• Title/Summary/Keyword: $Co_3O_4/MnO_2$

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Influence of sandblasting and primer on shear bond strength of resin cement to zirconia (샌드블라스팅과 프라이머가 지르코니아와 레진시멘트의 전단결합강도에 미치는 영향)

  • Lee, Jung-Haeng;Kim, Hyeong-Seob;Pae, Ah-Ran;Woo, Yi-Hyung
    • The Journal of Korean Academy of Prosthodontics
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    • v.49 no.1
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    • pp.49-56
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    • 2011
  • Purpose: The aim of this study was to evaluate the effect of mechanical, chemical surface treatments on the zirconia-to-resin cement shear bond strength (SBS). Materials and methods: Eighty zirconia discs (Lava, 3M ESPE) and eighty zirconia/alumina composite (Zirace, Acucera) were embedded in an epoxy resin base. Zirconia discs were randomly divided in to four treatment groups(10 for each manufacturer): $50\;{\mu}m$ $Al_2O_3$ sandblasting (S50), $110\;{\mu}m$ $Al_2O_3$ sandblasting (S110), $50\;{\mu}m$ $Al_2O_3$ and primer (Z-Prime Plus, Bisco Inc) (S50z) and $110\;{\mu}m$ $Al_2O_3$ and primer (Z-Prime Plus) (S110z). Two resin-based luting cements (Calibra, Panavia F) were used to build 2 mm diameter cylinders onto the zirconia. After 24 h of storage in water, SBS testing was evaluate using a universal testing machine. Bond strength data were analyzed with one-way ANOVA, two-way ANOVA test and post hoc comparison was done using Tukey test (${\alpha}$ = .05). Results: Groups using primer showed the high shear bond strength. The groups that did not use primer presented lower shear bond strengths. Conclusion: The use of primer (Z-Prime Plus, Bisco) had significantly higher shear bond strengths.

A Study on the Water Quality of Domestic Mineral Water (Saeng Su) (국내 보존음료수(생수)의 성분에 관한 연구)

  • 류의형;이중근;김성조
    • Journal of Environmental Health Sciences
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    • v.16 no.2
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    • pp.41-45
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    • 1990
  • This study was performed to analyze for the mineral water (Saeng Su) from 12 pure beverage Co. products, which was obtained during March to May in 1988. The results were as follows: 1. The analytical results of contaminant materials in all the samples were suitable for drinking water standard. The mean value of NH$_{3}$-N, NO$_{3}$-N, Cl-and KMnO$_{4}$ consumption were ND, 49mg/l, 1.08mg/l and 8.14mg/l, respectively. 2. Total bacterial counts were 3/cc in average and Coliforms was negative in all samples. 3. The analytical results of Heavy metals were not detected or detected in a small amount, and the contents were different from each company. The CN, Hg, P were not detected in all the samples and the mean value of Cu, Fe, Mn were 0.0087mg/l, 0.0303mg/l, 0.018mg/l, respectively and it's contents were low. 4. The mean value of Pb, Zn, Cr$^{+6}$, As and Cd were 0.016mg/l, 0.015mg/l, 0.0025mg/l. 0.0059mg/l and 0.0011mg/l respectively.

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Effect of the Al(III) Coagulant Basicity on Phosphorus Removal in Sewage Treated Water (하수처리수의 인 제거에 미치는 Al(III) 응집제 염기도의 영향)

  • Han, Seung-Woo;Lee, Chul-Hee;Lee, Jae-Kwan;Kang, Lim-Seok
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.3
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    • pp.149-154
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    • 2012
  • According to the coagulation tests for PACs with various basicities, the PACB with lower basicity showed higher coagulation efficiencies of organics and phosphorus than the PAC with higher basicity. The PACB contained higher amount of monomeric Al (III) hydrolytic species comparing with PAC. In case of the coagulation for the sewage treated water, the coagulation efficiency by the charge neutralization and sweep floc formation was higher with PACB than with PAC. Accordingly, when $Al_2O_3$ concentration was similar in the coagulant, PACB showed higher removal efficiencies of turbidity, $COD_{Mn}$, TP, and $PO_4$-P comparing with PAC, especially in the lower range of coagulant dose.

