• 제목/요약/키워드: $NO_2/NO_x$ ratio

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엑스선 촬영 시 보조도구 재료로써 탄소 섬유 강화 플라스틱의 유용성 (Usefulness of Carbon Fiber Reinforced Plastics as a Material of Auxiliary Tool for X-ray Imaging)

  • 문준호;구본열
    • 대한방사선기술학회지:방사선기술과학
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    • 제46권3호
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    • pp.197-205
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    • 2023
  • When taking X-rays, various auxiliary tools were used to fix a patient's exact shooting position and posture. In this study, we evaluated the usefulness of carbon fiber reinforced plastics(CFRP) 3K as a material of auxiliary tools by comparing poly methyl metha acrylate(PMMA), polycarbonate(PC), and CFRP 3K each of which has high radiolucency. X-ray radiolucencies were measured by stacking 1 mm panels of each material, and contrast to noise ratio(CNR) and signal to noise ratio(SNR) of images of each material were measured by comparing with None, which stands for images that are taken without any material. All three materials showed over 90% X-ray radiolucencies within 2 ㎜ thickness, and there was no significant difference. PC, PMMA and CFRP 3K had high CNR and SNR in order, and CFRP 3K showed the closest CNR and SNR to those of None. While taking X-rays, by using CFRP 3K material within 2 ㎜ thickness as a material of auxiliary tools, which are used to reduce re-shooting and X-ray exposure by fixing a patient's exact shooting position and posture and improve the quality of medical images, a high X-ray radiolucency of over 90% would be obtained, and the influence on the image could be minimized.

Biological Aerated Filter에서 유입 질소농도에 따른 아질산화 특성 (Nitritation Characteristics Depending on Influent Nitrogen Concentration in a Biological Aerated Filter)

  • 유익근
    • 한국물환경학회지
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    • 제30권1호
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    • pp.1-7
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    • 2014
  • The purpose of this study was to investigate the nitrification characteristics of biological aerated filter (BAF) packed with ceramic media, especially focusing on nitrite build-up during nitrification. When increasing the nitrogen load above $1.63kgNH_4{^+}-N/m^3{\cdot}d$, ammonium removal efficiency decreased to less than 60% and the nitrite ratio ($NO_2{^-}-N/NO_x-N$) of higher than 75% was achieved due to the inhibitory free ammonia (FA, $NH_3-N$) concentration and oxygen limitation. FA inhibition, however, is not recommended strategy to promote nitrite build-up since FA concentration in the reactor is coupled with decreased ammonium removal efficiency. Nitrite ratio in the effluent was also affected by aeration rate and influent ammonium concentration. Ammonium oxidation was enhanced at a higher aeration rate regardless of influent ammonium concentration but, the nitrite ratio was dependent on both aeration rate and influent ammonium concentration. While a higher nitrite ratio was obtained when BAFs were fed with $50mgNH_4{^+}-N/L$ of influent, the nitrite ratio significantly decreased for a greater influent concentration of $200-300mgNH_4{^+}-N/L$. Taken together, aeration rate, influent ammonium concentration and FA concentrations kept in the BAF were found to be critical variables for nitrite accumulation in the BAF system.

$H_2/HCl/Air$ 예혼합 화염의 질소산화물 생성에서 염화수소의 영향 (The Effect of Hydrogen Chloride on the $NO_x$ Production in $H_2/HCl/Air$ Premixed Flame)

  • 권영석;이기용
    • 한국연소학회지
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    • 제9권4호
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    • pp.28-34
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    • 2004
  • Numerical simulations of freely propagating flames burning $H_2/HCl/Air$ Air mixtures were performed at atmospheric pressure in order to understand the effect of hydrogen chloride on flame structures. The chemical and physical effects of hydrogen chloride on flame structures were observed. A chemical kinetic mechanism was developed, which involved 26 gas-phase species and 198 forward elementary reactions. Under several equivalence ratios the flame speeds were calculated and compared with those obtained from the experiments, the results of which were in good agreement. As hydrogen chloride as additive was added into $H_2/Air$ flame, the flame speed, radical concentration and NO production rate were decreased. The chemical effect of hydrogen chloride caused the reduction of radical concentration, and then the decrease of the net rate of NO production. It was found that the influence in the reduction of $EI_{NO}$ with the addition of hydrogen chloride was attributed more due to the chemical effect than the physical effect.

