• Title/Summary/Keyword: $H_2$ atmosphere

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Effect of Corrosion Atmosphere and Strain Rate on the Stress Corrosion Cracking of High Strength 7xxx Aluminum Alloy (고강도 7xxx 알루미늄 합금의 응력부식균열에 미치는 부식환경과 응력속도의 영향)

  • Yun, Yeo-Wan;Kim, Sang-Ha
    • Journal of the Korean institute of surface engineering
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    • v.41 no.3
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    • pp.121-128
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    • 2008
  • High strength 7xxx aluminum alloys have been applied to automotive bump back beam of the some limited model for light weight vehicle. The aluminum bump back beam is manufactured through extrusion, bending and welding. The residual stress given on these processes combines with the corrosive atmosphere on the road spreaded with corrosive chemicals to melt snow to occur the stress corrosion cracking. The composition of commercial 7xxx aluminum has Zn/Mg ratio about 3 and Cu over 2 wt% for better strength and stress corrosion cracking resistivity. But this composition isn't adequate for appling to the automotive bump back beam with high resistance to extrusion and bad weldability. In this study the composition of 7xxx aluminum alloy was modified to high Zn/Mg ratio and low Cu content for better extrusion and weldability. To estimate the resistivity against stress corrosion cracking of this aluminum alloy by slow strain rate test, the corrosion atmosphere and strain rate separate the stress corrosion cracking from conventional corrosion must be investigated. Using 0.6 Mol NaCl solution on slow strain rate test the stress corrosion cracking induced fracture was not observed. By adding 0.3% $H_2O_2$ and 0.6M $Na_2SO_4$ to 1M NaCl solution, the corrosion potential and current density of polarization curve moved to active potential and larger current density, and on the slow strain rate test the fracture energy in solution was lower than that in pre-exposure. These mean the stress corrosion cracking induced fracture can be estimated in this 1M NaCl + 0.3% $H_2O_2$ + 0.6M $Na_2SO_4$ solution. When the strain rate was below $2{\times}10^{-6}$, the stress corrosion cracking induced fracture start to be observed.

Grain Boundary Behavior and Heat Treatment Effect of AlN Ceramics Prepared from Al-isopropoxide (Al-isopropoxide로부터 AlN 소결체의 입계상 거동 및 열처리 효과)

  • 황해진;이홍림
    • Journal of the Korean Ceramic Society
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    • v.28 no.4
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    • pp.269-278
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    • 1991
  • Fine AlN powder was synthesized by carbothermal reduction and nitridation of alumimun hydroxide prepared from Al-isopropoxide. AlN ceramics with Y2O3 and CaO were prepared by hot-pressing under the pressure of 30 MPa at 180$0^{\circ}C$ for 1 h in N2 atmosphere. Grain boundary behavior and purification mechanism of AlN lattice were examined by heat treatment of AlN ceramics at 185$0^{\circ}C$ for 1-6 h in N2 atmosphere. AlN ceramics without sintering additives showed poor sinterability. However, Y2O3-doped and CaO-doped AlN ceramics were fully densified nearly to theoretical density. As the heat treatment time increased, c-axis lattice parameter increased. This is attributed to the removal of Al2O3 in AlN lattice. This purification effect of AlN attice depended upon the quantity of secondary oxide phase in the inintial stage of heat treatment and the heat treatment time.

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Ecological Studies on the Coastal Plants in Korea -On the Sand Duen Vegetation of the Western Coast- (韓國海岸植物의 生態學的 硏究 - 西海岸의 沙丘植生에 關하여 -)

  • Lee,Woo Tchul;Sang-Keun Chon
    • The Korean Journal of Ecology
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    • v.7 no.2
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    • pp.74-84
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    • 1983
  • The dominant species of the sand vegetation in the western coast of Korea were Carex pumila, Ischaemum antheporoides, Calystegia soldanella, Carex kobomugi and Imperata cylindrica var. koenigii. The salt content of the sand dune soil and of the atmosphere of surveyed areas ranged from 3.93 to 13.86 mg% and from 25.81 to 168.86mg% respectively. Between the salt content of the atmosphere and that of the soil positive relationship was found. Species density and Simpson's index increased with the distance from the coast, the former was exponential, however, the latter was linear. The composition of biological types in the investigated stands were H-D4-R1-3-e or H-D4-R1-3-t. Relative numbers of psammophytes and rhizome psammophytes decreased with the distance from the coast, but those of other plants increased. The standing crop of the sand dune vegetation ranged from 0.04 to 491.64g/m2 and the average 27.77g/m2. This was varied as the stands and showed a linear increment as the distance from the coast was increased. The salt content of atmosphere significantly affected the density, T/R ratio in the standing crop and Simpson's index. The salt content of soil showed similar tendency on the density and the T/R ratio.

