• Title/Summary/Keyword: $NO_x$ gas

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Characteristic of do-$NO_x$ for $BaTiO_3$ - sludge hybrid packed bed type reactor ($BaTiO_3$ - sludge hybrid packed bed형 반응기에서 $NO_x$제거특성)

  • Park, Jae-Yoon;Koh, Hee-Suk;Park, Sang-Hyun;Song, Won-Sub;Lee, Jae-Dong;Son, Sung-Do;Lee, Hyung-Ho
    • Proceedings of the KIEE Conference
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    • 2000.07c
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    • pp.2053-2056
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    • 2000
  • The experiment on characteristic of $NO_x$ removal for $BaTiO_3$-sludge hybrid packed bed type reactor was conducted. Gas flow rate was 5(${\ell}/min$) and NO concentration was 50, 100 and 150(ppm). The effect on volume percent of $BaTiO_3$ to sludge was investigated, sludge pellets was added to $BaTiO_3$ pellets to increase $NO_x$ removal rate. In the result, when sludge pellets was added, NO removal rate of $BaTiO_3$ - sludge hybrid type was increased from 90.6% to 95%. However $NO_2$ decreased from 88ppm to 10ppm. $O_3$ decreased from 77ppm to 2ppm. $NO_x$ removal rate was increased to 74%.

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De-NOX evaluation of SCR catalysts adding vanadium-graphene nanocomposite (바나듐 담지된 그래핀 나노복합체를 첨가한 SCR 촉매의 제조 및 활성 평가)

  • Jeong, Bora;Lee, Heesoo;Kim, Eok-Soo;Kim, HongDae
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.25 no.6
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    • pp.252-256
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    • 2015
  • Nitrogen oxides ($NO_X$) was emitted from flue gas of stationary sources and exhaust gas of mobile sources, can leads to various environments problems. Selective Catalysts Reduction (SCR) is the most effective $NO_X$ removal system. Commercial $V_2O_5-WO_3/TiO_2$ catalysts, usually containing $V_2O_5$ 0.5~3 wt%, $WO_3$ 5~10 wt%, and $V_2O_5$ is active in the reduction of $NO_X$ but also in the desired oxidation of $SO_2$ to $SO_3$. To reduce the amount of vanadium, using graphene matrix supported vanadium to synthesize nanocomposite. Then, we fabricated to 1 inch honeycomb type of SCR catalysts adding graphene-vanadium nanocomposite. The chemical-physical characteristics and the catalytic activity were performed by XRD, XRF, BET and Micro-Reactor (MR). As a result, the De-NOX performance was showed, similar to the commercial catalyst activity as 77.8 % and using nanocomposite catalyst as 77.1 % at $350^{\circ}C$.

Combustion characteristics of DI diesel engine according to various timings of split injection (분할 분사시기 변화에 따른 직분식 디젤엔진의 연소 특성)

  • Youn, In-Mo;Roh, Hyun-Gu;Lee, Chang-Sik
    • 한국연소학회:학술대회논문집
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    • 2005.10a
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    • pp.104-109
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    • 2005
  • This paper describes the effect of the split injection on combustion and emission characteristics in a common rail diesel engine at various operating conditions. The combustion pressures and exhaust emissions such as $NO_x$ and soot were measured at various split injection timings. The experimental apparatus of this study is composed of 4 cylinder engine installed with piezoelectric pressure sensor, EC dynamometer, and exhaust gas analyzer for the measurement of $NO_x$, CO, HC and soot emissions. Results show that the split injection has a great effect on reducing the rapid premixed combustion and $NO_x$ emissions.

