• Title/Summary/Keyword: $NO_2$ gas

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Calculation of thermodynamical equilibrium composition of combustion gases (燃燒氣體의 熱力學的 平衡組成計算에 관한 硏究)

  • 허병기;이청종
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.11 no.1
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    • pp.177-188
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    • 1987
  • A compute program based on the minimization of total Gibbs' free energy and enthalpy balance was developed to calculate the chemical equilibrium composition and adiabatic flame temperature, especially stressed on NO and CO concentration of Heavy oil. Twenty four components of combustion gases which would be produced from the combustion of Heavy oil were chosen and utilized for the products composition analysis of competing combustion reaction. As the results, following conclusions were turned out; (1) Maximum adiabatic flame temperature was found around to be 2900K, when the stoichiometric air ratio was 0.8. (2) Maximum NO quantity in adiabatic process was occurred when supplied air quantity was around 120% of theoretical air requirement. (3) NO and CO quantities were increased with combustion gas temperature at constant stoichiometric air ratio. (4) At constant temperature of combustion gas, NO quantity was increased and Co quantity was decreased with supplied air quantity.

Effects of Gamma-Irradiated Korean Ginseng on Fertility and General Reproductive Toxicity in Rats (방사선 조사 인삼이 랫드의 수태능 및 일반 생식독성에 미치는 영향에 관한 연구)

  • 박귀례;한순영;김판기;이유미;신재호;장성재
    • Toxicological Research
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    • v.17 no.2
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    • pp.97-106
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    • 2001
  • Korean ginseng products have been fumigated with ethylene oxide (EO) for sterilization and prolongation of storage periods. However, there had been controversies indicating that the consumption of food treated with EO might cause harmful effects in human. Since, in Korea the use of EO gas for food treatment was banned in 1991. Since then, irradiation technique has been developed as an alternative. This study was carried out to investigate the effects of irradiated ginseng on fertility, and reproductive and developmental toxicity. Either EO gas fumigated or gamma-irradiated ginseng was administered to male rats by oral gavage for 63 days during the premating period. Female rats were administered from 14 days before mating to day 20 of gestation or to day 21 of lactation. The exposure amount of irradiation used was 5, 10 and 30 kGy, respectively. There were no treatment related changes of darns in clinical signs, and parturition. No treatment related changes in food consumption, body/organ weights, male/female reproductive and fertility performances were observed. F1 fetuses showed no external abnormality. Reflex/sensory junctions, physical/behavioral development, and reproductive performance of F1 rats were not adversary affected. The results of this study show that gamma-irradiated ginseng, up to 30 kGy, has no adverse effects on the fertility, reproduction and development in Wistar rats.

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A Study on the Double Dielectric Barrier Discharge for $NO_x$ reduction (이중 베리어 방전 반응기를 사용한 $NO_x$ 제거에 관한 연구)

  • Kim, Dong-Ook;Kim, Eung-Bok;Chung, Young-Sik
    • Proceedings of the KIEE Conference
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    • 1999.07e
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    • pp.2182-2185
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    • 1999
  • In this experimental study we propose the double dielectric barrier discharge(DDBD) reactor to produce as high an electric field as possible. DDBD reactor is designed to remove $NO_x$ at atmospheric pressures from the moving pollution source such as diesel automobile DDBD reactor consisted of two cylinder glass tubes arranged so that the gas flow was directed between the two tubes. Inside of the inner tube was filled with small metal beads and outside of the inner tube was wounded with stainless wire to form the electrode. The outer tube was surrounded by an aluminum foil In this reactor there are three electrodes, i.e. metal bead(C), helical wire(I) and aluminum foil(0). By using DDBD reactor we will report some interesting results of treatment of the gas which is the dilute mixtures of NO in N2. And then we compared thee results with the results of cylinder-wire(CW) which is one of popularly used reactor in non-thermal plasma applications.

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Effects of Input Gases on the Growth Characteristics of Vertically Aligned Carbon Nanotubes in Plasma Enhanced Hot Filament Chemical Vapor Deposition

  • Han, Jae-Hee;Yang, Ji-Hun;Yang, Won-Suk;Yang, Cheol-Woong;Yoo, Ji-Beom;Park, Chong-Yun
    • Journal of Korean Vacuum Science & Technology
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    • v.4 no.2
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    • pp.55-60
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    • 2000
  • Vertically aligned carbon nanotubes on nickel coated glass substrates were obtained at low temperatures below 600$\^{C}$ by plasma enhanced hot filament chemical vapor deposition where acetylene gas was used as the carbon source and ammonia gas was used as the dilution gas and catalyst. The diameters of the nanotubes decreased from 96 m to 41 m as NH$_3$/C$_2$H$_2$ ratio increased from 2:1 to 5:1. Total flow rate of input gases with constant NH$_3$/C$_2$H$_2$ ratio did not change the diameter of carbon nanotubes. No growth of the carbon nanotubes was observed with only C$_2$H$_2$ nor N$_2$ instead of NH$_2$. G line and D line in Raman spectra were observed, which implies that there were many structural defects in carbon nanotubes.

