• Title/Summary/Keyword: $NO_2$ reduction

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Pollutants Behavior in Oxy-CFBC by Application of In-Furnace deSOx/deNOx Method (순산소 순환유동층에서 로내 탈황 및 탈질법 적용에 따른 오염물질 거동특성)

  • Choi, Gyung-Goo;Na, Geon-Soo;Shin, Ji-Hoon;Keel, Sang-In;Lee, Jung-Kyu;Heo, Pil-Woo;Yun, Jin-Han
    • Clean Technology
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    • v.24 no.3
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    • pp.212-220
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    • 2018
  • Oxy-fuel combustion is considered as a promising greenhouse gas reduction technology in power plant. In this study, the behaviors of NO and $SO_2$ were investigated under the condition that in-furnace $deNO_x$ and $deSO_x$ methods are applied in oxy-fuel circulating fluidized bed combustion condition. In addition, the generation trends of $SO_3$, $NH_3$ and $N_2O$ were observed. For the purpose, limestone and urea solution were directly injected into the circulating fluidized bed combustor. The in-furnace $deSO_x$ method using limestone could reduce the $SO_2$ concentration in exhaust gas from ~403 to ~41 ppm. At the same experimental condition, the $SO_3$ concentration in exhaust gas was also reduced from ~3.9 to ~1.4 ppm. This trend is mainly due to the reduction of $SO_2$. The $SO_2$ is the main source of the formation of $SO_3$. The negative effect of $CaCO_3$ in limestone, however, was also appeared that it promotes the NO generation. The NO concentration in exhaust gas reduced to ~26 - 34 ppm by appling selective non-catalytic reduction method using urea solution. The $NH_3$ concentration in exhaust gas was appeared up to ~1.8 ppm during injection of urea solution. At the same time, the $N_2O$ generation also increased with increase of urea solution injection. It seems that the HNCO generated from pyrolysis of urea converted into $N_2O$ in combustion atmosphere. From the results in this study, the generation of other pollutants should be checked as the in-furnace $deNO_x$ and $deSO_x$ methods are applied.

Production of Tantalum Powder and Characteristics by Temperature (온도에 따른 탄탈 분말 제조와 특성)

  • Yun, Jae-Sik;Park, Hyeong-Ho;Bae, In-Seong;Lee, Sang-Baek;Kim, Byeong-Il
    • Korean Journal of Materials Research
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    • v.11 no.12
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    • pp.1052-1056
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    • 2001
  • Pure tantalum powder has been produced by sodium as a reluctant, $K_2TaF_7$as a feed material and KCl/KF as a diluent in an inconel stainless steel bomb by the metallothermic reduction. The influence of experimental variable, such as temperature of reduction on the yield and characteristics of the Ta powder has been studied. As the temperature of the reduction was varied from$ 800{\circ}C~980{\circ}C$, the yield of tantalum powder increased from 41% to 56%. However no appreciable improvement was observed above$920{\circ}C$. The fraction of fine Ta Powder decreased appreciably with the increase of temperature, and particle size was$2~3{\mu}m$at reduction temperature of$920{\circ}C$.Therefore a reduction temperature of$920{\circ}C$was optimally fixed for subsequent runs.

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Numerical Study of the Effects of Hydrocarbon Addition and Corresponding Chemical Kinetics on the Promotion of NO Oxidation in Nonthermal Plasma DeNOx Treatment (비열 플라즈마에 의한 NO의 산화에서의 탄화수소 첨가 효과와 그 반응역학에 대한 수치적 연구)

  • Shin, Hyun-Ho;Yoon, Woong-Sup
    • Journal of the Korean Society of Combustion
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    • v.5 no.2
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    • pp.37-50
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    • 2000
  • In the present study, a systematic chemical kinetic calculations were made to investigate the augmentation of $NO-NO_2$ conversion due to the addition of various hydrocarbons (methane, ethylene, ethane, propylene, propane) in the nonthermal plasma treatment. It is included in the present conclusion that the reaction between hydrocarbon and oxygen radicals induced by electron collision, is believed to be a primarily process for triggering the overall NO oxidation and the eventual NOx reduction. Upon the completion of the initiating step, various radicals (OH, $HO_2$ etc.) successively are produced by hydrocarbon decomposition form the primary path of $NO-NO_2$ conversion. When the initiating step is not activated, hydrocarbon consumption rate appeared to be very low, thereby the targeted level of NO conversion can only be achieved by the addition of more input energy. Present study showed ethylene and propylene to have higher affinity with O radical under all conditions, thereby both of these hydrocarbons show very fast and efficient $NO-NO_2$ oxidation. It was also shown that propylene is superior to ethylene in the aspect of NOx removal.

