• Title/Summary/Keyword: $NH_4$

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Changes in Heavy Metal Phytoavailability by Application of Immobilizing Agents and Soil Cover in the Upland Soil Nearby Abandoned Mining Area and Subsequent Metal Uptake by Red Pepper (광산 인근 밭토양에서 중금속 안정화제 처리 및 복토층 처리에 의한 토양 중 중금속 식물유효도 변화 및 고추의 중금속 흡수)

  • Kim, Kwon-Rae;Park, Jeong-Sik;Kim, Min-Suk;Koo, Nam-In;Lee, Sang-Hwan;Lee, Jin-Su;Kim, Sung-Chul;Yang, Jae-E;Kim, Jeong-Gyu
    • Korean Journal of Soil Science and Fertilizer
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    • v.43 no.6
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    • pp.864-871
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    • 2010
  • At the current situation of continuous utilization of heavy metal contaminated upland for agricultural purpose in Korea, minimizing transport of heavy metals from soil to crops is important for securing safety of human health. The present study (in field scale) examined the efficiency of several soil amendments (dolomite, steel slag, lime, zeolite, and compost) on reduction of phytoavailable heavy metals (Cd, Cu, Pb, and Zn) in soil through comparison with no amendment treatment and clean soil cover treatment. For determination of the phytoavailability, 1 M $NH_4NO_3$ extraction and red pepper cultivation were introduced. Among the amendments, in general, dolomite and steel slag were the most effective in reduction of metal (Cd, Pb, and Zn) phytoavailability resulting in less accumulation of these metals in shoot and fruit of red pepper. However, dolomite and steel slag treatment was not as effective as clean soil cover treatment which showed the least metal accumulation in red pepper fruit. Nevertheless, with taking into account the cost, treatment of dolomite or steel slag can be competitive method because the current study showed that dolomite or steel slag treatment reduced accumulated heavy metal concentration effectively in both shoot and fruit of red pepper compared to those from control soil and the concentration in fruit was within the standard value (<0.2 mg $kg^{-1}$ for both Cd and Pb).

Reasonable Split Application Method of Nitrogen Fertilizer for Early Dry Seeding Culture of Rice in Honam Plain Area (호남평야지에서 벼 건답직파 조기파종재배에 알맞은 질소 분시방법)

  • Kim, Sang-Su;Choi, Weon-Young;Back, Nam-Hyun;Choi, Min-Gyu;Park, Hong-Kyu
    • Korean Journal of Soil Science and Fertilizer
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    • v.40 no.6
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    • pp.460-464
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    • 2007
  • This study was carried out to elucidate the proper split application method of nitrogen fertilizer for early dry seeding culture of rice in Honam plain area from 1997 to 1998 in Korea. Dongjinbyeo was selected as rice variety for this experiment. The rate of $160kg\;ha^{-1}$ of nitrogen was split as 40-30-30% of total nitrogen at three different application time combination ; T1) basal-5th leaf-panicle formation(PF) stage, T2) 3rd leaf-5th leaf-PF, and T3) 3rd leaf-7th leaf-PF. The content of $NH_4-N$ in soil at 5th leaf stage was higher in top dressing plots(T2, T3) compared with basal application(T1), at 7th leaf stage it was most in top dressed at 3rd leaf and 5th leaf stage, but there was no difference at heading stage. Amount of nitrogen uptake and nitrogen use efficiency was higher in the order of T3, T2 and T1(basal application). Spikelet number per unit area was more in the order of T3, T2 and T1, but rate of ripened grain and 1,000 grain weight were not significantly different among three nitrogen split application methods. Milled rice yields were higher in top dressed plots compared with basal nitrogen application plots. From the results of this experiment, reasonable nitrogen split application method for early dry seeding culture of rice could be 40-30-30% of total nitrogen at 3rd leaf, 7th leaf and panicle formation stage.

