• Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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• v.3 no.2
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• pp.121-129
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• 1999

Photosynthesis and transpiration rates were simultaneously measured in attached sunflower leaves(Helianthus annuusL. cv. Russian Mammoth) during exposure to $NO_2$ and $O_3$ to determine the effect of mixed gan on photosynthesis and the stomatal aperture. The application of $O_3$ alone reduced both the net photosynthetic and transpiration rates. An analysis of the $CO_2$ diffusive resistances indicated that the main cause affecting photosynthesis reduction during $O_3$ exposure was not the internal gas phase of the leaf $(rCO_2^{liq})$ but rather the liquid phase or mesophyll diffusive resistance $(rCO_2^{liq})$, suggesting that there is a very concomitant relation between photosynthetic reduction and $rCO_2^{liq}$. The application of NO2 alone caused a marked reduction of the net photosynthesis yet no significant reduction of transpiration, indicating that NO2 affects the $CO_2$ fixation processes with no inluence on the stomatal aperture. A greter reduction in the photosynthesis of sunflower plants was caused by the application of $NO_2$ alone as compared to a combination of $NO_2$ and $O_3$. $NO_2$ alone reduced the photosynthetic rate by 90%, whereas a mixture of NO2 and O3 reduced it by 50%.

• Journal of the Korean Ceramic Society
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• v.34 no.4
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• pp.387-393
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• 1997

In order to apply WO3 thin films to the semiconducting NOx gas sensors as a sensing material, which have been expected to show good electrical properties, such as large sensitivity, rapid responsibility, and high selectivity, the fabrication method and their sensing characteristics were studied. The variations of surface morphologies, crystallographic orientations and crystallinity with the WO3 thin film growing methods thermal evaporation and DC sputtering methods were investigated by using scanning electron microscopy (SEM) and X-ray diffraction(XRD) analysis. As a result of sensitivity (Rgas/Rair) measurements for the 5 ppm NO2 test gas, the sensitivity values were 113 for the sputtered films and 93 for the evaporated films. It was also observed that the recovery rate of a sensing signal after measuring sensitivity was faster in the sputtered films than in the evaporated films.

• Journal of the Korean Ceramic Society
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• v.32 no.12
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• pp.1369-1376
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• 1995

The WO3 thin-film NOx sensor which is of practical use and includes the heater and the temperature sensor was fabricated. The WO3 thin films as a gas-sensing layer was deposited at ambient temperature in a high-vacuum resistance heated evaporator. The highest sensitivity of the WO3 thin-film sensor to NOx was obtained under the condition of the annealing temperature of 50$0^{\circ}C$ and the operating temperature of 30$0^{\circ}C$. The gas sensing characteristics of this sensor was excellent, i.e. high sensitivity (Rgas/Rair in 3 ppm NO2=53) and fast response time (4 seconds).

• Proceedings of the KAIS Fall Conference
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• 2006.05a
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• pp.223-226
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• 2006

The micro-gas sensor based on carbon nanotubes (CNTs) was fabricated and its gas sensing characteristics on nitrogen dioxide ($NO_2$) have been investigated. The sensor consists of a heater, an insulating layer, a pair of contact electrodes, and CNT-sensing film on a micromachined diaphragm. The heater plays a role in the temperature change to modify sensor operation. Gas sensor responses of CNT-film to $NO_2$ at room temperature are reported. The sensor exhibits a reversible response with a time constant of a few minutes at thermal treatment temperature of $130^{\circ}C$.

• Korean Journal of Materials Research
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• v.28 no.1
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• pp.12-17
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• 2018

$In_2O_3$ doped $WO_3$ powders were prepared by a polymer solution route and their $NO_2$ gas sensing properties were analyzed. The synthesized powders showed nano-sized particles with specific surface areas of $6.01{\sim}21.5m^2/g$ and the particle size and shape changed according to the content of $In_2O_3$. The gas sensors fabricated with the synthesized powders were tested at operating temperatures of $400{\sim}500^{\circ}C$ and 100~500 ppm concentrations of $NO_2$ atmosphere. The particle size and $In_2O_3$ content affected on the initial sensor resistance in an air atmosphere. The highest sensitivity (8.57 at $500^{\circ}C$), which was 1.77 higher than the sensor consisting of the pure $WO_3$ sample, was measured in the 0.5 mol% $In_2O_3$ doping sample. In addition, the response time and recovery time were improved by the addition of $In_2O_3$.

