• Title/Summary/Keyword: $Mo(CO)_6$

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Characterization of Low-Trans Solid Fat from Canola and Fully Hydrogenated Soybean Oil by Lipase-Catalyzed Interesterification Reaction (효소적 에스테르 교환 반응 시 카놀라유와 대두극도경화유의 비율에 따른 저트랜스 고체지방의 특성)

  • Kim, Young-Joo;Lyu, Hyun-Kyeong;Lee, Seon-Mo;Lee, Ki-Teak
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.39 no.9
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    • pp.1320-1327
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    • 2010
  • Lipase-catalyzed interesterification of canola (CO) and fully hydrogenated soybean oil (FHSBO) at different weight ratios (70:30, 75:25, and 80:20) was performed in a batch type reactor to produce low-trans solid fats. Each reaction was conducted in the shaking water bath for various reaction times (1, 3, 6, 18 and 24 hr) at 70oC and 220 rpm using Lipozyme TLIM (20 wt% of total substrate) from Thermomyces lanuginosus. After 24 hr reaction, solid fat content (SFC) by differential scanning calorimetry (DSC), fatty acid and triacylglycerol (TAG) composition of low-trans solid fats were determined. SFC of the products was reduced when the content of canola oil in the reaction mixture was increased. Major fatty acids were stearic acid (C18:0), oleic acid (C18:1) and linoleic acid (C18:2). Trans fatty acid content in the low-trans solid fats showed less than 0.3 wt%. In the HPLC analysis, major TAG species showed LOO (linoleyl-oleoyl-oleoyl), OOO, POO/SOL, SOO, and SOS.

Methane Fermentation of Pit in Pond System for Ecological Treatment and Recycling of Animal Excreta (생태적 축산폐수 처리 및 재활용 연못시스템의 Pit 메탄발효)

  • Yang, Hong-Mo
    • Korean Journal of Environmental Agriculture
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    • v.18 no.2
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    • pp.191-195
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    • 1999
  • An integrated wastewater treatment pond system is developed for treatment and recycling of excreta from dairy cattle. It is composed of three ponds in series. A pit with a capacity of $10m^3$, 2-day hydraulic residence time, and overflow velocity of $1.5m^3m^{-2}day^{-1}$ is located internally in primary pond. It is designed for efficient sludge sedimentation and effective methane fermentation. It receives $5m^3/day$ of diluted cattle excreta by the water used for clearing stalls. A submerged gays collector for the recovery of methane is installed on the top of the pit. The average BOD_5 concentration of influent is 398.7mg/l. That of the effluent from primary pond is 49.2mg/l. About 88% of BOD_5 are removed in primary pond. It is assumed that about 60% of the influent BOD_5 is removed in the pit and that almost all of the carbon of the removed BOD_5 in the pit is converted to methane and carbon dioxide. Methane fermentation of the pit is well established at $16^{\circ}C$. This phenomena results from temperature stability, complete anaerobic condition, and neutral pH of the pit. Gas from the collector is almost 90% methane, less than 9% nitrogen, and less than 1% carbon dioxide. Thus a purified methane is produced, which can be used as energy source.

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Extraction of organic carbon from the condensate of food waste dry feed process (음식물류폐기물의 건식사료화 공정에서 발생되는 응축수로부터 유기탄소 추출)

  • Kim, Min-Kyung;Kwon, Ki-Wook;Mo, Kyung;Cui, Feng-Hao;Park, Se-Yong;Kim, Moon-Il
    • Journal of the Korea Organic Resources Recycling Association
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    • v.28 no.2
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    • pp.41-48
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    • 2020
  • In this study, organic carbon was extracted from the condensed water of food waste drying process to estimate the applicability as external organic carbon sources. The COD, TN, TP and TS of condensed water were 21,374 mg/L, 148 mg/L, 4.19 mg/L, and 455.7 mg/L, respectively. In addition, the content of biodegradable organics in condensed water was 47%. The fractional distillation and the vacuum evaporation were employed for extracting organic carbon. There were 8 extraction conditions, but 4 conditions were available for extraction. They were 1) 0mmHg, 110℃ 2) -600mmHg, 70℃ 3) -500mmHg, 80℃ 4) -600mmHg, 80℃. All 4 conditions showed the highest organic concentration and the highest quantity of organics when extracted 10% of initial volume. It was estimated that optimum conditions were 80℃, -600mmHg and 10% extraction. Then, extraction concentration, extraction quantity, extraction efficiency, extraction time, BOD/TCOD ratio, TVFAs/TCOD ratio and NH3-N were 174,200 mg/L, 8,710 mg, 46%, 10 min, 0.97, 0.74 and 75.5 mg/L respectively. Therefore, the extracted organic carbon can be utilized as external organic carbon sources.

