• 제목/요약/키워드: $MgO_24$

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레이저 열원을 이용한 마그네슘 합금의 용접성에 관한 연구 (II) - AZ31B-H24 및 AZ31B-O 레이저 용접부의 기계적 특성 - (A Study on the Weldability of Magnesium Alloy by Laser Heat Source (II) - Mechanical Properties of laser-welded AZ31B-H24 and AZ31B-O -)

  • 이정한;김종도;이문용
    • Journal of Welding and Joining
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    • 제30권6호
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    • pp.56-61
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    • 2012
  • Magnesium alloy sheet which is commercially available in the market presently is AZ31B, a Mg-Al-Zn three elements alloy. AZ31B is used by being classified into AZ31B-H24 and AZ31B-O depending on temper designation. In this study, AZ31B-H24 and AZ31B-O alloy sheets with 1.25mm thickness were butt-welded using CW Nd:YAG laser. And the effect of materials on mechanical properties was investigated by tensile and hardness tests. As a result of this study, regardless of materials, the butt-welded joint did not show a significant difference in tensile strength and hardness values. However, compared with the basemetal, the AZ31B-O showed more outstanding mechanical properties than AZ31B-H24, and that is because H24 material lost the effect of work hardening during welding.

Peroxidase and Photoprotective Activities of Magnesium Protoporphyrin IX

  • Kim, Eui-Jin;Oh, Eun-Kyoung;Lee, Jeong K.
    • Journal of Microbiology and Biotechnology
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    • 제24권1호
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    • pp.36-43
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    • 2014
  • Magnesium-protoporphyrin IX (Mg-PPn), which is formed through chelation of protoporphyrin IX (PPn) with Mg ion by Mg chelatase, is the first intermediate for the (bacterio)chlorophyll biosynthetic pathway. Interestingly, Mg-PPn provides peroxidase activity (approximately $4{\times}10^{-2}units/{\mu}M$) detoxifying $H_2O_2$ in the presence of electron donor(s). The peroxidase activity was not detected unless PPn was chelated with Mg ion. Mg-PPn was found freely diffusible through the membrane of Escherichia coli and Vibrio vulnificus, protecting the cells from $H_2O_2$. Furthermore, unlike photosensitizers such as tetracycline and PPn, Mg-PPn did not show any phototoxicity, but rather it protected cell from ultraviolet (UV)-A-induced stress. Thus, the exogenous Mg-PPn could be used as an antioxidant and a UV block to protect cells from $H_2O_2$ stress and UV-induced damage.

개질 고로 슬래그에 관한 연구 (유리 제조에 관한 연구) (Effects of Processed Slag as Glassmaking Raw Material (on Soda-Lime Glass))

  • 양중식
    • 한국세라믹학회지
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    • 제18권2호
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    • pp.112-118
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    • 1981
  • A study was made on the processing of domestic blast furnace slag by flotation and chemical purification for the use of slag as a raw material in making soda lime glasses. Feasibility study has been made for the use of reprocessing slag as a source material for both coloring and chemical components (such as CaO, $Al_2O_3$, MgO and etc.) in the glass making process. Chemical composition of chemically purified slags ranges; $SiO_2$ 34.5~37.5, $Al_2O_3$, 16.2~14.1, $Fe_2O_3$ 0.33~0.14, CaO 34.5~38.8, MgO 4.0~5.2, NmO 0.16~0.39, $TiO_2$ 0.23~0.35, S 0.08~0.42, ignition loss 3.3~8.4 and others 0.48~0.51%. It was found that either amber or greenish color could be easily obtained with the addition of salg up to 24%, however the slag addition to glass batches much impaired the transmitancy of glass products, thus a glass made with 7% slag addition showed 82% in transmitancy value at 510 nm.

