• Title/Summary/Keyword: $In_2S_3$

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Optical Properties of $In_2S_3$ and $In_2S_3:Co^{2+}$ single crystal ($In_2S_3$$In_2S_3:Co^{2+}$ 단결정의 광학적 특성에 관한 연구)

  • Oh, Seok-Kyun;Park, Kwang-Ho;Hyun, Seung-Cheol;Jeong, Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.156-156
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    • 2008
  • Single crystal of $In_2S_3$ and $In_2S_3:Co^{2+}$ were grown successfully with a good quality by the CTR(Chemical Transport Reaction)method. XRD analysis showed that the grown In2S3 and $In_2S_3:Co^{2+}$ single crystals were cubic structure. The optical absorption spectra of $In_2S_3:Co^{2+}$ single crystal showed impurity absorption peaks due to cobalt impurity. These impurity absorption pesks were assigned to the ligand transition between the split energy levels of $Co^{2+}$ ions with $T_d$ symmetry of these semiconductor host lattice.

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Molecular Characterization and Expression Analysis of Clathrin-Associated Adaptor Protein 3-δ Subunit 2 (AP3S2) in Chicken

  • Oh, Jae-Don;Bigirwa, Godfrey;Lee, Seokhyun;Song, Ki-Duk
    • Korean Journal of Poultry Science
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    • v.46 no.1
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    • pp.31-37
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    • 2019
  • A chicken clathrin-associated adaptor protein $3-{\delta}$ subunit 2 (AP3S2) is a subunit of AP3, which is involved in cargo protein trafficking to target membrane with clathrin-coated vesicles. AP3S2 may play a role in virus entry into host cells through clathrin-dependent endocytosis. AP3S2 is also known to participate in metabolic disease developments of progressions, such as liver fibrosis with hepatitis C virus infection and type 2 diabetes mellitus. Chicken AP3S2 (chAP3S2) gene was originally identified as one of the differentially expressed genes (DEGs) in chicken kidney which was fed with different calcium doses. This study aims to characterize the molecular characteristics, gene expression patterns, and transcriptional regulation of chAP3S2 in response to the stimulation of Toll-like receptor 3 (TLR3) to understand the involvement of chAP3S2 in metabolic disease in chicken. As a result, the structure prediction of chAP3S2 gene revealed that the gene is highly conserved among AP3S2 orthologs from other species. Evolutionarily, it was suggested that chAP3S2 is relatively closely related to zebrafish, and fairly far from mammal AP3S2. The transcriptional profile revealed that chAP3S2 gene was highly expressed in chicken lung and spleen tissues, and under the stimulation of poly (I:C), the chAP3S2 expression was down-regulated in DF-1 cells (P<0.05). However, the presence of the transcriptional inhibitors, BAY 11-7085 (Bay) as an inhibitor for nuclear factor ${\kappa}B$ ($NF{\kappa}B$) or Tanshinone IIA (Tan-II) as an inhibitor for activated protein 1 (AP-1), did not affect the expressional level of chAP3S2, suggesting that these transcription factors might be dispensable for TLR3 mediated repression. These results suggest that chAP3S2 gene may play a significant role against viral infection and be involved in TLR3 signaling pathway. Further study about the transcriptional regulation of chAP3S2 in TLR3 pathways and the mechanism of chAP3S2 upon virus entry shall be needed.

Structural Interpretation on the Mechanism of High $La_2S_3$ Solubility in $GeS_2-Ga_2S_3-La_2S_3$Glasses ($GeS_2-Ga_2S_3-La_2S_3$ 유리 구조 분석을 통한 $La_2S_3$ 용융성 규명)

  • Yoon, Joong-Min;Heo, Jong;Ryou, Sun-Youn
    • Journal of the Korean Ceramic Society
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    • v.34 no.8
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    • pp.870-876
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    • 1997
  • Ge-Ga-S glasses, contrary to other well-known chalcogenide glasses, show high rare-earth solubility. Raman spectra of GeS2-Ga2S3 glasses showed that two peaks at 260 cm-1 and 385 cm-1 increased in intensity with the addition of Ga2S3. These peaks are associated with the vibration of Ge-Ge bonds and edge-shared [GsS4] tetrahedra, respectively. In GeS2-Ga2S3-La2S3 glasses, the peak at 260 cm-1 decreased in intensity with addition of La2S3 and the one at 375 cm-1 due to the vibration of tetrahedra with non-bridging sulfurs increased. It indicated that La, or rare-earths in general, can easily be dissolved into the glass network as charge compensators for non-bridging sulfurs which were formed through the dissociation of Ge-Ge bonds and edge-shared [GaS4] tetrahedra. Since no such structural modification is expected in glasses as Ga-As-S, these peculiar transitions on the connection scheme in Ga-containing chalcogenide glasses seem to be playing the most important role on the enhanced rare-earth solubility.

