• 제목/요약/키워드: $NO_x$ conversion

검색결과 166건 처리시간 0.021초

메탄/합성가스 혼합물에 의한 발전용 SI 가스엔진의 성능에 관한 연구 (Study on the Performance of a Spark Ignition Gas Engine for Power Generation fueled by the Methane/Syngas Mixture)

  • 차효석;허광범;송순호
    • 한국가스학회지
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    • 제19권5호
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    • pp.7-12
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    • 2015
  • 현재까지 수소는 주로 천연가스의 연료 개질에 의해 발생된 합성가스를 이용해 생산된다. 합성가스 내의 수소 수율을 높이기 위해선 추가적인 공정이 필요하다. 하지만, 수소의 수율 향상을 위한 공정에는 별도의 에너지원과 경제적 비용이 수반된다. 그러므로 보다 효율적으로 합성가스를 활용하기 위해 그 자체로 혼합물로 이용하는 방법에 관한 관련 연구들이 이루어지고 있다. 본 연구에서는 30kW급 발전용 스파크 점화 가스엔진에서 메탄/합성가스 혼합물이 엔진의 주요 성능에 미치는 영향을 조사하였다. 그 결과 메탄/합성가스 혼합물에 의해서 최대 실린더 내부 압력과 그 때의 크랭크 각도와 같은 엔진 내 연소 현상은 개선되는 것으로 나타났다. 이를 통해 메탄-합성가스 혼합물의 연료 전환 효율은 메탄-수소 혼합물의 약 98% 수준으로 향상시킬 수 있고 질소산화물 배출량은 메탄-수소 혼합물의 약 12%만큼 감소시킬 수 있다.

공개용과 상업용 DICOM STL 파일변환 프로그램으로 출력한 삼차원 프린팅 쇄골 골절 모델의 품질비교 (Comparison of the Quality of Clavicle Fracture Three-dimensional Model Printing by Open Source and Commercial use Digital Imaging and Communications in Medicine Stereolithography File Conversion Program)

  • 오왕균;김형균
    • 대한방사선기술학회지:방사선기술과학
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    • 제41권1호
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    • pp.61-66
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    • 2018
  • The recent 3D printing technology is used in various medical, manufacturing, and education fields and is more efficient in terms of production process, time, and cost than existing production. Especially in fracture surgery, interest and research have been focused on improving accuracy, shortening of operation time and recovery time, and reducing reoperation. However, because of the financial and technical problems of the 3D printer and the file conversion program, the 3D printing is made directly at the hospital, and it is not generally used for diagnosis of fracture and surgical research. In this study, to solve those problems, clavicle CT imaging was switched into Osirix Open Source DICOM Viewer, Stereolithography file conversion programs and commercial Terarecon 3D DICOM Viewer, file conversion programs, and then clavicle fracture model was directly made through 3D printer of fused filament fabrication wire additive processing method, and then the accuracy of the shape was compared and analyzed. Clavicle fracture models printed in two methods were blind-tested on clinicians of general hospitals' orthopedics and radiologic technicians with over 10 years of experiences, and then their analysis opinions of resolution reviews were analyzed. The result showed no difference. The 3D printing model with open source DICOM STL file conversion program used was applicable to clinical, so it is considered useful in precision diagnosis of fracture and operation plans.

세리아가 첨가된 니켈 치환 하이드로탈사이트로부터 유도된 촉매에 의한 메탄의 부분산화 (Partial Oxidation of Methane Over Ceria-promoted Catalysts Derived from Ni-substituted Hydrotalcite)

  • 이승환;김미소;곽정훈;임태훈;남석우;홍성안;윤기준
    • 신재생에너지
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    • 제4권2호
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    • pp.39-44
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    • 2008
  • Partial oxidation of methane was carried out by ceria-promoted Ni-substituted hydrotalcite-derived catalysts ($Ce_xNi_3$-HTlc ; x=$0.3{\sim}1.2$) in a fixed-bed reactor. The Ce/Ni ratio of 0.3/3 in the catalyst showed the best catalytic activity but the Ce/Ni ratio became higher above 0.3/3, the catalyst became less active in short-term tests. No ceria promoted catalyst was started to decrease $CH_4$ conversion after 20 h but the Ce/Ni ratio 0.3/3 catalyst was kept its stability in long-term tests.

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대기내 발생하는 복잡한 광화학반응에 대한 수치실험 (Numerical Simulation of Complicated Photochemical Reactions Occurring in the Atmosphere)

  • 원경미;김유근;이화운;김희정
    • 한국환경과학회지
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    • 제15권3호
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    • pp.203-209
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    • 2006
  • In predicting oxidants concentration, the most important fact is to select a suitable photochemical reaction mechanism. Sensitivity analysis of $O_3$ and other important photochemical oxidants concentrations was conducted by using CBM-IV model. The predicted oxidants concentration was considerably related with the initial concentration of formaldehyde, $[NO_2]/[NO],\;NO_x$, RH and RCHO. As the initial concentration of formaldehyde increased, concentration of $NO_2$ increased. $O_3$ concentration was proportional to the $[NO_2]/[NO]$ ratio. When the initial concentrations of RH and RCHO were high, photochemical reaction was more reactive, including more rapid conversion of NO to $NO_2$ and increased oxidants. Also, the sensitivities of ozone formation to rate constants, $K_l,\;K_2\;and\;K_3$ in the $NO_2$ photolysis were studied.