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Effects of Sb-Incorporation on the 2223 Phase in the Superconducting Bi-Pb-Sr-Ca-Cu-O System

  • Seong Han Kim;Dong Hoon Lee;Jong Sik Park;Seung Koo Cho;Sung Han Lee;Keu Hong Kim
    • Bulletin of the Korean Chemical Society
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    • 제15권2호
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    • pp.115-118
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    • 1994
  • Samples of ($Bi_{2-x}Sb_x)PbSr_2Ca_2Cu_3O_y$, compositions with x=0.0, 0.1, and 0.2 were prepared by solid-state reaction. The solubility of Sb into the 2223 phase is lower than 0.05 for the ratio of Sb/Bi. The lack of stability of the Sb-substituted $Bi_2O_2$ double layers is likely to cause the solubility low. There is no great dependence of lattice parameters on the Sb-content, and bonds around the square-pyramidal Cu atom are not affected by the $Sb^{3+}$ ion substituted. The superconducting transition temperature of this system is decreased gradually with increase of Sb, which is tentatively attributable to the perturbation of the Bi 6p-O 2p band and/or to the low volume fraction of the 2223 phase.

아세테이트 토우 데니아와 필터권지 기공도가 담배 연기희석에 미치는 영향 (Effect of Acetate Tow Denier and Porous Plug Wrapping Paper on the Ventilation of Filter Cigarettes)

  • 이근회;김성한;심철호;양광규
    • 한국연초학회지
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    • 제5권2호
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    • pp.77-82
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    • 1983
  • The ventilation of cigarette samples made by the combination of various acetate tow denier and porous plug wrapping paper have been investigated The ventilation rate increased no longer in the acetate tow with high mono denier and low total denier but changed slightly in that with low mono denier and high total denier when the porosity of plug wrapping paper was more than 6500cm/min. cbar. Tip pressure drop ratio, Y, was significantly influenced by tip ventilation rate, X. i. e., Y = 1.0880-0.0042x The relationships of ventilation rate, $X_v$. and smoke delivery, Y, were as follows; Tar : $Y_r$= -14.0458-0.1650$X_v$ Nicotine : $Y_N$= - 1.1045-0.0125$X_v$ CO : $Y_{co}$=17.2806-0.2090$X_v$

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화력발전소 배출량 제거에 따른 여름철 O3 농도의 변화 특성 (Effect of Removal of Power Plant Emissions on the characteristics of Ozone Concentration Changes in Summer)

  • 김동진;전원배;박재형;문정혁
    • 한국지구과학회지
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    • 제42권2호
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    • pp.149-163
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    • 2021
  • 본 연구에서는 광화학 대기질 모델인 CMAQ을 활용해 화력발전소 배출량 제거에 따른 O3 농도의 변화 특성을 분석하였다. 하동 화력발전소를 대상으로 주변 지역의 O3 농도 변화에 대한 발전소 배출량의 영향을 조사하기 위해 하동 화력발전소의 배출량 제거 전과 후의 CMAQ 수치 모의를 수행하였다. 수치 모의 결과 O3의 주요 전구 물질인 NOx (-18.87%)와 VOCs (-11.27%)의 농도가 감소한 반면에 O3 (25.24%)의 농도는 증가한 것으로 나타났다. 화력발전소 배출량 제거로 인한 NO와 O3 농도의 상대적인 변화를 비교해 본 결과 높은 음의 상관관계(R= -0.72)를 나타내는 것이 확인되었다. 이러한 결과는 O3의 농도 증가가 NO 농도 감소로 인한 O3의 적정 효과 완화로 설명 될 수 있음을 의미한다. 해당 지역의 O3의 농도 증가가 NO의 농도 감소에 주로 영향을 받은 이유는 해당 지역이 VOC-limited (i.e., NOx-saturated) 지역이기 때문으로 분석되었다. 이러한 결과는 특정 지역의 O3의 농도가 단순히 배출량의 증감에 따라 비례하게 나타나지 않을 수 있다는 것을 암시한다. 따라서 화력발전소 배출량 저감 조치로 인한 대기 중 O3 농도 개선 효과를 정확히 예측 및 평가하기 위해서는 지역 별 O3의 생성 및 소멸 기작에 대한 심도 있는 이해가 필요하다.

