• Title/Summary/Keyword: $Mn^Ⅱ,Ⅲ$ cluster

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Nutrient Removal Hybrid Process to Use Suspended and Attached Growth Microorganisms and Apply the Contact and Stabilization Process (부유 및 부착성장 미생물을 이용한 접촉안정형 영양염류처리 하이브리드 공정)

  • Kim, Man-Soo;Park, Jong-Woon;Lee, Sang-Ill;Park, Chul-Whi
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.4
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    • pp.452-459
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    • 2007
  • Nutrient removal hybrid process to use suspended and attached growth microorganisms and apply the contact and stabilization process was process obtaining good results to HRT within 6 hours to dominate nitrifier and to promote separation and growth of autotrophs and heterotrophs to pack with EPS(Expanded Poly-Styrene) media in nitrification reactor. An average effluent quality of this process was below 5.2 mg/L, 7.3 mg/L, 4.9 mg/L as $BOD_5,\;COD_{Mn}$, SS concentration and 6.8 mg/L, 0.6 mg/L as T-N, T-P concentration. Also, An average removal efficiency of this process was 94.6%, 79.8%, 94.9% as $BOD_5,\;COD_{Mn}$, SS and 70.8%, 76.9% as T-N, T-P. 16S-rRNA analysis result of microorganisms attached to EPS media was researched Nitrosomonas and Nitrosococcus blown to ammonia-oxidizing bacteria cluster to include Gallionella and these microorganisms were researched to involve about 6% of biofilm attached EPS media. Consequently, this process was treated below 10 mg/L and 1.0mg/L as T-N, T-P concentration at short hydraulic retention time(about 6 hr) to dominate nitrifier.

Revealing the Paleo-ocean Environment of OSM-XX in the Western Pacific Magellan Seamount with Mineralogical and Geochemical Properties of Ferromanganese Crust (서태평양 마젤란해산군 OSM-XX 해저산 망간각의 광물학적, 지화학적 특성과 고해양 고환경 복원 연구)

  • Jinsub Park;Kiho Yang
    • Economic and Environmental Geology
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    • v.56 no.1
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    • pp.55-63
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    • 2023
  • Variations in geochemical and mineralogical properties of the ferromanganese(Fe-Mn) crust reflect environmental changes. In the present study, geochemical and mineralogical analyses, including micro X-ray fluorescence and X-ray diffraction, were utilized to reconstruct the paleo-ocean environment of western Pacific Magellan seamount cluster. Samples of the Fe-Mn crust were collected using an epibenthic sledge from the open seamount XX (151° 51.12' 7.2" E and 16° 8.16' 9.6" N, 1557 meters below sea level) in the Western Pacific Magellan Seamount. According to the structure and phosphating status, the Fe-Mn crust of the OSM-XX can be divided into the following: phosphatizated (L4-L5), massive non-phosphatizated (L3), and porous non-phosphatizated (L1-L2) portions. All ferromanganese layers contain vernadite, and owing to the presence of carbonate fluorapatite (CFA), the phosphatizated portion (L4-L5) is rich in Ca and P. The massive non-phosphatizated section (L3) contains high Mn, Ni, and Co, whereas the porous non-phosphatizated portion (L1-L2), which comprises detrital quartz and feldspar, is rich in Fe. Variations in properties of the Fe-Mn crust from the OSM-XX reflect changes in the nearby marine environment. The formation of this crust started at approximately 51.87 Ma, and precipitation of the CFA during the global phosphatization event that occurred at approximately 36-32 Ma highlights an elevated sea level and low temperature during the associated period. The high Mn, Ni, and Co concentrations and elevated Mn/Fe ratios of samples from the massive phosphatizated portion indicate that the oxygen minimum zone (OMZ) was enhanced, and reducing conditions prevailed during the crust formation. The high Fe and low Mn/Fe ratios in the porous portion indicate a weak OMZ and dominantly oxidizing conditions. These data reflect environmental changes following the end of the Mi-1 glacial period in the Miocene-Oligocene boundary. Subsequently, Mn/Fe and Co/Mn ratios increased slightly in the outermost part of Fe-Mn crust because of the enhanced bottom current and OMZ associated with the continued cooling from approximately 9 Ma. However, the reduced carbonate dissolution rate in the Pacific Ocean from approximately 6 Ma decreased the growth rate of the Fe-Mn crust.