Nutritional Evaluation of Chinese Nonconventional Protein Feedstuffs for Growing-Finishing Pigs - 2. Rapeseed Meal

  • Li, Defa;Qiao, S.Y.;Yi, G.F.;Jiang, J.Y.;Xu, X.X.;Thacker, P.;Piao, X.S.;Han, In K.
    • Asian-Australasian Journal of Animal Sciences
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    • 제13권1호
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    • pp.46-52
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    • 2000
  • Two experiments were conducted to determine ileal digestibilities for the amino acids contained in rapeseed meal using the regression technique and then applying the values obtained, in a growth trial, using growing-finishing pigs. For the digestibility trial, four 20 kg crossbred $(Yorkshire{\times}Landrace{\times}Beijing\;Black)$ barrows were fitted with simple T-cannula in the terminal ileum. After recovery, the barrows were fed one of four experimental diets according to a $4{\times}4$ Latin Square design. The pigs were fed corn-soybean meal based diets supplemented with 0, 25, 50 or 75% rapeseed meal. For the growth trial, 80 crossbred $(Yorkshire{\times}Landrace{\times}Beijing\;Black)$ growing pigs $(20{\pm}2.4kg)$ were fed corn-soybean meal diets supplemented with 0, 3, 6, 9 or 12% rapeseed meal. Four pens (2 gilts and 2 castrates) were assigned to each treatment. With the exception of isoleucine and methionine, the digestibility coefficients for the indispensible amino acids declined as the level of rapeseed meal in the diet increased. There was little agreement between the amino acid digestibilities determined with the regression technique and values previously published for rapeseed meal. During the growing (22-42 kg) period, the addition of rapeseed meal had no significant effects on gain, feed intake or feed conversion. During the finishing period (58-91 kg), daily gain was not affected by rapeseed meal inclusion but feed conversion declined (p<0.04) as the level of rapeseed meal in the diet increased.

유기 태양전지의 개발 현황과 기술 과제 (Technical Tasks and Development Current Status of Organic Solar Cells)

  • 장지근;박병민;임성규;장호정
    • 한국재료학회지
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    • 제24권8호
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    • pp.434-442
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    • 2014
  • Serious environmental problems have been caused by the greenhouse effect due to carbon dioxide($CO_2$) or nitrogen oxides($NO_x$) generated by the use of fossil fuels, including oil and liquefied natural gas. Many countries, including our own, the United States, those of the European Union and other developed countries around the world; have shown growing interest in clean energy, and have been concentrating on the development of new energy-saving materials and devices. Typical non-fossil-fuel sources include solar cells, wind power, tidal power, nuclear power, and fuel cells. In particular, organic solar cells(OSCs) have relatively low power-conversion efficiency(PCE) in comparison with inorganic(silicon) based solar cells, compound semiconductor solar cells and the CIGS [$Cu(In_{1-x}Ga_x)Se_2$] thin film solar cells. Recently, organic cell efficiencies greater than 10 % have been obtained by means of the development of new organic semiconducting materials, which feature improvements in crystalline properties, as well as in the quantum-dot nano-structure of the active layers. In this paper, a brief overview of solar cells in general is presented. In particular, the current development status of the next-generation OSCs including their operation principle, device-manufacturing processes, and improvements in the PCE are described.

Role of Nitric Oxide in Pepsinogen Secretion from Rat Gastric Chief Cells

  • Sung, Dae-Suk;Seo, Dong-Wan;Choi, Don-Woong;Ahn, Seong-Hoon;Hong, Sung-Youl;Lee, Hoi-Young;Han, Jeung-Whan;Lee, Hyang-Woo
    • Biomolecules & Therapeutics
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    • 제7권2호
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    • pp.105-111
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    • 1999
  • Nitric oxide (NO), a cellular messenger synthesized from L-arginine by NO synthase (NOS, EC.1.14.13.39), is considered to be a regulator of gastric secretion. In the present study, the role of NO in the regulation of exocrine secretion was investigated in rat gastric chief cells. Treatment of chief cells with carba-chol resulted in an increase in the arginine conversion to citrulline, the amount of $NO_{x}$, the release of pepsine-gen, and the level of cGMP Especially, carbachol-stimulated increase of arginine to citrulline transformation, the amount of $NO_{x}$, cGMP level and the release of pepsinogen were partially reduced by the natural NOS inhibitor, $N^{G}$-monomethyl-L-arginine (MMA) and $N^{G}$, $N^{G}$-dimethyl-L-arginine (DMA). Furthermore, MMA- and DMA-induced decrease of pepsinogen secretion showed dose-dependent patters. Activation of NOS is one of the early events in receptor-mediated cascade of reactions in gastric chief cells and NO, not completely, but partially mediates gastric secretion. Agonist-stimulated pepsinogen secretion in chief cells has been considered to be mediated in adenosine 3',5'-cyclic monophosphate pathway and/or guanosine 3', 5'-cyclic monophosphate (cGMP) pathway. Taken together, the above results suggest that partial decrease of exocrine secretion following treatment of NOS inhibitor may result from the inactivation of NOS and subsequent guano- late cyclase, and NO/cGMP pathway may play a pivotal role in exocrine secretion.