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The Effect of Promoter on the SO2-resistance of Fe/zeolite Catalysts for Selective Catalytic Reduction of NO with Ammonia (NO의 암모니아 선택적 촉매환원반응을 위한 철 제올라이트 촉매의 내황성에 미치는 조촉매 효과)

  • Ha, Ho-Jung;Choi, Joon-Hwan;Han, Jong-Dae
    • Clean Technology
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    • v.21 no.3
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    • pp.153-163
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    • 2015
  • The effects of H2O and residue SO2 in flue gases on the activity of the Fe/zeolite catalysts for low-temperature NH3-SCR of NO were investigated. And the addition effect of Mn, Zr and Ce to Fe/zeolite for low-temperature NH3-SCR of NO in the presence of H2O and SO2 was investigated. Fe/zeolite catalysts were prepared by liquid ion exchange and promoted Fe/zeolite catatysts were prepared by liquid ion exchange and doping of Mn, Zr and Ce by incipient wetness impregnation. Zeolite NH4-BEA and NH4-ZSM-5 were used to adapt the SCR technology for mobile diesel engines. The catalysts were characterized by BET, X-ray diffraction (XRD), SEM/EDS, TEM/EDS. The NO conversion at 200 ℃ over Fe/BEA decreased from 77% to 47% owing to the presence of 5% H2O and 100 ppm SO2 in the flue gas. The Mn promoted MnFe/BEA catalyst exhibited NO conversion higher than 53% at 200 ℃ and superior to that of Fe/BEA in the presence of H2O and SO2. The addition of Mn increased the Fe dispersion and prevented Fe aggregation. The promoting effect of Mn was higher than Zr and Ce. Fe/BEA catalyst exhibited good activity in comparison with Fe/ZSM-5 catalyst at low temperature below 250 ℃.

A Problem on the Election of Remedies for the Aggrieved Party under the CISG (CISG에서의 피해당사자(被害當事者)의 구제방안(救濟方案) 선택문제(選擇問題) - 대금감액(代金減額)과 손해배상제도(損害賠償制度)를 중심(中心)으로 -)

  • Choi, Myung-Kook
    • THE INTERNATIONAL COMMERCE & LAW REVIEW
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    • v.12
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    • pp.201-225
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    • 1999
  • This article is focused on the review of price reduction and measuring damages under the CISG together with the law relating to sale of goods in main countries when the goods delivered did not conform with the contract. And also reviewed on the election of remedies for the aggrieved party, that is, which one between the two remedies would provide more compensation for the non-conformity. This article can be summarized as below. 1. Price reduction has its principal significance when the buyer accepts non-conforming goods and plays important role only when the seller is not liable for the non-conformity because the same price reduction formula applies for all circumstances. Of course, the buyer must bear any further damages, such as shutdown expenses and other consequential damages. 2. If the seller is liable for the damages and the price level rises, the buyer normally will claim damages since this approach is much more favorable result than price reduction. 3. In case the seller is liable for the damages and the buyer suffers no consequential damages, if the price level falls, price reduction would provide more compensation for the non-conformity than would damages and if there is no change in the market level, the allowance for defects in the goods will be normally the same under the price reduction and damages. By the way, In case the seller is liable for the damages and the buyer suffers consequential damages, it is desired that the buyer firstly elect the price reduction and later seeks to claim for consequential losses when the price level falls and unchanged.

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Arthroscopic-assisted Reduction and Percutaneous Screw Fixation for Glenoid Fracture with Scapular Extension

  • Kim, Se Jin;Lee, Sung Hyun;Jung, Dae Woong;Kim, Jeong Woo
    • Clinics in Shoulder and Elbow
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    • v.20 no.3
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    • pp.147-152
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    • 2017
  • Background: To evaluate the clinical and functional outcomes of arthroscopic-assisted reduction and percutaneous screw fixation for glenoid fractures with scapular extension, and investigate the radiologic and clinical benefits from the results. Methods: We evaluated patients treated with arthroscopic-assisted reduction and percutaneous screw fixation for glenoid fractures with scapular extension from November 2008 to September 2015. Fractures with displacement exceeding one-fourth of the anterior-articular surface or more than one-third of the posterior-articular surface in radiographic images were treated by surgery. Clinical assessment was conducted based on range of motion, Rowe score, and Constant score of injured arm and uninjured arm at last follow-up. Results: Fifteen patients with Ideberg classification grade III, IV, and V glenoid fracture who underwent arthroscopic-assisted reduction using percutaneous screw fixation were retrospectively enrolled. There were no differences in clinical outcomes at final follow-up compared to uninjured arm. Bone union was seen in all cases within five months, and the average time to bone union was 15.2 weeks. Ankylosis in one case was observed as a postoperative complication, but the symptoms improved in response to physical therapy for six months. There was no failure of fixation and neurovascular complication. Conclusions: We identified acceptable results upon radiological and clinical assessment for the arthroscopic-assisted reduction and percutaneous fixation. For this reason, we believe the method is favorable for the treatment of Ideberg type III, IV, and V glenoid fractures. Restoration of the articular surface is considered to be more important than reduction of fractures reduction of the scapula body.

