• Title/Summary/Keyword: $H_2O$ content

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Magnetic Properties of Chip Inductors Prepared with V2O5-doped Ferrite Pastes (V2O5 도핑한 페라이트 페이스트로 제조된 칩인덕터의 자기적 특성)

  • Je, Hae-June
    • Journal of the Korean Magnetics Society
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    • v.13 no.3
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    • pp.109-114
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    • 2003
  • The purpose of this study Is to investigate the effect of $V_2$O$_{5}$ addition on the microstructures and magnetic properties of 7.7${\times}$4.5${\times}$1.0 mm sized multi-layer chip inductors prepared by the screen printing method using 0∼0.5 wt% $V_2O_{5}$-doped NiCuZn ferrite pastes. With increasing the $V_2O_{5}$ content, the exaggerated grain growth of ferrite layers was developed due to the promotion of Ag diffusion and Cu segregation into the grain boundaries oi ferrites, which affected significantly the magnetic properties of the chip inductors. After sintering at $900^{\circ}C$, the inductance at 10 MHZ of the 0.5 wt% $V_2O_{5}$-doped chip inductor was 3.7 ${\mu}$H less than 4.2 ${\mu}$H of the 0.3 wt% $V_2O_{5}$-doped one, which was thought to be caused by the residual stress at the ferrite layers increased with the promotion of Ag diffusion and Cu segregation. The quality factor of the 0.5 wt% $V_2O_{5}$-doped chip inductor decreased with increasing the sintering temperature, which was considered to be caused by the electrical resistivity of the ferrite layer decreased with the promotion of Ag/cu segregation at the grain boundaries and the growth of the mean grain size of ferrite due to exaggerated grain growth of ferrite layers.

Hydration in the System of Fluorogypsum-Blast Furnace Slag (불산석고-고로슬래그계의 수화반응)

  • 송종택;고상열;노재성
    • Journal of the Korean Ceramic Society
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    • v.35 no.9
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    • pp.933-938
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    • 1998
  • The hydration for the system of fluorogypsum and 20wt% blast furnace slag was investigated at liquid/soild ratio of 0.45 for 1, 3, and 7 days by using 3 kinds of accelerators such as K2SO4 Al2(SO4)3 $.$16-18H2O and AlK(SO4)2$.$12H2O After curing the hardened specimen was characterized by the compressive strength the content of combined water XRD, DTA and SEM It was found that the activating effect was increased in the order of K2SO4

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Synthesis and Superconductivity in $(Ru_{0.8}Nb_{0.2})Sr_2(Gd_{1.5-x}Nd_xCe_{0.5})Cu_2O_z$ System ($(Ru_{0.8}Nb_{0.2})Sr_2(Gd_{1.5-x}Nd_xCe_{0.5})Cu_2O_z$ 계의 합성 및 초전도 특성)

  • Lee, H.K.;Bae, S.M.
    • Progress in Superconductivity
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    • v.10 no.2
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    • pp.128-132
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    • 2009
  • Polycrystalline samples of $(Ru_{0.8}Nb_{0.2})Sr_2(Gd_{1.5-x}Nd_xCe_{0.5})Cu_2O_z$($ 0{\leq}x{\leq}1.25$) have been synthesized by a solid-state reaction route. The X-ray diffraction data revealed that the Nd solubility limit can be placed between x=0.5 and x=0.75. The superconducting transition temperature decreased with increasing Nd content, confirming that Nd entered the lattice. Room-temperature thermoelectric power measurements showed that all the samples are in the underdoped state and the partial substitution of Nd for Gd resulted in a decrease in the carrier density on the superconducting layers.

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Effect of Kamihaengche-tang Plus Yukmijihwang-tang Oxidant-induced Liver Cell injury (Oxidant에 의한 간독성유발에 가미행체엽탕 합 육미지황탕의 효과)

  • 이수행;김우환
    • Journal of Life Science
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    • v.8 no.4
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    • pp.464-471
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    • 1998
  • This study was carried out to determine whether Kamihaengche-tang plus Yukmijihwang-tang (KCYH) exerts the protective effect against oxidant-induced liver cell injury. Cell injurt was estimated by measuring lactate dehydrogenase (LDH) and alanine aminotransferase (ALT) release, and lipid peroxidation was estimated by measuring malondialdehyde, a product of lipid peroxidation in rabbit liver slices. $H_2O_2$increased LDH release which was significantly prevented by 1% KCYHT. The protective effect of KCYH against $H_2O_2$-induced cell injury was dose-dependent in the range of 0.05-1% concentrations. Similary, KCYH inhibited $H_2O_2$ induced lipid peroxidation in a dose-dependent manner. When liver tissuse were exposed to Hg(0.5 mM), ALT activity in the medium and lipid erpoxidation in tissues were markedly increased. These changes were prevented by 1% KCYH. KCHY restored Hg-induced inhibition of cellular GSH content. These result indicate that KCYH exerts the protective effect oxidant-induced liver cell injury, and this effect is attributed to prevented to prevention of lipid peroxidation. These dffects may be due to an increase in concentration of endogenous antioxidants.

