• Title/Summary/Keyword: $Ga_{2}O_{3}$

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Preparation and Luminescent Properties of Zn2SiO4:Mn, Ga Phosphors (Zn2SiO\4:Mn, Ga 형광체의 제조와 발광특성)

  • Lee, Ji-Young;Yu, Yun-Sik;Yu, Il
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.2
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    • pp.158-162
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    • 2009
  • $Zn_2SiO_4$:Mn green phosphors doped with Ga for PDP were synthesized by solid state reaction method. Photoluminescence measurements showed a new emission peak at around 600 nm for $Zn_2SiO_4$:Mn phosphors doped with Ga. Also, the luminescent color with doping $Ga^{3+}$ in the $Zn_2SiO_4$:Mn phosphors changed to green from yellowish green. Consequently, the new peak and charge of the luminescent color in the $Zn_2SiO_4$:Mn, Ga phosphors were attributed to $^2E{\rightarrow}^6A_2$ transition of $Mn^{4+}$.

Characteristics of Ga2O3/4H-SiC Heterojunction Diode with Annealing Process (후열 처리에 따른 Ga2O3/4H-SiC 이종접합 다이오드 특성 분석)

  • Lee, Young-Jae;Koo, Sang-Mo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.33 no.2
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    • pp.155-160
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    • 2020
  • Ga2O3/n-type 4H-SiC heterojunction diodes were fabricated by RF magnetron sputtering. The optical properties of Ga2O3 and electrical properties of diodes were investigated. I-V characteristics were compared with simulation data from the Atlas software. The band gap of Ga2O3 was changed from 5.01 eV to 4.88 eV through oxygen annealing. The doping concentration of Ga2O3 was extracted from C-V characteristics. The annealed oxygen exhibited twice higher doping concentration. The annealed diodes showed improved turn-on voltage (0.99 V) and lower leakage current (3 pA). Furthermore, the oxygen-annealed diodes exhibited a temperature cross-point when temperature increased, and its ideality factor was lower than that of as-grown diodes.

${\beta}-Ga_2O_3$ Nanomaterials Synthesized from Mechanically Ground GaN Powders by a Thermal Annealing (기계적으로 연마한 GaN 분말로부터 열처리로 합성된 ${\beta}-Ga_2O_3$ 나노물질)

  • Park, Kwang-Soo;Sun, Kyu-Tae;In, Ki-Joo;Sung, Man-Young;Kim, Sang-Sig
    • Proceedings of the KIEE Conference
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    • 2001.11a
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    • pp.158-160
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    • 2001
  • ${\beta}-Ga_2O_3$ nanobelts and nanoparticles were synthesized by a thermal annealing of as-milled GaN powders at $930^{\circ}C$ in nitrogen and oxygen atmosphere. respectively. The width of the nanobelts are $20\;nm{\sim}1000\;nm$. the thickness of the nanobelts are 100 nm. A bundle of the nanobelts is several centimeters in length. The lattice structure of these nanobelts and nanoparticles was identified to be a monoclinic ${\beta}-Ga_2O_3$ by X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), and selected area electron diffraction (SAED).

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Effects of Doping Concentration on the Properties of Ga-doped ZnO Thin Films Prepared by RF Magnetron Sputtering (Ga의 도핑농도에 따른 ZnO 박막의 특성)

  • Kim, Hyoung Min;Ma, Dae Young;Park, Ki Cheol
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.12
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    • pp.984-989
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    • 2012
  • We have investigated the structural, electrical and optical properties of Ga-doped ZnO (GZO) thin films prepared by RF magnetron sputtering with laboratory-made ZnO targets containing 1, 3, 5, 7 wt% of $Ga_2O_3$ powder as a doping source. The GZO thin films show the typical crystallographic orientation with c-axis regardless of $Ga_2O_3$ content in the targets. The $3,000{\AA}$ thick GZO thin films with the lowest resistivity of $7{\times}10^{-4}{\Omega}{\cdot}cm$ are obtained by using the GZO ($Ga_2O_3$= 5 wt%) target. Optical transmittance of all films shows higher than 80% at the visible region. The optical energy band gap for GZO films increases as the carrier concentration ($n_e$) in the film increases.

