• Journal of the Korean Ceramic Society
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• v.31 no.9
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• pp.975-980
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• 1994

The thermal properties of cordierite (2MgO.2Al2O3.5SiO2)+30 wt% clay+ Xwt% MnO2 of infrared radiator have been investigated as a function of MnO2 additives (X=0,0.1,0.25,0.5,1.0,1.5,2.0,2.5). The thermal expansion coefficient was decreased with increasing amounts of MnO2 additives. Otherwise, the spectral emissivity was increased in the below 4.5 ${\mu}{\textrm}{m}$ wavelength. Also, the infrared radiator of cordierite system which spectral emissivity was approximately 1.0 can be attainable at from 4.5 ${\mu}{\textrm}{m}$ to 8 ${\mu}{\textrm}{m}$ wavelength. The spectral emissivity was decreased from 8 ${\mu}{\textrm}{m}$ to 14 ${\mu}{\textrm}{m}$ above X=2.5.

• The Transactions of the Korean Institute of Electrical Engineers
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• v.44 no.6
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• pp.799-805
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• 1995

An infrared radiator of cordierite system were manufactured byslurry casting anddry pressing method. The characteristics of cordierite (2MgO.2Al$_{2}$O$_{3}$.5SiO$_{2}$)+30wt% clay+Xwt% MnO$_{2}$ of infrared radiator have been investigated as a function of MnO$_{2}$ additives (X=0, 0.1, 0.25, 0.5, 1.0, 1.5, 2.0, 2.5). The thermal expansioncoefficient was decreased with increasing amounts of MnO$_{2}$ additives. Otherwise, the spectral emissivity was increased in the below 4.5.mu.m wavelength. Also, the infrared radiator of cordierite system which spectral emissivity was approximately 1.0 can be attainable at from 4.5.mu.m to 8.mu.m wavelength. The spectral emissivity was decreased from 8.mu.m to 14.mu.m above X=2.5.

• Proceedings of the Korean Magnestics Society Conference
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• 2002.12a
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• pp.102-103
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• 2002

LaMnO$_3$에 Ca을 치환한 Mn계 perovskite 구조(ABO3)의 물질에서 초거대자기저항 현상이 발견된 이후 R$_{1-x}$$^{3+}$ A$_{x}$$^{2+}$MnO$_3$(R=La, Nd, Pr: 희토류금속, A=Ca, Sr, Ba, Cd, Pb; 2가 양이온)계의 Mn 산화물의 연구가 고감도 자기 저항 센서와 자기기록 등의 활용가능성을 중심으로 활발히 진행되고 있다. 자기적 특성이 뛰어난 초거대자기저항물질에 대한 미시적인 자성에 대한 연구는 그 메커니즘이 복잡하고 다양한 접근방식에 따른다. (중략)

• Korean Journal of Materials Research
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• v.9 no.12
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• pp.1234-1239
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• 1999

Electromagnetic wave asorbing properties of the $Ni_{0.5}-Zn_{0.4}-X_{0.1}{\cdot}Fe_2O_4$, where X was replaced by substitution elements Cu, Mg, Mn, have been studied. The structure, shape, size and magnetic properties of the $Ni_{0.5}-Zn_{0.4}-X_{0.1}{\cdot}Fe_2O_4$ were analyzed by XRD, SEM, VSM. The relative complex permittivity, permeability, and electromagnetic wave absorbing properties were measured by Network Analyzer. The structure, shape, size and magnetization value of the $Ni_{0.5}-Zn_{0.4}-X_{0.1}{\cdot}Fe_2O_4$ were found to be similar in spite of substitution elements. The coercive force and hysteresis-loss showed maximum value when Mg was substituted for X. The dielectric loss(${\varepsilon}_r"/{\varepsilon}_r'$) was found to be maximum value when Mn was substituted for X. Also the magnetic loss(${\mu}_r"/{\mu}_r'$} was found to be maximum with Cu substitution. The electromagnetica wave absorbing property of the $Ni_{0.5}-Zn_{0.4}-X_{0.1}{\cdot}Fe_2O_4$-Rubber composite with 4mm thickness was excellent as over - 40dB at 9GHz, and the $Ni_{0.5}-Zn_{0.4}-X_{0.1}{\cdot}Fe_2O_4$-Rubber composite with 8mm thickness was over-40dB at 2GHz. Those composites also showed superior microwave absorbing properties.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2003.11a
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• pp.99-102
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• 2003

