• Title/Summary/Keyword: $M_7C_3$

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A study on the effects of additives and sintering temperature on isotropic and anisotropic characteristics of $SrO-5.7Fe_2O_3$ ($SrO-5.7Fe_2O_3$ 페라이트의 등방성 및 이방성 특성에 미치는 소결온도와 첨가제의 영향)

  • 송준태;신용덕;진홍범
    • Electrical & Electronic Materials
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    • v.3 no.4
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    • pp.306-314
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    • 1990
  • SrO-5.7Fe$_{2}$O$_{3}$의 Magnetoplumbite형 Sr페라이트에 첨가제 SiO$_{2}$, H$_{3}$BO$_{3}$CaCO$_{3}$, SrCO$_{3}$을 0.1-0.1wt%로 변화시켜 만든 등방성과 이방성의 자기이력곡선, 밀도, 감자곡선, 고유보자력 및 미세구조특성에 미치는 영향을 조사하였다. 위 첨가제는 페라이트 생성 및 특성개선에 효과적이었도 특히 등방성에서의 입도크기를 3.5.mu.m에서 1.7.mu.m로 하였을때 소결온도가 40.deg.C 낮은 1220.deg.C에서 잔류자속밀도가 2300G, 보자력이 1950Oe, 밀도가 4.51g/Cm$^{3}$, 교유보자력이 3500Oe로 각각 증가하였다. 이방성은 등방성 보다 원등히 우수하였고 최대에너지적 (BH)$_{max}$이 소결온도가 10.deg.C 낮은 1210.deg.C에서 1.13으로 부터 3.3MGOe로 증가하였다. 이값은 이론치의 61%에 도달하고 있다.

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A Study of Calcium Phosphate Crystal Phases Prepared from Oyster Shells (굴 껍질로부터 제조된 calcium phosphate 결정상에 관한 연구)

  • Ryu, Su Chak
    • Korean Journal of Materials Research
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    • v.13 no.4
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    • pp.246-250
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    • 2003
  • Calcium phosphate was prepared by chemical reaction formula using Oyster shells and $H_3$$PO_4$solutions. After added to 0.1 M∼0.9$ M H_3$$PO_4$ solution for oyster shell, prepared powders were investigated for heating properties and formation phase with heat treatment temperatures. As the results of XRD analysis of heated powders at $500^{\circ}C$$1200^{\circ}C$,$ CaCO_3$ phases were observed at the temperature of below 900 TEX>$^{\circ}C$ and in the condition of 0.1 M∼0.9 M $H_3$$PO_4$ solutions. However, $CaCO_3$, $CaPO_3$(OH) and $Ca_3$($PO_4$)$_2$ phases were appeared at the temperature range between $500∼900^{\circ}C$ and in the solution of 0.7 M to 0.9 M $H_3$$PO_4$. $Ca_{ 5}$($PO_4$)$_3$(OH) and CaO phases due to the decarbonation of oyster shells($CaCO_3$) were appeared at above $1000^{\circ}C$ and in the solution of below 0.5 M $H_3$X$PO_4$. However in the case of above 0.7 M $H_3$$H_4$ solutions, $Ca_{5}$ ($PO_4$)$_3$(OH) was decomposed into $Ca_3$($PO_4$)$_2$ at more higher 100$0^{\circ}C$. Thus $Ca_3$(X$Ca_4$)$_2$ phases were appeared at higher than 100$0^{\circ}C$.

Purification and Characterization of Lactate Dehydrogenase Isozymes in Channa argus (가물치(Channa argus) 젖산탈수소효소 동위효소들의 정제 및 특성)

