• Korean Journal of Ecology and Environment
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• v.43 no.3
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• pp.418-427
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• 2010

In the four swamps of Jjokjibeol, Mokpo, Upo and Sajipo in the Upo wetland, the nitrogen nutrients, phosphorus nutrients and chl-$\alpha$ had been observed during the period from April 2005 to December 2009 on monthly basis. Based on the results, the fluctuations of trophic state in the Upo wetland were estimated. Measurements of the nitrogen nutrients such as $NO_3$-N, $NH_3$-N and T-N showed to be generally decreased in comparison with those in the precent studies. Yet the T-N was still considerably higher than the general concentration level of eutrophication and algal blooming. $PO_4$-P and T-P showed to have reduced considerably in comparison to precedent studies. However, T-P also turned out to be dissolved over the nutrient standard. Nitrogen nutrients and phosphorus nutrients were the lowest in Jjokjibeol in the Upo wetland. The chl-$\alpha$ concentrations were the highest at summer periods in Jjokjibeol and Mokpo. However, the highest at non-summer periods in Upo and Sajipo. Among the four swamps, Upo had the highest density on average of chl-$\alpha$, and Mokpo the lowest. Through TRIX (Trophic Index) analysis evaluating trophic state of the Upo wetland, all four swamps were estimated of poor water quality (eutrophication).

• Proceedings of the Korea Water Resources Association Conference
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• 2011.05a
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• pp.287-287
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• 2011

모니터링 자료의 부족으로 인하여 다양한 토지이용에서 발생하는 비점오염물질의 관리에 어려움을 겪고 있는 실정이다. 현재 환경부에서는 현행 토지계의 원단위를 세부적으로 분류하여 재산정하기 위하여 지목별로 장기 모니터링이 수행되고 있다. 특히, 산림 지역의 경우 도시 및 축산지역에 비하여 강우유출수의 농도는 낮더라도 유량적인 측면에 보았을 때 전체 수계에 대한 부하량 기여도는 매우 높다고 볼 수 있다. 따라서 본 연구는 장기모니터링의 일환으로 산림지역에 대한 비점오염물질 유출 특성을 파악하기 위하여 모니터링 및 분석을 실시하였으며, 이러한 결과는 향후 비점오염원 평가기반을 마련하고자 한다. 본 연구는 활엽수지역을 대상으로 2010년 4월부터 10월까지 총 16회에 걸쳐 모니터링이 수행되었으며, 시료의 성분 변화를 막기 위해 냉장기능이 있는 자동채수기를 이용하여 시료를 채취하였다. 수질분석항목은 BOD, COD, DOC, SS, T-N, $NO_3$-N, $NH_3$-N, T-P, $PO_4$-P로 총 9가지 항목을 분석하였다. 강우사상에 대한 모니터링 결과, 총강우량은 7.0~76.5mm, 강우지속시간은 1~30hr, 평균 강우강도는 0.88~18.50mm/hr의 범위를 보이고 있으며, EMC(Event Mean Concentration, 유량가중평균농도)결과 BOD는 0.4~2.4mg/L, T-N은 1.156~14.777mg/L, T-P는 0.009~0.562mg/L인 것으로 나타났으며, SS는 1.8~71.9mg/L 로 비교적 높은 값을 나타내는 것으로 분석되었다. 농도 변화 및 유출경향의 패턴을 볼 때, 유량이 증가함에 따라 농도도 점점 증가하여 첨두유량이 발생된 후 감소하는 경향을 나타내는 것으로 분석되었다. 또한 우리나라의 경우, 시험유역을 대개 산지 소유역에 설치하는 경우가 많아서 일반적으로 지연시간이 짧은 경우가 많기 때문에 이 지역 역시 강우가 내린 후 계류유출량의 증가에 영향을 주는 강우의 유출속도는 비교적 빠른 것으로 나타났다. 그리고 단기 수문곡선상에서 강우량이 많을 시 유출이 빠르게 일어나 첨두 유량에 도달하는 시간이 짧고, 강우량이 적을 시에는 첨두 유량의 출현시간이 늦어지는 것을 볼 수 있었다.

• Journal of Integrative Natural Science
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• v.4 no.2
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• pp.103-112
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• 2011

