    • pp.9-14
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    • 2003
  • High temperature air combustion technology has been utilized by using preheated air over 1100 K and excessive exhaust gas recirculation. Numerical analysis was performed to investigate the combustion characteristics with high temperature deficient oxygen air combustion by adopting a counterflow as a model problem accounting for detailed chemical kinetics. Methane($CH_4$) was used as a test fuel and calculated oxidizer conditions were low temperature high oxygen (300K, $X_{O2}=0.21$) and high temperature low oxygen (1300K, $X_{O2}=0.04$) conditions. The latter case showed that the flame temperature is lower than the former case and its profile showed monotonic decrease from oxidizer to fuel side, without having local maximum flame temperature at high stretch rate. Also, heat release rate was one order lower and it has one peak profile because of low oxygen concentration and heat release rate integral is almost same for stretch rate. High temperature low oxygen air combustion shows low NO emission characteristics.

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The Effect of Exhaust Gas Recirculation (EGR) on Combustion Stability, Engine Performance and Exhaust Emissions In a Gasoline Engine

  • Jinyoung Cha;Junhong Kwon;Youngjin Cho;Park, Simsoo
    • Journal of Mechanical Science and Technology
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    • 제15권10호
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    • pp.1442-1450
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    • 2001
  • The EGR system has been widely used to reduce nitrogen oxides (NO$\_$x/) emission, to improve fuel economy and suppress knock by using the characteristics of charge dilution. However, as the EGR rate at a given engine operating condition increases, the combustion instability increases. The combustion instability increases cyclic variations resulting in the deterioration of engine performance and emissions. Therefore, the optimum EGR rate should be carefully determined in order to obtain the better engine performance and emissions. An experimental study has been performed to investigate the effects of EGR on combustion stability, engine performance,70x and the other exhaust emissions from 1.5 liter gasoline engine. Operating conditions are selected from the test result of the high speed and high acceleration region of SFTP mode which generates more NO$\_$x/ and needs higher engine speed compared to FTP-75 (Federal Test Procedure) mode. Engine power, fuel consumption and exhaust emissions are measured with various EGR rate. Combustion stability is analyzed by examining the variation of indicated mean effective pressure (COV$\_$imep/) and the timings of maximum pressure (P$\_$max/) location using pressure sensor. Engine performance is analyzed by investigating engine power and maximum cylinder pressure and brake specific fuel consumption (BSFC)

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