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Characterization of DNJ production for large-scale fermentation of mulberry leaf

  • Kwon, O-Chul;Ju, Wan-Taek;Kim, Hyun-Bok;Sung, Gyoo-Byung;Kim, Yong-Soon
    • International Journal of Industrial Entomology and Biomaterials
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    • v.35 no.2
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    • pp.111-117
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    • 2017
  • Mulberry leaves containing 1-deoxynojirimycin (DNJ) known to be a strong inhibitory effect for ${\alpha}-glucosidase$. Thus, DNJ has been recognized as a potentially important source for prevent or treat hyperglycemia. More effective method for the DNJ high-production is needed because DNJ content of natural mulberry leaf are as low as 0.1%. Many researchers have studied for the DNJ high-production in mulberry leaves such as the harvest season, fermentation using microorganisms, optimal culture conditions, and optimal extraction conditions. In order to provide for useful data that is anticipated at the level of industrial scale, we investigated ${\alpha}-glucosidase$ inhibitory activity, pH value and DNJ content in large-scale based on the optimal culture conditions for mulberry leaf fermentation of small-scale in our previous study. The ${\alpha}-glucosidase$ inhibitory activity, pH value, and DNJ content in this study were measured from the mulberry leaf fermentation broth for 7 days. During mulberry leaf fermentation, the ${\alpha}-glucosidase$ inhibitory activity and DNJ content was increased until 2 to 4 days, but after 4 day was decreased. The pH value showed a decreasing trend up to 2 day, and little changes in 2 to 4 days. However, the pH was started to increase after 4 days.

Optical, Mechanical and Tribological Properties of Boronnitride Dispersed Silicon Nitride Ceramics

  • Joshi, Bhupendra;Fu, Zhengyi;Niihara, Koichi;Lee, Soo-Wohn
    • Korean Journal of Materials Research
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    • v.20 no.8
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    • pp.444-449
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    • 2010
  • Transparent ceramics are used in new technology because of their excellent mechanical properties over glasses. Transparent ceramics are nowadays widely used in armor, laser windows, and in high temperature applications. Silicon nitride ceramics have excellent mechanical properties and if transparent silicon nitride is fabricated, it can be widely used. h-BN has a lubricating property and is ductile. Therefore, adding h-BN to silicon nitride ceramics gives a lubricating property and is also machinable. Translucent silicon nitride was fabricated by hot-press sintering (HPS) and 57% transmittance was observed in the near infrared region. A higher wt. % of h-BN in silicon nitride ceramics does not favor transparency. The optical, mechanical, and tribological properties of BN dispersed polycrystalline $Si_3N_4$ ceramics were affected by the density, ${\alpha}:{\beta}$-phase ratio, and content of h-BN in sintered ceramics. The hot pressed samples were prepared from the mixture of $\alpha-Si_3N_4$, AlN, MgO, and h-BN at $1850^{\circ}C$. The composite contained from 0.25 to 2 wt. % BN powder with sintering aids (9% AlN + 3% MgO). A maximum transmittance of 57% was achieved for the 0.25 wt. % BN doped $Si_3N_4$ ceramics. Fracture toughness increased and wear volume and the friction coefficient decreased with an increase in BN content. The properties such as transmittance, density, hardness, and flexural strength decreased with an increase in content of h-BN in silicon nitride ceramics.

Reaction Characteristics of Combined Steam and Carbon Dioxide Reforming of Methane Reaction Using Pd-Ni-YSZ Catalyst (Pd-Ni-YSZ 촉매를 이용한 수증기-이산화탄소 복합개질 반응 특성)

  • Kim, Sung Su
    • Applied Chemistry for Engineering
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    • v.29 no.4
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    • pp.382-387
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    • 2018
  • In this study, the reaction characteristics of combined steam and carbon dioxide reforming of methane (CSCRM) reaction using Pd-Ni-YSZ catalyst were investigated according to types of catalysts and gas compositions. Catalysts were prepared in the form of powder and porous disk. The injected gases were supplied at different ratios of $CH_4/CO_2/H_2O$. As a result, the conversion of $CH_4$ and $CO_2$ was improved as a result of using the porous disc type catalyst as compared with that of the powder type catalyst. When the $CH_4/CO_2/H_2O$ ratio of the feed gas was 1 : 0.5 : 0.5, the $H_2/CO$ ratio was adjusted close to 2. However, after 6 hours of the reaction, $CH_4$ conversion was partially reduced by the carbon deposition and the pressure drop increased from 0.1 to 0.8. This issue was then solved by optimizing the water content. As a result, it was confirmed that the durability was secured by preventing the carbon deposition when the gas was supplied at a $CH_4/CO_2/H_2O$ ratio of 1 : 0.5 : 1, and the conversion rate was maintained at a relatively high level.