Geochemical Characteristics of Groundwater for Dry and Rainy Seasons in Ddan-sum Island (갈수기와 홍수기의 김해 딴섬지역 지하수의 지구화학 특성)

  • Kim, Gyoobum;Jeon, Hangtak;Shin, Seonho;Park, Joonhyeong
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.9
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    • pp.31-44
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    • 2012
  • Seasonal changes in groundwater geochemistry exist in Ddan-sum island. In the farming season of April, the spatial distribution of ions explains that $Fe^{2+}$, Fe(total), $Mn^{2+}$, $Ca^{2+}$, $Mg^{2+}$, $SiO_2$, ${HCO_3}^-$, and ${NO_3}^-$ are high in the center of the island, but $Na^+$ and $K^+$ are relatively low and these high anions indicates the effect of fertilizer used for strawberry cultivation. Spatial variation of ion concentration is smaller in August than April because of low agricultural activity and heavy rainfall. Geochemical type of groundwater shows that the center of island has the characteristics of recharge zone but the rim area corresponds to a mixing zone between groundwater and stream water. According to the analysis of saturation index for Fe and Mn ions, hematite, goethite, and rhodochrosite under supersaturation have a possibility of additional mineral deposition, and siderite, $Fe(OH)_3$, manganite, pyrolusite, and pyrochroite under unsaturation may exist as a type of dissolved ion.

High-Speed Self-Organzing Map for Document Clustering

  • Rojanavasu, Ponthap;Pinngern, Ouen
    • 제어로봇시스템학회:학술대회논문집
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    • 2003.10a
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    • pp.1056-1059
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    • 2003
  • Self-Oranizing Map(SOM) is an unsupervised neural network providing cluster analysis of high dimensional input data. The output from the SOM is represented in map that help us to explore data. The weak point of conventional SOM is when the map is large, it take a long time to train the data. The computing time is known to be O(MN) for trainning to find the winning node (M,N are the number of nodes in width and height of the map). This paper presents a new method to reduce the computing time by creating new map. Each node in a new map is the centroid of nodes' group that are in the original map. After create a new map, we find the winning node of this map, then find the winning node in original map only in nodes that are represented by the winning node from the new map. This new method is called "High Speed Self-Oranizing Map"(HS-SOM). Our experiment use HS-SOM to cluster documents and compare with SOM. The results from the experiment shows that HS-SOM can reduce computing time by 30%-50% over conventional SOM.

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Classification of Ambient Particulate Samples Using Cluster Analysis and Disjoint Principal Component Analysis (군집분석법과 분산주성분분석법을 이용한 대기분진시료의 분류)

  • 유상준;김동술
    • Journal of Korean Society for Atmospheric Environment
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    • v.13 no.1
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    • pp.51-63
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    • 1997
  • Total suspended particulate matters in the ambient air were analyzed for eight chemical elements (Ca, Co, Cu, Fe, Mn, Pb, Si, and Zn) using an x-ray fluorescence spectrometry (XRF) at the Kyung Hee University - Suwon Campus during 1989 to 1994. To use these data as basis for source identification study, membership of each sample was selected to represent one of the well defined sample groups. The data sets consisting of 83 objects and 8 variables were initially separated into two groups, fine (d$_{p}$<3.3 ${\mu}{\textrm}{m}$) and coarse particle groups (d$_{p}$>3.3 ${\mu}{\textrm}{m}$). A hierarchical clustering method was examined to obtain possible member of homogeneous sample classes for each of the two groups by transforming raw data and by applying various distances. A disjoint principal component analysis was then used to define homogeneous sample classes after deleting outliers. Each of five homogeneous sample classes was determined for the fine and the coarse particle group, respectively. The data were properly classified via an application of logarithmic transformation and Euclidean distance concept. After determining homogeneous classes, correlation coefficients among eight chemical variables within all the homogeneous classes for calculated and meteorological variables (temperature. relative humidity, wind speed, wind direction, and precipitation) were examined as well to intensively interpret environmental factors influencing the characteristics of each class for each group. According to our analysis, we found that each class had its own distinct seasonal pattern that was affected most sensitively by wind direction.ion.