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Efficient Isolation of Dihydrophaseic acid 3'-O-β-D-Glucopyranoside from Nelumbo nucifera Seeds Using High-performance Countercurrent Chromatography and Reverse-phased High-performance Liquid Chromatography

  • Rho, Taewoong;Yoon, Kee Dong
    • Natural Product Sciences
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    • 제24권4호
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    • pp.288-292
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    • 2018
  • High-performance countercurrent chromatography (HPCCC) coupled with reversed-phase highperformance liquid chromatography (RP-HPLC) method was developed to isolate dihydrophaseic acid 3'-O-${\beta}$-D-glucopyranoside (DHPAG) from the extract of Nelumbo nucifera seeds. Enriched DHPAG sample (2.3 g) was separated by HPCCC using ethyl acetate/n-butanol/water system (6:4:10, v/v/v, normal-phase mode, flow rate: 4.0 mL/min) to give 23.1 mg of DHPAG with purity of 88.7%. Further preparative RP-HPLC experiment gave pure DHPAG (16.3 mg, purity > 98%). The current study demonstrates that utilization of CCC method maximizes the isolation efficiency compared with that of solid-based conventional column chromatography.

사천만의 해수 및 표층 퇴적물의 세균학적 및 이화학적 특성 (Bacteriological and Physiochemical Quality of Seawater and Surface Sediments in Sacheon Bay)

  • 박준용;김영인;배기성;오광수;최종덕
    • 농업생명과학연구
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    • 제44권2호
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    • pp.7-15
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    • 2010
  • 이 연구는 2009년 1월부터 9월까지 총 4회(1월, 4월, 7월 9월) 사천만에서 해수와 표층퇴적물의 세균학적 이화학적 특성을 조사한 것이다. 조사기간 중에 수온은 $5.3{\sim}24.9^{\circ}C$(평균 $17.7{\pm}0.4^{\circ}C$), 투명도는 1.4~2.5m(평균 $1.8{\pm}0.5m$), 부유물질 농도는 16.2~35.8mg/L(평균 $24.2{\pm}2.2mg/L$), 화학적산소요구량 (COD)는 $1.42{\sim}3.29mgO_2/L$(평균 $2.06{\pm}0.55mgO_2/L$), 용존산소(DO)는 6.7~9.5mg/L(평균 $7.9{\pm}0.6mg/L$)로 각각 조사되었다. 대장균군과 분변계대장균의 검출 범위는 <1.8~7,900 MPN/100mL (GM 214.7 MPN/100mL)과 <1.8~330 MPN/ 100mL (GM 9.7 MPN/100mL)로 각각 나타났다. 대장균군은 시료의 75.0%, 분변계대장균은 57.1%가 각각 양성을 나타내었다. 대장균군에 대한 분변계대장균의 양성율은 76.2%로 나타났다. 조사기간 중에 사천만에서의 표층퇴적물의 수분함량, 강열감량, COD 및 AVS의 평균값은 $53.28{\pm}2.58%$, $9.38{\pm}0.42%$, $14.23{\pm}3.36mgO_2/g$, $0.09{\pm}0.07mgS/g$로 각각 조사되었다.

Determination of Initial Denitrification in Intact Cores under Various Freshwater Wetland Types

  • Seo, Dong-Cheol;Delaune, R.D.;Lane, Robert R.;Day, John W.
    • 한국토양비료학회지
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    • 제45권1호
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    • pp.20-24
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    • 2012
  • Denitrification rate was determined for various freshwater wetland types in the Mississippi River Coastal delta plain. Site 1 and 4 were collected from forested-tupelo dominated wetland, and site 2 and 3 were from floating emergent marsh. The maximum $N_2O$ emission was $7.47mg\;N\;m^{-2}$ for site 1 at day 6 after the addition of nitrate, $6.96mg\;N\;m^{-2}$ for site 2 at day 4, $6.63mg\;N\;m^{-2}$ for site 3 at day 3, and $9.64mg\;N\;m^{-2}$ for site 4 at day 4. The denitrification rate was determined using the acetylene inhibition method $1.24mg\;N\;m^{-2}d^{-1}$ for site 1, $1.93mg\;N\;m^{-2}d^{-1}$ for site 2, $2.24mg\;N\;m^{-2}d^{-1}$ for site 3, and $2.78mg\;N\;m^{-2}d^{-1}$ for site 4. The maximum denitrification rate was in the order of site 4 > site 3 > site 2 > site 1.