Piezoelectric and Dielectric Properties of Low Temperature Sintered Pb(Mn1/3Nb2/3)0.02(Ni1/3Nb2/30.12(ZrxTi1-x)0.86O3 System Ceramics

  • Yoo, Ju-Hyun;Lee, Sang-Ho
    • Transactions on Electrical and Electronic Materials
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    • v.10 no.4
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    • pp.121-124
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    • 2009
  • In this study, in order to develop compositions of ceramics suitable for piezoelectric actuator and ultrasonic vibrator applications using low temperature sintering, multilayer, PMN-PNN-PZT ceramics were fabricated using $Li_2CO_3$ and $Na_2CO_3$ as sintering aids. Their structural, piezoelectric and dielectric characteristics were investigated according to the Zr/Ti ratio. As the Zr/Ti ratio increased, the electromechanical coupling factor $k_p$, and piezoelectric constant $d_{33}$ and the mechanical quality factor $Q_m$ all increased with Zr/Ti ratio and then decreased after the ratio exceeded 50/50. At the ratio of Zr/Ti =49/51 and sintering temperature of $900^{\circ}C$; the density, electromechanical coupling factor $k_p$, dielectric constant ${\varepsilon}_r$ piezoelectric $d_{33}$ constant and mechanical quality factor $Q_m$ all showed the optimum values of 7.900 $g/cm^3$, 0.576, 856, 312 pC/N, 1,326, respectively. These property values are very suitable for multilayer ceramics actuator applications.

Effect of SipJeonDaeBo-Decoction on Blood Metal Level in Rats (십전대보탕(十全大補湯)을 투여한 흰쥐의 혈액중 금속농도변화에 관한 연구)

  • Joh Hoo-Li;Lee Sun-Dong
    • Journal of Society of Preventive Korean Medicine
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    • v.3 no.2
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    • pp.151-170
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    • 1999
  • This study was to investigate the metal accumulation from SipJeonDaeBo-Decoction to rat blood of Sprague Dawley. 1. There were no significance in body weight, water dose feed ingestion quantity, liver, kidney, brain, bone weights between the control and the experimental groups. Under the experiment with drinking waters was no metal ${\sim}\;0.65mg/L$ detected. Metal level within feed found 0.0001-376.983mg/kg. 2. In the pack of SipJeonDaeBo-decoction, there detected no metal ${\sim}2.086mg/L$ 3. After P.O(per os) SipJeonDaeBo-decoction, As is detected $2.390{\pm}0.812mg/kg$ in blood; Cd $0.001{\pm}0.001mg/kg$, Co $0.003{\pm}0.001mg/kg$, Cr $0.432{\pm}0.234mg/kg$, Cu $1.013{\pm}0.373mg/kg$, Fe $426.293{\pm}114.842mg/kg$, no Hg, Mn $0.109{\pm}0.082mg/kg$, Ni $0.122{\pm}0.068mg/kg$, Zn $3.584{\pm}1.270mg/kg$. 4. The concentration of Hazardous heavy metal (As, Cd, Co, Cr, Hg, Ni, Pb) within blood control group is searched $0.488{\pm}0.138\;mg/l$; experiment I group $0.432{\pm}0.080mg/l$, experiment II group $0.588{\pm}0.213mg/l$. In the concentration of non hazardous heavy metal(Cu, Fe, Mn, Zn) control group $101.409{\pm}6.832mg/l$; experiment I group $96.062{\pm}5.732\;mg/l$, experiment II group $125.139{\pm}044.820mg/l$. 5. Correlation among every metal in blood Zn and Cr was 0.87956 ; Cd and As -0.02316, Pb and As -0.08738, Ni and As 0.07824, Mn and As 0.07824, Mn and Cd 0.04999. Briefly under the injection of SipJeonDaeBo-decoction, this study was defined within safety in blood level by P.O. during 10 days.