  • Park, Eun-Mi;Yum, Jung-Joo
    • Journal of Life Science
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    • v.20 no.2
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    • pp.260-268
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    • 2010
  • The lactate dehydrogenase (EC 1.1.1.27, LDH) isozymes in tissues from Channa argus were purified and characterized by biochemical, immunochemical and kinetic methods. The activity of LDH in skeletal muscle was the highest at 380.4 units and those in heart, eye and brain tissues were 13.4, 3,5 and 5.4 units, respectively. Citrate synthase (EC 4.1.3.7, CS) activity in heart tissue was the highest at 20.7 units. LDH/CS in skeletal muscle, heart, eye and brain tissues were 172.9, 0.6, 0.32 and 0.47. Protein concentration in skeletal muscle tissue was 14.7 mg/g and specific activities of LDH in skeletal muscle, heart, eye and brain tissues were 25.88, 0.79, 0.31 and 1.38 units/mg, respectively. Therefore, skeletal muscle tissue was anaerobic and heart tissue was aerobic. The LDH isozymes in tissues were identified by polyacrylamide gel electrophoresis, immunoprecipitation and Western blot with antiserum against $A_4$, $B_4$, and eye-specific $C_4$. LDH $A_4$, $A_3B$, $A_2B_2$. $AB_3$ and $B_4$ isozymes were detected in every tissue, $C_4$, $AC_3$, $A_2C_2$ and $A_3C$ were detected in eye tissue, and $A_3C$ was found in brain tissue. LDH $A_4$, $A_3B$, $A_2B_2$, $AB_3$, $B_4$, eye-specific $C_4$ isozymes were purified by affinity chromatography and Preparative PAGE Cells. The LDH $A_4$ isozyme was purified in the fraction from elution with $NAD^+$ containing buffer of affinity chromatography. Eye-specific $C_4$ isozyme was eluted right after $A_4$, after which $B_4$ isozyme was eluted with plain buffer. As a result, one part of molecular structures in $A_4$, $B_4$ and eye-specific $C_4$ were similar, but were different from each other in $B_4$ and $C_4$. Therefore the subunit A may be conservative in evolution, and the evolution of subunit B seems to be faster than that of subunit A. The activity of LDH $A_4$, $A_2B_2$, $B_4$, and eye-specific $C_4$ isozymes remained at 39.98, 21.28, 19.67 and 16.87% as a result of the inhibition by 10 mM of pyruvate, so the degree of inhibition was very high. The $Km^{PYR}$ values were 0.17, 0.27 and 0.133 mM in $A_4$, $B_4$ and eye-specific $C_4$ isozymes, respectively. The optimum pH of LDH $A_4$, $B_4$, eye-specific $C_4$, $A_2B_2$, $A_3B$, and $AB_3$ were pH 6.5, pH 8.5, pH 5.5, pH 6.0-6.5, pH 5.0 and pH 7.5. The $A_4$ and heterotetramer isozymes stabilized a broad range of pH. Especially, LDH activities in skeletal muscle tissue were high, resulting in a high degree of muscle activity.LDH metabolism in eye tissue seems to be converted faster from pyruvate to lactate by eye-specific $C_4$ isozyme as eye-specific $C_4$ have the highest affinity for pyruvate, and right after the conversion, oxidation of lactate was induced by $A_4$ isozyme. It was found that expression of Ldh-C, affinity to substrate and reaction time of $C_4$ isozyme were different according to the ecological environmental and feeding capturing patterns.

Variations of superconducting characteristics of $YBa_2Cu_3O_{7-\delta}$ by Ag-doping (은 첨가에 의한 $YBa_2Cu_3O_{7-\delta}$의 초전도 특성 변화)

  • 강형부;김현택;이영철
    • Electrical & Electronic Materials
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    • v.6 no.6
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    • pp.514-522
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    • 1993
  • 본 연구에서는 Ag/ 첨가에 의한 YB $a_{2}$C $u_{3}$ $O_{7-{\delta}}$산화물의 초전도 특성 변화를 조사하였다. Ag가 첨가된 YB $a_{2}$C $u_{3-x}$A $g_{x}$ $O_{7-{\delta}}$ 산화물 시료를 만들고 이 시료들에 대한 X-ray 회절분석, IR흡수 스펙트럼분석, 임계온도(Tc)측정 및 자화(M-H)특성 측정등을 통하여 제조된 시료의 물리적 성질을 조사하였다. X-ray 회절실험 결과로 부터 x.leq.0.03인 경우에는 YB $a_{2}$C $u_{3-x}$A $g_{x}$ $O_{7-{\delta}}$가 단일상의 물질로 존재하고 x가 증가함에 따라 불순물상( $Y_{2}$ $O_{3}$, 순Ag)이 나타남을 알 수 있었다. IR흡수의 실험결과에서 Cu와 치환되어 들어간 Ag의 Ag-O 결합에 의한 흡수 스펙트럼(670$cm^{-1}$ /)이 관측되었다. 실험 결과로 부터 치환된 Ag의 양 x가 증가함에 따라 Tc가 조금씩 낮아지는 경향이 있었으며 자화의 세기 및 임계자장( $H_{C2}$)은 급격히 감소함을 알 수 있었고 또 M-H특성곡선에는 히스테리시스 특성이 나타났다.났다..났다.다.

