• Title/Summary/Keyword: $CuLaO_2$

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Simultaneous Removal of NOx/SOx by Catalyst-loaded Cordierite Porous Filter (촉매 담지 코디어라이트 다공성 필터의 NOx/SOx 동시제거에 대한 연구)

  • Lee, Shi-Hee;Chung, Koo-Chun;Kim, Jee-Woong;Shin, Min-Chul;Lee, Hee-Soo
    • Analytical Science and Technology
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    • v.15 no.3
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    • pp.256-262
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    • 2002
  • After porous filters were manufactured using cordierite powder whose mean paricle size was 200${\mu}m$, they were loaded with catalysts such as $V_2O_5$, CuO and $LaCoO_3$ by vacuum impregnation method. And the NOx/SOx simultaneous removal efficiency was measured by passing NO and $SO_2$ through catalyst-loaded ceramic filters. The cordierite porous filters had the apparent porosity of 61.6%, the compressive strength of 12.3 MPa and the pressure drop of 147 pa at the face velocity of 5 cm/sec. According to the analysis of NO/$SO_2$ simultaneous removal efficiency, perovskite $LaCoO_3$ catalyst was the most efficient for the simultaneous NO and $SO_2$ removal. The $LaCoO_3$ catalyst-loaded filter could remove more than 90% for NO and more than 80% for $SO_2$.

Ce0.8Sm0.2O2 Sol-gel Modification on La0.8Sr0.2Mn0.8Cu0.2O3 Cathode for Intermediate Temperature Solid Oxide Fuel Cell

  • Lee, Seung Jin;Kang, Choon-Hyoung;Chung, Chang-Bock;Yun, Jeong Woo
    • Journal of the Microelectronics and Packaging Society
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    • v.22 no.4
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    • pp.77-82
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    • 2015
  • To increase the performance of solid oxide fuel cell operating at intermediate temperature ($600^{\circ}C{\sim}800^{\circ}C$), $Sm_{0.2}Ce_{0.8}O_2$ (SDC) thin layer was applied to the $La_{0.8}Sr_{0.2}Mn_{0.8}Cu_{0.2}O_3$ (LSMCu) cathode by sol-gel coating method. The SDC was employed as a diffusion barrier layer on the yttria-stabilized zirconia(YSZ) to prevent the interlayer by-product formation of $SrZrO_3$ or $La_2Zr_2O_7$. The by-products were hardly formed at the electrolyte-cathode interlayer resulting to reduce the cathode polarization resistance. Moreover, SDC thin film was coated on the cathode pore wall surface to extend the triple phase boundary (TPB) area.

Catalytic Combustion of Benzene over Perovskite-type Oxides Prepared Using Malic Acid Method (능금산법으로 제조된 페롭스카이트형 산화물에서 벤젠의 촉매연소반응)

  • Jung, Won-Young;Hong, Seong-Soo
    • Clean Technology
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    • v.18 no.3
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    • pp.259-264
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    • 2012
  • Perovskite-type oxides were successfully prepared using malic acid method, characterized by TG/DTA, XRD, XPS, TEM and $H_2$-TPR and their catalytic activities for the combustion of benzene were determined. Almost of catalyst showed perovskite crystalline phase and 15-70 nm particle size. The $LaMnO_3$ catalysts showed the highest activity and the conversion reaches almost 100% at $350^{\circ}C$. The catalysts were modified to enhance the activity through substitution of metal into the A or B site of the perovskite oxides. In the $LaMnO_3$-type catalyst, the partial substitution of Sr into site the A-site enhanced the catalytic activity in the benzene combustion. In addition, the partial substitution of Co or Cu into site the B-site also enhanced the catalytic activity and the catalytic activity was in the order of Co > Cu > Fe in the $LaMn_{1-x}B_xO_3$ (B = Co, Fe, Cu) type catalyst.

Study of Laser Ablated Y-Ba-Cu-O Thin Films on $LaAlO_3$(100)Substrates (Laser Ablation에 의하여 $LaAlO_3$(100) 기판 위에 증착된 Y-Ba-Cu-O 박막에 대한 연구)

  • 조윌렴;이규철;고도경;이헌주;노태원;김정구;허필화
    • Journal of the Korean Ceramic Society
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    • v.28 no.12
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    • pp.1005-1011
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    • 1991
  • Y-Ba-Cu-O thin films were in-situ fabricated on LaAlO3(100) substrates using the second harmonics of a pulsed Nd:YAG laser. Thin films were deposited under 200 (mtorr) of oxygen atmosphere, when the substrate temperature was changed between 67$0^{\circ}C$ and 82$0^{\circ}C$. After deposition, the films were in-situ annealed at 50$0^{\circ}C$ under 2/3 bar of oxygen pressure. We showed that the deposition temperature affects the formation of superconducting phase, the resistance, and the surface morphology. The Y-Ba-Cu-O thin films deposited at 76$0^{\circ}C$ show the zero resistance critical temperature of 85 K.