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Studies on acid protease produced from Aspergillus tubingensis I (Aspergillus tubingensis의 acid protease에 관한 연구 I)

  • Chung, Yun-Su;Cho, Young;Han, Suk-Hyun
    • Korean Journal of Microbiology
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    • v.20 no.3
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    • pp.105-112
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    • 1982
  • The strain of Aspergillus, 6368A, producing acid protease showing high activity was isolated from soil, as a result of wide research about mold group. This strain was identified as a species of Aspergillus tubingensis by the investigation of morphological characteristics. The change of the enzyme production under the various media and culture condition was also studied. The optimum pH and stability of crude acid protease are 2.5, 2.0~4.5 and the optimum temeprature and thermal inactivation waas shown $50^{\circ}C,\;55^{\circ}C$, respectively. From the result of the study on the effects of metal ions, it was found that $MnCl_2,\;CoCl_2,\;CuCl_2,\;SrCl_2,\;and\;NiCl_2$ slightly increased the enzyme activity, on the other hand $ZnCl_2,\;CaCl_2,\;MgCl_2,\;SLS,\;and\;KMnO_4$ decreased it.

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Magnetic Tunnel Junctions with AlN and AlO Barriers

  • Yoon, Tae-Sick;Yoshimura, Satoru;Tsunoda, Masakiyo;Takahashi, Migaku;Park, Bum-Chan;Lee, Young-Woo;Li, Ying;Kim, Chong-Oh
    • Journal of Magnetics
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    • v.9 no.1
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    • pp.17-22
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    • 2004
  • We studied the magnetotransport properties of tunnel junctions with AlO and AlN barriers fabricated using microwave-excited plasma. The plasma nitridation process provided wider controllability than the plasma oxidization for the formation of MTJs with ultra-thin insulating layer, because of the slow nitriding rate of metal Al layers, comparing with the oxidizing rate of them. High tunnel magnetoresistance (TMR) ratios of 49 and 44% with respective resistance-area product $(R{\times}A) of 3 {\times} 10^4 and 6 {\times} 10^3 {\Omega}{\mu}m^2$ were obtained in the Co-Fe/Al-N/Co-Fe MTJs. We conclude that AlN is a hopeful barrier material to realize MTJs with high TMR ratio and low $R{\times}A$ for high performance MRAM cells. In addition, in order to clarify the annealing temperature dependence of TMR, the local transport properties were measured for Ta $50{\AA} /Cu 200 {\AA}/Ta 50 {\AA}/Ni_{76}Fe_{24} 20 {\AA}/Cu 50 {\AA}/Mn_{75}Ir_{25} 100 {\AA}/Co_{71}Fe_{29} 40 {\AA}/Al-O$ junction with $d_{Al}= 8 {\AA} and P_{O2}{\times}t_{0X}/ = 8.4 {\times} 10^4$ at various temperatures. The current histogram statistically calculated from the electrical current image was well in accord with the fitting result considering the Gaussian distribution and Fowler-Nordheim equation. After annealing at $340^{\circ}C$, where the TMR ratio of the corresponding MTJ had the maximum value of 44%, the average barrier height increased to 1.12 eV and its standard deviation decreased to 0.1 eV. The increase of TMR ratio after annealing could be well explained by the enhancement of the average barrier height and the reduction of its fluctuation.

Association between Subjective Distress Symptoms and Argon Welding among Shipyard Workers in Gyeongnam Province (경남소재 일개조선소 근로자의 건강이상소견과 아르곤 용접과의 관련성)