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Superconducting transitions of LuBa2Cu3O7-z heated under various atmospheres

  • Lee, M.S.;Lee, H.K.
    • Progress in Superconductivity and Cryogenics
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    • v.16 no.1
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    • pp.6-8
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    • 2014
  • The influence of quenching temperature, heating atmosphere and annealing time on superconducting characteristics has been studied for $LuBa_2Cu_3O_{7-z}$ compound which has been recently synthesized in a nearly phase-pure form. Resistivity measurements for the as-prepared sample heated at $300^{\circ}C$ in oxygen and subsequently quenched into liquid nitrogen revealed that there is no significant change in $T_c$. On the other hand, $T_c$ of the sample slightly increased when the sample was heated at $300^{\circ}C$ either in air or in $N_2$ atmosphere. It was also found that $T_c$ of the sample decreased when the annealing temperature in $N_2$ atmosphere increased above $400^{\circ}C$. The experimental results indicated that the as-prepared sample is under overdoped state. The enhanced superconducting transition observed in the samples after heating at $300^{\circ}C$ in air or $N_2$ atmosphere was discussed in conjunction with a slight removal of oxygen and ordering of oxygen atoms in the as-prepared sample.

High-Temperature Vaporization of $MgFe_2O_4$ in $H_2-CO_2$ Aatmosphere ($H_2-CO_2$ 분위기하에서 $MgFe_2O_4$의 고온증발)

  • 이홍림;최승철
    • Journal of the Korean Ceramic Society
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    • v.19 no.3
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    • pp.193-198
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    • 1982
  • The vaporization of $MgFe_2O_4$ was studied in $H_2-CO_2$ atmosphere over the temperature range of 600 to 90$0^{\circ}C$ by means of the transpiration method. It was found that the rate of vaporization for $MgFe_2O_4$ is controlled by a first order phase-boundary chemical reaction. The obtained activation energy of vaporization is 17.1 Kcal/mol.

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Hydrogen Behavior in the Steelmaking Process (제강공정에서 수소의 거동)

  • Shim, Sang-chul;Cho, Jung-wook;Hwang, Sang-taek;Kim, Kwang-chun
    • Korean Journal of Metals and Materials
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    • v.46 no.10
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    • pp.662-671
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    • 2008
  • The behavior of hydrogen in the steel making process was investigated. The relation between the composition of ladle slag and hydrogen concentration in molten steel was considered. The hydrogen distribution ratio between ladle slag and molten steel was increased with increasing basicity of the slag; it was about 20 when the basicity of slag was 15. Hydroxyl capacity measured from the hydrogen distribution ratio between slag and the molten steel was comparatively corresponding to the value of hydroxyl capacity measured by the equilibrium reaction of slag and $H_2O$ gas. However, it is considerably different from the value calculated by regular solution model. The influence of hydrogen on a sticking type breakout is considered. The effect of hydrogen and $H_2O$ gas on the crystallization behavior of mold powder was investigated by DHTT (Dual hot thermocouple technique). As a result, it was proved that mold powder could be crystallized by $H_2O$ gas in the atmosphere. Therefore, it is concluded that $H_2O$ gas in the atmosphere can be a possible cause of the sticking type breakout that occasionally occurs in the continuous casting process.

