• Title/Summary/Keyword: $Ca_3(PO_4)_2$

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Chemical Properties of Soil Solution under Larix leptolepis, Pinus koraiensis, and Quercus mongolica Stands (일본잎갈나무, 잣나무, 신갈나무 임분 토양의 층위별 토양수의 화학적 특성)

  • Ryu, Soung-Ryoul;Son, Yo-Whan
    • Korean Journal of Environmental Agriculture
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    • v.17 no.4
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    • pp.341-345
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    • 1998
  • Soil solutions were collected by zero-tension lysimeters at Kwangju, Kyunggi Province to estimate differences in ion concentration among species and horizons. Zero-tension lysimeters were installed in O, A, and B horizons in Larix leptolepis, Pinus koraiensis, and Quercus mongolica stands. Soil solution samples were collected from September 1996 through August 1998 and analyzed for $K^+$, $NA^+$, $NH_4^+$, $Mg^{2+}$, $Ca^{2+}$, $Al^{3+}$, $Cl^-$, $SO_4^{2-}$, $NO_3^-$, and $PO_4^{3-}$. The experimental site had high nitrogen loading from the atmosphere, and $NO_3^-$ was positively correlated with $K^+$ and $Mg^{2+}$. However, $NO_3^-$ and $NH_4^+$ showed a positive correlation only in the O horizon of Q. mongolica stand. Mg^(2+) deficit in the soil was predicted owing to the positive relationship of $Mg^{2+}$ with $NO_3^-$. Concentrations of $K^+$ and $Ca^{2+}$in soil solution were estimated higher in L. leptolepis than in other stands because of high leaching from the plant. Concentration of $Al^{3+}$ in soil solution was negatively correlated with soil solution pH. Mean soil solution pH of A and B horizons in P. koraiensis was lower than 4.7, however the $Al^{3+}$ concentration was lower than the toxic level to plants.

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Formation and Chemical Characteristics of Dewfall in Western Busan Area (부산 서부지역의 이슬 생성과 화학적 특성)

  • Jeon Byung-Il;Hwang Yong-Sik;Park Moon-Po
    • Journal of Environmental Science International
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    • v.13 no.12
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    • pp.1079-1088
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    • 2004
  • In order to understand chemical characteristics and dewfall formation in western Busan area, we analysed monthly distribution of dewfall, and investigated the correlation between dewfall formation amount and meteoro­logical factors. This study used the modified teflon plate $(1m{\times}1m)$ at Silla university in Busan from August 2002 to April 2003. In order to estimate qualitatively water soluble components, IC, ICP and UV methods for water soluble ions are also used respectively. Dewfall amount of sampling periods (47 day) collected 3.8 mm. Meteorological conditions for the formation of dewfall above $50\;g/m^{2}$ showed that temperature diurnal $range(^{\circ}C)\;was\;5.6^{\circ}C$ above, cloud amounts (1/10) at dawn of the sampling day was 7/10 below, mean wind speed at dawn (0~6hr) of the sampling day was 4.4 m/sec below, and mixing ratio at 6hr of the sampling day was 3.2 g/kg above. Distribution of water soluble ions in dewfall founded the highest concentration (206.1\;{\mu}eq/{\ell}\;for\;SO_{4}^{2-},\;42.4\;{\mu}eq/{\ell}\;for\;NH_{4}^{+},\;249.2\;{\mu}eq/{\ell}\;for\;Ca^{2+},\;and\;42.0\;{\mu}eq/{\ell}\;for\;Mg^{2+})$ during the March, the lowest concentration $(73.0\;{\mu}eq/{\ell}\;for\;SO_{4}^{2-},\;4.6\;{\mu}eq/{\ell}\;for\;NH_{4}^+\;and\;72.7\;{\mu}eq/{\ell}\;for\;Ca^{2+})$ during the August. Monthly equivalent ratio of $[SO_{4}^{2-}]/[NO_{3}^-]$ showed the highest value (4.99) during the October, the lowest value (1.84) during the August, and the mean value was 3.45.