The Metallic Composition of PM2.5 and PM10 in a Northeast Region of Seoul During the Spring 2001 (2001년 봄철 서울시 북동부지점에서 관측한 중금속성분의 농도분포)

  • Choi, Gyoo-Hoon;Kang, Chang-Hee;Kim, Ki-Hyun
    • Journal of the Korean earth science society
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    • v.23 no.6
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    • pp.514-525
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    • 2002
  • The analysis of heavy metals associated with both PM2.5 and PM10 fraction of aerosols was made from a northeast region of Seoul during the spring period of 2001. The mean concentrations of fine (PM2.5), coarse (PM10-PM2.5), and PM10 fraction were observed as 49.3${\pm}$29.2, 50.5${\pm}$35.0, and 95.5${\pm}$46.1 ${\mu}g$/m$^3$, respectively during this study period. According to the results of enrichment factor (EF) analysis between different particle fractions, major elements (including Fe, Ca, Na, and K) were found to exhibit EF values of less than 10. However, heavy metal components (like Zn and Pb) showed very high EF values. Comparison of fine/coarse (F/C) concentration ratio showed that Zn, Cr, Pb, and Ni have higher ratio values than others. The metallic composition of particles was also compared on both absolute and relative terms. The results of our analysis showed an evidence that the increase in the total metallic contents is prominent during the spring period due mostly to the Asian Dust event.

A study on Economic Evaluation of the Theater Stage Lighting System Using LED (공연장 LED 조명시스템 구성의 경제성 평가에 관한 연구)

  • Lee, Kwong-Mo;An, Kyong-Sok;Gu, Seung-Hwan;Han, Hak-Soo;Choi, Sung-Jin
    • The Journal of the Korea Contents Association
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    • v.15 no.6
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    • pp.43-53
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    • 2015
  • This study analyzes economic feasibility of the LED lighting system compare to the halogen. To evaluate economic feasibility of the LED devices, we analyzed the size of theater, current value of the lighting devices in kinds, annual cost and annual cost according to the surface in case of designing stage lighting system with LED using WEELS 2011. Also, to compare energy consumption, we analyzed consumption and amount of electric energy by the surface and the amount of CO2 emission. Data showed that annual cost of the LED devices are highly inexpensive than halogen and now the value is of great. However initial cost of the equipment 200% higher than halogen. Though LED devices are expensive in startup setting, the value of utilization factor is large and depreciation years of LED(30years) are longer than halogen(2years). Therefore, annual cost of LED can make up the minus. Consider the tendency of reducing price of LED devices, we can assume that annual cost of the LED will be lower than halogen devices. Further, in 3years the expense of LED and halogen is reversed.

Proper Seeding Time for Mechanical Harvesting in Mungbean (녹두 기계수확을 위한 남부지역 파종적기)