Wet etching of α-Ga2O3 epitaxy film using a HCl-based solution (HCl 용액을 이용한 α-Ga2O3 epitaxy 박막의 습식 식각)

  • Choi, Byoung Su;Um, Ji Hun;Eom, Hae Ji;Jeon, Dae-Woo;Hwang, Sungu;Kim, Jin Kon;Yun, Young Hoon;Cho, Hyun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.32 no.1
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    • pp.40-44
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    • 2022
  • Wet etching of α-Ga2O3 epitaxy film was performed using a 35 % hydrochloric (HCl) acid solution. As the temperature of the 35 % HCl solution increased, the α-Ga2O3 etch rate increased, and the etch rate of 119.6 nm/min was obtained at 75℃, the highest temperature examined in this work. The activation energy for etch reaction was determined to be 0.776 eV, and this suggests that the wet etching of α-Ga2O3 in the 35 % HCl solution was dominated by the reaction-limited mechanism. AFM analysis showed that the surface roughness of the etched surface increased as the temperature of the etchant solution increased.

Fabrication and characterization of Zn-O-Ga structures by RF magnetron co-sputtering method

  • Hwang, Chang-Su;Park, In-Cheol;Kim, Hong-Bae
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.201-201
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    • 2010
  • 본 연구에서는 RF magnetron co-sputtering을 이용하여 Zn-O-Ga 구성비에 따른 광투과도 및 전기적 특성을 연구하였다. 타겟으로 ZnO 및 $Ga_2O_3$ 소결체를 이용하였으며, 두 개의 RF magnetron sputter의 RF power를 동시에 조절하여 타겟의 구성비를 조절하였으며, 기판과 타겟의 거리를 25 mm~75 mm 범위 내에 조절하여 거리에 따른 Zn-O-Ga 박막의 광투과 특성 및 전기적 특성을 관찰하였다. $Ga_2O_3$ 소결체의 magnetron sputter의 RF power를 30 watt에서 100 watt로 증가함에 따라 박막내의 Ga 성분은 0.5%에서 7.4%로 증가하였으며 Zn 성분은 46.3%에서 40.9%로 O성분은 53.2%에서 51.6%로 각각 줄어들었다. 이에 따라 ZnO의 우선방위 (002) 결정각($2{\theta}$)은 34.24에서 33.87로 줄어들었으며, 이동도 $5.5\;cm^2/Vs$ 에서 $1.99\;cm^2/Vs$ 정도로 감소하는 경향을 보였다. 광투과도는 가시광선 영역에서 85% 이상 보였으며, carrier 밀도는 $0.5\;{\sim}\;4.0^*10^{20}/cm^3$로 증가함에 따라 이동도는 $1.5{\sim}5.5\;cm^2/Vs$로 투명전도막의 특성을 보였다.

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Optical properties of the glass fiber by adding Ga$_2$O$_3$ in the SiO$_2$-PbO-K$_2$O-Al$_2$O$_3$ system for Infrared sensor (Ga$_2$O$_3$ 첨가에 따른 SiO$_2$-PbO-K$_2$O-Al$_2$O$_3$계 적외선 센서용 Glass fiber의 광학적 특성)

  • 윤상하;강월호
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.05a
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    • pp.68-71
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    • 1996
  • In the study, the thermal and optical properties of SiO$_2$-PbO-K$_2$O-Al$_2$O$_3$ g1asses were investigated. According to Ga$_2$O$_3$ addictions, the properties of bulk glass, transition temperature and softening temperature were increased, whereas thermal expansion coefficient was decreased; In the optical properties, refractive index was increased, and IR cut-off wavelength was enlarged from 4.64$\mu\textrm{m}$ to 5.22$\mu\textrm{m}$. But, the optical loss of fiber was decreased.