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Pt-Rh 이원금속 촉매의 구조와 반응성에 관한 연구 (A Study on Structure and Reactivity of Pt-Rh Bimetallic Catalysts)

  • 김영길;신기환;이재의
    • 공업화학
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    • 제7권4호
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    • pp.661-669
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    • 1996
  • NaY 제올라이트에 Pt/Rh비를 달리하여 이온교환법으로 제조한 Pt-Rh촉매의 특성을$^{129}Xe$-NMR과 EXAFS 방법으로 특성조사를 하였다. $^{129}Xe$-NMR과 EXAFS 자료는 PtRh 이원금속 클러스터의 표면으로 Rh 원자들이 모이는 것으로 나타났다. 모사 자동차 배기가스를 사용하여 희박, 과농 및 양론조건에서 CO, HC 및 $NO_x$ 전환율을 측정하였으며, Pt-Rh/NaY(Pt/Rh=1) 이원금속 촉매가 다른 촉매들보다 세가지 오염물질에 대한 반응활성이 높게 나타남을 알 수 있었다.

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직분사 디젤 엔진에서 1-옥탄올/경유 혼합 연료의 연소 및 배기 특성 연구 (Investigation of the Combustion and Emission Characteristics of 1-Octanol/Diesel Fuel Blends in a Direct Injection Diesel Engine)

  • 박철오;양정현;김범수;권재성
    • 한국수소및신에너지학회논문집
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    • 제34권1호
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    • pp.69-76
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    • 2023
  • An experimental study was conducted on a 4-stroke direct injection diesel engine to examine the combustion and emission characteristics of 1-octanol/diesel fuel blends. The concentration of 1-octanol in the fuel blends was 10%, 30%, and 50% by volume. Experiments were conducted by varying the engine torque from 6 Nm to 12 Nm at the same engine speed of 2,700 rpm. Results showed that the fuel conversion efficiency increased as the 1-octanol proportion increased under most experimental conditions. However, the brake specific fuel consumption increased due to the relatively low lower heating value of 1-octanol. The smoke opacity and the concentrations of NOx and CO emissions generally decreased with brake mean effective pressure as the 1-octanol proportion increased. On the other hand, the unburned hydrocarbon concentration increased with an ascending ratio of 1-octanol.

NO/cGMP Pathway is Involved in Exocrine Secretion from Rat Pancreatic Acinar Cells

  • Ahn, Seong-Hoon;Seo, Dong-Wan;Ko, Young-Kwon;Sung, Kae-Suk;Bae, Gyu-Un;Yoon, Jong-Woo;Hong, Sung-Youl;Han, Jeung-Whan;Lee, Hyang-Woo
    • Archives of Pharmacal Research
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    • 제21권6호
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    • pp.657-663
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    • 1998
  • The enzyme responsible for the synthesis of nitric oxide (NO) from L-arginine in mammalian tissues is known as nitric oxide synthase (NOS) (EC.1.14.13.39). In the present study, the role of NO in the regulation of exocrine secretion was investigated in rat pancreatic acinar cells. Treatment of rat pancreatic acinar cells with cholecystokinin-octapeptide (CCK-OP) resulted in an increase in the arginine conversion to citrulline, the amount of $NO_X$, the release of amylase, and the level of CGMP. Especially, CCK-OP-stimulated increase of arginine to citrulline transformation, the amount of $NO_X$, and CGMP level were completely counteracted by the inhibitor of NOS, NG-monomethyl-L-arginine (MMA), by contrast, that of amylase release was partially reduced. Furthermore, MMA-induced decrease of NOS activity and amylase release showed dose-dependent pattern. The data on the time course of CCK-OP-induced citrulline formation and CGMP rise indicate that NOS and guanylate cyclase were activated by treatment of CCK-OP. However, the mechanism of agonist-stimulated guanylate cyclase activation in acinar cells remains unknown. Therefore, activation of NOS is one of the early events in receptor-mediated cascade of reactions in pancreatic acinar cells and NO, not completely, but partially mediate pancreatic enzyme exocrine secretion.

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