• 제목/요약/키워드: $NO_2$ reduction

검색결과 3,633건 처리시간 0.031초

ECU 커먼레일 디젤기관에 있어서 매연 및 NOX 배출물 동시 저감용 일체형 요소-SCR 촉매필터 시스템의 특성에 관한 연구 (A Study on Characteristics of an Integrated Urea-SCR Catalytic Filter System for Simultaneous Reduction of Soot and NOX Emissions in ECU Common-rail Diesel Engines)

  • 배명환
    • 한국자동차공학회논문집
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    • 제22권4호
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    • pp.111-120
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    • 2014
  • The aim of this study is to develop an integrated urea-SCR catalytic filter system for reducing soot and $NO_X$ emissions simultaneously in diesel engines. In this study, the characteristics of exhaust emissions relative to reactive activation temperature under four kinds of engine loads are experimentally investigated by using a four-cycle, four-cylinder, direct injection type, water-cooled turbo intercooler ECU common-rail diesel engine with the integrated urea-SCR $MnO_2-V_2O_5-WO_3/TiO_2/SiC$ catalytic filter system operating at three kinds of engine speeds. The urea-SCR reactor is used to reduce $NO_X$ emissions, and the catalytic filter system is used to reduce soot emissions. The reactive activation temperature is very important for reacting a reducing agent with exhaust emissions. The reactive activation temperatures in this experiment is applied to 523, 573 and 623 K. The fuel is sprayed by the pilot and main injections at the variable injection timing between BTDC $15^{\circ}$ and ATDC $1^{\circ}$ according to experimental conditions. It is found that the $NO_X$ conversion rate is the highest as 83.9% at the reactive activation temperature of 523 K in all experimental conditions of engine speed and load, and the soot emissions shown by the average reduction rate of approximately 93.3% are almost decreased below 0.6% in all experimental conditions regardless of reactive activation temperatures. Also, the THC and CO emissions by oxidation reaction of Mn, V and Ti are shown in the average reduction rates of 70.3% and 38% regardless of all experimental conditions.

산화구리 촉매담지 세라믹 캔들필터를 이용한 NO 제거 (Removal of NO Using CuO/3Al2O3 · 2SiO2 Catalyst Impregnated Ceramic Candle Filters)

  • 홍민선;문수호;이재춘;이동섭
    • 한국대기환경학회지
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    • 제20권3호
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    • pp.291-302
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    • 2004
  • The CuO/$3AL_2O_3{\cdot}2SiO_2$ catalyst impregnated ceramic candle filters for nitrogen oxides removal were prepared by porous mullite($3AL_2O_3{\cdot}2SiO_2$) support and CuO catalyst deposited on this support to achieve uniformly dispersed CuO deposition, which are impregnated into the pores of available alumino-silicate ceramic candle filter. The CuO/3$AL_2O_3{\cdot}2SiO_2$ catalyst impregnated ceramic candle filters were characterized by XRD, BET, air permeability, pore size, SEM and catalytic tests in the reduction of NOx by NH$_3$. The observed effects of CuO/3$AL_2O_3{\cdot}2SiO_2$ impregnated ceramic candle filters in SCR reaction are as follows : (1) when the content of CuO catalyst increased further, activity of NO increased. (2) NO conversion at first increased with temperature and then decreased at high temperatures (above 40$0^{\circ}C$), possibly due to the occurrence of the ammonia oxidation reaction. (3) In pilot plant test for 3 months, NO conversion was greater than 90%.

C-arm을 이용한 EVAR(Endovascular Aneurysm Repair) 시술시 Lead Curtain 설치에 따른 Staff의 피폭선량 감소에 대한 연구 (The investigation of the exposure dose reduction of the Staff according to the Lead Curtain installation in EVAR(Endovascular Aneurysm Repair) surgical operation using C-arm)

  • 유인웅;정재연;이관섭
    • 대한디지털의료영상학회논문지
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    • 제14권2호
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    • pp.33-38
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    • 2012
  • In EVAR procedure using long time C-arm, we studied exposure dose reduction and effeciency through measuring surgical staff's ESD by installing lead curtain operating table next to. The height 3 the spot (50cm, 100cm, 150cm) dose was measured on 2 locations for 600sec in the X-ray radiation considering the surgical staff's movement. To install the curtains, we compared before and after the dose. As a result, it can confirm that dose of the installation former of 50cm height and after is reduced about 75% and 91% in 2 locations. In 100cm height, the reduction of the dose was a bit confirmed. There as to dose value, measured on 150cm height the installation former and after was nearly no change. This research examined the exposure dose about the radiation of the surgical staff during EVAR procedure in which the operation time is the long time. It was implemented in the object that it reduces the radiation exposure. It could confirm the certain effect of the experimental result exposure dose reduction In EVAR procedure using long time C-arm, we studied exposure dose reduction and effeciency through measuring surgical staff's ESD by installing lead curtain operating table next to. The height 3 the spot (50cm, 100cm, 150cm) dose was measured on 2 locations for 600sec in the X-ray radiation considering the surgical staff's movement. To install the curtains, we compared before and after the dose. As a result, it can confirm that dose of the installation former of 50cm height and after is reduced about 75% and 91% in 2 locations. In 100cm height, the reduction of the dose was a bit confirmed. There as to dose value, measured on 150cm height the installation former and after was nearly no change. This research examined the exposure dose about the radiation of the surgical staff during EVAR procedure in which the operation time is the long time. It was implemented in the object that it reduces the radiation exposure. It could confirm the certain effect of the experimental result exposure dose reduction.

