• Title/Summary/Keyword: $Cr_{23}C_6$

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Effects of Nitric Oxide Scavenger and Inhibitor on the Development of Bovine IVM/IVF Embryos (Nitric Oxide 화합물 첨가가 소 체외수정란의 체외발육에 미치는 효과)

  • Jang H. Y.;Kim J. T.;Park C. K.;Cheong H. T.;Kim C. I.;Yang B. K.
    • Reproductive and Developmental Biology
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    • v.28 no.3
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    • pp.161-166
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    • 2004
  • This study was designed to evaluate the effects of nitric oxide scavenger (hemoglobin) and inhibitor (L-nitro-L-arginine methyl ester; L-NAME) with or without cumulus cell on the development of bovine IVM/IVF embryos. When CR/sub 1aa/ medium were supplemented with different dosage (lug/m, 5ug/m and 10ug/ml) of hemoglobin at 48hrs for in vitro culture, the proportion of embryos developing beyond morulae stage in 0, 1ug/ml and 5ug/ml with or without cumulus cell were 23.8%, 33.3 % and 26.8%, and 39.5%, 54.8% and 48.8%, respectively. There was a significantly difference the developmental rate of 1ug/ml hemoglobin intact cumulus cells to any other groups (P<0.05). On the other hand, when added to hemoglobin at 96 hrs, 1 ug/ml hemoglobin with cumulus cell group was significantly increased the percentage of developing into morulae and blastocysts to any other groups (P<0.05), and similar trend that of added at 48hrs. The overall means of the percentage of developing into morulae and blstocysts in 1ug/ml hemoglobin group was significantly increased than those of any other groups (P<0.05) and cumulus co-culture with hemoglobin was increased the in vitro developing rate of IVM/IVF embryos. In CR/sub 1aa/ medium treated with L-NAME 0, 10, 50 and 100mM, the developmental rate of morula plus blastocysts were 55.6%, 64.9%, 58.8% and 66.7%, respectively. The L-NAME did not affect the developmental rate and the cell numbers of blastocysts in all treated groups. These results indicate that hemoglobin and cumulus co-culture can increase the proportion of embryos that developed into morulae and blastocysts, but cell numbers of blastocysts were not affect in all groups.

Microstructure of Co-base superalloy prepared by a investment casting (정밀주조법으로 제조된 Co계 초내열 합금의 미세구조)

  • Lee, Jung-Il;Lee, Ho Jun;Cho, Hyun Su;Paeng, Jong Min;Park, Jong Bum;Ryu, Jeong Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.27 no.6
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    • pp.313-318
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    • 2017
  • The microstructure of a cobalt-base superalloy (ECY768) obtained by an investment casting process was studied. This work focuses on the resulting microstructures arising from different melt and mold temperatures in normal industrial environmental conditions. The characterization of the samples was carried out using optical microscopy, field emission scanning electron microscopy and energy-dispersive spectroscopy. In this study, the as-cast microstructure is an ${\alpha}-Co$ (face-centered cubic) dendritic matrix with the presence of a secondary phase, such as $M_{23}C_6-type$ carbides precipitated at grain boundaries. These precipitates are the main strengthening mechanism in this type of alloy. Other minority phases, such as the MC-type phase, was also detected and their presence could be linked to the manufacturing process and environment.

Effects of V and C additions on the Thermal Expansion and Tensile Properties of a High Strength Invar Base Alloy (고강도 인바계 합금의 열팽창 및 인장 특성에 미치는 바나듐과 탄소 원소 첨가 영향)

  • Yun, A.C.;Yun, S.C.;Ha, T.K.;Song, J.H.;Lee, K.A.
    • Transactions of Materials Processing
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    • v.24 no.1
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    • pp.44-51
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    • 2015
  • The current study seeks to examine the effects of V and C additions on the mechanical and low thermal expansion properties of a high strength invar base alloy. The base alloy (Fe-36%Ni-0.9%Co-2.75%Mo-0.7Cr-0.23Mn-0.17Si-0.3%C, wt.%) contains $Mo_2C$ carbides, which form as the main precipitate. In contrast, alloys with additions of 0.4%V+0.3%C (alloy A) or 0.4%V+0.45%C (alloy B) contain $Mo_2C$+[V, Mo]C carbides. The average thermal expansion coefficients of these high strength invar based alloys were measured in the range of $5.16{\sim}5.43{\mu}m/m{\cdot}^{\circ}C$ for temperatures of $15{\sim}230^{\circ}C$. Moreover, alloy B showed lower thermal expansion coefficient than the other alloys in this temperature range. For the mechanical properties, the [V, Mo]C improved hardness and strengths(Y.S. and T.S.) of the high strength invar base alloy. T.S.(tensile strength) and Y.S.(yield strength) of hot forged alloy B specimen were measured at 844.6MPa and 518.0MPa, respectively. The tensile fractography of alloy B exhibited a ductile transgranular fracture mode and voids were initiated between the [V, Mo]C particles and the matrix. Superior properties of high strength and low thermal expansion coefficient can be obtained by [V, Mo]C precipitation in alloy B with the addition of 0.4%V and 0.45%C.

