• 제목/요약/키워드: $MnO_x$

검색결과 865건 처리시간 0.033초

NTC 서미스터용 스페넬 페라이트의 특성 (Properties of Spinel Ferrites for NTC Thermistor)

  • 오영우;허정섭;김현식;이승관
    • 한국전기전자재료학회논문지
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    • 제11권7호
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    • pp.546-551
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    • 1998
  • $Mn{1-X}Fe{2+X}O_4, Mg_{1-X}Fe_{2+X}O_4$ (x=0.0, 0.025, 0.1, 0.2) for negative temperature coefficient (NTC) thermistor was prepared by calcination at $800^{\circ}C$ and sintering at form 1100 to $1250^{\circ}C$ with $50^{\circ}C$ intervals. The best linear property was obtained in the Mn-based sample sintered at $1200^{\circ}C$ with x=0.0 composition. Temperature coefficient of resistance, $\alpha$, was $-5.6%/^{\circ}C$ in the Mn-based sample, $-5.2%/^{\circ}C$ in the MM-based sample, and $-1.6%/^{\circ}C$ in the Mg-based sample. thermistor parameter, B, was in the range of 2665~7780 K. The results show the possibility that Mn-Ni-Co based thermistor could be substituted by the composition used in this study.

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저온에서 소결한 Pb(Mg,Te,Mn,Nb)$O_3-Pb(Zr,Ti)O_3$세라믹스의 전기적 특성 (Electrical properties of Low Fired Pb(Mg,Te,Mn,Nb)$O_3-Pb(Zr,Ti)O_3$ Ceramics)

  • 정수태;조상희
    • E2M - 전기 전자와 첨단 소재
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    • 제9권7호
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    • pp.652-659
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    • 1996
  • Sintering characteristics and electrical properties of xPb(Mg$_{1}$8/Te$_{1}$8/Mn$_{1}$4/Nb$_{1}$2/) $O_{3}$-(1-x) Pb (Zr$_{1}$2/ $Ti_{1}$2/) $O_{3}$ (x=0.075, 0.1, 0.125) ceramics are investigated. A sintering temperature of ceramics could be reduced to 950.deg. C by a reaction between PbO and B site compound material. The physical properties of 0.1Pb(Mg, Te, Mn, Nb) $O_{3}$ - 0.9Pb(Zr, Ti) $O_{3}$ bulk ceramic with 3wt% glass frit(0.857PbO-0.143W $O_{3}$) were following : den = 7.95 g/cm$^{3}$, T$_{c}$=340.deg. C, .epsilon.$_{33}$= 754, k$_{31}$=0.3 and Q.=1780. The 3-layer piezoelectric transformer by using a tape casting method showed a good monolithic structure, and its voltage setup ratio was 2.5 times higher than that of a single device by using bulk ceramics.s.s.

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리튬 2차 전지용 정극 활물질 LiMn$_2$O$_4$의 X-선 회절 분석 및 전기화학적 특성 (X-ray diffraction and electrochemical properties of cathode active material LiMn$_2$O$_4$ for Lithium rechargeable batteries)

  • 정인성;성창호;박계춘;박복기;구할본
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1997년도 춘계학술대회 논문집
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    • pp.107-110
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    • 1997
  • LiMn$_2$O$_4$ is prepared by reacting stoichiometric mixture of LiOH . $H_2O$ and MnO$_2$ (mole ratio 1 ; 1) and heating at 80$0^{\circ}C$, $700^{\circ}C$ for 24h, 36h, 48h, 60h and 72h. We obtained through X-ray diffraction that lattice parameter varied as function of calcined temperature and time. Cathode active materials calcined at 80$0^{\circ}C$ for 36h, (111)/(311) peak ratio was 0.37. It showed good charge/discharge characteristics. When (111)/(311) peak ratio was 0.37, it was that crystal structure is formed very well. In the result of charge/discharge test, when heated at 80$0^{\circ}C$ for 36h, charge/discharge characteristics of LiMn$_2$O$_4$ is the best.

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La$_{1-x}Ca_xMnO_3$ 박막에서 p파 초전도의 가능성 (Possible p-wave condensed conductor (or superconductor) for La$_{1-x}Ca_xMnO_3$ films)

  • 김현탁;강광용
    • 한국초전도학회:학술대회논문집
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    • 한국초전도학회 1999년도 High Temperature Superconductivity Vol.IX
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    • pp.200-205
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    • 1999
  • In the ferromagnetic phase with electrons for La$_{1-x}$(Ca or Sr)$_x$MnO$_3$, films, a remnant resistivity of the order of 10$^{-8}$ ${\omega}$m is observed up to 100 K and increases exponentially with temperature up to T$_c$ and above one Tesla as a function of magnetic field strength (a positive magnetoresistivity). The phase below T$_c$ is regarded as a polaronic state with a polaronic tunneling conduction. Possible p-wave condensation (or superconductor) with a parabolic density of states and the phase separation are discussed on the basis of the two-fold degeneracy of ${\varrho}_{\delta}$ orbitals.

