• Title/Summary/Keyword: $MgO_24$

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Application of Photocatalytic Degradation for Efficient Treatment of Organic Matter in Landfill Leachate in Jeju Island (제주도 매립장 침출수 중 유기물의 효율적 처리를 위한 광촉매 분해 반응의 응용)

  • Lee, Chang-Han;Lee, Taek-Kwan;Cho, Eun-Il;Kam, Sang-Kyu
    • Journal of Environmental Science International
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    • v.31 no.8
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    • pp.677-689
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    • 2022
  • In order to photocatalytically treat organic matter (CODCr) and chromaticity effectively, chemical coagulation and sedimentation processes were employed as a pretreatment of the leachate produced from landfill in Jeju Island. This was performed using FeCl3·6H2O as a coagulant. For the treated leachate, UV/TiO2 and UV/TiO2/H2O2 systems were investigated, using 4 types of UV lamps, including an ozone lamp (24 W), TiO2 as a photocatalyst, and/or H2O2 as an initiator or inhibitor for photocatalytic degradation. In the chemical coagulation and sedimentation process using FeCl3·6H2O, optimum removal was achieved with an initial pH of 6, and a coagulant dosage of 2.0 g/L, culminating in the removal of 40% CODCr and 81% chromaticity. For the UV/TiO2 system utilizing an ozone lamp and 3 g/L of TiO2, the optimum condition was obtained at pH 5. However, the treated CODCr and chromaticity did not meet the emission standards (CODCr: 400 mg/L, chromaticity: 200 degrees) in a clean area. However, for a UV/TiO2/H2O2 system using 1.54 g/L of H2O2 in addition to the above optimum UV/TiO2 system, the results were 395 mg/L and 160 degrees, respectively, which were within the emission standard limits. The effect of the UV lamp on the removal of CODCr, and chromaticity of the leachate decreased in the order of ozone (24 W) lamp > 254 nm (24 W) lamp > ozone (14 W) lamp > 254 nm (14 W) lamp. Only CODCr and chromaticity treated with the ozone (24 W) lamp met the emission standards.

Characterization of Fly Ash Produced from a Sewage Sludge Incineration Facility in Korea (국내 하수슬러지 소각시설에서 발생되는 비산재의 특성 분석)

  • Kim, Seong-beom;Lee, Wontae
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.2
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    • pp.96-99
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    • 2016
  • This study characterized fly ash produced from a sewage sludge incineration facility in Korea to determine if the byproducts can be utilized. All the incinerated sewage sludge was from a city in Korea. To characterize fly ash and to determine if it can be utilized, pH, water contents, elemental components, particle size, surface morphology, heavy metal compositions, and others were analyzed. In average, pH was 6.2, and water contents was about 5%. T-N and $T-P_2O_5$ were 3% and 24.5%, respectively. Particle size averaged 836 nm; surface morphology did not exhibit any significant results. X-ray diffraction (XRD) analysis results revealed that major components of the fly ash were $P_2O_5$, CaO, MgO, $K_2O$. Composition of heavy metals by the Korea Standard Methods for Waste Quality did not exceed the criteria for specified wastes in Korea.

Study on the Nicotine-Degrading Bacteria(2) -The Optimal Growth Condition of Nicotinophiles- (니코틴 분해 세균에 관한 연구(2) -니코틴 분해 세균의 최적 생장조건 연구-)

