• Title/Summary/Keyword: $CoSe_2$

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Enhanced Stability of LiCoO2 Cathodes in Lithium-ion Batteries Using Surface Modification by Atomic Layer Deposition

  • Jung, Yoon-S.;Cavanagh, Andrew S.;Dillon, Anne C.;Groner, Markus D.;George, Steven M.;Lee, Se-Hee
    • Journal of the Korean Ceramic Society
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    • v.47 no.1
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    • pp.61-65
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    • 2010
  • Ultrathin atomic layer deposition (ALD) coatings were found to enhance the performance of lithium-ion batteries (LIBs). Previous studies have demonstrated that $LiCoO_2$ cathode powders coated with metal oxides with thicknesses of $\sim100-1000{\AA}$ grown using wet chemical techniques improved LIB performance. In this study, $LiCoO_2$ powders were coated with conformal $Al_2O_3$ ALD films with thicknesses of only $\sim3-4{\AA}$ established using 2 ALD cycles. The coated $LiCoO_2$ powders exhibited a capacity retention of 89% after 120 charge-discharge cycles in the 3.3~4.5 V (vs. $Li/Li^+$) range. In contrast, the bare $LiCoO_2$ powders displayed only a 45% capacity retention. This dramatic improvement may result from the ultrathin $Al_2O_3$ ALD film acting to minimize Co dissolution or to reduce surface electrolyte reactions.

The CO Gas Sensing Properties of ZnO-WO$_3$Composite Ceramics (ZnO-WO$_3$복합체의 일산화탄소 가스 감응특성)

  • 김태원;정승우;최우성;박춘배
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.401-404
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    • 1997
  • We prepared 0~20mo1% WO$_3$added ZnO composite ceramics in order to promote a CO gas sensitivity. Using SE,. we observed the microstructure of sample. The resistances of sample were measured by High Voltage Measure/source Unit in the temperature range of +5V~-5V. The measured 1000ppm CO sensitivities of pure ZnO were about 1~4.3, and the measured 1000ppm CO sensitivities of ZnO-WO$_3$composite ceramics were about 1~8.2. Therefore, the 1000ppm CO sensitivities of ZnO-WO$_3$composite ceramics were about 2 times larger than that of pure ZnO.

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Gas Permeation Characteristics by Pebax/ZIF-9 Mixed Matrix Membrane (Pebax/ZIF-9 혼합막에 의한 기체투과 특성)

  • Yoon, Soong Seok;Hong, Se Ryeong
    • Membrane Journal
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    • v.32 no.5
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    • pp.325-335
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    • 2022
  • In this study, zeolitic imidazolate framework-9 (ZIF-9) was synthesized and Pebax/ZIF-9 mixed membranes were prepared by varying the content in poly(ether-b-amide)-1657 (Pebax-1657), and then a single gas (N2, CO2) was permeated to investigate the gas permeation characteristics of the mixed membrane. As the ZIF-9 content incorporated into the pure Pebax membrane increased, the N2 permeability gradually decreased, and the CO2 permeability increased up to the Pebax/ZIF-9 3 wt% mixed membrane, and then decreased at the content thereafter. And among the mixed membranes, the Pebax/ZIF-9 3 wt% mixed membrane showed the highest selectivity of 69.3 by selectively accepting CO2 as the gate-opening phenomenon occurred for the polar gas, CO2. In addition, both the CO2 permeability and the CO2/N2 selectivity increased, resulting in the closest Robeson upper-bound.

Gas Permeation Characteristics by Chitosan/Pebax Composite Membranes (Chitosan/Pebax 복합 막에 의한 기체투과 특성)

  • Kim, Sun Hee;Hong, Se Ryeong
    • Membrane Journal
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    • v.27 no.4
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    • pp.319-327
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    • 2017
  • Chitosan/Pebax composite membranes were prepared with 1 : 1, 1 : 2, 1 : 10, 1 : 30 mass ratio of pebax and chitosan. Gas permeation test were carried out under pressure $6kgf/cm^2$, 35, $45^{\circ}C$ and $65^{\circ}C$ at different temperatures. The gas permeability and selectivity ($CO_2/N_2$) of $N_2$ and $CO_2$ for the Chitosan/Pebax composite membranes were investigated. As the amount of Pebax added to chitosan was increased the gas permeability of both $N_2$ and $CO_2$ increased. The selectivity ($CO_2/N_2$) was 6.9~44.3 in the Chitosan/Pebax composite membranes. With the increase of contents of Pebax and the decrease of temperature, the selectivity ($CO_2/N_2$) increased.

Development and Properties of Carbon monoxide Detector for Ambient Air monitoring (대기오염 측정용 일신화 탄소 검출기의 제작 및 특성)

  • Cho, Kyung-Haeng;Lee, Sang-Wha;Lee, Joung-Hae;Choi, Kyong-Sik
    • Analytical Science and Technology
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    • v.13 no.2
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    • pp.222-228
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    • 2000
  • A detector for monitoring carbon monoxide (CO) in ambient air by nondispersive infrared (NDIR) spectroscopy has been developed and investigated its sensitivity and stability. The essential parts of the absorption cell are three spherical concave mirrors so as to improve the sensitivity by increasing the light path length in the cell. The radius and center of curvature of mirrors and position in the cell was calculated by computer simulation in order that the light path length may be 16m into the 50cm cell. The number of traversals and optical path properties were confirmed by laser beam alignment in transparent absorption cell. The photoconductive type lead selenide (PbSe) was used as CO sensing material, which was cooled to increase the responsibility by thermoelectric cooling method. The detection limit and span drift of the developed CO detector was 0.24ppm and 0.03ppm(v/v) respectively.

