• Transactions of the Korean Society of Automotive Engineers
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• v.17 no.1
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• pp.137-145
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• 2009

The steady-state kinetics of the selective catalytic reduction (SCR) of $NO_X$ with $NH_3$ has been investigated over a commercial ${V_2}{O_5}/TiO_2$ catalyst. In order to account for the influence of transport effects the kinetics are coupled with a fully transient two-phase 1D+1D monolith channel model. The Langmuir-Hinshelwood (L-H) mechanism is adopted to describe the steady-state kinetic behavior of the ${V_2}{O_5}/TiO_2$ catalyst. The reaction rate expressions are based on previously reported papers and are modified to fit the experimental data. The steady-state chemical reaction scheme used in the present mathematical model has been validated extensively with experimental data of selective $NO_X$ reduction efficiency for a wide range of inlet conditions such as space velocity, oxygen concentrations, water concentration, and $NO_2/NO$ ratio. The parametric investigations are performed to examine how the $NH_3$ slip from a SCR $DeNO_X$ catalyst and the conversion of $NO_X$ are affected by the reaction temperature, $NH_3/NO_X$ feed ratio, and space velocity for feed gas compositions with $NO_2/NO_X$ ratios of 0 and 0.5.

• Journal of Korean Medical classics
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• v.31 no.2
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• pp.141-153
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• 2018

Objectives : Acupuncture therapy's reinforcement and reduction method is now widely used in the clinical practices. Meanwhile, there has been a voice of concern since the past that acupuncture has no reinforcement. This thought has not been given enough discussion, and the paper attempts to remedy this absence and verify the validity of the concern. Methods : The acupunctural reinforcement and reduction method found in the Huangdineijing is reviewed, and a number of medical books that discuss the idea of lack of reinforcement in acupuncture are studied. Results : Huangdineijing describes the acupunctural unique feature of reduction. The text explains that acupuncture work in a way that is different that medicine, and thus cannot be used for a disease based on deficiency. In addition, it warned the loss of the primordial qi when needling oneself. Reinforcement in the reinforcement and reduction technique as described in Huangdineijing mainly revolves around preventing the loss of the primordial qi. Conclusions : The purpose of the acupunctural reinforcement and reduction is to control the body's disproportional qi deficiency and excess, where some parts of the body has more qi than others. The reinforcement in "acupunctural reinforcement and reduction method" and the reinforcement in "acupuncture only has reduction and no reinforcement" within the thought of "acupuncture has no reinforcement" are different in that one deals with controlling the imbalance of qi in body, and the other deals with dispelling the deficiency by flowing the qi in the viewpoint of entering and out. This calls for a need to establish the proper acupunctural points, numbers, and times for each disease based on the theory of "acupuncture has no reinforcemen."

• Transactions of the Korean Society of Mechanical Engineers
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• v.17 no.6
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• pp.1556-1571
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• 1993

Nitrogen oxides ($NO_x$) are air pollutants which are generated from the combustion of fossil fuels. Stage combustion is an effective method to reduce $NO_x$ emissions. The effects of $NO_x$ reduction by stage combustion in a pilot scale combustor(6.6kW) have been investigated using propane gas flames laden with NH$_{3}$ as Fuel-N. The results in this study are follows; (1) $NO_x$ emissions are dependent on the reducing environment of fuel-rich zone regardless of total air ratio. The maximum $NO_x$ reduction is at the stoichiometric ratio of 0.8 to 0.9 in the reducing zone. (2) $NO_x$ reduction is maximum when burnout air is injected at the point where the oxygen in reducing zone is almost consumed. (3) $NO_x$ reduction is dependent upon the temperature of reducing zone with best effect above 950.deg. C in the reducing zone. (4) The fuel stage combustion is more effective to reduce $NO_x$ formation in the wide range of stoichiometric ratio than two stage combustion. (5) The results of this study could be utilized mainly in a design strategy for low $NO_x$ emission from the combustion of high fuel-nitrogen in energy sources ratio than as an indication of the absolute levels of $NO_x$ which can be achieved by stage combustion techniques in large scale facilities.