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Regioselective Synthesis of [1]Benzopyrano [4,3-c]pyrazol-4-(1H)-one and [1]Benzopyrano[3,4-c]pyrazol-4(3H)-one Derivatives

  • Hassaneen, Hamdi M.;Shawali, Ahmad S.;Algharib, Mohammed S.;Elwan, Nehal M.
    • Archives of Pharmacal Research
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    • v.16 no.1
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    • pp.75-77
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    • 1993
  • The cycloaddition reaction of N-phenyl-C-cinnamonitrilimine 4 to coumarin leads to the for-mation of 3-styrylbenzopyrano[4,3-c]pyrazole derivative 6, whereas 3-phenylsulfonylcoumarin 9 or 3-bromocoumain 10 or 3-cyanocoumarin 11 gives 1-styrylbenzopyrano[3,4]pyrazole derivative 7. Also, the cycloaddition of 4 to 3-acetylocoumarin 15 and 3-benzoylocumain 16 gives the corresponding dihydropyrano[3,4-c]pyrazole adducts 17 and 18 respectively. Oxidation of 17 and 18 gives 7.

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Stress in Olive Flounder (Paralichthys olivaceus) and Fat Cod (Hexagrammos otakii) by the Sudden Drop and Rise of Water Temperature (수온의 급하강과 급상승이 넙치 (Paralichthys olivaceus)와 쥐노래미(Hexagrammos otakii)에 미치는 스트레스)

  • CHANG Young Jin;HUR Jun Wook;LIM Han Kyu;LEE Jong Kwan
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.34 no.2
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    • pp.91-97
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    • 2001
  • The effects of sudden changes of water temperature (WT) on the stress response and physiological change of the cultured olive flounder in large (FL) and small (FS) size, and fat cod (FC) were examined by manipulating WT (2 types) in a flow through seawater culture system with 6 tanks (water vol. 270 L/tank). The WT was decreased from $20^{\circ}C$ to $10^{\circ}C$ within 5 hours ($2^{\circ}C/hour$) and maintained at $10^{\circ}C$ for 21 hours (Exp. I), and it was raised from $20^{\circ}C$ to $30^{\circ}C$ within 5 hours and maintained at $30^{\circ}C$ for 21 hours (Exp.II). In Exp. I, the levels of blood hematocrit at 5 hours ($10^{\circ}C$) in FS was significantly decreased from $13.5\pm2.0\%\;to\;11.3\pm2.3\%$, but FC at 2.5 hours ($15^{\circ}C$) ($19.0\pm0.3\%\;to\;23.2\pm3.8\%$) was increased, The blood hemoglobin concentration of all fish in Exp, II was significantly increased until 8 hours after raising WT from $20^{\circ}C$ to $30^{\circ}C$. In Exp. I and II , the levels of plasma cortisol in FL, FS and FC was changed from $5.2\pm8.5ng/mL,\;4.4\pm4.5ng/mL\;and\;2.7\pm0.4ng/mL$, respectively, before sudden drop and rise of WT. The levels of plasma cortisol of in FL ($164.0\pm53.1ng/mL$) and FC ($207.9\pm25.4ng/mL$) were significantly increased by the lowering WT sharply during whole experiment. The FL ($12.6\pm2.0ng/mL$) and FS ($4.0\pm3.9ng/mL$) showed no significant differences in cortisol level according to sudden rise of WT (5 hours). But it in FC ($44.7\pm18.2ng/mL$) was increased. In Exp. I, the plasma glucose levels of all fish groups were decreased after 5 hours ($10^{\circ}C$), The plasma lactic acid concentration of FL and FS showed no significant differences until 5 hours after raising WT from $20^{\circ}C$ to $30^{\circ}C$, But it in FC was significantly increased with WT raise.