PWHT Cracking Susceptibility in the Weld Heat-Affected Zone of Reduced Activation Ferritic/Martensitic Steels (핵융합로 구조용 저방사화강의 용접열영향부 후열처리 균열 감수성)

  • Lee, Jinjong;Moon, Joonoh;Lee, Chang-Hoon;Park, Jun-Young;LEE, Tae-Ho;Hong, Hyun-Uk;Cho, Kyung-Mox
    • Journal of Welding and Joining
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    • v.34 no.6
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    • pp.47-54
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    • 2016
  • Post-Weld Heat Treatment (PWHT) cracking susceptibility in the weld heat-affected zone (HAZ) of reduced activation ferritic-martensitic (RAFM) steels was evaluated through stress-rupture tests. 9Cr-1W based alloys including different C, Ta and Ti content were prepared. The coarse grained heat-affected zone (CGHAZ) samples were simulated with welding condition of 30 kJ/cm heat input. CGHAZ samples consisted of martensite matrix. Stress rupture experiments were carried out using a Gleeble simulator at temperatures of $650-750^{\circ}C$ and at stress levels of 125-550 MPa, corresponding to PWHT condition. The results revealed that PWHT cracking resistance was improved by Ti addition, i.e., Ti contributed to the formation of fine and stable MX precipitates and suppression of coarse M23C6 carbides, resulting in improvement of stress rupture ductility. Meanwhile, rupture strength increased with increasing solute C content.

A Study on the Development of Compactability and Electrical Resistivity for P/M Fecralloy (P/M Fecralloy의 성형성 및 전기저항특성 향상에 관한 연구)

  • Park, Jin-Woo;Ko, Byung-Hyun;Jung, Woo-Young;Park, Dong-Kyu;Ahn, In-Shup
    • Journal of Powder Materials
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    • v.23 no.6
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    • pp.426-431
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    • 2016
  • The Fe-Cr-Al alloy system shows an excellent heat resistance because of the formation of an $Al_2O_3$ film on the metal surface in an oxidizing atmosphere at high temperatures up to $1400^{\circ}C$. The Fecralloy needs an additive that can act as a binder because of its bad compactability. In this study, the green compacts of STS434L and Al powder added to Fecralloy are oxidized at $950^{\circ}C$ for up to 210 h. Fecralloy and Al is mixed by two types of ball milling. One is vented to air and the other was performed in a sealed jar. In the case of Al addition, there are no significant changes in the electrical resistance. Before the oxidation test, Al oxides are present in the Fecralloy surface, as determined from the energy dispersive spectroscopy results. The addition of Al improves the compactability because of an increased density, and the addition of STS434L increases the electrical resistivity by forming a composite oxide.

Design of Omni-directional Reflector for Synthetic Aperture Radar (합성개구레이더용 전방향 반사기의 설계)

  • Chang, Geba;Oh, Yi-Sok;Yang, Chan-Su
    • Korean Journal of Remote Sensing
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    • v.23 no.6
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    • pp.501-506
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    • 2007
  • Basic research is conducted to identify a target using corner reflectors which are commonly used in calibration of synthetic aperture radar (SAR) systems. At first, an omni-directional reflector is fabricated by combining four 15-cm rectangular trihedral corner reflectors. Then, its radar cross section (RCS) characteristics are measured at C-band (5.3 GHz) for vv-, hh-, hv-, and vh- polarizations at a range of horizontal angle, $-90^{\circ}{\le}{\phi}{\le}90^{\circ}$. The measured RCS angular variation of the omni-directional reflector is much smaller for vv-polarization than other polarizations, and the difference between the maximum and minimum RCSs for vv-polarization is about 8 dB. Peak RCS values are shown at $0^{\circ}$ (normal to plates) and $45^{\circ}$ (direction of bore sight). It is shown that the measurements agree quite well with numerical simulation and theoretical computation results.

Nondestructive Evaluation for Mechanical Degradation of Ultrasuper-Critical Heat-Resistance Steel by Reversible Permeability (가역투자율를 이용한 초초임계압 내열강의 기계적 열화에 관한 비파괴평가)

  • Ahn, SeongBin;Kim, JaeJin;Seo, DongMin;Kim, ChungSeok
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.17 no.6
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    • pp.46-52
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    • 2018
  • Nondestructive evaluation for mechanical degradation of ultrasuper-critical (USC) heat-resistance steel, which is attractive to the next generation of power plants is studied by magnetic reversible permeability. The interrelationship between reversible permeability and high-temperature mechanical degradation has been investigated by precise measurement of permeability nondestructively. Also, the effects of microstructural variation on reversible permeability are discussed. Isothermal aging was observed to coarsen the tempered carbides ($Cr_{23}C_6$), generated the intermetallic phases ($Fe_2W$), and grow rapidly during aging. The dislocation density also decreases steeply within lath interior. The peak to peak interval (PPI) of reversible permeability profile decreased drastically during the initial 500 h aging period, and was thereafter observed to decrease only slightly. The variation in PPI is closely related to the decrease in the number of pinning sites and the degradation in tensile strength.