This study was carried out on 4 batch reactors to determine the specific ammonium oxidizing rate (SAOR), specific nitrate forming rate (SNFR) and inhibitory degree of nitrifying activities with saline concentrations. Under salt free condition ammonia was consumed during the reaction period within 200 min. When the salt level increased to 10, 20 and 30 g $NaClL^{-1}$ in reactor, ammonia depletion took 250, 300 and above 350 min, respectively. During concentration above 10 g $NaClL^{-1}$, there was nitrite accumulation. Also, at 30 g $NaClL^{-1}$ ammonia did not depleted and $NO_2{^-}$-N accumulated until the final reaction. Nitrate formation rates decreased with increasing salt concentration. SAOR and SNFR showed a decreasing trend as salinity concentrations were increased. The SAOR was reduced from 0.2 to 0.08 mg $NH_4{^+}$-N $g^{-1}VSS\;day^{-1}$ as the salt concentration increased from 0 to 30 g $NaClL^{-1}$. Similarly, the SNFR decreased from 0.26 kg $NO_3{^-}$-N $kg^{-1}VSS\;day^{-1}$ at saline free to 0.1 kg $NO_3{^-}$-N $kg^{-1}VSS\;day^{-1}$ at saline 30 g L-1. A severe inhibition of nitrifiers activity was observed at increased salt concentrations. The inhibition ratio of specific ammonium oxidation rates were 17, 47 and 60% on the reactor of 10, 20 and 30 g $NaClL^{-1}$ added, respectively. The inhibition ratio of specific nitrate forming rates also were inhibited 30, 53 and 62% on the reactor of 10, 20 and 30 g $NaClL^{-1}$ added, respectively. As the salinity concentrations increased from 0 to 30 mg $NaClL^{-1}$, the average MLSS concentration increased from 1,245 to 1,735 $mgL^{-1}$. The SS concentration of supernatant in reactor which settled about 30 minutes was not severely difference between concentration of salt free reactor and one of those high salt contained reactors.

• Korean Journal of Soil Science and Fertilizer
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• v.18 no.4
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• pp.336-347
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• 1985

Soils and rice plants subject to smoke from the Jang-hang Smelter were samples at two depths to assess the nature and extend of Cd, Cu, Pb, and Zn contamination, particularly with respect to distance from pollution source. Soils at east site within 1km of the center of the smelter were highly contaminated with Cd, Cu, Pb, and Zn. Metal levels in the smoke-polluted area were higher in surface soil than in subsurface soil, and decreased rapidly with distance reaching nearly background levels at 5km from pollution source. A position correlation was found between contents of total and 0.1 N HCl-extractable, or 1.0N $CH_3COONH_4$- extractable heavy metals in surface soils of pollution. Contents of heavy metals in soils were positively correlated with soil organic matter and cation exchange capacity. The contents of heavy metals in brown rice collected from the paddy field around the Jang-hang Smelter were in the range of 0.23-1.33 ppm for Cd, 2.39-6.25 for Cu, 0.95-8.32 ppm for Pb and 14.60-27.31 for Zn. The contents of Cd, Cu, and Zn in rice straw were positively correlated with those in the brown rice. Negative correlation was found between the contents of Cd, Cu, Pb, and Zn in brown rice and the distance from the source.

• Korean Journal of Materials Research
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• v.22 no.4
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• pp.202-206
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• 2012

$CoSi_2$ was formed through annealing of atomic layer deposition Co thin films. Co ALD was carried out using bis(N,N'-diisopropylacetamidinato) cobalt ($Co(iPr-AMD)_2$) as a precursor and $NH_3$ as a reactant; this reaction produced a highly conformal Co film with low resistivity ($50\;{\mu}{\Omega}cm$). To prevent oxygen contamination, $ex-situ$ sputtered Ti and $in-situ$ ALD Ru were used as capping layers, and the silicide formation prepared by rapid thermal annealing (RTA) was used for comparison. Ru ALD was carried out with (Dimethylcyclopendienyl)(Ethylcyclopentadienyl) Ruthenium ((DMPD)(EtCp)Ru) and $O_2$ as a precursor and reactant, respectively; the resulting material has good conformality of as much as 90% in structure of high aspect ratio. X-ray diffraction showed that $CoSi_2$ was in a poly-crystalline state and formed at over $800^{\circ}C$ of annealing temperature for both cases. To investigate the as-deposited and annealed sample with each capping layer, high resolution scanning transmission electron microscopy (STEM) was employed with electron energy loss spectroscopy (EELS). After annealing, in the case of the Ti capping layer, $CoSi_2$ about 40 nm thick was formed while the $SiO_x$ interlayer, which is the native oxide, became thinner due to oxygen scavenging property of Ti. Although Si diffusion toward the outside occurred in the Ru capping layer case, and the Ru layer was not as good as the sputtered Ti layer, in terms of the lack of scavenging oxygen, the Ru layer prepared by the ALD process, with high conformality, acted as a capping layer, resulting in the prevention of oxidation and the formation of $CoSi_2$.

• Journal of Wetlands Research
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• v.11 no.3
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• pp.145-151
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• 2009

Recently the water quality management policy has been changed from managing the point source to controlling the nonpoint sources (NPSs) because of TMDL program. Most NPSs are accumulated on the surface during dry periods. These accumulated pollutants are washed-off during a storm event and highly impairing the water quality of the receiving water bodies. Usually NPS has high uncertainty and is hard to control because of the variability of the rainfall and watershed characteristics. Also, NPS is derived from various land uses. The Ministry of Environment (MOE) is studying and monitoring the pollutant loads from each land use since 2007 to determine the unit pollutant loads. This research was a part of long-term monitoring program conducted to characterize the washoff and provide the mean EMC of artificial grassland. The average EMCs result of BOD, COD, DOC, SS, TN, NH4-N, NO3-N, TP, and PO4-P of the artificial grassland were deterined to 8.2, 17.5, 11.3, 110.1, 3.07, 0.20, 0.75, 0.86 and 0.08 mg/L, respectively. The results of statistical analysis conducted showed a low correlation to the contaminants.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.48 no.3
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• pp.179-183
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• 2003