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Conversion Characteristics of MSW at Various Pyrolytic and Oxidative Conditions (열분해 및 산화조건에서 MSW의 물질전환특성 연구)

  • Byen, Kyong-Hee;Lee, Yong-Jin;Yoon, Kyoon-Duk;Dong, Jong-In
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.11
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    • pp.1955-1968
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    • 2000
  • Thermal gravimetric change characteristics and gas phase product - CO, NO, $NO_2$, VOCs - generated in the process of pyrolysis and oxidation. were investigated with variation of process parameters including furnace reactor temperature both in pyrolytic and oxidative conditions. For the thermal gravimetric change characteristics. paper and wood were mainly decomposed at lower temperatures and they had similar thermal gravimetric change trend due to their similar compositions; plastics were mainly decomposed at higher temperatures; in the case of textile. natural compounds were decomposed at lower temperatures and synthetic compounds at relatively higher temperatures; food was decomposed in the wide range of temperatures possibly due to their different kinds of components. For the analysis results of gas phase product. the concentrations of NO, $NO_2$ were detected at higher level at the oxidative conditions than at the pyrolytic conditions except that of CO, which is due to complete combustion with sufficient oxygen at the oxidative condition; food gave off CO, NO, $NO_2$ more than the other wastes. VOCs were emitted more at the pyrolytic conditions than at the oxidative conditions.

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An Establishment of Greenhouse Gas Information System using Excel Spreadsheets (엑셀 스프레드시트를 활용한 온실가스 정보시스템 구축)

  • Lee, Hae-Jung;Chung, Young-Bae
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.40 no.4
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    • pp.129-136
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    • 2017
  • Climate change is the biggest environmental issue of our times. A variety of activities to reduce greenhouse gas emissions have been in progress to observe the Kyoto Protocol. Especially, the Energy Target Scheme is created to reduce greenhouse emission with the supervision of Korean government. This includes Green-house Gas Information Systems to promote activities in the private sector to reduce green-house gas emissions, to cut a cost of energy use, and to reduce GHG emissions. Also, the system has calculated the amount of greenhouse gases. Without any additional investment, 2.75% savings are increased over the previous year. In service sector, a cooperation of customers and employees is necessary. A reduction of GHG emissions requires a proper service organization, considering an amount of investment and payback period. Without any additional investment or replacement, employees can save energy easily turning off ventilation systems an hour before employees' departure, installing timers to turn off water purifiers and vending machines after some period of no use. The Green-house Gas Information System is similar to that of Environmental Management System. However, the Excel is the best program to calculate an amount of green-house gas emissions, and to assess for a reduced amount of GHG emissions. A goal of this research is to propose a practical method in the private sector to calculate an amount of green-house gases. The Green-house gas Information System based on Excel spreadsheet gives standards for good evaluation. The greenhouse gas information system establishes and executes the policies and objectives related to greenhouse gas emissions Similar to ISO 14001 environment management system structures, the advantages of using simplified Excel Sheet for calculating GHG emissions and reducing GHG emissions are easy to access.

Application of a Gas Chromatography/Luminol Detection System for Peroxyacetyl Nitrate Airborne Measurement

  • Khang, Bumju;Ahn, Joon Young;Song, Dasol;Lee, Gangwoong
    • Asian Journal of Atmospheric Environment
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    • v.7 no.2
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    • pp.105-113
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    • 2013
  • We constructed and tested an airborne peroxyacetyl nitrate (PAN) monitoring system based on luminol chemiluminescence detection with fast gas chromatography. This system allowed for simultaneous measurement of PAN and nitrogen dioxide ($NO_2$) with a time resolution of <2 min. Actual sample masses within the fixed volume sample loop at various altitudes and temperatures were adjusted to standard atmosphere, using measured pressures and temperatures. The airborne PAN measurement system was evaluated during two field studies above the southern Korean Peninsula in August and October 2009. The detection limit based on the ISO approach was 0.035 ppbv PAN, well below the observed concentrations of 0.185-1.49 ppbv during these studies. Under these conditions, the PAN mixing ratios were positively correlated with $O_x$ ($O_x=O_3+NO_2$), with slopes varying between 0.014 and 0.033 and intercepts between 22.6 and 55.1 ppbv $O_x$. The intercepts corresponded roughly to background $O_x$ mixing ratios in central Europe; however, the slopes were above the range of slopes reported in other studies. We also enhanced the durability, safety, and ease of maintenance of the PAN monitoring system by redesigning the structure of the conventional luminol cell.