Distribution and Pollution Status of Organic Matter and Heavy Metals in Surface Sediment Around Goseong Bay, a Shellfish Farming Area, Korea (패류양식해역인 고성만 주변 표층 퇴적물의 유기물과 중금속 분포 및 오염현황)

  • Lee, Garam;Hwang, Dong-Woon;Hwang, Hyunjin;Park, Jung-Hyun;Kim, Hyung-Chul;Kwon, Jung-No
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.23 no.6
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    • pp.699-709
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    • 2017
  • We measured the grain size, total organic carbon (TOC), total nitrogen (TN), and heavy metals (As, Cd, Cr, Cu, Fe, Hg, Mn, Pb, and Zn) in order to understand the spatial distribution and pollution level of organic matter and metals in surface sediment around Goseong Bay, a shellfish farming area, Korea. The surface sediments were composed of finer sediments such as mud and clay. The concentration of TOC, TN, and heavy metals were much higher in the innermost bay than in the mouth and outside of bay. The spatial distribution of organic matter and heavy metals and C/N ratio (5-10) in sediment showed that the organic matter and heavy metals in sediment of the study region were significantly influenced by oceanic origin organic matter and anthropogenic sources, respectively. Based on the results of four assessment techniques (sediment quality guideline, geoaccumulation index, pollution load index, ecological risk index), the sediments around the Goseong Bay were a little polluted for heavy metals and the high metal concentrations in the northern region of bay could adverse impact on benthic organisms in sediment. Thus, the systematic management plan for the improvement of water and sediment environment and the concentrated monitoring of pollutants for sustainable aquaculture and seafood safety around Goseong Bay are necessary in the future.

The Creep Characteristics of Zirconium-base Alloy (Zirconium계 합금의 Creep특성)

  • Im, S.H.;Rhim, S.K.;Kim, K.H.;Choi, J.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.10 no.3
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    • pp.198-208
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    • 1997
  • The-steady-state creep mechanism and behavior of Zircaloy-4 used as cladding materials in PWR have been investigated in air environment over the temp, ranges from 600 to $645^{\circ}C$ and stress ranges from 4 to $7kg/mm^2$. The stress exponents for the creep deformation of this alloy, n were decreased 4.81, 4.71, 4.64, and 4.56 at 600, 615, 630 and $645^{\circ}C$, respectively; the stress exponents decreased with increasing the temperature and got closer to about 5. The apparent activation energies, Q, were 62.1, 60.0, 57.9 and 55.4 kcal/mole at stresses of 4, 5, 6, $7kg/mm^2$, respectively; the activation energies decreased with increasing the stress and were close to those of volume self diffusion of Zr in Zr-Sn-Fe-Cr system. In results, it can be considered that the creep deformation for Zircaloy-4 was controlled by the dislocation climb over the ranges of this experimental conditions. Larson-Miller parameter, P, for the crept specimens was obtained as P=(T+460)(logt,+23). The failure plane observed by SEM slightly showed up intergranular fracture at this experiment ranges. However, it was essentially dominated by the dimple phenomenon, which was a characteristics of the transgranular fracture.

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Evaluation of Creep Crack Growth Failure Probability at Weld Interface Using Monte Carlo Simulation (몬테카를로 모사에 의한 용접 계면에서의 크리프 균열성장 파손 확률 평가)

  • Lee Jin-Sang;Yoon Kee-Bong
    • Journal of Welding and Joining
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    • v.23 no.6
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    • pp.61-66
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    • 2005
  • A probabilistic approach for evaluating failure risk is suggested in this paper. Probabilistic fracture analyses were performed for a pressurized pipe of a Cr-Mo steel reflecting variation of material properties at high temperature. A crack was assumed to be located along the weld fusion line. Probability density functions of major variables were determined by statistical analyses of material creep and creep crack growth data measured by the previous experimental studies by authors. Distributions of these variables were implemented in Monte Carlo simulation of this study. As a fracture parameter for characterizing growth of a fusion line crack between two materials with different creep properties, $C_t$ normalized with $C^*$ was employed. And the elapsed time was also normalized with tT, Resultingly, failure probability as a function of operating time was evaluated fur various cases. Conventional deterministic life assessment result was turned out to be conservative compared with that of probabilistic result. Sensitivity analysis for each input variable was conducted to understand the most influencing variable to the analysis results. Internal pressure, creep crack growth coefficient and creep coefficient were more sensitive to failure probability than other variables.