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Simultaneous Removal of $SO_2$ and NOx Using Ozone Generator and Absorption- Reduction Technique (오존발생장치와 흡수환원법을 이용한 배기가스 동시 탈황 탈질 공정)

  • Mok, Young-Sun;Lee, Joo-Hyuck;Shin, Dong-Nam;Koh, Dong-Jun;Kim, Kyong-Tae
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.2
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    • pp.191-196
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    • 2006
  • The injection of ozone, produced by dielectric barrier discharge, into the exhaust gas gives rise to a rapid oxidation of NO that is the main component of nitrogen oxides($NO_x$) in most practical exhaust gases. Once NO is converted into $NO_2$, it on readily be reduced to $N_2$ in the next step by a reducing agent such as sodium sulfide and sodium sulfite. The reducing agents used ca also remove $SO_2$ effectively, which makes it possible to treat $NO_x\;and\;SO_2$ simultaneously. The present two-step process made up of an ozonizing chamber and an absorber containing a reducing agent solution was able to remove about 95% of the $NO_x$ and 100% of the $SO_2$, initially contained in the simulated exhaust gas. The formation of $H_2S$ from sodium sulfide was prevented by using a strong basic reagent(NaOH) together with the reducing agent. The removal of $NO_x$\;and\;SO_2$ was more effective for $Na_2S$ than $Na_2SO_3$.

A Study on the Engine Performance and Emission Characteristics in a LP EGR System with Electronic Throttle Control (ETC를 적용한 저압 EGR시스템의 엔진성능 및 배출가스 특성에 관한 연구)

  • Park, Jun-Heuk;Lim, Jong-Han;Yoon, Jun-Kyu
    • Journal of Advanced Marine Engineering and Technology
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    • v.35 no.4
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    • pp.379-387
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    • 2011
  • Research and development of LP EGR system for the performance improvement and emission reduction on diesel engine is proceeding at a good pace. LP EGR system seems to be helpful method to further reduce$NO_x$ emissions while maintaining PM emissions at a low level because the boost pressure is unchanged while varying EGR rate. This study is experimentally conducted on a 2.0L common rail DI engine at the medium load condition (2000 rpm, BMEP 1.0 MPa, boost pressure 181.3 kPa) that difficult to use large amount of EGR gas because of deteriorations of performance and fuel consumption. And we investigated the characteristics of performance and fuel consumption while varying EGR systems. The overall results using LP EGR system equipped with ETC identified benefits on reduction of PM and improvement of fuel consumption and thermal efficiency while keep the $NO_x$ level compared to HP EGR and LP EGR with back pressure valve.

Experimental Study on Combustion Characteristics of a Swirl-stabilized Conical Burner (스월 예혼합 버너의 연소 특성에 관한 실험적 연구)

  • Kim, Gu;Cho, Ju Hyeong;Lee, Dong Suk;Kim, Han Seok;Sohn, Chae Hoon;Lee, Sang Min;Kim, Min Kuk;Ahn, Kook Young
    • Journal of the Korean Society of Combustion
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    • v.19 no.3
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    • pp.1-7
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    • 2014
  • Experimental study has been carried out to understand combustion characteristics of a swirl-stabilized premixed gas turbine combustor for power generation. $NO_x$ and CO emissions, extinction limit, pressure loss, and temperature distribution were measured for various operating conditions. Results show that, with increasing inlet air temperature, $NO_x$ is increased due to a higher adiabatic flame temperature while CO is increased or decreased for low or high A/F ratio regime, respectively. depending on the flame location. With decreasing load from the design condition, $NO_x$ is decreased as thermal load is reduced. With further decreasing load, however, $NO_x$ is increased due to a longer residence time. CO is decreased and then increased with decreasing load. Flame extinction limit is extended with increasing inlet air temperature as the recirculation strength is enhanced.