공진법 기반의 [011] 분극 Pb(In1/2Nb1/2)O3-Pb(Mg1/3Nb2/3)O3-PbTiO3 압전단결정 물성규명 (Characterization of [011] Poled Pb(In1/2Nb1/2)O3-Pb(Mg1/3Nb2/3)O3-PbTiO3 Single Crystals by Resonance Method)

  • 제엽;심민섭;조요한;이원옥;이상구;이정민;서희선
    • 한국전기전자재료학회논문지
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    • 제34권6호
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    • pp.466-474
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    • 2021
  • [011] poled ternary Pb(In1/2Nb1/2)O3-Pb(Mg1/3Nb2/3)O3-PbTiO3 (PIN-PMN-PT) single crystals have been investigated for active materials for acoustic transducers because of their high piezoelectric properties in both shear and transverse modes. In order to use [011] poled PIN-PMN-PT single crystals for acoustic transducers, the characterization of full-matrix material properties is required. In this study, full sets of compliance, dielectric, and piezoelectric constants of [011] poled rhombohedral PIN-PMN-PT were measured by a resonance method. Dimensions and geometries of 12 samples were proposed for measuring 17 independent material constants of [011] poled rhombohedral PIN-PMN-PT single crystals. Two sets of samples with different PT concentrations, 0.24PIN-0.49PMN-0.27PT and 0.24PIN-0.46PMN-0.30PT, were fabricated and their material properties were measured. Measured impedance spectra and simulated impedance spectra of the samples were compared to check the accuracy of the measurements.

금속환원법에 의한 바나듐 분말 추출 (Extraction of Vanadium Powder by Metallothermic Reduction)

  • 이동원;허상현;염종택;왕제필
    • 한국분말재료학회지
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    • 제20권1호
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    • pp.43-47
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    • 2013
  • The extraction of metallic pure vanadium powder from raw oxide has been tried by Mg-reduction. In first stage, $V_2O_5$ powders as initial raw material was reduced by hydrogen gas into $V_2O_3$ phase. $V_2O_3$ powder was reduced in next stage by magnesium gas at 1,073K for 24 hours. After reduction reaction, the MgO component mixed with reduced vanadium powder were dissolved and removed fully in 10% HCl solution for 5 hours at room temperature. The oxygen content and particle size of finally produced vanadium powders were 0.84 wt% and 1 ${\mu}m$, respectively

Brief low [Mg2+]o-induced Ca2+ spikes inhibit subsequent prolonged exposure-induced excitotoxicity in cultured rat hippocampal neurons

