• Archives of Craniofacial Surgery
• /
• v.22 no.2
• /
• pp.93-98
• /
• 2021

Background: Pediatric nasal fractures, unlike adult nasal fractures, are treated surgically as early as 7 days after the initial trauma. However, in some cases, a week or more elapses before surgery, and few studies have investigated the consequences of delayed surgery for pediatric nasal fractures. The purpose of this study was to evaluate the postoperative outcomes of pediatric nasal fractures according to the time interval between the initial trauma and surgery. Methods: The records of pediatric patients under 12 years old who underwent closed reduction of nasal bone fracture from March 2012 to February 2020 were reviewed. The interval between trauma and surgery was divided into within 7 days (early reduction) and more than 7 days (delayed reduction). Postoperative results were classified into five grades (excellent, good, moderate, poor, and very poor) based on the degree of reduction shown on computed tomography. Results: Ninety-eight patients were analyzed, of whom 51 underwent early reduction and 47 underwent delayed reduction. Forty-two (82.4%) of the 51 patients in the early reduction group showed excellent results, and nine (17.6%) showed good results. Thirty-nine (83.0%) of the 47 patients in the delayed reduction group showed excellent results and eight (17.0%) showed good results. No statistically significant difference in outcomes was found between the two groups (chi-square test p= 0.937). However, patients without septal injury were significantly more likely to have excellent postoperative outcomes (chi-square test p< 0.01). Conclusion: No statistically significant difference was found in the outcomes of pediatric nasal fractures between the early and delayed reduction groups. Successful surgical results were found even in patients who received delayed reduction (more than 7 days after trauma).

• Journal of the Korean Society of Combustion
• /
• v.10 no.2
• /
• pp.18-25
• /
• 2005

An experimental study has been conducted to evaluate the effects of reburning on $NO_x$ reduction and also to examine heat transfer characteristics from LPG flame. Experiments were performed in flames stabilized by a co-flow swirl burner, which was mounted at the bottom of the furnace. Tests were conducted using LPG gas as main fuel and also as reburn fuel. The effects of reburn fuel fraction and injecting location of reburn fuel are studied. The paper reports data on flue gas emissions, temperature distribution in furnace and various heat fluxes at the wall for a wide range of experimental conditions. In a steady state, the total as well as radiative heat flux from the flame to the wall of furnace has been measured using a heat flux meter. Temperature distribution and emission formation in furnace have been also measured and compared.

• Korean Chemical Engineering Research
• /
• v.52 no.4
• /
• pp.443-450
• /
• 2014

Selective catalytic reduction of nitrogen monoxide by hydrogen ($H_2$-SCR of NO) over platinum catalysts impregnated on zirconia-incorporated silica ($ZrO_2-SiO_2$) and manganese oxide ($MnO_x$) was investigated. $Pt-MnO_x$ catalyst showed low conversions and low yields of $N_2O$ and $NO_2$ at $100{\sim}350^{\circ}C$. On the other hand, NO conversions over $Pt/ZrO_2-SiO_2$ were very high, but $N_2O$ was predominantly produced at $100-150^{\circ}C$ and the yield of $NO_2$ increased with temperature at $200-300^{\circ}C$, resulting in poor $N_2$ yields. $Pt-MnO_x/ZrO_2-SiO_2$ exhibited a small enhancement in $N_2$ yield at $100-150^{\circ}C$ due to the synergy of $MnO_x$ and $ZrO_2-SiO_2$. The surface composition and oxidation state of the catalyst components and the acidity of the catalysts were examined. IR spectra of the adsorption of NO and their subsequent reactions with hydrogen on these catalysts were also recorded. The variations of conversion and product yield according to the catalyst components in the $H_2$-SCR of NO were discussed in relation to their catalytic roles.

• Journal of Korean Academy of Oral and Maxillofacial Radiology
• /
• v.24 no.2
• /
• pp.337-345
• /
• 1994

Arthrography of the temporomandibular joint is a useful method of demonstrating the soft tissue abnormalities related to disc dysfunction. In this study, 19 asymptomatic joints, 31 joints with anterior disc displacement with reduction, 31 joints with anterior disc displacement without reduction which were classified by arthrotomography under fluoroscopy were evaluated to determine the linear measurement of anterior recess of inferior joint space and the relationship between the condylar anterior translation and the severity of the internal derangements. Their fluoroscopic images were also evaluated to describe the characteristics of condylar paths in internal derangements of the temporomandibular joints. The results were as follows; 1. The mean lengths of the anterior recess in asymptomaic group. reduction group. and non-reduction group were 8.7±1.6㎜. 11.2±1.7㎜, 12.8±1.7㎜ respectively. The length of the anterior recess was increased according to the severity of the internal derangements(P<0.05). 2. Linear measurements of anterior movement of condyle on maximum mouth opening were 13.1 ±4.2㎜, 15.9±4.1㎜, 5.0±3.7㎜ in asymptomatic group. reduction group, and non-reduction group respectively. Compared with asymptomatic group, reduction group showed hypermobolity of the condyle and non-reduction group showed hypomobility. 3. Condyles moved beyond the crest of articular eminence in 80% of reduction group and did not reach it in 70% of non-reduction group. 4. The condyle moved mainly superiorly in reduction group(66%) and horizontally in asymptomatic group(47%). There were no cases to move superiorly in non-reduction group.