Management Strategies and the Relationship between Argyroneta aquatica and Environmental Factors in Aquatic Ecosystem (천연기념물 물거미(Argyroneta aquatica)와 수생태 환경 요인과의 관계와 관리 방안)

  • Jeong, Heon Mo;Kim, Hae Ran;Cho, Kyu Tae;Lee, Seungyeon;You, Young Han;Hong, Seungbum
    • Korean Journal of Ecology and Environment
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    • v.52 no.2
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    • pp.136-142
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    • 2019
  • Water spider(Argyroneta aquatica) inhabits only a small size wetland in Eundae-ri, Yeoncheon-gun. In this study to investigate environmental factors influencing on population of A. aquatica, we analyzed the relationship between density of A. aquatica and various physicochemical and biological factors. Density of A. aquatica increased with small habitat area and high $NH_4$ and electric conductivity. The relationship between density of A. aquatica and prey or predator was low but the water spider decreased with density of Pomacea canaliculata. And density of A. aquatica was not related to the coverage of emergent plant. However density of A. aquatica decreased as the increase of floating plant and increased as the increase of submerged plant. These results indicated that aquatic plants are important in the habitat environment of A. aquatica. Therefore we suggest necessity of management strategies for the invasive species, P. canaliculata which is a notorious predator of aquatic plants.

Statistical Analysis of the Spatio-temporal Water Quality Characteristics of the Nakdong River (낙동강수계 수질의 시·공간적 특성에 대한 통계학적 분석)

  • Seo, Mijin;Cho, Changdae;Im, Taehyo;Kim, Sanghun;Yoon, Hyunjeong;Kim, Yongseok;Kim, Gyeonghoon
    • Journal of Environmental Science International
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    • v.28 no.3
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    • pp.303-320
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    • 2019
  • Water quality is characterized by various complex factors. Therefore, a systematic understanding of water quality trends is required to carry out a proper evaluation. In this study, we analyzed the spatio-temporal water quality characteristics of the Nakdong River using five-year data from 2012 to 2016. Data was collected on the pH, DO, BOD, COD, SS, TN, TP, TOC, WT, EC, $NH_3-N$, $NO_3-N$, $PO_4-P$, Chl-a, rainfall, and total and fecal coliforms. A total of 38 water quality measurement stations, from Andong1 to Gupo, were considered. Statistical analyses including trend, cluster, and factor analyses were conducted to identify the dominant water quality components affecting the Nakdong River. The Nakdong River was spatially classified into three groups for up-stream (Andong1 to Sangju1), mid/up-stream (Donam to Dalseong), and mid/down-stream (Hwawonnaru to Gupo) data collection, and temporally into two groups for summer/fall (7~10), and the rest of the season (11~6) data. The water quality of the entire Nakdong River showed trends similar to the mid/down-stream section, which indicates the importance of water quality management in this section. Suspended solids, phosphorus, and coliform groups were established as important factors to be considered in the summer/fall season across the river, especially in the mid/down-stream section. Nitrogen and organic matter were identified as important factors to be considered in the rest of the season, especially in the mid/up-stream section. This study could help determine the water quality components that should be intensively monitored in the Nakdong River.

Synthesis and Optical Property of (GaN)1-x(ZnO)x Nanoparticles Using an Ultrasonic Spray Pyrolysis Process and Subsequent Chemical Transformation (초음파 분무 열분해와 화학적 변환 공정을 이용한 (GaN)1-x(ZnO)x 나노입자의 합성과 광학적 성질)