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Effects of $Ca^{2+}\;:\;K^+$ Ratio in Nutrient Solution on the Growth and Quality of Marjoram(Origanum majorana) and Oregano(Origanum vulgare) Grown in Hydroponic Culture (수경재배시 Ca 및 K 이온의 조성비율 차이가 마죠람과 오레가노의 생육 및 품질에 미치는 영향)

  • Park, Kuen-Woo;Na, Cheol-Wook;Kang, Ho-Min
    • Journal of Bio-Environment Control
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    • v.12 no.4
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    • pp.240-244
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    • 2003
  • The purpose of this study was to investigate a proper $Ca^{2+}\;:\;K^+$ ratio in nutrient solution to produce marjoram and oregano by hydroponics. Two herbs were grown for 40 days with the $Ca^{2+}\;:\;K^+$ ratio of 3.5;13, 4.5:11(standard herb's nutrient solution), 5.5:9 and 6.5:7mM${\cdot}L^{-1}$ of herb's nutrient solution developed by European Vegetable R &D Center, Belgium. The ratio of 5.5:9, and 6.5:7 mM${\cdot}L^{-1}$ showed better results in growth of marjoram than other treatments. Vitamin C contents and amounts of esential oil were the highest in the ratio of 5.5:9 and 6.5:7, respectively. Inoregano, the growth and vitamin C contents were the highest in the ratio of 5.5:9 and 6.5:7 mM${\cdot}L^{-1}$, respectively. The content (%) and amount (mg/plant) of essential oil were the highest in the ratio of 6.5:7mM${\cdot}L^{-1}$. These results indicated that 5.5:9 and 6.5:7 mM${\cdot}L^{-1}$were proper $Ca^{2+}\;:\;K^+$ ratio of nutrient solution of marjoram and oregano, respectively, by hydropoinics.

Phytoplankton community of Motjae-neup at Hapchŭn gun, Korea (합천 못재늪의 식물성 플랑크톤군집)

  • Kim, Eun-Hee;Lee, Ho-Won;Lee, Sang-Myung
    • Journal of Wetlands Research
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    • v.3 no.2
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    • pp.143-151
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    • 2001
  • The community of phytoplankton, dominant species and environmental factor were investigated in Motjae-neup from January to September, 1996. A total 45 taxa were identified during the investigation period and composed of 5 classes, 8 orders, 13 families, 24 genera, 37 species, 6 varieties, 2 formation. The most important group was Chlorophyceae with 19(42.2%) taxa, followed by the Bacillariophyceae with 13(28.9%) taxa, Euglenophyceae with 7(15.6%) taxa, Cyanophyceae with 5(11.1%) taxa and Dinophyceae with 1(2.2%) taxon. Frustulia rhomboides, Eunotia lunaris, and Stauroneis anceps were important dominant species at Motjae-neup. The common species of all season are Microsystis aeruginosa, Melosira. varians, Frustulia rhomboides, Pinnularia braunii var. amphicephala, Stauroneis anceps. Ranges of environmental factors were measured : temperature, $3^{\circ}C{\sim}38^{\circ}C$; water temperature, $3.3^{\circ}C{\sim}26.5^{\circ}C$; pH, 5.7~6.38; BOD, $4.3{\sim}19.6mg/{\ell}$; chlorophyll a, $6.9mg/m^3{\sim}25.9mg/m^3$; SS, $26mg/{\ell}{\sim}52mg/{\ell}$; COD, $24{\sim}46mg/{\ell}$; total-N, $0.9538mg/{\ell}{\sim}2.3036mg/{\ell}$; total-P, $0.1057mg/{\ell}{\sim}0.1909mg/{\ell}$; electron conductivity, $25.5{\mu}s/m^3{\sim}2.3036{\mu}s/m^3$.