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Interaction of Alkali Oxide and $SO_3$ on $3CaO.SiO_2$ Formation and Microstructure ($3CaO.SiO_2$ 생성반응과 미세조직에 있어서 Alkali Oxide와 $SO_3$의 상호작용)

  • 정해문;최상흘
    • Journal of the Korean Ceramic Society
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    • v.30 no.12
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    • pp.1071-1079
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    • 1993
  • Interaction of alkali oxides and SO3 and C3S formation and microstructure was studied using K2CO3 and Na2CO3 as alkali sources and (NH4)2SO4 for SO3. When SO3/K2O=1.43 as mole ratio, K2O and SO3 react to form K2SO4, this phase is immiscible with other oxide melt and thus could not affect C3S formation as well as its microstructure. In a condition of SO3/K2O 1, C3S crystals were round and grown in a much larger size. With addition of Na2O and SO3 by only 1wt% each, C3S formation was strongly hindered. Since C2S was stabilized by Na+ and SO4-2, it could not react to give C3S formation. However in the condition of SO3/Na2O=1.43, a little amount of C3S was formed. It is considered that small amount of Na2SO4 was formed, this phase was immiscible with clinker liquid, and the C3S crystals were formed locally in the liquid part of relatively low Na2O and SO3 compositions. These crystals had irregular and rough surfaces and contained more inclusions than those grown from K2O.SO3 system.

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Optical energy gap properties of $Co^{2+}$ -doped $In_2S_3$ single crystal ($In_2S_3$ : $Co^{2+}$ 단결정의 광학적 에너지 갭 특성)

  • Kim, Hyung-Gon;Kim, Nam-Oh;Choi, Young-Il;Lee, Kyoung-Sub
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.05b
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    • pp.42-46
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    • 2000
  • ${\beta}{\cdot}In_2S_3$${\beta}{\cdot}In_2S_3:Co^{2+}$$In_2S_3$+S+ZnS를 출발물질로 하여 ($ZnCl_2+I_2$)를 수송매체로 사용한 chemical transport reaction method로 성장시켰다. 성장된 단결정은 tetragonal structure를 갖고 298K에서 indirect optical energy gap은 2.240eV, 1.814eV로 각각 주어졌고, direct optical energy gap은 2.639eV, 2.175eV로 각각 주어졌다. ${\beta}{\cdot}In_2S_3:Co^{2+}$ single crystal에서 impurity optical absorption peak가 나타났으며, 이들 peaks의 origin은 $Co^{2+}(Td)$ ion의 energy level 간의 electron transition임을 crystal field theory를 적용하여 규명하였다.

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Experimental studies on anti-tumor and immunomodulatory effects according to it's (종양(腫瘍)의 치법(治法)에 관(關)한 실험적(實驗的) 연구(硏究) -부정법(扶正法), 부정거사법(扶正祛邪法), 공사법(攻邪法)의 비교연구(比較硏究)-)