고온·고압 조건에서 바이오디젤의 가연한계 예측 (A Prediction on the Flammability Limits of Biodiesel Fuel in the High Temperature and Pressure Conditions)

  • 임영찬;정준우;서현규
    • 한국분무공학회지
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    • 제24권4호
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    • pp.157-162
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    • 2019
  • This numerical study was analyzed to predict the flammability limits of biodiesel and diesel fuels in the high temperature and pressure conditions. To achieve this, the biodiesel fuel was simulated with the chemical species of n-heptane (n-C7H16), methyl decanoate (C11H22O2), and methyl-9-decenoate (C11H20O2), and the diesel fuel was substituted the chemical species of n-heptane. The closed 0-D homogeneous reactor model which was employed the 1100 K of ambient temperature and 35 atm of ambient pressure was used for the simulation of constant volume combustion, and the equivalence ratio was changed from 0.3 to 2.5 conditions. In addition, a comparative analysis study was conducted with the results of HCCI engine simulation and flammability limits according to the changes of equivalence ratio. The results of combustion temperature, pressure, and ignition delay were increased when the equivalence ratio elevated from 0.3 to 1.3 conditions because the increase in fuel oxidation rate affects the chemical reaction of the overall combustion process. Furthermore, the CO and NOX production under the rich combustion conditions are considered to have a trade off relationship since the OH radicals and O2 chemical species are greatly affected the CO and NOX production and oxidation processes.

Studies on hydrophobic drug-soluble carrier coprecitates 2

  • Shin, Sang-Chul
    • Archives of Pharmacal Research
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    • 제2권1호
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    • pp.49-64
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    • 1979
  • In an atempt to elucidate further physicochemical properties of furosemide-PVP coprecipitates, extensive investigations such as TLC, UV,IR, NMR, X-ray diffraction, TGA and DTA studies were carried out for the furosemide test systems. X-ray diffraction studies revealed that the pure furosemide and the furosemide contained within a physical mixture were crystalline in nature. However, there was no crystallinity evident in the 1:5 furosemide-PVP 40,000 coprecipitate system, even after standing for two years. The various ratio furosemide-PVP 40,000 coprecipitate systems revealed that the coprecipitate containing a greater amount of PVP 40,000 than that of furosemide showed a crystalline state of furosemide and that the minimum amounts of PVP to make amorphous form of furosemide was 1:1 ratio of furosemide to PVP. From the furosemide-PVP coprecipitate systems with PVP of different molecular weights of 10,000, 40,000 and 360,000, all the 1:1 ratio coprecipitates did not exhibit any crystallinity of furosemide, whereas all the 2:1 ratio coprecipitates showed a presence of crystalline furosemide. All the coprecipitated preparations with PEG 4,000 and with PEG 6,000 showed the diffraction peaks indicating the presence of crystalline furosemide. The comparison of infrared spectra of the physical mixture and the coprecipitate showed an interaction such as association between the functional groups of furosemide and PVP in the molecular level, whereas the studies by TLC, UV and NMR showed its dissociation in methanol solution. The weight losses in TGA curves showed all the same patterns. However, a little different transition form in DTA thermograms was shown between the physical mixture and the coprecipitate, indicating the different thermal property.