Adsorption-Desorption Characteristics of NO, $N_2O$ and $O_2$ over Mixed Oxide Catalysts of AlCoPd (1/1/0.05) and AlCoFe (1/1/2) (AICoPd (1/1/0.05) 및 AICoFe (1/1/2)의 혼합금속산화물 촉매에 의한 NO, $N_2O$$O_2$의 흡탈착 특성 연구)

  • Han, A-Reum;Hwang, Young-Ae;Chang, Kil-Sang
    • Clean Technology
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    • v.17 no.2
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    • pp.142-149
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    • 2011
  • The adsorption and desorption behaviors of NO and $N_2O$ over two mixed oxide catalysts, AlCoPd (1/1/0.05) and AlCoFe (1/1/2), have been investigated for the lean $NO_x$ trap applications. The catalysts showed good adsorption capabilities for NO and $N_2O$ without needing oxidation step. The adsorption decreased a lot when they are co-adsorbed with oxygen. While NO kept high adsorbability and selectivity with respect to oxygen, those of $N_2O$ decreased sharply. From the TPD results, NO and $N_2O$ are considered to decompose into nitrogen and oxygen in the higher temperature range and the oxygen seems to be strongly attached to the catalysts even at high temperature.

Microalgal Removal of $CO_2$from Flue Gases: Changes in Medium pH and Flue Gas Composition Do Not Appear to Affect the Photochemical Yield of Microalgal Cultures

  • Olaizola, Miguel
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.8 no.6
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    • pp.360-367
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    • 2003
  • Our research objectives are to determine under what conditions microalgal-based $CO_2$capture from flue gases is economically attractive. Specifically, our objective here was to select microalgae that are temperature, pH and flue gas tolerant. Microalgae were grown under five different temperatures, three different pH and five different flue gas mixtures besides 100% $CO_2$(gas concentrations that the cells were exposed to ranged 5.7-100% $CO_2$, 0-3504ppm SO$_2$, 0-328ppm NO, and 0-126ppm NO$_2$). Our results indicate that the microalgal strains tested exhibit a substantial ability to withstand a wide range of temperature (54 strains tested), pH (20 strains tested) and flue gas composition (24 strains tested) likely to be encountered in cultures used for carbon sequestration from smoke stack gases. Our results indicate that microalgal photosynthesis is a limited but viable strategy for $CO_2$capture from flue gases produced by stationary combustion sources.

Effect of Compression Ratio Change on Emission Characteristics of HCNG Engine (압축비 변화가 수소-천연가스 엔진의 배기특성에 미치는 영향)

  • Lee, Sung Won;Lim, Gi Hun;Park, Cheol Woong;Choi, Young;Kim, Chang Gi
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.5
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    • pp.473-479
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    • 2013
  • This study focused on a heavy-duty natural gas engine fuelled with HCNG (CNG: 70 vol%, hydrogen: 30 vol%) and CNG. To study the emission characteristics of an HCNG engine with high compression ratio, the exhaust gas of CNG and HCNG fuel were analyzed in relation to the change in the compression ratio at the half load condition. The results showed that the thermal efficiency improved with an increase in the compression ratio. Consequently, $CO_2$ emission decreased. CO emission increased with inefficient oxidation due to the low exhaust gas temperature. $NO_x$ emission with high compression ratio was increased at the same excess air ratio condition. However, $NO_x$ emission was not affected by a compression ratio exceeding ${\lambda}$ = 1.9 because of the same MBT timing.

A Study on Removal of NOx by Low Temperature Plasma (저온플라즈마에 의한 질소산화물의 제거에 관한 연구)

  • Park, Hei-Jae;Lee, Nae-Woo;Choi, Jae-Wook;Lim, Woo-Sub
    • Korean Chemical Engineering Research
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    • v.48 no.4
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    • pp.540-543
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    • 2010
  • In this study, we made low temperature plasma reactor in order to treat safely $NO_x$ which included in the gas. We investigated experimently and inspected efficiency characteristics of equipment about flow rate of reactant material and discharge input power which supplied into reactor. As a reaction gas, by using mixture gas of $NO/N_2$ and $N_2/O_2$, we setted up initial NO concentration and supplied the speed of a current to 1~4 l/min. When the amount of flow increased, reduction rate of NO was low. Also when discharge input power was high, decomposition of NO was easy. Also the longer delay time of reaction material and the higher discharge input power was, the higher decomposition energy efficiency was. And when the amount of flow was much, and the more discharge input power increased, the more ozone generated.