  • Kim, Dong-Kwan;Choi, Jin-Gyung;Jung, Byung-Joon;Son, Dong-Mo;Chon, Sang-Uk;Kim, Kyong-Ho
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.54 no.1
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    • pp.7-12
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    • 2009
  • Mungbean should be harvested several times according to its physiological characteristics and weather conditions of cultivation region. In Korea, mungbean is usually sown in June and harvested three or four times, and the cultivated area is being rapidly reduced. Therefore, the author developed cultivation techniques of mechanical harvesting suitable for the weather conditions of the southern part of the Korean peninsula. The optimum sowing time of mungbean for mechanical harvesting in southern part of Korea is around July 20. When sown around July 15, mungbean should be harvested twice and then the mechanical harvesting of mungbean was not possible. Meanwhile, when sown after July 25, the mechanical harvesting was possible but the maturing period was longer and the seed yield was decreased. Therefore, it is safe to say that in Korea the mechanical harvesting of mungbean is possible for the middle part of Korea when the plant is sown before July 20 and for the southern coastal region of Korea when sown after July 20 (if July 20 is set up as the baseline for the southern part of Korea). Out of Keumseong and Owool, which are popularized cultivars in Korea most, Owool is determined to be most appropriate for mechanical harvesting. Owool is favorable for mechanical harvesting because, when compared to Keumseong, it is higher both in plant height and in pod height, and also the seed yield is better.

Phenolic Compounds Content and DPPH, ADH, ALDH Activities of Mungbean Sprout Based on Growth Temperature (녹두나물 재배온도에 따른 페놀화합물 함량과 DPPH, ADH 및 ALDH 활성)

  • Kim, Dong-Kwan;Son, Dong-Mo;Chon, Sang-Uk;Lee, Kyung-Dong;Kim, Kyong-Ho;Rim, Yo-Sup
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.54 no.1
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    • pp.1-6
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    • 2009
  • This study is to analyze the effects of the growth temperature of mungbean sprouts ($15{\sim}30{\pm}1^{\circ}C$) on the yield ratio, content of phenolic compounds and DPPH (1,1-diphenyl-2-picrylhydrazyl), ADH (alcohol dehydrogenase), ALDH (aldehyde dehydrogenase) activities of the sprouts. When the growth temperature of mungbean sprouts was higher, the yield ratio of the sprouts was higher while the hard seed rate was lower, but $25{\pm}1^{\circ}C$ and $30{\pm}1^{\circ}C$ showed no regular tendency. The content of the total phenol from the ethanol extract of the sprouts was higher in the growth temperature of $15{\pm}1$, $20{\pm}1$, and $25{\pm}1^{\circ}C$, while the content of total flavonoid was higher in the growth temperature of $15{\pm}1$, and $20{\pm}1^{\circ}C$. The DPPH radical scavenging activity of the ethanol extract of the sprouts was higher when the growth temperature was lower, while the activity of ADH and ALDH showed no regular tendency according to the growth temperature. Considering the yield ratio, content of phenolic compounds, biological activities of mungbean sprouts, the optimum cultivation temperature of mungbean sprouts may be $20{\sim}25^{\circ}C$.

Isolation of Bacillus sp. Producing Poly-$\gamma$-glutamic Acid with High Efficiency and Its Characterization (고효율 Poly-$\gamma$-Glutamic Acid생산 균주의 분리 및 생산 특성)

  • You Kyung-Ok;Oh You-Na;Kim Byung-Woo;Nam Soo-Wan;Jeon Sung-Jong;Kim Dong-Eun;Kim Young-Man;Kwon Hyun-Ju
    • Microbiology and Biotechnology Letters
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    • v.33 no.3
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    • pp.200-206
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    • 2005
  • A bacterium with high productivity of poly-$\gamma$-glutamic acid (PGA) was isolated from the traditional Korean seasoning, ChungKookJang. The 16s ribosomal RNA sequence of isolated strain showed 97.6, 98.9 and $90.3{\%}$ of similarity to those of Bacillus sp. WL-3, Bacillus subtilis; ENV1 and B amy-loliquefaciens (T), respectively. Accordingly, this bacterium was identified as a Bacillus sp. However, some biochemical characteristics of this strain were different from those of B. subtilis: D-xylose fermentation and glycogen utility were negative. Maximum production of PGA was achieved when it was grown aerobically in a culture medium containing glutamic acid ($3{\%}$) and fructose ($4{\%}$) as carbon sources. The volumetric yield of PGA reached up to 27 g/l in the optimum culture medium. These results suggest that the present strain can be applicable for industrial purposes such as a prototype strain for food or cosmetics industry.