The electronic structure of ${\beta}-MnO_2$ having impurities in the site of Mn was theoretically investigated by $DV-X_{\alpha}$ (the discrete variation $X{\alpha}$) method, which is a sort of the first principle molecular orbital method using Hatre-Fock-Slater approximation. The used cluster model was $[Mn_{14}MO_{56}]^{-52}$ (M = transient metals). Madelung potential and spin polarization were considered for more exact calculations. As results of calculations, the energy levels of all electron included in the model were obtained. The energy band gap and positions of impurity levies were discussed in association with impurity 34 orbital that seriously affect electrical properties of $MnO_2$. It was shown that the energy band gap decreased with the increase of the atomic number of transient metal impurity.

• Journal of the Korean Electrochemical Society
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• v.15 no.2
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• pp.67-73
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• 2012

Spherical lithium manganese oxide spinel, $LiMn_{2-x}M_xO_4$ (M = Al, Mg, B) prepared by wet-milling, spray-drying, and sintering process has been investigated as a cathode material for lithium ion batteries. As-prepared powders exhibit various surface morphologies and internal density in terms of boron (B) doping level. It is found that the dopant B drives the growth of the primary particle and minimizes the surface area of the powder. As a result, the dopant enhances the internal density of the particles. Electrochemical tests demonstrated that the capacity of the synthesized material at 5 C could be maintained up to 90% of that at 0.2 C. The cycle performance of the material showed that the initial capacity was retained up to 80% even after 500 cycles under the high temperature of $60^{\circ}C$.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.07a
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• pp.386-387
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• 2005

anodic deposition법으로 제조된 $MnO_2$와 (Mn, Zn) 산화물의 전도도를 측정하였다. 제조된 Mn 산화물의 조성은 XRD와 EDS를 이용하여 $MnO_2$ 와 Mn 복합산화물로 확인되었다. DV-Xa법으로 계산된 이론 전자상태 계산 결과 천이금속을 첨가하게 되면, Mn 복합 산화물의 에너지 갭이 감소하는 것으로 나타났다. anodic deposition법으로 제조된 $MnO_2$와 Mn 복합 산화물의 전기전도도를 비교하면 천이금속이 첨가된 복합 산화물의 특성이 우수한 것으로 나타났다.

• Bulletin of the Korean Chemical Society
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• v.19 no.6
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• pp.661-666
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• 1998

Active reaction sites and electrochemical O2 reduction kinetics on La_{1-x}Sr_xMnO_{3+{\delta}} (x=0.1-0.4)/YSZ (yttria-stabilized zirconia) electrodes are investigated in the temperature range of 700-900 ℃ at $Po_2=10^{-3}$-0.21 atm. Results of the steady-state polarization measurements, which are formulated into the Butler-Volmer formalism to extract transfer coefficient values, lead us to conclude that the two-electron charge transfer step to atomically adsorbed oxygen is rate-limiting. The same conclusion is drawn from the $Po_2$-dependent ac impedance measurements, where the exponent m in the relationship of $I_o$ (exchange current density) ∝ $P_{o_{2}}^m$ is analyzed. Chemical analysis is performed on the quenched Mn perovskites to estimate their oxygen stoichiometry factors (δ) at the operating temperature (700-900 ℃). Here, the observed δ turns out to become smaller as both the Sr-doping contents (x) and the measured temperature increase. A comparison between the 8 values and cathodic activity of Mn perovskites reveals that the cathodic transfer coefficients $({\alpha}_c)$ for oxygen reduction reaction are inversely proportional to δ whereas the anodic ones $({\alpha}_a)$ show the opposite trend, reflecting that the surface oxygen vacancies on Mn perovskites actively participate in the $O_2$ reduction reaction. Among the samples of x= 0.1-0.4, the manganite with x=0.4 exhibits the smallest 8 value (even negative), and consistently this electrode shows the highest ${\alpha}_c$ and the best cathodic activity for the oxygen reduction reaction.

• Proceedings of the Materials Research Society of Korea Conference
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• 1994.11a
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• pp.109-109
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• 1994

• Proceedings of the Materials Research Society of Korea Conference
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• 1996.05a
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• pp.149-149
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• 1996