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Electrical and optical properties in relation to Ga concentration of GZO films deposited by DC magnetron sputtering (DC 마그네트론 스퍼터링법으로 증착한 GZO 박막의 Ga 함량에 따른 전기적 및 광학적 특성)

  • Lee, Jeong-Cheol;Park, Sang-Eun;Lee, Jin-Ho;Song, Pung-Geun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2007.11a
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    • pp.95-96
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    • 2007
  • DC magnetron sputtering 법으로 다양한 $Ga_2O_3$함량비( $2.27{\sim}$ 10.81 wt%)를 가진 고밀도 GZO 소결타겟을 사용하여 GZO박막을 증착한 후 도핑농도에 따른 광학적 특성과 전기적 특성을 조사하였다. GZO($Ga_2O_3$: 6.65 wt%)타겟을 사용하여 기판온도 $300^{\circ}C$에서 증착한 GZO박막은 상대적으로 낮은 비저항($5.1{\times}10^{-4}$ ${\Omega}cm$)과 85% 이상의 높은 투과율을 보였다. 또한 타겟의 $Ga_2O_3$함량이 6.65 wt%일때 광학적 밴드갭 에너지는 3.61 eV로 비교적 큰 흡수계수의 변화를 보였으며 그 이상의 $Ga_2O_3$농도에서는 밴드갭 에너지가 감소하는 경향을 보였다.

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Mössbauer Studies of CoGa0.1Fe1.9O4 Nanoparticles (나노분말 CoGa0.1Fe1.9O4의 Mössbauer 분광학적 연구)

  • Lee, Seung-Wha
    • Journal of the Korean Magnetics Society
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    • v.16 no.2
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    • pp.144-148
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    • 2006
  • $CoGa_{0.1}Fe_{1.9}O_4$ nanoparticles have been prepared by a sol-gel method. The structural and magnetic properties have been investigated by XRD, SEM, VSM and $M\ddot{o}ssbauer$ spectroscopy. $CoGa_{0.1}Fe_{1.9}O_4$ powder that was annealed at $250^{\circ}C$ has spinel structure and behaved superparamagnetically. The estimated size of superparammagnetic $CoGa_{0.1}Fe_{1.9}O_4$ nanoparticle is around 10 nm. The hyperfine fields at 4.2 K f3r the A and B patterns were found to be 518 and 486 kOe, respectively. The blocking temperature $(T_B)$ of superparammagnetic $CoGa_{0.1}Fe_{1.9}O_4$ nanoparticle is about 250 K. The magnetic anisotropy constant of $CoGa_{0.1}Fe_{1.9}O_4$ nanoparticle was calculated to be $3.0X10^5\;ergs/cm^3$. $CoGa_{0.1}Fe_{1.9}O_4$ nanoparticle was annealed at $250^{\circ}C$ will be used to candidate for biomedicine applications as magnetic carriers.

The Effects of $Y_{2}O_{3}$ and $Ga_{2}O_{3}$ Addtives on the Microstructure and Piezoelectric Properties of PNN-PZ-PT Ceramics (PNN-PZ-PT 세라믹스의 미세구조 및 암전특성에 대한 $Y_{2}O_{3}$$Ga_{2}O_{3}$의 첨가효과)

  • Kwon, Jeong-Ho;Choi, Hae-Yun;Jeong, Yeon-Hak;Kim, Il-Won;Song, Jae-Sung;Jeong, Soon-Jong;Lee, Jae-Shin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.334-337
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    • 2002
  • In this study, the microstructure, dielectric and piezoelectric properties of $0.15Pb(Ni_{1/3}Nb_{2/3})O_3-0.85(PbZr_{0.5}Ti_{0.5})O_3$(0.15PNN-0.85PZT) ceramics having compositions near the morphotropic phase boundary(MPB) was investigated with respect to the variation of $Y_2O_3$ and $Ga_2O_3$ addition amount. The dielectric properties increased and piezoelectric properties decreased with increasing the amount of $Ga_2O_3$. The solubility limit of $Y_2O_3$ is 0.5mol% in this system. The electro-mechanical coupling factor$(K_p)$ and dielectric constant(${\varepsilon}_r$) were 58.6% and 1755 when the amount of $Y_2O_3$ are 0.5mol%.

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