Breast Reduction through an Inframammary Incision (유방밑주름절개식 유방축소수술)

  • Hong, Yoon-Gi;Sim, Hyung-Bo
    • Archives of Plastic Surgery
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    • v.37 no.2
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    • pp.169-174
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    • 2010
  • Purpose: Reduction mammaplasty is a procedure with a relatively high patient satisfaction rate, however, associated scarring around the areola can be a serious problem. This study proposes a new modification of the breast reduction procedure by means of an inframammary incision alone. Methods: The breast is marked out preoperatively with standing position. Under the general anesthesia, an inframammary incision of approximately 7 - 8 cm is done. The subcutaneous plane is made in the lower pole of the breast, then the subglandular plane is entered and a sharp dissection is made up to 2 cm below the areola. The breast is mobilized from the chest wall and a cone-shaped parenchyme is removed in en-block except from the retroareolar central part. The remaining both pillars are gathered together with absorbable sutures and the base of the gland is narrowed to project the breast forward. The wound is closed in a layered fashion and taping of the breast mound is applied to redistribute the breast skin. Results: 21 patients (36 breasts) underwent this procedure from December 2004 to December 2009. Average follow up was 9 months (ranged from 6 months to 12 months). No major complication occurred. Most patients were pleased with the breast size, shape, and scars. However, 2 patients complained their hypertrophic scars which were corrected by revision. Conclusion: This technique is a simple approach to mild to moderate breast reduction through an inframammary incision alone. And, this technique provides an option with minimal complications and invisible scarring, which is especially important in the young patient group.

Major SNP Marker Identification with MDR and CART Application

  • Lee, Jea-Young;Choi, Yu-Mi
    • Communications for Statistical Applications and Methods
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    • v.15 no.2
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    • pp.265-271
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    • 2008
  • It is commonly believed that diseases of human or economic traits of livestock are caused not by single genes acting alone, but multiple genes interacting with one another. This issue is difficult due to the limitations of parametric-statistic methods of gene effects. So we introduce multifactor-dimensionality reduction(MDR) as a methods for reducing the dimensionality of multilocus information. The MDR method is nonparametric (i. e., no hypothesis about the value of a statistical parameter is made), model free (i. e., it assumes no particular inheritance model) and is directly applicable to case-control studies. Application of the MDR method revealed the best model with an interaction effect between the SNPs, SNP1 and SNP3, while only one main effect of SNP1 was statistically significant for LMA (p < 0.01) under a general linear mixed model.

A Study on the Mandibular Condylar Movement and the Temporomandibular Joint Sound Effected by the Stabilization Occlusal Splint (교합안전장치가 하악과두운동 및 악관절 잡음에 미치는 영향에 관한 연구)

  • Ku, Cheol-Ihn;Chung, Chae-Heon
    • The Journal of Korean Academy of Prosthodontics
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    • v.27 no.2
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    • pp.173-187
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    • 1989
  • The purpose of this study was to evaluate the effects of stabilization occlusal splint by using a simplified condylar path recorder and a dental sound checker. For this study, 11 subjects (10 men and 1 woman) with TMJ disorder were selected from students at Chosun University, School of Dentistry. And they were treated with the stabilization occlusal splint. The condylar movement and the TMJ sound of each subject were recorded and analyzed by using a simplified condylar path recorder and a dental sound checker. The obtained results were as follows: 1. No statistically significant reduction of reduced PRI scores occurred before and immediately after wearing of stabilization occlusal splint. 2. The reduced PRI scores after wearing of stabilization occlusal splint showed statistically significant reduction with the lapse of time. 3. After stabilization occlusal splint therapy, Fisher angle and Bennett angle had almost no change. 4. TMJ sound disappeared in 4 out of 11 subjects.

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Study on the Establishment of Reduction Goals for Air Pollutants Emissions from Diesel Locomotives in Korea by Comparison with Emission Regulation in United States (미국 디젤기관차의 매연 배출기준과 비교한 국내 디젤기관차의 매연 배출 저감목표 설정 연구)

  • Park, Duck-Shin;Kwon, Soon-Bark;Lim, In-Gwon;Cho, Young-Min
    • Proceedings of the KSR Conference
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    • 2006.11b
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    • pp.152-157
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    • 2006
  • The air pollutant emission from the railroad diesel locomotive is still a significant environmental concern in many countries including Korea and Unites States. The emission characteristics of the railroad diesel locomotive were extensively studied in this study. Particulate matter (PM) and nitrogen oxides ($NO_x$) emitted from a large locomotive engine (2-cycle, 16-cylinder, and 3,000-horsepower) under various engine-rating conditions was analyzed with a scanning mobility particle sizer and a gas stack sampler by using a dilution tunnel. We could gain the emission values of 2.1 g/horsepower-hour for PM and 42.7 g/horsepower-hour for $NO_x$. We proposed the emission reduction goal of the railroad diesel locomotive for Korea in comparison with the regulation of United States.

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