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Evaluation of Micro-defects and Air Tightness of Al Die-casting by Impregnation of Organic Solvent (유기용제 함침법을 통한 알루미늄 다이캐스팅의 미세결함 및 기밀성 평가)

  • Lee, Jin-Wook;Cho, Chang-hyun;Kim, Sung-Gye;Ko, Young-Gun;Kim, Dong-Ju
    • Journal of Korea Foundry Society
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    • v.42 no.4
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    • pp.218-225
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    • 2022
  • For hydrogen-vehicle applications (air pressure control valve housing, APCVH), an investigation was conducted to determine how micro-defects in a high- pressure die-casted Al alloy (industrial code: ALDC12) could be controlled by means of a post-treatment using an organic-based impregnation solution in order to improve the air- tightness of the die-casted Al sample. Two different impregnation solutions were proposed and its test results were compared to a imported product from Japan with respect to the processing variables used. A structural investigation of the components under study was conducted by means of computer tomography and 3D X-ray micro-CT. These observations revealed that the use of the impregnation treatment to seal micro-defects led to highly significant and beneficial changes which were attributed mainly to interconnections among inherent micro-pores. A leak test after impregnation revealed that the performance improvement rate of the die-casted Al sample was ~70% for INNO-01. Therefore, the developed impregnation solutions offer an effective strategy to control the micro-defects found in various vehicle parts via die-casting.

The effects of primary gas physical properties on the performance of annular injection type supersonic ejector (주유동 기체의 물리적 특성이 환형 분사 초음속 이젝터의 성능에 미치는 영향)

  • Jin, Jung-Kun;Kim, Se-Hoon;Park, Geun-Hong;Kwon, Se-Jin
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.33 no.12
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    • pp.68-75
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    • 2005
  • The effects of the physical properties of primary flow on the performance of a supersonic ejector were investigated. Axisymmetric annular injection type supersonic ejector was used for the study of the effects of molecular weight and the specific heat at constant pressure on the ejection performance. Test gases include; air, $CO_{2}$, Ar, $C_{3}H_{8}$, and $CCl_{2}F_{2}$ for different values of gas properties. As the molecular weight and CP of the primary gas increase, the secondary flow pressure increases at the same primary stagnation pressure and this behavior results from the combined effects of molar specific heat or specific heat ratio.

The Study of Hyperfine Fields for Co0.9Zn0.1Cr1.9857Fe0.02O4 (Co0.9Zn0.1Cr1.9857Fe0.02O4 물질의 초미세자기장 연구)

  • Choi, Kang-Ryong;Kim, Sam-Jin;Kim, Chul-Sung
    • Journal of the Korean Magnetics Society
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    • v.18 no.1
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    • pp.39-42
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    • 2008
  • [ $AB_2X_4$ ](A, B=Transition Metal, X=O, S, Se) are cubic spinel normal ferrimagnets, in which M ions occupy the tetrahedral sites and Cr ions occupy the octahedral sites. Recently, they have been investigated for behaviour of B site ions and A-B interaction. Polycrystalline $[Co_{0.9}Zn_{0.1}]_A[Cr_{1.98}{^{57}Fe_{0.02}}]_BO_4$ compound was prepared by wet-chemical process. The ferrimagnetic transition was observed around 90K. $M\"{o}ssbauer$ absorption spectra at 4.2K show that the well-developed two sextets are superposed with small difference in hyperfine fields($H_{hf}$). The hyperfine fields of $CoCr_{1.98}{^{57}Fe_{0.02}}O_4$ and $Co_{0.9}Zn_{0.1}Cr_{1.98}{^{57}Fe_{0.02}}O_4$ were determined to be 488, 478 kOe and 486, 468 kOe, respectively. We notice that the one of the magnetic hyperfine field values changes with Zn ion substitution. These results suggest the incommensurate states and spin-reorientation temperature($T_S=18K$) changes with Zn ions substitution below spin-reorientation temperature($T_S=28K$) of $CoCr_{1.98}{^{57}Fe_{0.02}}O_4$

Study on Vibration Characteristics in Terms of Airfoil Cross-Sectional Shape by using Co-Rotational Plane Beam Transient Analysis (Co-Rotational 보의 과도상태해석을 이용한 에어포일 단면 형상 변화에 따른 진동특성 연구)

  • Kim, Se-Ill;Kim, Yong-Se;Park, Chul-Woo;Shin, Sang Joon
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.29 no.5
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    • pp.389-395
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    • 2016
  • In this paper, vibration characteristics in terms of the airfoil cross-sectional shape was examined by using the EDISON co-rotational plane beam-transient analysis. Co-Rotational plane beam analysis is appropriate for large rotation and small strain. Assuming aircraft wing as a cantilevered beam, natural frequencies of each airfoil cross-sectional shape were estimated using VABS program and fast Fourier transformation(FFT). VABS conducts finite element analysis on the cross-section including the detailed geometry and material distribution to estimate the beam sectional properties. Under the same airfoil geometric configuration and material selection, variation of material induced difference in the deflection and natural frequencies. It was observed that variation of the natural frequency was dependent on variation of the airfoil shape and material.

A Case Study on the Validation of the Rolling Stock Requirement Statement (철도차량 요구사항서 논증 활동 사례 연구)

  • Kim Jin-Ill;Kim Jin-Hoon
    • Journal of the Korea Institute of Military Science and Technology
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    • v.7 no.2 s.17
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    • pp.57-64
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    • 2004
  • A Requirement statement validation process is suggested which was established and applied to the rolling stock development project of the Korean Railway Research Institute. The validation process includes team organization, selection of validation criteria, development of validation template, education of team members, validation, construction of database and management of requirement change. Many defects in the specification of requirement were found to be associated with the problem of non-uniqueness, describing solution instead of problem, ambiguity and redundancy. This paper described detailed activities at each step of the validation process and lessons learned from these activities.