• Title/Summary/Keyword: $FePO_4$

Search Result 344, Processing Time 0.035 seconds

Synthesis of Pd/Cu-Fe polymetallic nanoparticles for in situ reductive degradation of p-nitrophenol

  • Wenbin, Zhang;Lanyu, Liu;Jin, Zhao;Fei, Gao;Jian, Wang;Liping, Fang
    • Membrane and Water Treatment
    • /
    • v.13 no.2
    • /
    • pp.97-104
    • /
    • 2022
  • With a small particle size, specific surface area and chemical nature, Pd/Cu-Fe nanocomposites can efficiently remove the organic compounds. In order to understand the applicability for in situ remediation of contaminated groundwater, the degradation of p-nitrophenol by Pd/Cu-Fe nanoparticles was investigated. The degradation results demonstrated that these nanoparticles could effectively degrade p-nitrophenol and near 90% of degradation efficiency was achieved by Pd/Cu-Fe nanocomposites for 120 min treatment. The efficiency of degradation increased significantly when the Pd content increased from 0.05 wt.% and 0.10 wt.% to 0.20 wt.%. Meanwhile, the removal percentage of p-nitrophenol increased from 75.4% and 81.7% to 89.2% within 120 min. Studies on the kinetics of p-nitrophenol that reacts with Pd/Cu-Fe nanocomposites implied that their behaviors followed the pseudo-first-order kinetics. Furthermore, the batch experiment data suggested that some factors, including Pd/Cu-Fe availability, temperature, pH, different ions (SO42-, PO43-, NO3-) and humic acid content in water, also have significant impacts on p-nitrophenol degradation efficiency. The recyclability of the material was evaluated. The results showed that the Pd/Cu-Fe nanoparticles have good recycle performance, and after three cycles, the removal rate of p-nitrophenol is still more than 83%.

Production of Microbial Ghitosan from Rhizopus japonicus (Rhizopusjaponicus균체에 의한 키토산의 생산)

  • 박헌국;이계호
    • The Korean Journal of Food And Nutrition
    • /
    • v.9 no.3
    • /
    • pp.336-340
    • /
    • 1996
  • Rhizopus japonicus had the highest chitosan productivity compared with the chitosan productivity among Rhizopus sp. strains. To increase the productivity of microbial chitosan from Rhizopus faponicus, production medium and incubation conditions were optimized. The composition of the medium and the incubation conditions were as follows : starch 2%, yeast extract 2.5%, KH2PO4 0.05%, MgSO4 0.01%, FeSO4 0.002%, MnSO4 0.002%, ZnSO4 0.002%, CaC12 0.002%, PH 5.5, incubation temperature medium compared with chitosan productivity.

  • PDF

Effect of Nitrification Inhibition on Soil Phosphate Release and Nutrient Absorption and Growth of Rice Plant (질산화작용 억제 처리가 논토양의 인산 가용화와 벼의 양분흡수 및 생육에 미치는 영향)

  • Chung, Jong-Bae;Kim, Byoung-Ho
    • Korean Journal of Environmental Agriculture
    • /
    • v.29 no.4
    • /
    • pp.336-342
    • /
    • 2010
  • In a pot experiment, we studied the effect of nitrification inhibition on Fe reduction and P release in paddy soil and growth and nutrient uptake of rice plant. Recommended level of fertilizers, 6 kg N, 5 kg $P_2O_5$ and 4 kg $K_2O$ per 10a, were applied, and for N fertilizer urea, urea+N-serve, and $KNO_3$ were included. Four 30-day-old seedlings were transplanted in a waterlogged 9 L pot filled with Yuga series soil, and 3 pots were prepared in each N fertilizer treatment. Changes of soil redox potential and concentration of ${NH_4}^-$, ${NO_3}^-$, $Fe^{2+}$ and ${PO_4}^{3-}$ in soil solution at 10 cm depth were monitored, and also the growth and nutrient uptake of rice plants were measured. Concentration of ${NH_4}^+$ in soil solution was highest in urea+N-serve treatment, and followed by urea and $KNO_3$ treatments. Addition of N-serve could effectively inhibit nitrification in the soil. In the treatment of $KNO_3$, relatively higher ${NO_3}^-$ concentration was found at 10 cm depth soil. In urea+N-serve treatment redox potential was lower than -100 mV during the experiment, but in the treatment of $KNO_3$ the potential was maintained above 0 mV until ${NO_3}^-$ remaining in soil solution. Reduction of Fe(III) and solubilization of P were highly correlated with redox potential changes in the three N fertilizer treatments. Concentrations of Fe(II) and ${PO_4}^{3-}$ in soil solution at 10 cm depth were much higher in the urea+N-serve treatment. The most vigorous rice seedling growth was found in the urea treatment. Although the availability of N and P in soil was enhanced in the urea+N-serve treatment through the suppression of nitrification, excessive solubilization of Fe could limit the growth of rice plants.