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NOx 제거를 위한 금속 담지 ZSM-5 촉매 평가 (Evaluation of ZSM-5 supported metal catalyst for NOx removal)

  • 김진걸;유승준;김성수
    • 한국산학기술학회논문지
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    • 제10권8호
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    • pp.2015-2020
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    • 2009
  • 상압, $200^{\circ}C - 500^{\circ}C$ 조건에서 연소후 배기가스중의 질소산화물 감소 연구가 금속 담지 ZSM-5 촉매에서 수행되었다. 제조된 촉매의 특성은 XRD, SEM, EDX, ICP, ITR 분석 장치를 사용하여 분석하였다. EDX와 ICP 결과로부터 전이 금속이 촉매 표면에 분산된 것을 확인하였다. 금속 담지 ZSM-5 촉매중 Fe/ZSM-5가 최대 NOx 제거율을 보이는 온도 범위($380^{\circ}C-400^{\circ}C$)는 ITR 결과의 최대 환원 속도를 나타내는 온도 $400^{\circ}C$와 일치하므로, 환원 속도가 HC-SCR 반응 속도를 조절하는 것으로 판단된다.

측두하악관절조영술을 이용한 측두하악관절장애의 임상적 연구 (A CLINICAL STUDY OF TEMPOROMANDIBULAR JOINT DISORDERS BY USING ARTHROGRAPHY)

  • 이승현;황의환;이상래
    • 치과방사선
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    • 제28권1호
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    • pp.155-169
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    • 1998
  • The purpose of this study was to prove the relationship between arthrographic and clinical features in temporomandibular joint disorders. In order to carry out this study, ninety-eight arthrographic examinations of temporomandibular joints were performed on eighty-two patients who had the temporomandibular joint disorders. As the arthrographic examination, the cases were classified in three groups, disk displacement with reduction, disk displacement without reduction, within normal limit. After this, the cases were clinically examined, and the results were compared and analyzed in each other group. The obtained results were as follows; 1. As the classification by arthrographic examination, three groups (disc displacement with reduction, disc displacement without reduction, within normal limit) were 41 %, 54%, 5% of total cases in this study, respectively. 2. The third decade(65%) was most frequent in this study. The average age of each group (disc displacement with reduction, disc displacement without reduction, within normal limit) was 24, 28, 21, and disc displacement without reduction group was higher than any other group. 3. In the chief complaint, pain was the most frequent in all three groups. Joint sound was also frequent in disc displacement with reduction group, but in disc displacement without reduction group, limitation of mouth opening was more frequent. 4. Of the various pain, the movement pain was most frequent ( 61 %) in this study. In joint sound, click(63%) was the most frequent in disc displacement with reduction group, but sound history(42%) and no sound (31 %) were more frequent in disc displacement without reduction group. 5. The average maximum opening of each group (disc displacement with reduction, disc displacement without reduction, within normal limit) was 44mm, 32.9mm, 44mm, and disc displacement without reduction group was less than any other group. 6. The masticatory disturbance of each group (disc displacement with reduction, disc displacement without reduction, within normal limit) was 53%, 79%, 40%, and the trauma history of each group was 50%, 40%,60%.

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소형 고속 디젤엔진의 배기 배출물에 미치는 플르즈마의 영향에 관한 실험적 연구 (An Experimental Study on Effect of Plasma for Exhaust Emissions in Small High-Speed Diesel Engine)

  • 백태실
    • Journal of Advanced Marine Engineering and Technology
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    • 제23권6호
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    • pp.755-760
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    • 1999
  • To remove nitrogen oxides(NOx) in exhaust gas of diesel engine three-way catalytic process with plasma discharger has great possibilities. Characteristics of NOx removal depends on NO conver-sion to $NO_2$ and /or $HNO_3$ due to high activation energies for NO oxidation and reduction, NOx removal efficiency by using three-way catalytic with plasma discharger indicated about 50% at 40watt power consumption condition.