  • 강은희
    • Journal of the Korean Society of Tobacco Science
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    • v.2 no.2
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    • pp.20-37
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    • 1980
  • Among the 34 strains of Nicotinophiles selected in the previous experiments, strain NCT27 identified with Pseudomonas putida and strain NCT30 identified with Arthrobacter oxydans biotype nan thus were Investigated for optimization of growth conditions for nicotine degradation and other cultural characteristics. The compositions of optimized medium were to be following: $KH_2PO_4$ 2.Ogr, KCI 5.Ogr, $MgSO_4$.$7H_2O$ 20mg, $MnSO_4$.$6H_2O$ 0.2mg, $FeSO_4$.$7H_2O$ 1.Omg, Col$^{++}$ (Cobalt Acetate),2.O$\gamma$, N1$^{++}$ (NiSO4,6H2O) 0.5$\gamma$, and yeast extract 80mg per liter. The optimum initial concentrations of nicotine for growth were 0.4% for Pseudomonas and 0.1% for Arthrobacter, respectively. The optimum temperature and pH were 3$0^{\circ}C$ and 7.0 for both of strains. The pH of culture medium of Pseudomonas was changed from acidic condition to basic one in going from the logarithmic growth phase to the stationary growth phase. In contrast with Pseudomonas, it remained constant in case of Arthrobacter. The growth of Arthrobacter was completely inhibited in the nicotine concentration of 0.7&. However, Pseudomonas could grow even in the nicotine concentration of 1.0%. Moreover, it could grow successfully in the tobacco extract media as well as media containing carbon and nitrogen sources other than nicotine. The maximum rates of nicotine degradation were to be 1.22 gr./hr./liter for Pseudomonas and 0.186 gr./hr./liter for Arthrobacter, respectively.

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Optimization of Fabrication Conditions for Immunosensor Strip to Detect Escherichia coli O157 : H7 (Escherichia coli O157 : H7 탐지용 면역센서스트립 제작 조건 최적화)

  • Park, So-Jung;Kim, Young-Kee
    • KSBB Journal
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    • v.24 no.3
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    • pp.253-258
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    • 2009
  • In this study, the optimization of fabrication conditions was accomplished to make immuno-strip biosensor by the combination of enzyme linked immunosorbent assay (ELISA) and immuno-chromatographic strip techniques for the detection of Escherichia coli O157 : H7. Optimal fabrication conditions of capture antibody concentration, detection antibody concentration, and additive composition of running buffer solution were determined. Optimal concentration was determined as 1.0 mg/mL for both of capture antibody and detection antibody. A composition of 0.5% Tween20 and 3% BSA were selected as optimal additive for buffer solution to prevent non-specific binding.

Removal of toxic hydroquinone: Comparative studies on use of iron impregnated granular activated carbon as an adsorbent and catalyst

  • Tyagi, Ankit;Das, Susmita;Srivastava, Vimal Chandra
    • Environmental Engineering Research
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    • v.24 no.3
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    • pp.474-483
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    • 2019
  • In this study, iron (Fe) impregnated granular activated carbon (Fe-GAC) has been synthesized and characterized for various properties. Comparative studies have been performed for use of Fe-GAC as an adsorbent as well as a catalyst during catalytic oxidation of hydroquinone (HQ). In the batch adsorption study, effect of process parameter like initial HQ concentration ($C_o=25-1,000mg/L$), pH (2-10), contact time (t: 0-24 h), temperature (T: $15-45^{\circ}C$) and adsorbent dose (w: 5-50 g/L) have been studied. Maximum HQ adsorption efficiency of 75% was obtained at optimum parametric condition of: pH = 4, w = 40 g/L and t = 14 h. Pseudo-second order model best-fitted the HQ adsorption kinetics whereas Langmuir model best-represented the isothermal equilibrium behavior. During oxidation studies, effect of various process parameters like initial HQ concentration ($C_o:20-100mg/L$), pH (4-8), oxidant dose ($C_{H2O2}:0.4-1.6mL/L$) and catalyst dose (m: 0.5-1.5 g/L) have been optimized using Taguchi experimental design matrix. Maximum HQ removal efficiency of 83.56% was obtained at optimum condition of $C_o=100mg/L$, pH = 6, $C_{H2O2}=0.4mL/L,$ and m = 1 g/L. Overall use of Fe-GAC during catalytic oxidation seems to be a better as compared to its use an adsorbent for treatment of HQ bearing wastewater.