  • Kim, Sun-Hee;Choi, Jong-Baek;Kim, Sang-Chan
    • Herbal Formula Science
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    • v.5 no.1
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    • pp.127-145
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    • 1997
  • This study was aimed to investigate the anti-tumor and immune response effect of Samyongtang(S1; this medicine represents for 'ENERGIZER'), Yangjeongjejeoktang(S2; this is the 'INTERMEDIATE METHOD' of S1 and S3) and Onbeakwon(S3; this is 'ATTACK' the disease of mass) on the experimental rats induced by Sarcoma-180 and Methotrexate. And to observed the differences S1, S2, and S3 treatment groups. Tumor weight(TW) in vivo, interleukin-2(IL-2), hemagglutinin titer(H.A), hemolysin titer(HL), rossete forming cell(RFC), delayed type hypersensitivity(DTH), and natural killer cell activity(NKCA) in vivo were measured in rats. The obtained results were summarized as follows. 1. Tumor weight was decreased in all treatment groups (S2>S3>S1) as compared with control group, but the difference was not statistically significant each treatment groups. 2. Interleukin-2 was increased in all treatment groups (S1>S2>Ss) as compared with control group, but the difference was not statistically significant each treatment groups. 3. Hemagglutinin titer was increased in all treatment groups (S1>S2>S3) as compared with control group, but the difference was not statistically significant each treatment groups. 4. Hemolysin titer was increased in all treatment groups (S1>S2>S3) as compared with control group, but the difference was not statistically significant each treatment groups. 5. Rossete forming cell(RFC) was increased in all treatment groups (S1>S2>S3) as compared with control group, but the difference was not statistically significant each treatment groups. 6. Delayed type hyperseneitivity(DTH) was increased in S1, S2 treatment groups (S1>S2) as compared with control group, but it was decreased in S3 treatment group. Therefore, S1 group was statistically significant compared with S3 groups. 7. Natural killer cell activity(NKCA) was increased in all treatment groups (S2>S3>S1) as compared with control group, but the difference was not statistically significant each treatment groups. Based on the above mentioned results, it is suggested that S1, S2 and S3 will have anti-tumor substances and enhance effect of immune response. But the differences were not statistically significant in each treatment groups, except for delayed type hypersensitivity.

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Optical properties of $\beta$-$In_2S_3$ and $\beta$-$In_2S_3$:$Co^{2+}$ Thin Films

  • Kim, Hyung-Gon;Kim, Nam-Oh;Jin, Moon-Seog;Oh, Seok-Kyun;Kim, Wha-Tek
    • Transactions on Electrical and Electronic Materials
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    • v.2 no.1
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    • pp.27-31
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    • 2001
  • $\beta$-$In_2S_3$ and $\beta$-$In_2S_3$:$Co^{2+}$ thin films were grown using the spray pyrolysis method. The thin films crystallized into tetragonal structures. The indirect energy band gap of the thin films was found to be 2.32 eV for $\beta$-$In_2S_3$ and 1.81 eV for $\beta$-$In_2S_3$:$Co^{2+}$(Co:1.0 mol%) at 198K. The direct energy band gap was found to be 2.67 eV for $\beta$-$In_2S_3$ and 2.17 eV for $\beta$-$In_2S_3$:$Co^{2+}$(Co:1.0 mol%). Impurity optical absorption peaks were observed for the ${\beta}$-$In_2S_3$:$Co^{2+}$ thin films. These impurity absorption peaks are assigned, based on the crystal field theory, to the electron transitions between the energy levels of the $Co^{2+}$ ion sited in $T_{d}$ symmetry.

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Photoluminescence of Multinary-compound Semiconductor $ZnGaInS_4:Er^{3+}$ Single Crystals (다원화합물 반도체 $ZnGaInS_4:Er^{3+}$ 단결정의 광발광 특성)

  • Kim, Nam-Oh;Kim, Hyung-Gon;Bang, Tae-Hwan;Hyun, Seung-Cheol;Kim, Duck-Tae
    • Proceedings of the KIEE Conference
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    • 2000.07e
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    • pp.35-39
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    • 2000
  • $ZnIn_2S_4$ and $ZnGaInS_4:Er^{3+}$ single crystals crystallized in the rhombohedral (hexagonal) space group $C_{3v}^5(R3m)$, with lattice constants $a=3.852{\AA},\;c=37.215{\AA}$ for $ZnIn_2S_4$, and $a=3.823{\AA}$, and $c=35.975{\AA}$ for $ZnIn_2S_4:Er^{3+}$. The optical absorption measured near the fundamental band edge showed that the optical energy band structure of there compounds had a direct and indirect band gap, the direct and indirect energy gaps are found to be 2.778 and 2.682 eV for $ZnIn_2S_4$, and 2.725 and 2.651eV for $ZnIn_2S_4:Er^{3+}$ at 293 K. The photoluminescence spectra of $ZnIn_2S_4:Er^{3+}$ measured in the wavelength ranges of $500nm{\sim}900nm$ at 10 K. Eight sharp emission peaks due to $Er^{3+}$ ion are observed in the regions of $549.5{\sim}550.0nm,\;661.3{\sim}676.5nm$, and $811.1{\sim}834.1nm$, and $1528.2{\sim}1556.0nm$ in $CdGaInS_4:Er^{3+}$ single crystal. These PL peaks were attributed to the radiative transitions between the split electron energy levels of the $Er^{3+}$ ions occupied at $C_{2v}$, symmetry of the $ZnIn_2S_4$ single crystals host lattice.