Pectinase-treated Panax ginseng protects against chronic intermittent heat stress-induced testicular damage by modulating hormonal and spermatogenesis-related molecular expression in rats

  • Kopalli, Spandana Rajendra;Cha, Kyu-Min;Lee, Sang-Ho;Ryu, Ji-Hoon;Hwang, Seock-Yeon;Jeong, Min-Sik;Sung, Jong-Hwan;Kim, Si-Kwan
    • Journal of Ginseng Research
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    • v.41 no.4
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    • pp.578-588
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    • 2017
  • Background: Elevated testicular temperature disrupts spermatogenesis and causes infertility. In the present study, the protective effect of enzymatically biotransformed Panax ginseng Meyer by pectinase (GINST) against chronic intermittent heat stress-induced testicular damage in rats was investigated. Methods: Male Sprague-Dawley rats (4 wk old, 60-70 g) were divided into four groups: normal control (NC), heat-stress control (HC), heat-stress plus GINST-100 mg/kg (HG100), and heat-stress plus GINST-200 mg/kg (HG200) treatment groups. Each dose of GINST (100 mg/kg and 200 mg/kg) was mixed separately with a regular pellet diet and was administered orally for 24 wk. For inducing heat stress, rats in the NC group were maintained at $25^{\circ}C$, whereas rats in the HC, HG100, and HG200 groups were exposed to $32{\pm}1^{\circ}C$ for 2 h daily for 6 mo. At week 25, the testes and serum from each animal were analyzed for various parameters. Results: Significant (p < 0.01) changes in the sperm kinematic values and blood chemistry panels were observed in the HC group. Furthermore, spermatogenesis-related molecules, sex hormone receptors, and selected antioxidant enzyme expression levels were also altered in the HC group compared to those in the NC group. GINST (HS100 and HS200) administration significantly (p < 0.05) restored these changes when compared with the HC group. For most of the parameters tested, the HG200 group exhibited potent effects compared with those exhibited by the HG100 group. Conclusion: GINST may be categorized as an important medicinal herb and a potential therapeutic for the treatment of male subfertility or infertility caused by hyperthermia.

Application of Rare Earth Compounds for the Treatment of Phosphate and Fluoride in Wastewater (인산염 및 불소폐수 처리제로서의 희토류 화합물 적용에 관한 연구)

  • Kim, Jin-Wha;Shin, Sung-Hye;Song, Hye-Won;Kim, Dong-Su;Woo, Sang-Mo;Kwon, Young-Shik
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.6
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    • pp.1127-1137
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    • 2000
  • Applications of lanthanum ion and crude rare earth chloride to the phosphate wastewater and fluorine wastewater, respectively, as treatment agents were studied. For the investigation of phosphate removal characteristics according to the amount of lanthanum ion, initial phosphate content was decreased by about 50% when molar ratio of [$La^{3+}$]:[$PO_4{^{3-}}-P$] was 0.25 and nearly all of phosphate was removed when the molar ratio of [$La^{3+}$]:[$PO_4{^{3-}}-P$] to be doubled. The removal of phosphate by $La^{3+}$ appeared to reach equilibrium state rapidly, and it was exothermic reaction since the removed amount of phosphate was diminished somewhat when the reaction temperature was increased. The zeta potential of combined particulate compound of lanthanum ion and phosphate was located for its isoelectric point at pH 5.5 and the turbidity of treated wastewater was found to vary according to the pH in a similar manner as the absolute value of zeta potential of the combined particulate compound did. For the treatment of fluorine wastewater by crude rare earth chloride, the remaining fluorine content after treatment decreased as the dosage of crude rare earth chloride increased. Whereas, the turbidity of treated wastewater and the amount of sludge generated were shown to increase as more crude rare earth chloride was added. The remaining fluorine content and the turbidity of treated wastewater were decreased and the amount of sludge generated was observed to increase according the increase of coagulant dosage under the condition of constant input of crude rare earth chloride.

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