• Journal of the Korean Applied Science and Technology
• /
• v.17 no.1
• /
• pp.1-5
• /
• 2000

The selective catalytic reduction(SCR) of nitric oxide by ethane in the presence of oxygen was investigated on Cu-ZSM-5, Co-ZSM-5 and Ga-ZSM-5 catalysts over a range of 400, 450 and $500^{\circ}C$. The catalysts were prepared by ion-exchange method. The composition of the reactant gases were 1000 ppm of NO, 1000 ppm of $C_{2}H_{6}$ and 2.5% of $O_{2}$, and the reaction was conducted in a fixed-bed reactor at 1 atm. For the 20wt% Co-ZSM-5(50) catalyst, the NO conversion reached up to 100%, while the $C_2H_6$ conversion and the CO selectivity were about 50% and 25%, respectively, at $450^{\circ}C$. For the 20wt% Cu-ZSM-5(50) catalyst, the NO conversion and the C2H6 conversion were about 80% and 100%, respectively, but there was no CO produced. The metal ion-exchanged ZSM-5 catalysts exhibited a tendency to increase the NO conversion with the Si/Al ratio of the ZSM-5, that is, NO conversion was inversely proportional to the acidity of the catalysts. But, the effect of the acidity on NO conversion was not so large. From the XRD results of the catalysts before and after SCR reaction it was found that there was no structural change.

• Clean Technology
• /
• v.22 no.3
• /
• pp.141-153
• /
• 2016

Numerous stationary NO_x emission sources have employed a suitable deNO_x technology that is typically selective catalytic reduction (SCR) of NO_x by NH₃ over V₂O₅/TiO₂-based catalysts with on-demand monolithic structures. These structured catalysts undergo a time-on-deterioration of deNO_xing activity on site. Thus, we need more efficient, more deactivation-tolerant, more economic deNO_x systems and for which, their performance management is essential. This review has covered details of strategies to successfully manage the performance of SCR catalysts and timely replace them to new or rejuvenated ones. Key considerations to maintain the catalyst activity will be reviewed. Details of the sequential addition of new catalysts and the replacement of life-end catalysts and their regeneration will be discussed with general guidances to determine the time for such a replacement. Finally, a better way to get more economic approaches to deNO_x system management will be proposed here.

• Korean Chemical Engineering Research
• /
• v.46 no.5
• /
• pp.868-874
• /
• 2008

The Ni based adsorbent was prepared by co-precipitation method and its performance for removing carbon monoxide was investigated. Here, silica, aluminium silicate and ${\gamma}$-alumina were used for carriers of catalyst. $Ni(NO_3)_2{\cdot}6H_2O$ and $Ni(CH_3COO)_2{\cdot}4H_2O$ were utilized for Ni precursors. Precipitants were urea and citric acid. After precipitation of Ni salt on the carrier and following reduction using $H_2$ gas, adsorbent was prepared and its performance was analyzed based on EDS, TPR and XRD experiments. In accordance with change of precipitation agents, Ni salts on carrier, carriers and reduction condition. Adsorbent performance for removing carbon monoxide was investigated. The adsorbent with 54.8 wt% Ni prepared using urea precipitant under reduction condition at $500^{\circ}C$ for 3 h exhibited the best CO removal performance.

• Journal of the Korean Chemical Society
• /
• v.33 no.2
• /
• pp.225-231
• /
• 1989

The heterogeneous rate constants for the electrochemical reduction by $trans-[Co(en)_2X_2](ClO_4)_n$(where X is cyanide, nitrite, ammonia, and isothiocyanate) at mercury and glassy carbon electrode were investigated by cyclic voltammetry, DC polarography, and by using rotating disk electrode. The good linear relationship was obtained between the activation energy of reduction and absorption wave number of complexes on glassy carbon electrode. At mercury electrode, $NO_2^-$ ligated complex showed the large deviation from the linear relationship. The difference in the value of rate constants for $NO_2^-$ ligated complex between mercury and glassy carbon electrode was about three order of magnitude which was much larger than the other complexes. It was suggested that $NO_^-$ ligated complex was reduced by inner-sphere mechanism on mercury electrode from the larger value of activation energy and entropy on mercury than carbon electrode.

• Journal of Korean Society of Environmental Engineers
• /
• v.35 no.9
• /
• pp.675-680
• /
• 2013

This research was done to evaluate the potential for destruction of perchlorate in municipal sewage. Laboratory experiments were conducted in flasks containing 3 liters of raw sewage. Sewage was mixed with defined amount of perchlorate and various additives. Perchlorate reduction in sewage did occur, but was quite variable, ranging from 0 to 72% over 72 hour. Addition of even a small amount of perchlorate acclimated biomass (167 mg/L SS) significantly reduced the lag and resulted in complete perchlorate removal. Perchlorate reduction in sewage-brine mixtures was inhibited when the dissolved oxygen level was greater than 2 mg/L, and when the mixture salinity was relatively high (conductivity = 14 mS with equivalent TDS = 8 g/L). When nitrate ($NO_3{^-}$) was present with perchlorate in the laboratory flask tests of sewage-brine mixtures, nitrate reduction proceeded first. A significant amount of nitrite ($NO_2{^-}$) accumulated in the sewage-brine mixtures, accounting for about 66% of initial nitrate nitrogen ($NO_3$-N).

• Bulletin of the Korean Chemical Society
• /
• v.15 no.4
• /
• pp.321-323
• /
• 1994