Preparation and Oxygen Permeation Properties of La0.07Sr0.3Co0.2Fe0.8O3-δ Membrane (La0.07Sr0.3Co0.2Fe0.8O3-δ 분리막의 제조 및 산소투과 특성)

  • Park, Jung Hoon;Kim, Jong Pyo;Baek, Il Hyun
    • Applied Chemistry for Engineering
    • /
    • v.19 no.5
    • /
    • pp.477-483
    • /
    • 2008
  • $La_{0.7}Sr_{0.3}Co_{0.2}Fe_{0.8}O_{3-{\delta}$ oxide was synthesized by a citrate method and a typical dense membrane of perovskite oxide has been prepared using as-prepared powder by pressing and sintering at $1300^{\circ}C$. Precursor of $La_{0.7}Sr_{0.3}Co_{0.2}Fe_{0.8}O_{3-{\delta}$ prepared by citrate method was investigated by TGA and XRD. Metal-citrate complex in precursor was decomposed into perovskite oxide in the temperature range of $260{\sim}410^{\circ}C$ but XRD results showed $SrCO_3$ existed as impurity at less than $900^{\circ}C$. Electrical conductivity of membrane increased with increasing temperature but then decreased over $700^{\circ}C$ in air atmosphere ($Po_2=0.2atm$) and $600^{\circ}C$ in He atmosphere ($Po_2=0.01atm$) respectively due to oxygen loss from the crystal lattice. The oxygen permeation flux increased with increasing temperature and maximum oxygen permeation flux of $La_{0.7}Sr_{0.3}Co_{0.2}Fe_{0.8}O_{3-{\delta}$ membrane with 1.6 mm thickness was about $0.31cm^3/cm^2{\cdot}min$ at $950^{\circ}C$. The activation energy for oxygen permeation was 88.4 kJ/mol in the temperature range of $750{\sim}950^{\circ}C$. Perovskite structure of membrane was not changed after permeation test of 40 h and the membrane was stable without secondary phase change with 0.3 mol Sr addition.

Applications of Nutrient-Controlling and Growth-Regulating Chemicals to Enhance Yield of Once-Over Harvest Red Pepper (Capsicum annuun L.)