• Journal of Mechanical Science and Technology
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• v.18 no.12
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• pp.2303-2309
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• 2004

Flue gas recirculation (FGR) is a method widely adopted to control NOx in combustion system. The recirculated flue gas decreases flame temperature and reaction rate, resulting in the decrease in thermal NO production. Recently, it has been demonstrated that the recirculated flue gas in fuel stream, that is, the fuel induced recirculation (FIR), could enhance a much improved reduction in NOx per unit mass of recirculated gas, as compared to the conventional FGR in air. In the present study, the effect of FGR/FIR methods on NOx reduction in turbulent swirl flames by using N$_2$ and CO$_2$ as diluent gases to simulate flue gases. Results show that CO$_2$ dilution is more effective in NO reduction because of large temperature drop due to the larger specific heat of CO$_2$ compared to N$_2$ and FIR is more effective to reduce NO emission than FGR when the same recirculation ratio of dilution gas is used.

• Asian Journal of Atmospheric Environment
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• v.8 no.4
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• pp.202-211
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• 2014

In this study, long-term rainfall data with irregular spatial distribution in Seoul, Korea, were separated into individual precipitation events by the inter-event time definition of 6 hours. Precipitation washout of $PM_{10}$ and $NO_2$ concentrations in the air considering various complex factors were analyzed quantitatively. Concentrations of $PM_{10}$ and $NO_2$ in the atmosphere were lower under condition of rainfall compared to that of non-precipitation, and a noticeable difference in average $PM_{10}$ concentrations was observed. The reduction of concentrations of $PM_{10}$ and $NO_2$ by rainfall monitored at road-side air monitoring sites was also lower than that of urban air monitoring sites due to continuous pollutant emissions by transportation sources. Meanwhile, a relatively smaller reduction of average $PM_{10}$ concentration in the atmosphere was observed under conditions of light rainfall below 1 mm, presumably because the impact of pollutant emission was higher than that of precipitation scavenging effect, whereas an obvious reduction of pollutants was shown under conditions of rainfall greater than 1 mm. A log-shaped regression equation was most suitable for the expression of pollutant reduction by precipitation amount. In urban areas, a lower correlation between precipitation and reduction of $NO_2$ concentration was also observed due to the mobile emission effect.

• Advances in pediatric surgery
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• v.2 no.2
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• pp.81-87
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• 1996

Although nonoperative reduction plays a major role in the management of uncomplicated intussusception in the pediatric age group, surgical treatment is still a necessary alternative when nonoperative reduction is unsuccessful. The author analyzed the clinical features of 68 patients requiring operation in order to identify factors which might influence the type of operative management. A nine-year experience at Ewha Womans University Hospital was reviewed, and the findings compared to previous reports. Barium was used for the initial reduction attempt in 33 cases, saline in 35. Manual reduction by milking at operation achieved success in 41 cases(60.3%). Fifteen cases(22.1%) required resection of bowel, and 12 patients(17.6%) were found to have spontaneous and complete reduction of the intussusception at operation. Two cases had pathologic leading points. There were no perforations due to nonoperative reduction. There were no significant differences in demographic data, clinical findings, laboratory data, and anatomic type of intussusception between barium and saline reduction groups. However, a significant number of cases with spontaneous reduction were in saline reduction group(p<0.05). There was a slight chance of spontaneous reduction in infants under 6 month of age(p<0.001). Age under 6 month. body temperature over $38^{\circ}C$, symptom over 24 hours, and ileo-colic and ileo-ileo-colic intussusception contributed significantly to the necessity for bowel resection(p<0.05-0.001). The author believes that the age, body temperature, duration of illness, and anatomic type of intussusception strongly influence operative management.

• Transactions of the Korean Society of Automotive Engineers
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• v.11 no.3
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• pp.71-76
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• 2003

A numerical simulation of selective catalytic reduction (SCR) for NO with $NH_3$ is conducted over the $V_2O_5/TiO_2$ and $WO_3-V_2O_5/TiO_2$ catalysts. The governing $NH_3$ and NO transport equations are considered by using the time-dependent FCT (Flux-Corrected Transport) algorithm. After a validating simulation for $NH_3$ step feed and shut-off experiments is analyzed, transient behavior of $NH_3$ and NO concentration in a SCR catalyst is investigated by changing such parameters as inflow $NH_3$ concentration, temperature of the catalyst, and $NH_3$/NOx ratios.