  • Kim, Hee Jung;Yang, Ji Seon;Yoon, Shin Hee
    • The Korean Journal of Physiology and Pharmacology
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    • 제20권1호
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    • pp.101-109
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    • 2016
  • Reducing $[Mg^{2+}]_o$ to 0.1 mM can evoke repetitive $[Ca^{2+}]_i$ spikes and seizure activity, which induces neuronal cell death in a process called excitotoxicity. We examined the issue of whether cultured rat hippocampal neurons preconditioned by a brief exposure to 0.1 mM $[Mg^{2+}]_o$ are rendered resistant to excitotoxicity induced by a subsequent prolonged exposure and whether $Ca^{2+}$ spikes are involved in this process. Preconditioning by an exposure to 0.1 mM $[Mg^{2+}]_o$ for 5 min inhibited significantly subsequent 24 h exposure-induced cell death 24 h later (tolerance). Such tolerance was prevented by both the NMDA receptor antagonist D-AP5 and the L-type $Ca^{2+}$ channel antagonist nimodipine, which blocked 0.1 mM $[Mg^{2+}]_o$-induced $[Ca^{2+}]_i$ spikes. The AMPA receptor antagonist NBQX significantly inhibited both the tolerance and the $[Ca^{2+}]_i$ spikes. The intracellular $Ca^{2+}$ chelator BAPTA-AM significantly prevented the tolerance. The nonspecific PKC inhibitor staurosporin inhibited the tolerance without affecting the $[Ca^{2+}]_i$ spikes. While $G{\ddot{o}}6976$, a specific inhibitor of $PKC{\alpha}$ had no effect on the tolerance, both the $PKC{\varepsilon}$ translocation inhibitor and the $PKC{\zeta}$ pseudosubstrate inhibitor significantly inhibited the tolerance without affecting the $[Ca^{2+}]_i$ spikes. Furthermore, JAK-2 inhibitor AG490, MAPK kinase inhibitor PD98059, and CaMKII inhibitor KN-62 inhibited the tolerance, but PI-3 kinase inhibitor LY294,002 did not. The protein synthesis inhibitor cycloheximide significantly inhibited the tolerance. Collectively, these results suggest that low $[Mg^{2+}]_o$ preconditioning induced excitotoxic tolerance was directly or indirectly mediated through the $[Ca^{2+}]_i$ spike-induced activation of $PKC{\varepsilon}$ and $PKC{\xi}$, JAK-2, MAPK kinase, CaMKII and the de novo synthesis of proteins.

잉여슬러지의 오존분해에 따른 VFA의 생성 및 인 방출을 위한 탄소원으로의 재이용 가능성에 관한 연구 (The Study on Ozone Treatment of Wasting Activated Sludge for VFA Production and Reuse as Carbon Source for Phosphorus Release)

  • 고은택;조진우;박은영;안규홍
    • 대한환경공학회지
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    • 제27권10호
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    • pp.1052-1057
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    • 2005
  • 본 연구에서는 오존분해 된 슬러지를 인 방출을 위한 외부 탄소원으로 사용하기 적절한지 평가하기 위하여 오존 주입량 변화에 따라 오존분해된 슬러지의 성상변화와 함께 인 방출 실험 및 VFA(Volatile Fatty Acid) 생성량을 살펴보았다. 슬러지를 오존 주입량 0.5 g $O_3/g$ SS로 분해했을 경우 TCOD(Total Chemical Oxygen Demand)와 TSS(Total Suspended Solid)는 오존분해 전 7050, 4900 mg/L에서 5850, 2867 mg/L로 각각 17, 41% 감소하였다. 또한, pH는 6.6에서 3.8로 감소하였고, SCOD(Soluble Chemical Oxygen Demand)는 38.7 mg/L에서 2760 mg/L로 약 70배 증가함을 보였다. 오존 분해에 의해 acetic acid와 같은 VFA도 새로이 생성됨을 확인하였다. Acetic acid의 경우 0.05 g $O_3/g$ SS로 분해된 슬러지에서 50.24 mg/L가 생성되었으며, 0.5 g $O_3/g$ SS로 분해된 슬러지의 경우는 123.56 mg/L로 증가되었다. 그러나 혐기성 소화에 의한 VFA의 증가량은 0.05 g $O_3/g$ SS로 분해된 슬러지에서 Acetic acid가 50.24 mg/L에서 219.28 mg/L로 가장 많이 증가되었다. 또한 낮은 오존 주입량(0.05, 01 g $O_3/g$ SS)으로 분해된 슬러지에서 관찰되지 않았던 Propionic acid는 46 mg/L가 새로이 증가하였다. 그 외 혐기성 소화로 인해 n-Butyric Acid, Propionic Acid, n-Butyric Acid, Isovaleric Acid, Valleric Acid의 농도도 증가하였다. 오존 주입량에 따라 SCOD, VFA의 농도는 증가하지만 인 방출 속도 및 경제성을 고려하여 적정 오존 주입 농도는 0.05-0.1 g $O_3/g$ SS로 조사되었다.