In comparison of physicochemical properties between expanded rice hulls (ERH) and a commercial nursery soil (Bunong), the pH and content of organic matters were higher in ERH than those of Bunong soil. However, the content of available phosphate, $\textrm{NH}_4\textrm{-N}$ and $\textrm{NO}_3\textrm{-N}$ were lower in ERH as compared with Bunong soil. The growth characteristics of seedlings were evaluated for 15-day old seedlings grown in five different nursery soils including ERH. The plant height was the tallest (22.8cm) in Bunong soil and shortest (12.8cm) in ERH. There was no difference in number of leaves among five types of nursery soils. The best results based on the seedling quality and root intensity was obtained from the seedlings grown in the nursery soil which ERH was used for bedding and Bunong soil for covering in the seed tray. The weight of a seed tray with Bunong soils was 27% heavier than that of 'ERH + Bunong soil'.

• Journal of Environmental Impact Assessment
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• v.18 no.6
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• pp.461-467
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• 2009

This paper provides two case studies of environmental impacts with socio-economic values. The first case is on flood protection levees conducted from 2003 to 2004 in Phu Tan district, An Giang province. The impacts were found by comparing full flood protection levees area (FFPL) to non-full flood protection levees area (NFFPL). Participatory Rural Appraisal (PRA) tools per each group of rich, middle, and poor people were used to list the impacts. Then, major impacts were selected by ranking and interviewing 60 households per site, and assessed by Cost Benefit Analysis (CBA) in rice production from 1996 to 2002 between two areas. The tested research indicated moving system of NFFPL to that of FFPL lost about 11 million VND/ha/year. The second case is on impacts of Penaeid shrimp farming conducted in Duyen Hai District, Tra Vinh Province in 2004-2005. Ninety households and 12 local officials were interviewed. Four PRAs were conducted and 36 water samples were taken inside and outside shrimp pond to measure values of DO, COD, Fe total, TSS, N-$NO_3{^-}$, N-$NH_4{^+}$, P-$PO{_4}^{3-}$, and Chlorophyll-a. Research results showed only 36.7% of the households got profit from shrimp farming. Highest financial efficiency was 0.72 for the semi-intensive system. Tested water indicators showed surface water quality did not match Vietnamese standard for surface water in coastal area (TCVN 5943-1995) and in rain. The water was very muddy and contaminated by organic aluminum. Summarily, the impacts were clarified more obviously via adding socio-economic values to assessment. Importantly, the values were transformed to household's income which is an indicator for policy-makers to consider the impacts obviously. Besides, data of different group of people impacted are cases contributing to consideration of the impacts in an appropriate social level.

• Journal of the Korean Chemical Society
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• v.5 no.1
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• pp.42-47
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• 1961

A titration of a small amount of iron with standard potassium ferrocyanide using potassium thiocyanate as indicator has been studied. A sample solution containing $0.1{\sim}1.0$ mg. $Fe^{3+}$ in 60 ml. is pipeted into 100 ml. Erlenmyer flask and the pH of the solution is adjusted to $1.5{\sim}3.0$ with 0.1 N or 1 N $HNO_3$ and $NH_4OH.$ To this solution one ml. of 1 M KCNS solution as indicator is added. The solution colored by iron thiocyanate complex is titrated with 1/200 M or 1/400 M standard solution of potassium ferrocyanide from a 5 ml. micro-buret. Near the end point, when the color of sample changes from deep red to green, about 20 ml. of ether is added and shake the flask vigorously. The red color is extracted to the ether layer. To settle the ether layer a few drops of ethanol is added and then standard solution is added dropwise and shake vigorously. The end point is reached when the color of the ether layer disappears owing to the quantitative formation of $Fe_4[Fe(CN)_6]_3.$ In this titration, 0.lmg. of $Fe^{3+}$ can be determined within 1.0% of titration error, provided the following optimum conditions, i.e., pH $1.5{\sim}3.0$, final concentration of KCNS indicator; $0.01{\sim}0.02M$, at room temperature. The titration found to be interfered by the presence of slightly soluble salts, stable complex forming ions and the ions which would be reduced by ferrocyanide or oxidized by ferric ion.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.34 no.2
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• pp.120-126
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• 1989

This experiment was carried out to investigate the lectin of soybean (Glycine max L.) seed. Purification was done by 50-80% ammonium sulfate precipitation, CM-cellulose and Sephadex G-100 column. The purity was ascertained by electrophoresis. The molecular weight of purified lectin was estimated as 132,000. It was composed of three subunits which molecular weight was 45,000. The lectin was identified as glycoprotein by Schiff's reagent staining and Dubois method. The lectin agglutinated erythrocytes of rabbit and human. The amounts of the lectin to agglutinate human erythrocytes differed among the blood types: The blood type A required the least amount, the next was B, O, and AB in order. The agglutination was specifically inhibited by 5${\mu}$g/ml of N -acetyl.-D-galactoseamine and 200${\mu}$g/ml of D-galactose. Other tested sugars could not inhibit the agglutination of the erythrocytes by the lectin.