  • Kim, Jeong Hyun;Ryu, Cheol-Hui;Ji, Myungjun;Choi, Yomin;Lee, Young-In
    • Journal of Powder Materials
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    • v.28 no.2
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    • pp.143-149
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    • 2021
  • In this study, (GaN)1-x(ZnO)x solid solution nanoparticles with a high zinc content are prepared by ultrasonic spray pyrolysis and subsequent nitridation. The structure and morphology of the samples are investigated by X-ray diffraction (XRD), field-emission scanning electron microscopy, and energy-dispersive X-ray spectroscopy. The characterization results show a phase transition from the Zn and Ga-based oxides (ZnO or ZnGa2O4) to a (GaN)1-x(ZnO)x solid solution under an NH3 atmosphere. The effect of the precursor solution concentration and nitridation temperature on the final products are systematically investigated to obtain (GaN)1-x(ZnO)x nanoparticles with a high Zn concentration. It is confirmed that the powder synthesized from the solution in which the ratio of Zn and Ga was set to 0.8:0.2, as the initial precursor composition was composed of about 0.8-mole fraction of Zn, similar to the initially set one, through nitriding treatment at 700℃. Besides, the synthesized nanoparticles exhibited the typical XRD pattern of (GaN)1-x(ZnO)x, and a strong absorption of visible light with a bandgap energy of approximately 2.78 eV, confirming their potential use as a hydrogen production photocatalyst.

Cnidoscolus aconitifolius leaf pellet can manipulate rumen fermentation characteristics and nutrient degradability

  • Totakul, Pajaree;Matra, Maharach;Sommai, Sukruthai;Wanapat, Metha
    • Animal Bioscience
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    • v.34 no.10
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    • pp.1607-1615
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    • 2021
  • Objective: Chaya (Cnidoscolus aconitifolius) leaf has been found to be an important source of protein, vitamins, minerals, as well as phytonutrients. The present study aimed to evaluate the effect of Chaya leaf pellet (CHYP) with various level of crude protein (CP) in the concentrate on rumen fermentation characteristics and nutrient degradability in in vitro gas production technique. Methods: In an in vitro rumen fermentation study the dietary treatments were arranged according to a 3×5 factorial arrangement in a completely randomized design, consisting of Factor A: three levels of CP of concentrate mixtures (14%, 16%, and 18% CP, respectively) and Factor B: five levels of CHYP supplementation (at 0%, 2%, 4%, 6%, and 8% of dry matter substrates). Results: The gas production kinetics, fraction (a) and fraction (b) were lower (p<0.05) with an increasing CHYP addition. Additionally, the fraction (a+b) was found to yield a significant interaction (p<0.05) while the fraction (c) was not impacted by CHYP addition. However, in vitro DM degradability was enhanced and interactive (p<0.05), using 16% CP of concentrate with 6% and 8% CHYP, when compared with 18% CP in the non-addition. Additionally, the treatment with higher CP of the concentrate was higher in NH3-N concentration (p<0.001) and by CHYP supplementation group (p<0.05). Nevertheless, protozoal counts in the rumen were remarkably decreased (p<0.05) with increasing level of CHYP supplementation. Furthermore, rumen C2 concentration was lower (p<0.05) in the treatments with CHYP supplementation, while C3 was significantly increased and interactive (p<0.05) between levels of CP and CHYP supplementation especially at 8% CHYP supplementation. Conclusion: Based on this study, the results revealed CHYP as a promising feed supplement to enhance rumen fermentation and to mitigate methane production. However, in vivo feeding experiments should be subsequently conducted to elucidate the effect of CHYP supplementation on rumen fermentation, as well as ruminant production efficiency.

Radiation stability and radiolysis mechanism of hydroxyurea in HNO3 solution: Alpha, beta, and gamma irradiations

  • Yilin Qin;Wei Liao;Tu Lan;Fengzhen Li;Feize Li;Jijun Yang;Jiali Liao;Yuanyou Yang;Ning Liu
    • Nuclear Engineering and Technology
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    • v.54 no.12
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    • pp.4660-4670
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    • 2022
  • Hydroxyurea (HU) is a novel salt-free reductant used potentially for the separation of U/Pu in the advanced PUREX process. In this work, the radiation stability of HU were systematically investigated in solution by examining the effects of the type of rays (α, β, and γ irradiations), the absorbed dose (10-50 kGy), and the HNO3 concentration (0-3 mol L-1). The influence degree on HU radiolysis rates followed the order of the absorbed dose > the ray type > the HNO3 concentration, but the latter two had moderate effects on HU radiolysis products where NH4+ and NO2- were found to be the most abundant ones, suggesting that the differences of α, β, and γ rays should be considered in the study of irradiation effects. The radiolysis mechanism was explored using density functional theory (DFT) calculations, and it proposed the dominant radiolysis paths of HU, indicating that the radiolysis of HU was mainly a free radical reaction among ·H, eaq-, H2O, intermediates, and the radiolytic free radical fragments of HU. The results reported here provide valuable insights into the mechanistic understanding of HU radiolysis under α, β, and γ irradiations and reliable data support for the application of HU in the reprocessing of spent fuel.