A SIGNATURE OF CHROMOSPHERIC ACTIVITY IN BROWN DWARFS: A RECENT RESULT FROM NIRLT MISSION PROGRAM

  • Sorahana, Satoko;Suzuki, Takeru K.;Yamamura, Issei
    • Publications of The Korean Astronomical Society
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    • v.32 no.1
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    • pp.131-133
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    • 2017
  • We present the latest results from the Mission Program NIRLT (PI: I.Yamamura), the near-infrared spectroscopy of brown dwarfs using the AKARI/IRC grism mode with the spectral resolution of ~ 120. The near-infrared spectra in the wavelength range between 2.5 and $5.0{\mu}m$ are especially important to study the brown dwarf atmospheres because of the presence of major molecular bands, including $CH_4$ at $3.3{\mu}m$, $CO_2$ at $4.2{\mu}m$, CO at $4.6{\mu}m$, and $H_2O$ around $2.7{\mu}m$. We observed 27 sources, and obtained 16 good spectra. Our model fitting reveals deviations between theoretical model and observed spectra in this wavelength range, which may be attributed to the physical condition of the upper atmosphere. The deviations indicate additional heating, which we hypothesize to be due to chromospheric activity. We test this effect by modifying the brown dwarf atmosphere model to artificially increase the temperature of the upper atmosphere, and compare the revised model with observed spectra of early- to mid-L type objects with $H{\alpha}$ emission. We find that the chemical structure of the atmosphere changes dramatically, and the heating model spectra of early-type brown dwarfs can be considerably improved to match the observed spectra. Our result suggests that chromospheric activity is essential to understand early-type brown dwarf atmospheres.

Effect of annealing atmosphere on the properties of chemically deposited Ag2S thin films

  • Pawar, S.M.;Shin, S.W.;Lokhande, C.D.;Kim, J.H.
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.05a
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    • pp.34.2-34.2
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    • 2009
  • The silver sulphide (Ag2S) thin films have been chemically deposited from an alkaline medium (pH 8 to 10) by using a silver nitrate and thiourea as a Ag and S ion precursor sources. Ethylene Damine tetraacetic acid (EDTA) was used as a complexing agent. The effect of annealing atmosphere such as Ar, N2+H2S and O2 on the structural, morphological and optical properties of Ag2S thin films has been studied. The annealed films were characterized by using X-ray diffraction (XRD), scanning electron microscopy (SEM) and optical absorption techniques for the structural, morphological, and optical properties, respectively. XRD studies reveal that the as-deposited thin films are polycrystalline with monoclinic crystal structure, is converted in to silver oxide after air annealing. The surface morphology study shows that grains are uniformly distributed over the entire surface of the substrate. Optical absorption study shows the as-deposited Ag2S thin films with band gap energy of 0.92eV and after air annealing it is found to be 2.25 eV corresponding to silver oxide thin films.

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Seasonal and Spatial Variations of CO2 Fluxes Between Surface and Atmosphere in Foreshore, Paddy Field and Woods Sites (갯벌, 논 및 산림 부지에서 지표와 대기 사이의 이산화탄소 플럭스 계절/공간 변동 분석)

  • Kang, Dong-Hwan;Kwon, Byung-Hyuk;Yu, Hun-Sun;Kim, Park-Sa;Kim, Kwang-Ho
    • Journal of Environmental Science International
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    • v.20 no.8
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    • pp.963-975
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    • 2011
  • For this research, they were monitored $CO_2$ flux and environmental factors ($CO_2$ concentration, soil temperature, soil moisture, soil organic carbon, soil pH, soil Eh) in foreshore, paddy field and woods sites at the winter season (January 2009) and the summer season (September 2009). Seasonal and spatial variations for monitored data were analyzed, and linear regression functions of $CO_2$ flux as environmental factors were estimated. $CO_2$ fluxes averaged between surface and atmosphere monitored in foreshore and paddy field at the winter season were shown $-8\;mgCO_2m^{-2}hr^{-1}$ and $-25\;mgCO_2m^{-2}hr^{-1}$, respectively. $CO_2$ fluxes averaged between surface and atmosphere monitored in foreshore and paddy field at the summer season were shown $47\;mgCO_2m^{-2}hr^{-1}$ and $117\;mgCO_2m^{-2}hr^{-1}$, respectively. Thus, $CO_2$ was sunk from atmosphere to surface at the winter season and it was emitted from surface to atmosphere at the summer season. $CO_2$ fluxes in woods site were emitted $145\;mgCO_2m^{-2}hr^{-1}$ at the winter season and $279\;mgCO_2m^{-2}hr^{-1}$ at the summer season.