• Proceedings of the KIPE Conference
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• 2017.07a
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• pp.455-456
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• 2017

본 논문에서는 리튬 인산철 배터리($LiFePO_4$)의 내부 파라미터 추출 방법으로 전기화학적 기반인 정전류식 간헐적 적정 테크닉(galvanostatic intermittent titration technique;GITT)을 사용하였다. 배터리 관리 시스템(battery management system;BMS) 알고리즘의 기본적으로 들어가는 충방전 저항을 미세 구간으로 나누어 볼 수 있다. SOC(state-of-charge)에 맞는 저항 성분을 찾을 수 있고, 미소 용량 정보를 알아내어 특정 SOC 구간에서의 LFP 배터리 최적 운용 구간을 알 수 있다.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2007.06a
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• pp.350-351
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• 2007

The $LiFePO_4$ as cathode materials for lithium ion batteries was synthesized by the solid-state reaction using ballmiller and employed one step heat treatment at $650^{\circ}C$. The influence of the heating time on the structure, particle size and cycle performance was investigated. $LiFePO_4$ heated at $650^{\circ}C$ for 3 h exhibited higher discharge capacity of 140 mAh/g and excellent cycle performance.

• Proceedings of the KIPE Conference
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• 2018.11a
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• pp.121-122
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• 2018

리튬 인산철(LFP, $LiFePo_4$) 배터리의 경우 다른 종류의 배터리에 비해 내부 파라미터가 비선형적인 단점이 있다. 일반적인 배터리 등가회로 모델을 적용 시, 비선형성으로 인해 추정 성능이 감소한다. 배터리 등가회로 모델을 기반인 확장 칼만 필터(EKF, Extended Kalman Filter)를 통해 SOC (State of Charge) 추정 시 추정성능이 감소할 수 있다. 따라서 본 논문은 LFP 배터리의 SOC 추정 성능 향상을 위해 실시간 파라미터 관측기를 통한 배터리 등가회로 모델을 기반으로 EKF의 내부 파라미터를 분석하고 이에 따른 차등 모델을 제안한다.

• Clean Technology
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• v.30 no.1
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• pp.28-36
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• 2024

As demand for electric vehicles increases, the market for lithium-ion batteries is also rapidly increasing. The battery life of lithium-ion batteries is limited, so waste lithium-ion batteries are inevitably generated. Accordingly, lithium was selectively preleached from waste lithium iron phosphate (LiFePO₄, hereafter referred to as the LFP) cathode material powder among lithium ion batteries, and iron phosphate (FePO₄) powder was recovered. The recovered iron phosphate powder was mixed with alkaline sodium carbonate (Na₂CO₃) powder and heat treated to confirm its crystalline phase. The heat treatment temperature was set as a variable, and then the leaching rate and powder characteristics of each ingredient were compared after water leaching using Di-water. In this study, lithium showed a leaching rate of approximately 100%, and in the case of powder heat-treated at 800 ℃, phosphorus was leached by approximately 99%, and the leaching residue was confirmed to be a single crystal phase of Fe₂O₃. Therefore, in this study, lithium, phosphorus, and iron components were individually separated and recovered from waste LFP powder.

• Microbiology and Biotechnology Letters
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• v.17 no.3
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• pp.247-251
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• 1989

Effects of mineral salts on sisomicin fermentation were investigated. The optimal concentration of CoCl$_2$for accomplishing a high antibiotic yield was found to be 16.8 $\mu$M at which it could function as a cofactor. At this level the other mineral salts tested had no effect. On the other hand, at much higher concentration levels (above 1 mM), four mineral salts such as ZnSO$_4$, KH$_2$PO$_4$, FeSO$_4$and MgSO$_4$were used in order to liberate the intracellular sisomicin out-side the cells, because the sisomicin accumulated mostly in cells and it was supposed to limit the improvement of antibiotic yield. ZnSO$_4$and KH$_2$PO$_4$had no effect at all, and FeSO$_4$brought about some improvement. However, by keeping the concentration of MgSO$_4$to be 25 mM or higher in culture broths, the antibiotic yield could be improved by more than 100%, partially due to the enhanced liberation of the intracellular antibiotic.