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In2S3 Co-Sensitized PbS Quantum Dot Solar Cells

  • Basit, Muhammad Abdul;Park, Tae Joo
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.273-273
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    • 2014
  • Quantum-dot sensitized solar cells (QDSCs) are an emerging class of solar cells owing to their easy fabrication, low cost and material diversity. Despite of the fact that the maximum conversion efficiency of QDSCs is still far less than that of Dye-Sensitized Solar Cells (>12 %), their unique characteristics like Multiple Exciton Generation (MEG), energy band tune-ability and tendency to incorporate multiple co-sensitizers concurrently has made QDs a suitable alternative to expensive dyes for solar cell application. Lead Sulfide (PbS) Quantum dot sensitized solar cells are theoretically proficient enough to have a photo-current density ($J_{sc}$) of $36mA/cm^2$, but practically there are very few reports on photocurrent enhancement in PbS QDSCs. Recently, $Hg^{2+}$ incorporated PbS quantumdots and Cadmium Sulfide (CdS) co-sensitized PbS solarcells are reported to show an improvement in photo-current density ($J_{sc}$). In this study, we explored the efficacy of $In_2S_3$ as an interfacial layer deposited through SILAR process for PbS QDSCs. $In_2S_3$ was chosen as the interfacial layer in order to avoid the usage of hazardous CdS or Mercury (Hg). Herein, the deposition of $In_2S_3$ interfacial layer on $TiO_2$ prior to PbS QDs exhibited a direct enhancement in the photo-current (Isc). Improved photo-absorption as well as interfacial recombination barrier caused by $In_2S_3$ deposition increased the photo-current density ($J_{sc}$) from $13mA/cm^2$ to $15.5mA/cm^2$ for single cycle of $In_2S_3$ deposition. Increase in the number of cycles of $In_2S_3$ deposition was found to deteriorate the photocurrent, however it increased $V_{oc}$ of the device which reached to an optimum value of 2.25% Photo-conversion Efficiency (PCE) for 2 cycles of $In_2S_3$ deposition. Effect of Heat Treatment, Normalized Current Stability, Open Circuit Voltage Decay and Dark IV Characteristics were further measured to reveal the characteristics of device.

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Compensatory Growth of Juvenile Olive Flounder Paralichthys olivaceus during the Summer Season (하절기 넙치유어의 보상 성장)

  • Cho Sung-Hwoan
    • Journal of Aquaculture
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    • v.19 no.2
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    • pp.95-98
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    • 2006
  • This study was performed to determine possibility of compensatory growth of juvenile olive flounder fed a commercial feed during the summer season. Five treatments of fish with triplicates were prepared: C, S1, S2, S3 and S4. Fish in the control group (C) was hand-fed with the commercial feed to apparent satiation twice daily for 6 days a week during 6 weeks. Fish in S1, S2, S3, and S4 experienced 1, 2, 3, and 4 weeks of starvation before fed to satiation twice daily for 5, 4, 3, and 2 weeks, respectively. The feeding trial lasted far 6 weeks. Survival of flounder in C, S1 and S2 was significantly (P<0.05) higher than that offish in S4. Weight gain and specific growth rate (SGR) of flounder in C and S1 were significantly (P<0.05) higher than those of fish in S2, S3 or S4. And weight gain and SGR of flounder in S2 and S3 were significantly (P<0.05) higher than those of fish in S4. Feed consumption of flounder tended to increase with weeks of feeding. Feed efficiency ratio and protein efficiency ratio for flounder in C, S1, S2 and S3 were significantly (P<0.05) higher than those for fish in S4. Moisture content of the whole fish in C was lowest, but highest for fish in S4, respectively. Crude protein content of the whole fish in C was highest, but lowest far fish in S4, respectively. Crude lipid content of the whole fish in C, S1 and S2 was significantly (P<0.05) higher than that of fish in S4. In conclusion, full compensatory growth was obtained in juvenile olive flounder fed for 5 weeks after 1-week feed deprivation during the summer season. Compensatory growth of fish was well supported by improvement in feed efficiency ratio and protein efficiency ratio.