Rapid Fermentation Starter Enterococcus faecium of Soybean for Soy-Sauce Like Product (간장태 신속 대두발효 종균으로의 Enterococcus faecium)

  • Lee, Young-Duck;Park, Jong-Hyun
    • The Korean Journal of Food And Nutrition
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    • v.25 no.1
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    • pp.188-195
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    • 2012
  • To produce rapidly the traditional Kanjang soy sauce-like product with rich flavors, lactic acid bacteria of Enterococcus spp. isolated from Chungkukjang was used as one of starter cultures. Among 119 Enterococcus spp., eight strains were selected by protease-secreting activities and identified as four E. faecium, three E. faecalis, and one E. gallinarium. The strains showed low resistances toward eight antibiotics and had no resistant genes to the vancomycin. Especially, E. faecium O24 was cultivated well on 5% NaCl medium that was selected for further study as the starter. E. faecium O24 grew well on the steamed soybean and the counts increased by ten times overnight, which produced mostly 80 mg% glutamic acid and aspartic acid as the seasoning amino acids on the product. Various organic acids including principal lactic acid were also produced. Flavors of maltol and guaiacol, typical soy-sauce flavor, were produced in the mixed cultures of Zygosaccharomyces rouxii and Candida versatilis. Therefore, E. faecium O24 could be a starter of soybean fermentation for soy sauce-like product with rich flavors rapidly.

Effect of Lead Free Glass Frit Compositions on Properties of Ag System Conductor and RuO2 Based Resistor Pastes (Ag계 도체 및 RuO2계 저항체 페이스트의 특성에 미치는 무연계 글라스 프릿트 조성의 영향)

  • Koo, Bon-Keup
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.3
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    • pp.200-207
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    • 2011
  • Abstract: The effect of lead free glass frit compositions on the properties of thick film conductor and resistor pastes were investigated. Two types lead free frits, HBF-A(without $Bi_2O_3$) and HBF-B(with $Bi_2O_3$) were made from $SiO_2$, $B_2O_3$, $Al_2O_3$, CaO, MgO, $Na_2O$, $K_2O$, ZnO, MnO, $ZrO_2$, $Bi_2O_3$. And Ag based conductor pastes and $RuO_2$ based resistor paste were prepared by mixed with these frits and functional phase(Ag and $RuO_2$), and organic vehicle. The properties of thick film conductor and resistor sintered at $850^{\circ}C$ were studied after printing on $Al_2O_3$ substrate. The morphology of the sintered films surface were SEM and EDS were carried out to analysis the chemical composition on resistor surface and state of Ru atom in frit matrix.

Effect of Germanium Treatment on Growth and Production of Organic Germanium in Oplopanax elatus (게르마늄 처리에 따른 땃두릅나무의 생육 증진 효과 및 유기게르마늄 생산)

  • Kim, Hee Young;Seong, Eun Soo;Yoo, Ji Hye;Choi, Jae Hoo;Kang, Byeong Ju;Jeon, Mi Ran;Kim, Myong Jo;Yu, Chang Yeon
    • Korean Journal of Medicinal Crop Science
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    • v.24 no.3
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    • pp.214-221
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    • 2016
  • Background: This study was conducted to investigate the effects of germanium treatment on the growth and organic germanium production in the roots of Oplopanax elatus plantlets. Methods and Results: O. elatus plantlets were cultured in Murashige and Skoog (MS) medium with different concentrations of germanium dioxide ($GeO_2$) to analyze optimum growth conditions. Exogenous treatment of $10mg/{\ell}\;GeO_2$ promoted growth and an increase in the contents of chlorophyll a, b and carotenoid in O. elatus. The germanium accumulation and production in roots of O. elatus plantlets treated with organic germanium reached the highest levels. The growth of the aerial and underground portion of O. elatus with organic germanium was greater than that of the control. The accumulation and production of organic germanium reached the highest level ($40.89{\mu}g/plantlet$) with the treatment of $50mg/{\ell}\;GeO_2$. Antioxidant activity measured by DPPH and ABTS assays also increased with the germanium treatment and improved the DPPH and ABTS radical activity by 200% compared with that in the control. In addition, the total phenol and flavonoid contents of the plantlets with a treatment of $50mg/{\ell}\;GeO_2$ were higher than in the control. Conclusions: Taken together, the growth of O. elatus was increased with the treatment of $50mg/{\ell}\;GeO_2$ germanium and the biological references improved, with increased antioxidant activity and organic germanium production.