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Biological nitrogen removal of ammonium-rich industrial wastewater by suspended bacterial growth

  • 임준택;성세현;황석환
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2002년도 생물공학의 동향 (X)
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    • pp.399-402
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    • 2002
  • Industrial wastewater with high ammonium concentration was treated in batch biological systems which was a modified Ludzack- Ettinger process. Up to 78% conversion of $NH_4\;^+-N$ to $NO_x\;^--N$ was achieved in batch culture condition. Under anoxic condition with methanol as the carbon source, the denitrifiers decreased $NO_x\;^--N$ concentration from 608 mg/L to 5.6 mg/L in 22 d. As well as anoxic denitrification of $NO_x\;^-$ to $N_2$, dissimilatory nitrate reduction to ammonium also occurred under the condition as respiratory denitrification.

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유동층 반응기에서 우레아에 의한 NO 선택적 촉매 환원 (Selective Catalytic Reduction of NOx by Urea in a Fluidized Bed Reactor)

  • 노선아;정순화;김상돈
    • 한국에너지공학회:학술대회논문집
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    • 한국에너지공학회 1999년도 추계 학술발표회 논문집
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    • pp.35-39
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    • 1999
  • 현재 NO제거에 주로 사용되는 환원제로서 NH$_3$가 있는데 이는 NO에 대한 선택도가 우수하기 때문이다. 그러나, NH$_3$는 독성이 강하고 부식성이 있어 저장 및 수송에 많은 비용이 든다는 단점이 있다. 따라서 본 연구에서는 SOx/NOx 동시 제거 공정에 효과적으로 알려진 fresh and sulfated CuO/${\gamma}$-A1$_2$O$_3$촉매상에서 독성이 강한 NH$_3$를 대신하는 새로운 환원제로서 urea용액을 이용하여 유동층 반응기에서 SCR을 수행해 보고자 한다.(중략)

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Effects of Sibseonsan as an Anti-Inflammatory, Anti-Wrinkle, and Skin Whitening Treatment

  • Jo, Na Young
    • Journal of Acupuncture Research
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    • 제37권2호
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    • pp.88-93
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    • 2020
  • Background: The purpose of this study was to investigate whether Sibseonsan (SSS) is an effective antiinflammatory, anti-wrinkling, and whitening agent. Methods: To determine whether SSS had an anti-inflammatory effect, a murine macrophage cell line was used (RAW 264.7) and production of DPPH, NO, TNF-α, and PGE2 were measured. To ascertain potential anti-wrinkle effects of SSS in these cells, collagenase and elastase production were measured. To verify whether SSS had a whitening effect, tyrosinase activity and DOPA staining were performed using a melanoma cell line (B16/F10). Results: There was no significant reduction in survival of SSS-treated RAW 264.7 cells, up to 400 ㎍/mL. Free radical scavenging (23.96 ± 1.85%) was observed in RAW 264.7 cells treated with SSS at a concentration of 400 ㎍/mL. The SSS treatment group (400 ㎍/mL) significantly inhibited NO production compared with the LPS stimulated treatment group. The SSS treatment of macrophage cells appeared to reduce production of TNF-α in a concentration dependent manner. There was a significant reduction in the concentration of PGE2 by about 25% in the SSS treatment (400 ㎍/mL) group (p = 0.05). Compared with the control, the production of collagenase and elastase in B16/F10 cells treated with SSS (400 ㎍/mL) was greater by 26.37% and 45.71%, respectively. The SSS treatment (400 ㎍/mL) group showed a significant reduction by about 17% in tyrosinase production in B16/F10 cells. The SSS treatment group showed little change in DOPA staining. Conclusion: SSS extract may be useful for the treatment and prevention of inflammatory diseases and may have anti-wrinkle and whitening effects. These results may support the use of SSS in clinical practice.

디젤엔진의 후처리장치로서 PCD 플라즈마 시스템에 관한 연구 (A Study on the PCD Plasma System as an After Treatment Apparatus in Diesel Engine)

  • 유경현
    • 한국자동차공학회논문집
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    • 제20권2호
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    • pp.70-77
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    • 2012
  • The selective catalytic reduction(SCR) system used to reduce NOx in diesel engines requires an NO/$NO_2$ ratio of about 1 in exhaust emissions to realize the fast SCR mode at temperatures lower than $300^{\circ}C$. This study investigated the characteristics of a plasma system as a pre-active apparatus for the fast SCR reaction mode of an SCR system. Plasma was generated by the pulse corona discharge(PCD) method with a four-channel wire-cylinder reactor. This study showed that plasma was easily generated in the exhaust gas by the PCD system, and the peak voltage of the normal state condition for plasma generation was generally 12 kV. The PCD system easily converted NO into $NO_2$ at lower temperatures and the NO/$NO_2$ conversion ratio increased with the discharge current for plasma generation. But the PCD system could not convert NO into $NO_2$ at higher engine speeds and higher engine loads due to the lack of oxygen in exhaust gas. The PCD system also activated the diesel oxidation catalysts(DOC) system to reduce CO emissions.