A Study on the Development of Activated Carbon from Rice-Hull (왕겨를 이용한 활성탄 개발에 관한 연구 (I))

  • 이희자;조양석;조광명
    • Journal of Environmental Science International
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    • v.9 no.1
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    • pp.81-88
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    • 2000
  • Every year, 1.1 million tons of rice-hull are produced in South Korea by the by-product in pounding rice. But they has mainly been utilized as a fuel, agricultural compost and moisture proofs. So, it's very valuable to use waste rice-hull for activated carbon manufacture. SiO2 content was the highest among inorganics in rice-hull. Therefore, the SiO2 extraction experiments were carried out under the various conditions of pH 9 to 14, reaction time from 2 to 24 hrs and various temperature of 20 to 100℃. The results showed that increase in pH and temperature enhanced SiO2 extraction from the carbonized rice-hull. The surface area of the carbonized rice-hull indicating activated carbon adsorption capacity was very small as 178∼191 m2/g at first. However, it was increased to 610∼675 m2/g when extracted in alkali solution at 100℃. When the mixing rate of carbonized rice-hull and NaOH was 1:1.5, iodine No. and surface area of activated rice-hull during 10 min at 700℃ were 1,650 mg/g and 1837 m2/g, respectively. Subsequently, an activated carbon with specific surface area of 1,300∼1,900m2/g was manufactured in a short contact time of 10∼30 min with a mixing rate of 1:1.5 in carbonized rice-hull and NaOH, and iodine No. and specific surface area increased as the amount of SiO2 removal increased.

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DC Accelerated Aging Characteristics of $ZnO-Pr_{6}O_{11}$ Based Varistor Ceramics ($ZnO-Pr_{6}O_{11}$계 바리스터 세라믹스의 직류가속열화 특성)

  • Kim, Hyang-Suk;Nahm, Choon-Woo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.330-333
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    • 2002
  • The stability against DC accelerated aging stress of $Dy_{2}O_{3}-doped$ $ZnO-Pr_{6}O_{11}-based$ varistor ceramics was investigated. The calculated nonlinear exponent$(\alpha)$ in varistor ceramics without $Dy_{2}O_{3}$ was only 4.9, whereas the $\alpha$ value of the varistors with $Dy_{2}O_{3}$ was abruptly increased in the range of 48.8 to 58.6. The varistor ceramics with $Dy_{2}O_{3}$ content of 1.0 mol% exhibited maximum ${\alpha}$, reaching 58.6, whereas they exhibited very poor stability. While, The varistor ceramics doped with 0.5 mol% $Dy_{2}O_{3}$ exhibited not only the high nonlinearity, which the ${\alpha}$ is 55.3 and the leakage current is $0.1{\mu}A$, but also the highest stability, which the variation rates of varistor voltage and nonlinear exponent are -0.8% and -14.3%, respectively, under DC accelerated aging stress, $0.95 V_{1mA}/150^{\circ}C/24h$.

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Preparation and Properties of Waterborne Polyurethanes Based on Ttiblock Glycol $(CL)_{4.5}$-PTMG-$(CL)_{4.5}$ for Water Vapor Permeable Coatings: Effect of Soft Segment Content

  • Kwak, Yong-Sil;Kim, Han-Do
    • Fibers and Polymers
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    • v.3 no.4
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    • pp.153-158
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    • 2002
  • A series of waterborne polyurethanes (WBPU) were prepared from 4,4-dicyclohexylmethane diisocyanate ($H_{12}$MDI),2,2-bis(hydroxylmethyl) propionic acid (DMPA), othylenediarnine (EDA), triethylamine (TEA), and triblock glycol [TBG, ($\varepsilon$-caprolactone)$_{4.5}$-poly(tetramethylene ether) glycol (MW= 2000)-($\varepsilon$-caprolactone)$_{4.5}$: $(CL)_{4.5}$-PTMG-$(CL)_{4.5}$, MW=3000] as a soft segment. Two melting peaks of TBG at about 14$^{\circ}C$ and 38$^{\circ}C$ were observed indicating the presence of two different crystalline domains composed of CL and PTMG dominant component. The effect of soft segment content (60-75 wt%) on the colloidal properties of dispersion, and thermal and mechanical properties of WBPU films, the water vapor permeability (WVP) and water resistance (WR) of WBPU-coated Nylon fabrics, and the adhesive strength of WBPU- coated layer and Nylon fabrics was investigated. As soft segment contents increased, the water vapor permeability of WBPU- coated Nylon fabrics increased from 3615 to 4502 g/$m^2$day, however, the water resistances decreased from 1300 to 500 mm$H_2$O.O.