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Size Distribution and Source Identification of Airborne Particulate Matter and Metallic Elements in a Typical Industrial City

  • Ny, Mai Tra;Lee, Byeong-Kyu
    • Asian Journal of Atmospheric Environment
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    • v.4 no.1
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    • pp.9-19
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    • 2010
  • The size distribution of airborne particulate matter (PM) and the concentrations of associated metallic elements were investigated in a busy urban region of a typical Korean industrial city. The PM concentrations measured during the spring, except for those in the size range of 1.1 to 2.1 ${\mu}m$, were slightly higher than the PM concentrations in the summer. Coarse particles contributed greatly to the variation in PM concentrations in the spring, while fine and submicron particles contributed largely to the variation in PM concentrations in the summer. The difference in size modes of the PM concentrations between spring and summer may be explained by the Asian dust effect and its accompanying wind direction and speed. Extremely high enrichment factors (EFs) values (6,971 to 60,966) for all of the size distributions in PM were identified for cadmium (Cd). High EFs values (12 to 907) were also identified for other heavy metals including Cr, Cu, Ni, Pb, Zn and Mn. Low EF values (0.29 to 8.61) were identified for Ca, K, Mg and Na. These results support the common hypothesis that most heavy metals in ambient PM have anthropogenic sources and most light metals have crustal sources. The results of principal components analyses and cluster analyses for heavy metals indicate that the principal sources of PM and metals were emissions from non-ferrous metal smelters, oil combustion, incinerators, vehicular traffic and road dust.

Security Design for Efficient Detection of Misbehavior Node in MANET (MANET에서 비정상 노드를 효율적으로 탐지하기 위한 보안 설계)

  • Hwang, Yoon-Cheol
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.35 no.3B
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    • pp.408-420
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    • 2010
  • On a Mobile Ad hoc NETwork(MANET), it is difficult to detect and prevent misbehaviors nodes existing between end nodes, as communication between remote nodes is made through multiple hop routes due to lack of a fixed networked structure. Therefore, to maintain MANET's performance and security, a technique to identify misbehaving middle nodes and nodes that are compromise by such nodes is required. However, previously proposed techniques assumed that nodes comprising MANET are in a friendly and cooperative relationship, and suggested only methods to identify misbehaving nodes. When these methods are applied to a larger-scale MANET, large overhead is induced. As such, this paper suggests a system model called Secure Cluster-based MANET(SecCBM) to provide secure communication between components aperANET and to ensure eed. As such, this pand managems suapemisbehavior nodes. SecCBM consists apetwo stages. The first is the preventis pstage, whereemisbehavior nodes are identified when rANET is comprised by using a cluster-based hierarchical control structure through dynamic authentication. The second is the post-preventis pstage, whereemisbehavior nodes created during the course apecommunication amongst nodes comprising the network are dh, thed by using FC and MN tables. Through this, MANET's communication safety and efficiency were improved and the proposed method was confirmed to be suitable for MANET through simulation performance evaluation.

Li+ Extraction Reactions with Ion-exchange type Lithium Manganese Oxide and Their Electronic Structures (이온교환형 리튬망간산화물의 리튬이온 용출특성 및 전자상태)