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The Phase Stability and the Electrical Properties of the System $La(Ni_{1-x}Cu_x)O_3$ ($La(Ni_{1-x}Cu_x)O_3$계 화합물의 상안정 및 전기적 특성)

  • 변재동;선호정;송기영
    • Journal of the Korean Ceramic Society
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    • v.28 no.11
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    • pp.873-877
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    • 1991
  • The phase stability and the electrical properties of $La(Ni_{1-x}Cu_x)O_3$ (X=0.2, 0.4, 0.6, 0.8) have been investigated. The single phases were observed in the compositions of X=0.2, 0.4, and these single phases were stable up to $870^{\circ}C$ and $950^{\circ}C$ respectively. The electrical properties of these single phase samples showed metallic behavior similar to LaNiO3 from room temperature to the temperature at which the phase was stable.

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Carbon Dioxide Reduction to Alcoholson Perovskite-Type $La_{0.9}$$Sr_{0.1}$$CuO_3$ Electrodes (페로브스카이트 ($La_{0.9}$$Sr_{0.1}$$CuO_3$) 전극에서 이산화탄소의 전해환원에 의한 알콜류 생성)

  • 김태근;임준혁
    • Journal of Environmental Science International
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    • v.5 no.5
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    • pp.677-682
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    • 1996
  • The electrochemical carbon dioxide reduction to produce acetaldehyde, methanol and ethanol is investigated by using perovskite type electrode ($La_{0.9}$$Sr_{0.1}$$CuO_3$). The experiments were Performed under 100 mA/cm2 and -2 to -2.5 V vs. Ag/AgCl. The highest faradaic efficiencies for methanol, ethanol, acetaldehyde were 11.6, 15.3, and 6.2%, respectively. The experimental data demonstrated that the capability of the perovskite type oxide for the electrode of electrochemical carbon dioxide reduction to produce alcohols was superior to other metal electrode. Key words : Perovskite, Electrode, Alcohol Formation, Electrochemical Reduction, Carbon Dioxide Fixation.

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Growth of the substrate crystals for $La_{2-x}Sr_{x}CuO_{4}$ thick films

  • Watauchi, Satoshi;Tanabe, Hideyoshi;Tanaka, Isao;Kojima, Hironao
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.4
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    • pp.384-386
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    • 1999
  • The distribution coefficients of Ni and Zn to the Cu site in $La_{2-x}Sr_{x}CuO_{4}$(LCO) were investigated to determine the suitable solvent composition ofr crystal growth of $La_{2}{Cu}_{1-x}{M}_{x}{O}_{4}$(M=NI, Zn)(LCMO), and were found to be 4.2 for NI and 0.66 for Zn, respectively. Single crystals of LCO, and LCMO of high homogeneity were grown by traveling solvent floating zone technique using suitable solvents. NO diamagnetic signals were observed for all substituted crystals. This fact suggests that crystals of LCO partially substituted by Ni or Zn are useful as substrate crystals.

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Effect of CuO on the Microstructural and Electrical Properties of (Pb)(La,Nd)$TiO_3$ Ceramics (CuO가 (Pb)(La,Nd)$TiO_3$ 세라믹스에 첨가시 미세구조와 전기적 특성에 미치는 영향)

  • Min, S.K.;Yoo, J.H.;Park, C.Y.;Yoon, H.S.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.446-450
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    • 2001
  • In this study, microstructural and electrical properties of (Pb)(La,Nd)$TiO_3$ cerramics were investigated as a function of CuO addition. Taking into consideration Tc of $325^{\circ}C$, dynamic range of 49dB( at the wafer form) and density of $7.71g/cm^{3}$, it can be concluded that the specimen S2 sintered at $1200^{\circ}C$ is the best for the resonator application, Dynamic characteristics of energy-trapped 20MHz SMD type resonator as a function of internal dot size variation were also investigated. Dynamic range characteristics showed the highest value of 60.72dB at S2-4(dot size 1.13mm).

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Effect of CuO on the Microstructural and Electrical Properties of (Pb)(La,Nd)$TiO_3$ Ceramics (CuO가 (Pb)(La,Nd)$TiO_3$ 세라믹스에 첨가시 미세구조와 전기적 특성에 미치는 영향)

  • 민석규;류주현;박창엽;윤현상
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.446-450
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    • 2001
  • In this study, microstructural and electrical properties of (Pb)(La,Nd)TiO$_3$ ceramics were investigated as a function of CuO addition. Taking into consideration Tc of 3$25^{\circ}C$, dynamic range of 49dB( at the wafer form) and density of 7.71g/㎤, it can be concluded that the specimen S2 sintered at 120$0^{\circ}C$ is the best for the resonator application. Dynamic characteristics of energy-trapped 20MHz SMD type resonator as a function of internal dot size variation were also investigated. Dynamic range characteristics showed the highest value of 60.72dB at S2-4(dot size 1.13mm).

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