Production of Nucleotide by Immobilized Cell (고정화 미생물에 의한 뉴크레오타이드 생산)

  • CHO Jung-Il;JUNG Sung-Won
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.24 no.2
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    • pp.111-116
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    • 1991
  • The effective p.eduction of 5'-GMP(5'-Guanylic acid) by enzymatic conversion of 5'-XMP(5'-Xanthyic acid) was investigated. The Iyophilized Brevibacterium ammoniagenes ATCC 19216 which were used as the XHP aminase source, was immobilized by entrapping in K-carrageenan, agar, polyacrylamide or Ca-alginate. $3\%$ K-carrageenan was selected as the most suitable matrix. In the production of 5'-GMP using the free cells of 3. ammoniagenes ATCC 19216, the optimum conditions were $42^{\circ}C$, PH 7.0, 100mg/ml glucose, 120mg/ml cell ,8mg/ml $MgSO_4\cdot7H_2O$, 5mg/ml POESA, 5mg/ml phytic acid. Under the conditions, $94.5\%$ of 5'-GMP was converted within 8 hours. In the production of 5'-GMP using the immobilized whole cells of B. ammoniagenes ATCC 19216, the optimum conditions were $37^{\circ}C$, pH 7.5, 50mg/ml glucose, 1mg/ml $KH_2PO_4$, 10mg/ml phytic acid, 60mg/ml cell, 8mg/ml $MgSO_4\;\cdot\;7H_2O$, 5mg/ml POESA. Under the conditions, $64.7\%$ of 5'-GMP was converted within 40 hours.

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Sewage Treatment Using a Double Media Reed Constructed Wetland (복층여재 갈대 인공습지에 의한 생활하수 처리)

  • Seo, Jeoung-Yoon
    • Journal of Wetlands Research
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    • v.16 no.4
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    • pp.379-388
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    • 2014
  • A sewage was treated using a serially combined vertical(VFCW) and horizontal flow double media (sand and zeolite for VFCW and sand and waste oyster-shell for HFCW) reed constructed wetland(HFCW) with intermittent feeding (see Fig. 1). The sewage was fed into the reed constructed wetland for 10 minutes every 6 hours at the hydraulic load of $314L/m^2{\cdot}day$. The summarized results were as follows: pH values in the effluent depended very heavily on oyster-shell height filled in the HFCW. They were maintained at less than pH 6.24 when the height of the oyster-shell layer was 200 mm. Influent DO(oxygen demand) values(average 0.19 mg/L) were increased in the VFCW(average 7.65 mg/L) and decreased again in the HFCW(average 6.49 mg/L). They were higher in the winter than in the summer. The OTR(oxygen transfer rate) was $57.15g\;O_2/m^2{\cdot}day$ in the VFCW and $5.65g\;O_2/m^2{\cdot}day$ in the HFCW. The removal efficiency of $NH_4{^+}$-N was 80.17%(6.01 $NH_4{^+}$-N mg/L in the effluent). It was lower than that in the case where only zeolite was filled in the reed constructed wetland. But it was expected that treated sewage effluent using a double media reed constructed wetland with 300 mm zeolite layer could stably meet the Korean treated sewage effluent standard(20 mg T-N/L). Average removal efficiencies were SS 88.09%, BOD 88.12%, $COD_{Cr}$ 83.11%, $COD_{Mn}$ 85.58%, T-N 57.21%, $NH_4{^+}$-N 80.17%, T-P 86.73%. Nearly, The concentration of $NO_3{^-}$-N in the effluent of the VFCW was decreased in that of the HFCW. More than half of T-N in the effluent was $NO_3{^-}$-N(7.92 mg/L) but the concentration of $NO_2{^-}$-N in the effluent was average 0.90 mg/L. The removal efficiencies of T-P were 93.24%, 86.30% and 55.44% at the height of the oyster-shell-filled constructed wetland of 800 mm, 500 mm and 200 mm, respectively and therefore, they were proportional to oyster-shell height filled in the HFCW.