• Journal of Sensor Science and Technology
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• v.29 no.6
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• pp.382-387
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• 2020

Hydrogen (H₂) is considered as a new clean energy resource for replacing petroleum because it produces only H₂O after the combustion process. However, owing to its explosive nature, it is extremely important to detect H₂ gas in the ambient atmosphere. This has triggered the development of H₂ gas sensors. 2-dimensional (2D) graphene has emerged as one of the most promising candidates for chemical sensors in various industries. In particular, graphene exhibits outstanding potential in chemoresistive gas sensors for the detection of diverse harmful gases and the control of indoor air quality. Graphene-based chemoresistive gas sensors have attracted tremendous attention owing to their promising properties such as room temperature operation, effective gas adsorption, and high flexibility and transparency. Pristine graphene exhibits good sensitivity to NO₂ gas at room temperature and relatively low sensitivity to H₂ gas. Thus, research to control the selectivity of graphene gas sensors and improve the sensitivity to H₂ gas has been performed. Noble metal decoration and metal oxide decoration on the surface of graphene are the most favored approaches for effectively controlling the selectivity of graphene gas sensors. Herein, we introduce several strategies that enhance the sensitivity of graphene gas sensors to H₂ gas.

• Transactions of the Korean hydrogen and new energy society
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• v.27 no.3
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• pp.298-305
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• 2016

In this study, we treated pitch-based activated carbon fibers (ACFs) in hydrogen peroxide using electron beam (E-beam) irradiation to improve nitrogen monoxide (NO) sensing ability as an electrode material of gas sensor. The specific surface area of ACFs treated by E-beam irradiation with 400 kGy increased from $885m^2/g$ (pristine) to $1160m^2/g$ without any changes in structural property and functional group. The increase in specific surface area of the E-beam irradiated ACFs enhanced NO gas sensing properties such as response time and sensitivity. When the ACFs irradiated with 400 kGy, response time was remarkably reduced from 360 s to 210 s and sensitivity was increased by 4.5%, compared to the pristine ACFs. These results demonstrate convincingly that surface modification of ACFs using E-beam in hydrogen peroxide solution can enhance textural properties of ACFs and NO gas sensing ability of gas sensor at room temperature.

• Clean Technology
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• v.27 no.4
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• pp.367-371
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• 2021

The oxy-combustion system is one of the carbon recovery and storage technologies (CCS: Carbon capture & storage) that performs coal combustion using pure oxygen and recirculated flue gas. This is a technology that facilitates storage of carbon dioxide by generating an exhaust gas consisting of only carbon dioxide without a process of separating carbon dioxide and nitrogen when coal is burned using pure oxygen and recirculated flue gas mixture instead of a conventional air combustion system that produces carbon dioxide and nitrogen mixed exhaust gas. In this study, the characteristics of generated NO and SO₂ as atmospheric pollutants during oxy-combustion were examined using O₂/CO₂ mixed simulation gas. The reaction temperature was varied from 900 ℃ to 1200 ℃ and oxygen partial pressure was varied from 30% to 50%. The results showed that NO and SO₂ concentrations in flue gas increased as the oxygen concentration and the reaction temperature in the furnace increased. The partial pressure of CO₂ in flue gas also increased as the oxygen concentration and the reaction temperature in the furnace increased. As a results of comparing NO production of 30% O₂/CO₂ oxy-combustion with air combustion, NO in flue gas increased with reaction temperature in both experiments and NO of oxy-combustion was 40 ~ 80 ppm lower than that of air combustion.

• Journal of the Korean Institute of Telematics and Electronics T
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• v.36T no.1
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• pp.8-12
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• 1999

$\textrm{WO}_3$ semiconductive film, which is known to have a sensitivity on $\textrm{NO}_X$ gas was prepared on 8YSZ (8% Yttria stabilized $\textrm{ZrO}_2$) ionic conductor substrate that has oxygen ion pumping effect. Microstructure and electrical properity, especially $\textrm{NO}_X$ sensitivity as a function of DC voltage applied to 8YSZ substrate was examined. When the $\textrm{WO}_3$ film was annealed, it showed amorphous structure, while crystallization was occurred at $600^{\circ}$C revealing orthorhombic phase of $\textrm{WO}_3$. As the annealing temperature increases, (111) and (001) peaks of $\textrm{WO}_3$ film was enhanced. At $400^{\circ}C$ when DC voltage was applied, comparing with no DC bias, more stable and large response characteristics was showed, and the best sensitivity was observed at 2V. Recovery characteristics of NO gas was much better that that of $\textrm{NO}_2$ gas.

• Journal of Korean Society of Environmental Engineers
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• v.30 no.5
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• pp.552-559
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• 2008

Three dimensional numerical analysis were performed to investigate the combustion characteristics in a tangentially fired pulverized coal boiler. The predicted values at the outlet of economizer for the gas temperature, O$_2$, NO, CO were been compared with the measured data. By using the actual operating conditions of the power plant, the distribution of velocity, gas temperature, O$_2$, CO, CO$_2$ and NO as well as the particle tracking in the boiler were investigated. Throughout the present study, the non-uniform distribution of flue gas temperature in front of the final superheater might be resulted from the residual swirl flow in the upper furnace of the boiler. The present analysis on non-uniform distribution of the gas temperature could provide the useful information to prevent the frequent tube failure from happening in the final superheater of the tangentially coal-fired boiler.