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카본을 부극으로 사용하는 $LiMnO_2$ 전지의 전기화학적 특성 (Charge/Discharge Characteristics of $LiMnO_2$ Battery using Carbon as Anode Materials)

  • 김은미;임승규;김남인;구할본
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
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    • pp.277-278
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    • 2008
  • Orthorhombic $LiMnO_2$(o-$LiMnO_2$) has attracted public attentions as a cathode materials of Lithium ion battery because it has low cost and high theoretical discharge capacity of 285mAh $g^{-1}$. In our study, o-$LiMnO_2$ is synthesized by quenching method. To verify their phase structure, X-ray diffraction is accomplished. Test cells are assembled to check electrochemical characteristics using acquired o-$LiMnO_2$ cathode and carbon anode. Charge/Discharge cycling was carried out for 50cycles. And impedance was measured at 1, 2, 5, 10, 30, 50cycle. During cycle test, the max discharge capacity was recorded 139mAh $g^{-1}$ at 10cycle.

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Investigation of LiO2 Adsorption on LaB1-xB'xO3(001) for Li-Air Battery Applications: A Density Functional Theory Study

  • Kwon, Hyunguk;Han, Jeong Woo
    • 한국세라믹학회지
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    • 제53권3호
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    • pp.306-311
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    • 2016
  • Li-air batteries have received much attention due to their superior theoretical energy density. However, their sluggish kinetics on the cathode side is considered the main barrier to high performance. The rational design of electrode catalysts with high activity is therefore an important challenge. To solve this issue, we performed density functional theory (DFT) calculations to analyze the adsorption behavior of the $LiO_2$ molecule, which is considered to be a key intermediate in both the Li-oxygen reduction reaction (ORR) and the evolution reaction (OER). Specifically, to use the activity descriptor approach, the $LiO_2$ adsorption energy, which has previously been demonstrated to be a reliable descriptor of the cathode reaction in Li-air batteries, was calculated on $LaB_{1-x}B^{\prime}_xO_3$(001) (B, B' = Mn, Fe, Co, and Ni, x = 0.0, 0.5). Our fast screening results showed that $LaMnO_3$, $LaMn_{0.5}Fe_{0.5}O_3$, or $LaFeO_3$ would be good candidate catalysts. We believe that our results will provide a way to more efficiently develop new cathode materials for Li-air batteries.

MBE growth and magnetic properties of epitaxial FeMn2O4 film on MgO(100)

  • Duong, Van Thiet;Nguyen, Thi Minh Hai;Nguyen, Anh Phuong;Dang, Duc Dung;Duong, Anh Tuan;Nguyen, Van Quang;Cho, Sunglae
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.318.2-318.2
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    • 2016
  • FeM2X4 spinel structures, where M is a transition metal and X is oxygen or sulfur, are candidate materials for spin filters, one of the key devices in spintronics. Both the Fe and M ions can occupy tetrahedral and octahedral sites; therefore, these types of compounds can display various physical and chemical properties [1]. On the other hand, the electronic and magnetic properties of these spinel structures could be modified via the control of cation distribution [2, 3]. Among the spinel oxides, iron manganese oxide is one of promising materials for applications. FeMn2O4 shows inverse spinel structure above 390 K and ferrimagnetic properties below the temperature [4]. In this work, we report on the structural and magnetic properties of epitaxial FeMn2O4 thin film on MgO(100) substrate. The reflection high energy electron diffraction (RHEED) and X-ray diffraction (XRD) results indicated that films were epitaxially grown on MgO(100) without the impurity phases. The valance states of Fe and Mn in the FeMn2O4 film were carried out using x-ray photoelectron spectrometer (XPS). The magnetic properties were measured by vibrating sample magnetometer (VSM), indicating that the samples are ferromagnetic at room temperature. The structural detail and origin of magnetic ordering in FeMn2O4 will be discussed.

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4-러시안 알고리즘 기반의 편집거리 병렬계산 (Parallel Computation For The Edit Distance Based On The Four-Russians' Algorithm)