Analysis of Correlation Between the Number of Cyanobacterias and Water Quality Parameters in Geum River (금강유역의 남조류 세포수와 수질인자 간의 상관관계 분석)

  • Park, Gue Tae;Jang, Dong Woo
    • Proceedings of the Korea Water Resources Association Conference
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    • 2020.06a
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    • pp.213-213
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    • 2020
  • 최근 나타나는 지구온난화와 이상기후로 인해 가뭄과 홍수피해 같은 자연재해 발생 빈도가 높아졌고, 하천에서는 오염된 수질과 수생태계 복원 및 수변공간 조성, 수자원 관리 등의 목적으로 수질환경 개선사업이 진행되고 있다. 수질환경 측면에서 하천에서 발생하는 가장 큰 문제점으로는 녹조 즉, 남조류의 발생을 예로 들 수 있다. 본 연구에서는 최근 보 개방을 통하여 수질개선 효과가 나타나고 있는 금강을 대상으로 세종보, 공주보, 백제보 구간에 대하여 주요 수질인자에 대한 상관관계 분석을 수행하였다. 특히 남조류 세포수와 주요 하천 수질인자를 Pearson's correlation analysis를 이용하여 상관관계를 분석하였고, 보 위치별 남조류 세포수를 종속변수로 하고, 상관도가 높은 수질인자를 독립변수로 하는 다중회귀식을 도출하여 금강 내 주요 하천 수질인자의 농도에 따른 남조류 세포수 관계를 규명하고자 하였다. 분석기간은 2012년 1월부터 2019년 12월까지 보 건설 이후 시점으로 선정하였고, 월 평균 남조류 개체수가 조류경보제 발령기준 관심단계이상에 해당하는 금강수계의 3개 보에 대하여 남조류 세포수와 수질에 영향을 끼치는 인자인 강수량, (수온)W·T, (수소이온농도)pH, (용존산소)DO, (생물화학적산소요구량)BOD, (화학적산소요구량)COD, (부유물질량)SS, (총질소)TN, (총인)TP, (클로로필-a)Chl-a, (전기전도도)EC, (질산성질소)NO3-N, (암모니아성 질소)NH3-N, (인산염 인)PO4-P, (용존총질소)DTN, (용존총인)DTP, (총유기탄소)TOC 와의 상관관계를 분석하였다. 분석 결과 측정 지점별 남조류 세포수와 상관관계가 있는 인자는 서로 상이했지만 (수온)W·T과 pH의 경우 모든 지점에서 남조류 세포수와 양의 상관관계가 나타났다. 세종보는 W·T(0.383, P<0.01), pH(0.391, P<0.05)의 양의 상관계수를 나타냈고, 공주보에서는 (수온)W·T(0.436, P<0.05), pH(0.412, P<0.05)의 양의 상관관계를 나타냈다. 백제보에서는 (수온)W·T(0.415, P<0.01), pH(0.221, P<0.01)의 양의 상관성을 나타냈다. 남조류 세포수와 수질인자 간의 상관관계 분석에 따라 통계적으로 유의한 인자 중 (수온)W·T과 pH에 영향을 받는 영양염류와 퇴적물에 대한 후속 연구가 필요할 것으로 사료되며, 연구를 통해 제시된 남조류 세포수 다중회귀식은 주요 수질인자 농도에 따라 발생 가능한 남조류세포수를 예측하여 금강의 수질 관리에 활용될 수 있을 것으로 기대된다.