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플라즈마 화학반응에 의한 연소가스 중 NOx. SOx 동시제거 특성 (Simultaneous Removal Characteristics of NOx, SOx from Combustion Gases using Plasma Chemical Reaction)

  • 박재윤;고용술;이재동;손성도;박상현;고희석
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 춘계학술대회 논문집
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    • pp.406-409
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    • 1999
  • Experimental Investigations were carried out to remove NOx, SOx simultaneously from simulated flue gas[NO(0.02%)-SO$_2$(0.08%)-$CO_2$-Air-$N_2$] by using a plasma chemical reaction. Ammonia gas(14.81%) balanced by argon was diluted by all and was Introduced to mall simulated flue gas duct through NH$_3$ Injection system which is in downstream of reactor. The NH$_3$ molecular ratio(MR) was determined based on (NH3) to [NO+S0$_2$]. MR is 1, 1.5, 2.5. The NOx removal rate significantly increased with increasing NaOH bubble quantity. The SO$_2$ removal rate was not significantly effected by applied voltage, however it fairly Increased with increasing NH$_3$ molecule ratio. By-product aerosol particle was observed by XRD(X-ray diffraction) after sampling, The NOx, SOx removal rates, when H2O vapour bubbled by dry all was injected to plasma reactor, were better than those of other cases. When aqueous NaOH solution(20%) bubbled by 2.5( ι /min) of $N_2$ and 0.5 ( ι /min) NH$_3$(MR=1.5) were injected to simulated flue gas, The NOx. SOx removal rate was 95 ~ 100[%]

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흰쥐의 직장과 방광에 X-선 조사와 마이크로파 온열요법의 효과에 관한 실험적 연구 (An Experimental Study on the Effect of Combined X-ray and Microwave Hyperthermia on the Rectum and Urinary Bladder of Rats)

  • 이경자;이정식
    • Radiation Oncology Journal
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    • 제4권2호
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    • pp.115-128
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    • 1986
  • 온열요법은 암치료에 있어서 방사선과 병용하였을 때 상호보완 작용을 하여 방사선에 저항성이 높은 세포주기의 S-기에 민감하게 작용하며 세포의 준치사손상의 회복을 저지시킴으로써 방사선의 효과를 상승시킬 수 있다. 저자는 100Watt, 2450MHz의 마이크로파 온열기구를 제작하고 조직등가인 판톰을 이용하여 예비측정과 방열조사 조건 및 방법을 계획한 후 생물학적 반응을 관찰하기 위하여 흰쥐 102마리를 이용하여 온열요법, X-선조사 (6Gy-15Gy) 및 선 조사와 온열요법을 병행하여 직장과 방광의 조직학적 소견을 관찰하여 다음과 같은 결론을 얻었다. 1) 100Watt, 2450MHz의 소형마이코로파 온열발생장치로서 조직을 $40{\sim}50^{\circ}C$로 유지하여 1시간 이상 가열할 수 있었다. 2) 조직온열분포는 깊이 3cm, 직명 2-10cm의 넓이에 $40{\sim}44^{\circ}C$의 온도분포를 계속 유지할 수 있었다. 3) 온열요법 단독으로는 직장의 점막하층의 부종을 볼 수 있었으나 방광의 조직학적 변화는 볼 수 없었다. 4) 점막상피괴사는 직장에 X-선조사 6Gy의 15일군에서, 방광에 8Gy의 15일군에서 각각 나타나기 시작하였으며, 근층괴사는 직장에 X-선조사 8Gy의 15일군에서, 방광에 10Gy의 60일군에서 각각 나타났다. 5) X-선조사와 온열요법병행군에서 직장과 방광의 조직학적변화 (점막과 근층의 괴사)를 관찰하여 열증강율은 1.0으로 증가되지 않음으로서 직장과 방광의 내용선량의 변화가 없음을 시사하였다.

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