• Journal of Korean Society for Atmospheric Environment
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• v.33 no.2
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• pp.139-158
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• 2017

CMAQ (Community Multiscale Air Quality Model) simulations were carried out to estimate the potential range of contributions on surface $PM_{2.5}$ concentrations over the Seoul Metropolitan Area (SMA) with the gaseous precursors and Primary Particulate Matters(PPM) available from a recent national emissions inventory. In detail, on top of a base simulation utilizing the 2013 Clean Air Policy Supporting System (CAPSS) emission inventory, a set of Brute Force Method (BFM) simulations after reducing anthropogenic $NO_x$, $SO_2$, $NH_3$, VOCs, and PPM emissions released from area, mobile, and point sources in SMA by 50% were performed in turn. Modeling results show that zero-out contributions(ZOC) of $NH_3$ and PPM emissions from SMA are as high as $4{\sim}5{\mu}g/m^3$ over the region during the modeling period. On the contrary, ZOC of local $NO_x$ and $SO_2$ emissions to SMA $PM_{2.5}$ are less than $1{\mu}g/m^3$. Moreover, model analyses indicate that a wintertime $NO_x$ reduction at least up to 50% increases SMA $PM_{2.5}$ concentrations, probably due to increased HNO3 formation and conversion to aerosols under more abundant ozone and radical conditions after the $NO_x$ reduction. However, a nation-wide $NO_x$ reduction decreased SMA $PM_{2.5}$ concentrations even during winter, which implies that nation-wide reductions would be more effective to curtail SMA $PM_{2.5}$ concentrations than localized efforts.

• Journal of the Korean Society of Combustion
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• v.4 no.1
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• pp.27-38
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• 1999

We constructed a wire-cylinder type pulsed corona discharge system for $NO_x$ removal, which was operated in room temperature. A emission spectrometer was built with a boxcar averager and monochrometer equipped with photo-multiplier tube detector. The sensitivity of the emission spectrometer was greatly improved by synchronizing the emission spectrometer with pulsed corona discharge system using a triggered spark-gap switch. $N_2$ spectrum($c^3{\Pi}_u{\rightarrow}X^1{\Sigma}_g{^+}$) was measured in the range of 300 - 450 nm and oxidizing OH radical emission($A^2{\Sigma}^+{\rightarrow}X^2{\Pi}$) was measured in case $N_2$ was supplied with water bubbling. As wet gas composition of inlet $N_2$ supplied in the discharge system increased, the intensity of OH emission was increased and saturated at wet gas composition 50%. We also investigated additive effect of $C_2H_4,\;H_2O,\;H_2O_2$ on the intensity of OR emission and $NO/NO_2/NO_x$ reduction and analysed the related reaction mechanism in corona discharge process. $H_2O_2$ additive increased the intensity of OH emission and $NO/NO_x$ reduction.

• 한국연소학회:학술대회논문집
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• 2004.06a
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• pp.227-234
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• 2004

For gaseous fuel combustion with inherent $CO_2$ capture and low NOx emission, chemical-looping combustion(CLC) may yield great advantages of savings of energy to $CO_2$ separation and suppressing the effect on environment. In chemical-looping combustor, fuel is oxidized by metal oxide medium (oxygen carrier particle) in a reduction reactor. Reduced particles are transported to oxidation reactor and oxidized by air and recycled to reduction reactor. The fuel and the air are never mixed, and the gases from reduction reactor, $CO_2$ and $H_2O$, leave the system as separate stream. The $H_2O$ can be easily separated by condensation and pure $CO_2$ is obtained without any loss of energy for separation. The purpose of this study is to demonstrate inherent $CO_2$ separation and no NOx emission and to confirm high $CO_2$ selectivity, no side reaction (i.e., carbon deposition, hydrogen generation) by continuous reduction and oxidation experiment in a 50kWtb chemical-looping combustor. NiO/bentonite particle was used as a bed material and $CH_4$ and air were used as reacting gases for reduction and oxidation respectively.