  • Choi, Woo-Ho;Jin, Seong-Mi;Kweon, Deok-Heon;Kim, Jang-Rak;Kang, Yune-Sik;Jeong, Baek-Geum;Park, Ki-Soo;Hwang, Young-Sil;Hong, Dae-Yong
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.24 no.4
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    • pp.547-555
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    • 2014
  • Objective: This study was conducted to investigate the association between subjective distress symptoms and argon welding among workers in Gyeongnam Province shipyard. Method: 31 argon and 29 non-argon welding workers were selected as study subjects in order to measure concentrations of personal dust, welding fumes and other hazardous materials such as ZnO, Pb, Cr, FeO, MnO, Cu, Ni, $TiO_2$, MgO, NO, $NO_2$, $O_3$, $O_2$, $CO_2$, CO and Ar. An interviewer-administered questionnaire survey was also performed on the same subjects. The items queried were as follows: age, height, weight, working duration, welding time, welding rod amounts used, drinking, smoking, and rate of subjective distress symptoms including headache and other symptoms such as fever, vomiting and nausea, metal fume fever, dizziness, tingling sensations, difficulty in breathing, memory loss, sleep disorders, emotional disturbance, hearing loss, hand tremors, visual impairment, neural abnormality, allergic reaction, runny nose and stuffiness, rhinitis, and suffocation. Statistical analysis was performed using SPSS software, version 18. Data are expressed as the mean ${\pm}SD$. An ${\chi}^2$-test and a normality test using a Shapiro wilk test were performed for the above variables. Logistic regression analysis was also conducted to identify the factors that affect the total score for subjective distress symptoms. Result: An association was shown between welding type (argon or non-argon welding) and the total score for subjective distress symptoms. Among the rate of complaining of subjective distress symptoms, vomiting and nausea, difficulty breathing, and allergic reactions were all significantly higher in the argon welding group. Only the concentration of dust and welding fumes was shown to be distributed normally after natural log transformation. According to logistic regression analysis, the correlations of working duration and welding type (argon or non-argon) between the total score of subjective distress symptoms were found to be statistically significant (p=0.041, p=0.049, respectively). Conclusion: Our results suggest that argon welding could cause subjective distress symptoms in shipyard workers.

Improvement of Electrochemical Properties and Thermal Stability of a Ni-rich Cathode Material by Polypropylene Coating

  • Yoo, Gi-Won;Son, Jong-Tae
    • Journal of Electrochemical Science and Technology
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    • v.7 no.2
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    • pp.179-184
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    • 2016
  • The interface between the surface of a cathode material and the electrolyte gives rise to surface reactions such as solid electrolyte interface (SEI) and chemical side reactions. These reactions lead to increased surface resistance and charge transfer resistance. It is consequently necessary to improve the electrochemical characteristics by suppressing these reactions. In order to suppress unnecessary surface reactions, we coated cathode material using polypropylene (PP). The PP coating layer effectively reduced the SEI film that is generated after a 4.3 V initial charging process. By mitigating the formation of the SEI film, the PP-coated Li[(Ni0.6Co0.1Mn0.3)0.36(Ni0.80Co0.15Al0.05)0.64)]O2(NCS) electrode provided enhanced transport of Li+ ions due to reduced SEI resistance (RSEI) and charge transfer resistance (Rct). The initial charge and discharge efficiency of the PP-coated NCS electrode was 96.2 % at a current density of 17 mA/g in a voltage range of 3.0 ~ 4.3 V, whereas the efficiency of the NCS electrode was only 94.7 %. The presence of the protective PP layer on the cathode improved the thermal stability by reducing the generated heat, and this was confirmed via DSC analysis by an increased exothermic peak.

CHARACTERISTICS EVALUATION AND GROWTH OF $BI_4GE_3O_{12}$ SINGLE CRYSTAL BY CZOCHRALSKI METHOD

  • Cho, Yun-Ho;Kim, Yong-Kyun;Lee, Woo-Gyo;Kang, Byoung-Hwi;Kim, Jong-Kyung;Lee, Dong-Hoon;Park, Jae-Woo
    • Journal of Radiation Protection and Research
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    • v.34 no.2
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    • pp.83-86
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    • 2009
  • The single crystal scintillator of bismuth germinate ($Bi_4Ge_3O_{12}$:BGO) was successfully grown by the conventional Czochraski technique. The characteristics of the grown BGO were evaluated and presented on the excitation, emission responses and energy spectra of the $\gamma$-rays from $^{241}Am$, $^{133}Ba$, $^{57}Co$, $^{22}Na$, $^{137}Cs$ and $^{54}Mn$ radio-isotopes. The energy resolution of grown BGO, $\Delta$E/E, was estimated to be 12.1% at 662 keV of $\gamma$-ray for $^{137}Cs$ nuclide. Compared to the commercial BGO crystal, we confirmed that the grown BGO has a good performance and is comparable to reference one.