  • Kim, Yang-Soo;Chung, Kang-Sup;Lee, Jae-Chun
    • Korean Journal of Materials Research
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    • v.12 no.11
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    • pp.860-864
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    • 2002
  • $Li^{+}$ extraction reactions with ion-exchange type lithium manganese oxide in an aqueous phase were examined using chemical and x-ray diffraction (XRD) analysis. In the process of extraction reaction, the lithium manganese oxide showed a topotactic extraction of $Li^{+ }$ in the aqueous phase mainly through an ion-exchange mechanism, and the $Li^{+}$ extracted samples indicated a high selectivity and a large capacity for $Li^{+}$ . The electronic structures and chemical bonding properties were also studied using a discrete variational (DV)-X$\alpha$ molecular orbital method with cluster model of (Li$Mn_{12}$ $O_{40}$ )$^{27-}$ for tetrahedral sites and ($Li_{7}$ Mn $O_{38}$ )$^{3}$ for octahedral site in $Li_{1.33}$ $Mn_{1.67}$ / $O_{4}$ respectively. Li in the manganese oxides is highly ionized in both sites, but the net charge of Li was greater for tetrahedral sites than octahedral. These calculations suggest that the tetrahedral sites have higher $Li^{+}$ $H^{+}$ exchangeability than the octahedral sites, and are preferable for the selective adsorption for L $i^{+}$ ions.s.

Chemical Properties of Indoor Individual Particles Collected at the Daily Behavior Spaces of a Factory Worker

  • Ma, Chang-Jin;Kang, Gong-Unn;Sakai, Takuro
    • Asian Journal of Atmospheric Environment
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    • v.11 no.2
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    • pp.122-130
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    • 2017
  • The main purpose of the study was to clarify the properties of individual particles collected at each behavior space of a factory worker. The samplings of size-segregated ($PM_{2.1-1.1}$ and $PM_{4.7-3.3}$) indoor particles were conducted at three different behavior spaces of a factory worker who is engaged in an auto parts manufacturing plant (i.e., his home, his work place in factory, and his favorite restaurant). Elemental specification (i.e., relative elemental content and distribution in and/or on individual particles) was performed by a micro-PIXE system. Every element detected from the coarse particulate matters of home was classified into three groups, i.e., a group of high net-counts (Na, Al, and Si), a group of intermediate net-counts (Mg, S, Cl, K, and Ca), and a group of minor trace elements (P, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, and Pb). The results of EF for $PM_{4.7-3.3}$ in home indicated that several heavy metals were generated from the sources within the house itself. An exceptional feature shown in the individual particles in workplace is that Cr, Mn, and Co were clearly detected in both fine and coarse particles. Cluster analysis suggested that the individual coarse particles ($PM_{4.7-3.3}$) collected at the indoor of factory were chemically heterogeneous and they modified with sea-salt, mineral, and artificially derived elements. The principal components in individual coarse particles collected at restaurant were sea-salt and mineral without mixing with harmful trace elements like chromium and manganese. Compared to the indoor fine particles of home and restaurant, many elements, especially, Cl, Na, Cr, Mn, Pb, and Zn showed overwhelmingly high net-counts in those of factory.

Evaluation of Water Quality Characteristics and Water Quality Improvement Grade Classification of Geumho River Tributaries (금호강 수계 지류하천의 수질 특성 평가 및 수질개선 등급화 방안)

  • Jung, Kang-Young;Ahn, Jung-Min;Kim, KyoSik;Lee, In Jung;Yang, Duk Seok
    • Journal of Environmental Science International
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    • v.25 no.6
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    • pp.767-787
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    • 2016
  • In this study, we analyzed on-site monitoring data for 15 tributaries in Geumho watersheds for 3 years (2011-2013) in order to sort out priorities on water quality characteristics and improvement. As a result of estimating contribution to contamination of the tributary rivers, Dalseocheon showed the highest load densities, despite the smallest watershed area, with 22.7% $BOD_5$, 30.7% $COD_{Mn}$, 31.3% TOC and 47.6% TP. After conducting PCA (principal component analysis) and FA (factor analysis) to analyze water quality characteristics of the tributary rivers, the first factor was classified as $COD_{Mn}$, TOC, EC, TP and $BOD_5$, the second factor as pH, Chl-a and DO, the third factor as water temperature and TN, and the fourth factor as SS and surface flow. In addition, arithmetical sum of each factor's scores based on grading criteria revealed that Dalseocheon and Namcheon were classified into Group A for their highest scores - 96 and 93, respectively -, and selected as rivers that require water environmental management measures the most. Also, water environmental contamination inspection showed that Palgeocheon had the most number of aquatic factors to be controlled: $BOD_5$, $COD_{Mn}$, SS, TOC, T-P, Chl-a, etc.