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$High-J_c\;NdBa_2Cu_3O_{7-{\delta}}$ thin films on $SrTiO_3$(100) substrates prepared by the PLD process

  • Wee, Sung-Hun;Moon, Seung-Hyun;Yoo, Sang-Im
    • Progress in Superconductivity and Cryogenics
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    • v.11 no.2
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    • pp.1-6
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    • 2009
  • We report a successful fabrication of $high-J_c\;NdBa_2Cu_3O_{7-{\delta}}$ (NdBCO) films on $SrTiO_3$(STO) (100) substrates by pulsed laser deposition (PLD) in a relatively wide processing window. Under various oxygen pressures controlled by either 1%$O_2$/Ar mixture gas or pure $O_2$ gas, strongly c-axis oriented NdBCO films were grown at the substrate temperature $(T_s)\;of\;800^{\circ}C$ in 800 mTorr with 1%$O_2$/Ar gas and also in 400 and 800 mTorr with pure $O_2$ gas. These samples exhibited $T_c$ values over 90K and $J_c$ values of $2.8-3.5MA/cm^2$ at 77K in self-field (77K, sf). On the other hand, $J_c$ values over $1A/cm^2$ were obtained at the temperature regions of $700-830^{\circ}C$ in 800 mTorr with 1%$O_2$/Ar gas at those of $750-830^{\circ}C$ in 800 mTorr with pure $O_2$ gas. Unlike previous reports, resent results support that the PLD processing window for high-Jc NdBCO films is not narrow.

Studies on the Ultrarapid Freezing of In vitro Fertilized Bovine Embryos I. Studies on the Survival Rates after Slow and Ultrarapid Frozen -Thawing of In Vitro Fertilized Bovine Embryos (소 체외수정란의 초급속동결에 관한 연구 I. 소 체외수정란의 완만 및 초급속동결 융해후의 생존성에 관한 연구)

  • 김상근;이봉구;이규승
    • Korean Journal of Animal Reproduction
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    • v.15 no.2
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    • pp.133-139
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    • 1991
  • This stduy was carried out in order to investigate the effects of concentration and equilibration time of cryoprotective agents on survival rate of slow and ultrarapidly frozen in vitro fertilized bovine embryos. In vitro fertilized bovine embryos, following dehydration by cryoprotective agents and sucrose, were slowly freezed(from 2$0^{\circ}C$ to -7$^{\circ}C$/-1$^{\circ}C$/min., from -7$^{\circ}C$ -35$^{\circ}C$/-0.2$^{\circ}C$/min. from -35$^{\circ}C$ to -38$^{\circ}C$/-0.3$^{\circ}C$/min.) by cell freezer and directly plunged into liquid nitrogen and thawed in 38$^{\circ}C$ water. Survival rate was defined by development rate to the morula and blastocyst stage after in vitro cultured and FDA test. The results are summarized as follows : 1. The survival rates of in vitro fertilized bovine embryos after slow frozen-thawing in the freezing medium of 0.25M sucrose added 2.5M glycerol, 3.0M DMSO, 2.0M propanediol and 2.5M glycerol+2.0M propanediol were 84.3%, 85.9%, 77.8%, 74.3%, respectively. 2. The survival rates of in vitro fertilized bovine embryos after slow frozen-thawing in the freezing of 0.50M sucrose added 2.5M glycerol, 3.0M DMSO, 2.0M propanediol and 2.5M glycerol+2.0M propanediol were 83.8%, 85.1%, 71.4%, 74.6%, respectively. 3. The survival rates of in vitro fertilized bovine embryos after ultrarapid frozen-thawing in the freezing of 0.25M sucrose added 2.5M glycerol, 3.0M DMSO, 2.0M propanediol and 2.5M glycerol+3.0M propanediol were 69.3%, 70.8%, 63.2%, 67.1%, respectively. 4. The survival rates of in vitro fertilized bovine embryos after ultrarapid frozen-thawing in the freezing of 0.25M sucrose added 2.5M glycerol, 3.0M DMSO, 2.0M propanediol and 2.5M glycerol+2.0M propanediol were 69.4%, 70.1%, 62.3%, 63.5%, respectively. 5. The survival rates of in vitro fertilized bovine embryos after slow and ultrarapid fromthawing in the freezing medium of sucrose added cryoprotective agents were not significant difference between 5min. and 10min. of equilibration time.

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