  • Ahn, Byung-Koo;Kim, Hyeong-Goog;Kim, Myung-Jun;Lee, Jin-Ho
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.44 no.4
    • /
    • pp.575-580
    • /
    • 2011
  • The cultivation of once-over harvest pepper cultivars might be very valuable to Korean farmers who still depend on traditional hand-harvesting method. Thus, we conducted this experiment to obtain important information for enhancing the productivity of once-over harvest red pepper fruits by supplying several nutrient-controlling and growth-regulating chemicals, such as $KH_2PO_4$, $SiO_2$ and 2-chloroethylphosphonic acid (ethephon). Adequate fertilization was provided in each treatment plots. In this study, two once-over harvest pepper cultivars, Saengryeg No. 211 and 213 (SR 211 and SR 213), and one regular piecemeal harvest pepper cultivar, Kangryegdaetong (KRDT), were cultivated to evaluate the productivity of pepper fruit as affected by above chemicals. The distribution of macro- and micro-nutrients in pepper fruits among the cultivars were different in term of N, B, Cu, and Fe concentrations. In particular, the concentration of B in SR 213 was about 2 times higher than that in SR 211 and KRDT. However, overall red pepper productivity of SR 211 was markedly higher ($2.91{\sim}3.38Mg\;ha^{-1}$) than that ($1.68{\sim}2.37Mg\;ha^{-1}$) of SR 213. Also, the productivity of matured red pepper was significantly influenced by the treatments of $KH_{2}PO_{4}$, $SiO_2$ and ethephon. The yield indices for matured red pepper fruits were the highest with the treatment of $KH_2PO_4$ or $SiO_2$ with ethephon, which were 113~116% for SR 211 and 147~150% for SR 213. Thus, the applications of $KH_2PO_4$ or $SiO_2$ with ethephon would be suggested to enhance the productivity of matured red pepper fruit.

Studies on the production of lysine by fermentation process (1) -Isolation of lysine producing microorganisms and cultural conditions of lysine accumulation- (발효에 의한 라이신(L-lysine) 생산에 관한 연구(1) -라이신 생산균주의 분리 및 라이신 생산조건의 검토-)

  • Mheen, Tae-Ick;Kwon, Tai-Wan
    • Korean Journal of Food Science and Technology
    • /
    • v.3 no.1
    • /
    • pp.68-77
    • /
    • 1971
  • Ninty four strains of lysine producing micro-organisms in culture broth during fermentation have been isolated from soil and other sources. From the comparison of the amounts of lysine produced, 6 strains have been selected as the potentially useful strains, and identified tentatively as Micrococcus sp. (S-16-4), Corynebactcrium sp. (S-27-12, S-281-3, CBY-4) and Brevibacterium sp. (M-6-71, F-629-2), respectively. From the further studies with Corynebacterium sp., S-27-12, its maximum yield was found to be 4mg lysine/ml of synthetic medium, consist of glucose(7.5%), urea(0.6%), $KH_2PO_4(0.2%)$, $Na_2HPO_4(0.05%)$, $MgSO_4{\cdot}7H_2O(0.03%)$, $MnSO_4{\cdot}4H_2O(0.001%)$ and $FeSO_4{\cdot}7H_2O(0.0005%)$ at pH 7.2 and $30^{\circ}C$ after 4 days.

  • PDF

The State and Sources of Contamination with Heavy Metals and Anion in Stream Within Chonju City (전주시 하천의 중금속과 음이온에 대한 수질현황 및 오염원)

  • 오창환;이지선;김강주;정성석;황갑수;이영엽
    • Economic and Environmental Geology
    • /
    • v.34 no.1
    • /
    • pp.89-104
    • /
    • 2001
  • The Chonju and Samchun streams are passing though Chonju city and several contamination sources are located along these streams. The Samchun stream joins the Chonju stream in the Gosapyeong waste disposal site and the Chonju stream finally joins to the Mankyeong River. The objectives of this study are to determine the state and sources of contamination for heavy metals and anions in the Chonju and Samchun streams and to evaluate the effect of these streams on the contamination of the Mankyeong River. In order to select sampling locations, a stratified random sampling method was used. These streams was divided into several parts according to the expected contamination state, and samples were selected randomly from these parts. Generally, the water qualities of these streams were generally below the Drinking Water Level at the time of sampling in various heavy metals and anions. However, the levels of AI, Fe, $NH_{3}-N,Cl^{-}$, Cl- in these streams could be higher during dry season due to continuous inputs from various contamination sources. This study identified several contamination sources for these streams; two waste disposal sites along these streams for Fe, Mn, AI, Zn and $Cl^{-}$, the Chonju Waste Water Treatment Plant for Zn, Mn, $Cl^{-}$, $SO_{4}S$, $NO_{2}N$, and $NH_{3}-N$ and the untreated sewages for AI, Zn, Mn, $Cl^{-}$, $SO_{4}S$, $NH_{3}-N$ and $PO_{4}^{2-}$. This study also revealed that the Chonju stream itself is an important contamination source for Fe, Mn, $Cl^{-}$ and $SO_{4}S$ in the Mankyung River.