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Application Effects of Bacterial Inoculants Producing Chitinase on Corn Silage

  • Young Ho Joo;Seung Min Jeong;Jiyoon Kim;Myeong Ji Seo;Chang Hyun Baeg;Seong Shin Lee;Byeong Sam Kang;Ye Yeong Lee;Jin Woo Kim;Sam-Churl Kim
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.43 no.3
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    • pp.148-155
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    • 2023
  • This study was aimed to isolate bacterial inoculants producing chitinase and evaluate their application effects on corn silage. Four corn silages were collected from four beef cattle farms to serve as the sources of bacterial inoculants. All isolates were tested against Fusarium graminearum head blight fungus MHGNU F132 to confirm their antifungal effects. The enzyme activities (carboxylesterase and chitinase) were also measured to isolate the bacterial inoculant. Based on the activities of anti-head blight fungus, carboxylesterase, and chitinase, L. buchneri L11-1 and L. paracasei L9-3 were subjected to silage production. Corn forage (cv. Gwangpyeongok) was ensiled into a 10 L mini silo (5 kg) in quadruplication for 90 days. A 2 × 2 factorial design consists of F. graminearum contamination at 1.0104 cfu/g (UCT (no contamination) vs. CT (contamination)) and inoculant application at 2.1 × 105 cfu/g (CON (no inoculant) vs. INO (inoculant)) used in this study. After 90 days of ensiling, the contents of CP, NDF, and ADF increased (p<0.05) by F. graminearum contamination, while IVDMD, acetate, and aerobic stability decreased (p<0.05). Meanwhile, aerobic stability decreased (p<0.05) by inoculant application. There were interaction effects (p<0.05) on IVNDFD, NH3-N, LAB, and yeast, which were highest in UCT-INO, UCT-CON, CT-INO, and CT-CON & INO, respectively. In conclusion, this study found that mold contamination could negatively impact silage quality, but isolated inoculants had limited effects on IVNDFD and yeast.

The Effects of Korean Seaweeds on In vitro Ruminal Fermentation Characteristics and Methane Production (국내 자생 해조류 첨가가 in vitro 반추위 발효 성상 및 메탄 발생량에 미치는 영향)

  • Kim, Byul;Wi, Jisoo;Lee, Yookyung;Kim, Hyunsang;Seong, Pilnam;Lee, Sungdae;Hwang, Ilki;Kim, Hyunchul;Lee, Seongshin
    • Korean Journal of Organic Agriculture
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    • v.32 no.3
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    • pp.277-288
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    • 2024
  • The present study was conducted to investigate the effects of seaweeds on in vitro ruminal fermentation characteristics and methane gas production. Five seaweeds (Dictyota dichotoma, DD; Chrysymenia wrightii Yamada, CW; Codium fragile, CF; Sargassum fusiforme, SF; Gracilaria vermiculophylla, GV) were obtained from National Institute of Fisheries Science (NIFS) in South Korea. The ruminal fluids were collected from 3 rumen-cannulated Hanwoo steers (average 12-months-old). The buffered ruminal fluids (50 mL) were incubated with substrates (0.4 g of concentrate and 0.1 g of rice straw in dry matter basis) and seaweeds (5% of substrates) at 39℃ for 24 and 48 hours. The total gas and methane production of all treatments incubated for 24 hours were not affected by the seaweed. However, methane production (mL/g of digested dry matter) in the CW and CF treatments incubated for 48 hours was decreased compared to control (p<0.05). Additionally, the ruminal pH of all treatments incubated for 24 and 48 hours was lower than control (p<0.05). There was no signigicant difference in total VFA concentration at 24 hours of incubation, but it was higher in the CF treatment at 48 hours of incubation (p<0.05). The dry matter digestibility of all treatments incubated for 24 and 48 hours were not affected by the seaweed. In conclusion, Codium fragile reduced in vitro methane production without negative effects on rumen fermentation characteristics.