Fabrication and Gas-Sensing Characteristics of $NO_x$ Sensors using $WO_3$ Thin Films

$WO_3$ 박막을 이용한 $NO_x$ 센서의 제조 및 가스감도 특성

  • 유광수 (서울시립대학교 공과대학 재료공학과) ;
  • 김태송 (한국과학기술원 세라믹스연구부) ;
  • 정형진 (한국과학기술원 세라믹스연구부)
  • Published : 1995.12.01

Abstract

The WO3 thin-film NOx sensor which is of practical use and includes the heater and the temperature sensor was fabricated. The WO3 thin films as a gas-sensing layer was deposited at ambient temperature in a high-vacuum resistance heated evaporator. The highest sensitivity of the WO3 thin-film sensor to NOx was obtained under the condition of the annealing temperature of 50$0^{\circ}C$ and the operating temperature of 30$0^{\circ}C$. The gas sensing characteristics of this sensor was excellent, i.e. high sensitivity (Rgas/Rair in 3 ppm NO2=53) and fast response time (4 seconds).

Keywords

References

  1. Compiled from Ceramic Abstracts Database Ceramic Sensors The American Ceramic Society, Inc.
  2. Report No.6:Ceramic Sensors Japanese R and D Trend Analysis, Advanced Materials KRI International Inc.
  3. Chemical Sensor Technology v.5 Semiconductor NOx Sensors for Exhaust Monitoring T. Takeuchi;K. Satake;M.Aizawa(ed.)
  4. Solid State Tech. v.32 no.12 Survey of Toxic Gas Sensors and Monitoring Systems N.O. Korolkoff
  5. Sensors and Actuators B v.23 Thin-Film Gas Sensors Based on Semiconducting Metal Oxides H. Meixner;J. Gerblinger;U. Lampe;M. Fleischer
  6. Jpn Chem. Sensors v.9 no.SUP.B New Type NOx Sensor Based on Capacitance Change T. Ishihara;S. Sato;Y. Takita
  7. Sensors and Actuators B v.26-27 Nitrogen Oxide Sensors Based on Thin Films of BaSnO₃ U. Lampe;J. Gerblinger;H. Meixner
  8. Sensors and Actuators B v.13-14 NO₂Gas-Sensing Properties of Ga-Doped ZnO Thin Film S. Matsushima;D. Ikeda;K. Kobayashi;G. Okada
  9. Sensors and Actuators B v.13-14 Development of High-Performance Solid-Electrolyte Sensors for NO and NO₂ N. Miura;S. Yao;Y. Shimizu;N. Yamazoe
  10. Sensors and Actuators B v.23 NOx Sensor Using YBa₂Cu₃$O_7-\delta$ Thin Films S. Kudo;H. Ohnishi;T. Matsumoto;M. Ippommatsu
  11. Sensors and Actuators B v.13-14 Characteristics of the Substiuted Metal Phthalocyanme NO₂ Sensor K. Moriya;H. Enomoto;Y. Nakamura
  12. Sensors and Actuators B v.5 Surface Chemistry of Gas Sensors H₂S on WO₃Films D.J. Dwyer
  13. Phys Review. B v.24-26 Defect States in WO₃Studied with Photoelectron Spectroscopy R.D. Bringans;H. Hoechst;R.H. Shanks
  14. Jpn. J. Appl. Phys. v.48 no.10 Semiconductor Gas Sensors M. Nitta;M. Haradome
  15. J. Solid State Chem. v.72 Investigations of the Bulk Defect Chemistry of Polycrystalline Tin (Ⅳ) Oxide J. Maier;W. Gopel
  16. Solid State Phys. v.3 Relations between the Concentrations of Imperfections in Crystalline Solids F.A. Kroger;HJ. Vink
  17. J. Chem. Soc. Faraday Trans. v.83 Tin Dioxide Gas Sesnors J.F. McAleer;P.T. Moseley;J.O.W. Norris;D.E. Williams
  18. Thin Films by Chemical Vapor Deposition C.E. Morosanu
  19. Denki Kagaku v.40 no.3 Gas Detection by Activated Semiconductor Sensor T. Seiyama
  20. Sensors and Actuators v.12 Gas-Sensing Characteristics of Semiconducting Materials Based on ln₂O₃ Depending on Composition Changes K.S. Yoo;H.J. Jung
  21. Porc. of the 2nd Int'l Meeting on Chemical Sensors Development of Tin Oxide Gas Sensor and Monitoring System T. Oyabu
  22. Sensors and Actuators B v.1 Prototype Structure for Systematic Investigations of Thin-Film Gas Sensors K.D. Schicrbaum;S. Vaihinger;W. Gopel
  23. Introduction to Ceramics(2nd ed.) W.D. Kingery;H.K. Bowen;D.R. Uhlmann
  24. Handbook of Chemistry and Physics(74th ed.) CRC Press, Inc.
  25. Technical Digest of the 5th Int'l Meeting on Chemical Sensors Metal Oxide Semiconductor NO₂Sensor T. Inoue;K. Ohtsuka;Y. Yoshida;Y. Matsuura;Y. Kajiyama
  26. Surface Science v.221 Adsorption Behavior of CO and Interfering Gases on SnO₂ J. Tamaki;M. Nagaishi;Y. Teraoka;N. Miura;N. Yamazoe;K. Moriya;Y. Nakamura
  27. Technical Digest of the 5th Int'l Meeting on Chemical Sensors The Interaction of Different Oxidizing Agents on Doped Tin Oxide I. Sayago;J. Gutierrez;L. Ares;J.I. Robla;M.C. Horrillo;J. Getino;J.A. Agapito
  28. Jpn. Chem. Sensors v.9 no.SUP.B Tungsten Oxide-Based Semiconductor Sensor for Detection of Nitrogen Oxides in Combustion Exhaust M. Akiyama;Z. Zhang;J. Tamaki;T. Harada;N. Miura;N. Yamazoe