  • PDF

Production of Lactic Acid from 1,2-Propanediol by Yeast (1,2-Propanediol로부터 Lactic acid의 생성)

  • Chae, Ki-Soo;Seu, Jung-Hwn
    • Microbiology and Biotechnology Letters
    • /
    • v.9 no.2
    • /
    • pp.51-57
    • /
    • 1981
  • 1,2-propanediol-utilizing yeast, Y-1-4, was isolated from sludge sample by the enrichment culture technique. The product produced from 1,2-propanediol by the selected strain was identified as lactic acid by paper chromatography and infrared absorption spectrum. The strain assimilated ethanol, 1,2-propanediol, glycerine and glucose, but it produced lactic acid from 1,2-propanediol used as the sole carbon source. Under optimal conditions, the strain Y-1-4 was cultured with shaking at 3$0^{\circ}C$ for 4days in the medium containing 1,2-propanediol 20.0g, NH$_4$Cl 5.0g, KH$_2$PO$_4$ 1.0g, MgSO$_4$.7$H_2O$ 0.5g, FeSO$_4$.7$H_2O$ 0.25g, yeast extract 0.4g, CaCO$_3$ 3. 0g and tap water to one liter, and then the yield of lactic acid was about 12. 1g per liter of the culture broth.

  • PDF

Development of ESS Based on VRFB-LFPB Hybrid Batteries (VRFB-LFPB 하이브리드 배터리 기반의 ESS 개발에 관한 연구)

  • Cheon, Young Sik;Park, Jin Soo;You, Jinho;Lee, Jin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.31 no.1
    • /
    • pp.61-67
    • /
    • 2018
  • High-power lithium batteries are suitable for equipment with high power output needs, such as for ESS's initial start-up. However, their management cost is increased by the installation of air-conditioning to minimize the risk of explosion due to internal temperature rise and also by a restriction on the number of charge/discharge cycles. High-capacity flow batteries, on the other hand, have many advantages. They can be used for over 20 years due to their low management costs, resulting from no risk of explosion and a high number of charge/discharge cycles. In this paper, we propose an ESS based on hybrid batteries that uses a lithium iron phosphate battery (LiFePO) at the initial startup and a vanadium redox flow battery (VRFB) from the end of the transient period, with a bi-directional PCS to operate two batteries with different DC voltage levels and using an efficient energy management control algorithm.

Cultural Conditions of Exopolysaccharide KS-1 Produced by Bacillus polymyxa KS-1 (Bacillus polymyxa KS-1에 의한 다당류 KS-1 생산의 발효 조건)

  • 권기석;윤병대주현규
    • KSBB Journal
    • /
    • v.10 no.4
    • /
    • pp.441-448
    • /
    • 1995
  • Optimized fermentation medium and cultural conditions for the production or exopolysaccharide KS-1 with Bacillus polymyxa KS-1 was following as; 30g g1ucose, 2.59g yeast extract, $2.5g KH_2PO_4, 0.5g NaCl, 0.3g MgSO_4.7H_20, 0.1g CaC0_3 0.05g, FeSO_4.7H_2O, and 0.05g MnS0_4 . 4H_20in 1 liter distilled water. The exopolysaccharide production was influenced by the by the temperature and pH, the optimal conditions for the production of exopolysaccharide KS-1 seemed to be $30^{\circ}C$ and pH 7.0, respectively. About $10.3g/\ell$ of maximum exopolysaccharide was obtained al the initial pH 7.0, $30^{\circ}C$, 2vvm of aeration rate and 400 rpm of impeller speed in a jar fermentor.

  • PDF