• Journal of the Mineralogical Society of Korea
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• v.26 no.3
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• pp.151-160
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• 2013

A column experiment was carried out to study the reaction of Cr(VI) with organic carbon. Chemical analysis for the effluent collected at different times after the reaction of Cr(VI) with organic carbon in compost and SEM observation for the solid samples remaining after the reaction were conducted. Cr(VI) supplied to the column was not detected in the effluent from column at initial stage, but the concentration of Cr(VI) increased abruptly and maintained the initial supplied concentration (20 mg/kg), indicating that Cr(VI) was effectively removed from the solution at the first state. In general, the concentrations of cations and anions with the exception of $PO_4$ increased and decreased again. Considering that most of these ions were not detected or showed very low concentration, these ions are considered to originate from the organic carbon in the column. SEM observation showed that Cr was coprecipitated with Fe on the surface of organic carbon with small amount of other metals such as Mn, No, and Co. This indicated that on the reduction condition on the organic carbon, Cr(VI) was reduced to $Cr(OH)_3$ and coprecipitated with $Fe(OH)_3$, and that Fe is very important in the precipitation of Cr. After the soluble Fe and Mn are not dissolved any more, $Cr(OH)_3$ is not precipitated. Different from other ions, the concentrations of $PO_4$ decreased and increased, which was thought to be the result of the release of $PO_4$ from organic carbon and sorption on the precipitates. After the maximum sorption on the precipitates and no further release of Fe, the concentration of $PO_4$ returns to its original value measured for the ones released from the organic carbon.

• Journal of Electrochemical Science and Technology
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• v.9 no.2
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• pp.85-92
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• 2018

Olivine structure of $LiFePO_4$ (LFP) is one of the most commonly used materials in aqueous rechargeable lithium batteries (ARLBs), and can store and release charge through the insertion/de-insertion of $Li^+$ between LFP and FP. We have fabricated LFP and LFP/FP electrodes on titanium paper and studied their electrochemical properties in 2 M $Li_2SO_4$. The LFP/FP electrode was determined to be a suitable electrode for electo-ostmotic pump (EOP) in terms of efficiency in water and 0.5 mM $Li_2SO_4$ solution. Experiments to determine the effect of cations and anions on the performance of EOP using LFP/FP electrode have shown that $Li^+$ is the best cation and that the anion does not significantly affect the performance of the EOP. As the concentration of $Li_2SO_4$ solution was increased, the current increased. The flow rate peaked at $4.8{\mu}L/30s$ in 1.0 mM $Li_2SO_4$ solution and then decreased. When the EOP was tested continuously in 1.0 mM $Li_2SO_4$ solution, the EOP transported approximately 35 mL of fluid while maintaining a stable flow rate and current for 144 h.

• Proceedings of the Korean Magnestics Society Conference
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• 2009.05a
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• pp.29-30
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• 2009

• Proceedings of the Korean Ceranic Society Conference
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• 2003.10a
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• pp.212.1-212
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• 2003

• Journal of the Korean Magnetics Society
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• v.17 no.2
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• pp.65-70
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• 2007

In this paper, we composed the $LiFePO_4$ for the reversible use as the replacement material of the Li ion batteries and confirmed the good quality of the structure of the samples with the sintering temperature $675^{\circ}C,\;750^{\circ}C,\;and\;800^{\circ}C$ for 30 hours at nitrogen atmosphere. We also investigated the size of the particles through SEM picture and the change of the sintering temperature and the $Fe^{+3}$ content after charging the materials with 1 V, 160 mA and 3 V, 40 mA for 3 hours by Mossbauer spectroscopy. Also we can observe the increase on the $Fe^{+3}$ content at the charge condition and the increase of the amount ratio of the $Fe^{+3}$ ion only in sintering temperature $675^{\circ}C$ according to the increase of the electric charge. We cannot observe the change of the $Fe^{+3}$ ion in sintering temperature $800^{\circ}C$ after charging.