  • 김영호;정주희;강대웅;심정섭
    • 정보처리학회논문지:컴퓨터 및 통신 시스템
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    • 제2권2호
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    • pp.67-74
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    • 2013
  • 근사문자열매칭 문제는 다양한 분야에서 연구되어 왔다. 최근에는 차세대염기서열분석의 비용과 시간을 줄이기 위해 빠른 근사문자열매칭 알고리즘들이 이용되고 있다. 근사문자열매칭은 문자열들의 오차를 측정하기 위해 편집거리와 같은 거리함수를 이용한다. 알파벳 ${\Sigma}$에 대한 길이가 각각 m, n인 두 문자열 X와 Y의 편집거리는 X를 Y로 변환하기 위해 필요한 최소 편집연산의 수로 정의된다. 두 문자열의 편집거리는 잘 알려진 동적프로그래밍을 이용하여 O(mn) 시간과 공간에 계산할 수 있으며, 4-러시안 알고리즘을 이용해서도 계산할 수 있다. 4-러시안 알고리즘은 블록 크기를 t라 할 때, 전처리 단계에서 $O((3{\mid}{\Sigma}{\mid})^{2t}t^2)$ 시간과 $O((3{\mid}{\Sigma}{\mid})^{2t}t)$ 공간이 필요하며, 계산 단계에서 O(mn/t) 시간과 O(mn) 공간을 이용하여 편집거리를 계산하는 알고리즘이다. 본 논문에서는 4-러시안 알고리즘의 계산 단계를 병렬화하고 실험을 통해 CPU 기반의 순차적 알고리즘과 CUDA로 구현한 GPU 기반의 병렬 알고리즘의 수행시간을 비교한다. 본 논문에서 제시하는 4-러시안 알고리즘의 계산단계는 m/t개의 쓰레드를 사용하여 O(m+n) 시간에 편집거리를 계산한다. GPU 기반의 알고리즘이 CPU 기반의 알고리즘 보다 t = 1일 때 약 10배 빠르고, t = 2일 때 약 3배 빠른 결과를 보였다.

Effects of Sulfur Substitution on Chemical Bonding Nature and Electrochemical Performance of Layered LiMn0.9Cr0.1O2-xSx

  • Lim, Seung-Tae;Park, Dae-Hoon;Lee, Sun-Hee;Hwang, Seong-Ju;Yoon, Young-Soo;Kang, Seong-Gu
    • Bulletin of the Korean Chemical Society
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    • 제27권9호
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    • pp.1310-1314
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    • 2006
  • Sulfur-substituted $LiMn_{0.9}Cr_{0.1}O_{2-x}S_x$ $(0\;\leq\;x\;\leq\;0.1)$ layered oxides have been prepared by solid state reaction under inert atmosphere. From powder X-ray diffraction analyses, all the present lithium manganates were found to be crystallized with monoclinic-layered structure. Electrochemical measurements clearly demonstrated that, in comparison with the pristine $LiMn_{0.9}Cr_{0.1}O_2$, the sulfur-substituted derivatives exhibit smaller discharge capacities for the entire cycle range but the recovery of discharge capacity after the initial several cycles becomes faster upon sulfur substitution. The effect of the sulfur substitution on the chemical bonding nature of $LiMn_{0.9}Cr_{0.1}O_{2-x}S_x$has been investigated using X-ray absorption spectroscopic (XAS) analyses at Mn and Cr K-edges. According to Mn K-edge XAS results, the trivalent oxidation state of manganese ion remains unchanged before and after the substitution whereas the local structure around manganese ions becomes more distorted with increasing the substitution rate of sulfur. On the other hand, the replacement of oxygen with sulfur has negligible influence on the local atomic arrangement around chromium ions, which is surely due to the high octahedral stabilization energy of $Cr^{+III} $ ions. Based on the present experimental findings, we have suggested that the decrease of discharge capacity upon sulfur substitution is ascribable to the enhanced structural distortion of $MnO_6$ octahedra and/or to the formation of covalent Li-S bonds, and the accompanying improvement of cyclability would be related to the depression of Mn migration and/or to the pillaring effect of larger sulfur anion.

주입성형법으로 제조된 Cordierite계 적외선 방사체의 열적특성에 미치는 $MnO_2$의 영향 (Effect of $MnO_2$ Additives on the Thermal Properties of Infrared Radiator of Cordierite System Fabricated by Slurry Casting Method)

  • 신용덕
    • 한국세라믹학회지
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    • 제32권7호
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    • pp.769-776
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    • 1995
  • Infrared radiators of a cordierite system [cordierite (2MgO.2Al2O3.5SiO2)+30wt% clay+X wt% MnO2 (X=0, 0.1, 0.25, 0.5, 1.0, 1.5, 2.0, 2.5)] were manufactured by a slurry casting method. Thermal and physical properties of these infrared radiators were studied by the measurement of spectra emissivity, thermal expansion coefficient and apparent density, SEM and EPMA analyses were also carried out. The thermal expansion coefficient and apparent density were decreased with increasing amouonts of MnO2 additives. On the other hand, the spectral emissivity was increased in the wavelength below 4.5${\mu}{\textrm}{m}$. Also, infrared radiators of the cordierite system, of which the spectral emisivity was 0.8, could be attainable in the wavelength above 4.5${\mu}{\textrm}{m}$. The infrared radiator of the cordierite system with 2.0wt% MnO2, of which the spectral emissivity was approximately 1.0, could be attainable in the wavelength between 4.5${\mu}{\textrm}{m}$ and 8${\mu}{\textrm}{m}$. The spectral emissivity of the specimen containing 2.0wt% MnO2 was higher than others in the wavelength between 8${\mu}{\textrm}{m}$ and 14${\mu}{\textrm}{m}$.

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