Investigation on Structure and Physical Properties of Bioglasses with Various P2O5 Content (P2O5함량에 따른 Bioglass의 구조 분석 및 물성 측정)

  • 임기홍;황진명;김철영
    • Journal of the Korean Ceramic Society
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    • v.26 no.4
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    • pp.559-567
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    • 1989
  • Bioglasses have been known to be as one of the promising biomateials, which can be used for replacing defective hard and soft tissue. There have been many reports on biological results for this type of glass, but no systematic work has carried out on the structures and properties of the bioglass itself. In the present study, the effect of P2O5 in bioglasses on their structures and properties was examined. Infrared and Raman spectroscopy for the glass structural analysis, differential thermal and X-ray diffraction analysis for the crystallization of the bioglass were performed, and several physical properties were measured. When the glasses were heat-treated, Na2O.2CaO.3SiO2 was the major crystalline phase and $\beta$-NaCaPO4 crystal was found for the glass with high P2O5 content. The added P2O5 in the glasses enhanced the polymerization of silicate glass structure and it changed the chain-like glass structure to a sheet-like structure, and some P2O5 may stay as phosphate monomer. With addition of P2O5 in the glass the density of the glasses decreased, but not much changes in their thermal expansion coefficient, softening point and microhardness were observed.

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Impact of urbanization and industrialization on irrigation water quality of a canal - a case study of Tongi canal, Bangladesh

  • Zakir, H.M.;Islam, Md. Mahidul;Hossain, Md. Sohrab
    • Advances in environmental research
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    • v.5 no.2
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    • pp.109-123
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    • 2016
  • The Dhaka city, the capital of Bangladesh is one of the most densely populated cities in the world. Tongi canal is situated on the north of the city, which connected the Turag river to the west and the Balu river to the east. A total of 26 water samples were collected from the canal to measure irrigation water quality on the basis of their trace metal and major ionic constituents. Trace metals concentrations in water samples were determined using an Atomic Absorption Spectrophotometer. The amount of Fe, Mn, Zn and Pb in water samples ranged from 0.01-0.80, trace-1.02, trace-0.054 and $0.43-0.64{\mu}g\;mL^{-1}$, respectively. The mean concentration of Ca, Mg, Na, K, $HCO_3{^-}$, $Cl^-$, $BO{_3}^{3-}$, $PO{_4}^{3-}$ and $SO{_4}^{2-}$ in water samples were 45.32, 15.33, 151.65, 11.98, 516.06, 94.69, 0.33, 14.02 and $56.21{\mu}g\;mL^{-1}$, respectively. In respect of $HCO_3{^-}$, $SO{_4}^{2-}$, $PO{_4}^{3-}$ and K contents, most of the water samples were found problematic for irrigation. In context of RSC and hardness, 96 and 92% of water samples were graded as unsuitable and hard class, respectively. The study concluded that Pb content in canal water was comparatively high, so it is desirable to take necessary initiative to minimize the contamination level and to monitor its concentration in water routinely.

Influence of Bicarbonate Concentrations in Irrigation Solution on Growth of Lettuce and Changes in Chemical Properties of Root Media (원수의 중탄산 농도가 근권 화학성 변화 및 상추의 생장에 미치는 영향)

  • Shin, Bo Kyoung;Son, Jung Eek;Choi, Jong Myung
    • Journal of Bio-Environment Control
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    • v.22 no.1
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    • pp.65-72
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    • 2013
  • This study was conducted to investigate the influences of bicarbonate ($HCO_3^-$) concentrations in irrigation solution on growth of lettuce and change in chemical properties of root media. The blue leaf and red leaf lettuces with two true leaf stages were transplanted into 10 cm diameter plastic pots filled with perlite. The five treatments were made by dissolving $NaHCO_3$ into irrigation solution to reach 30, 70, 110, 150 and $180mg{\cdot}L^{-1}$ $HCO_3^-$. The crops were fed with fertilizer solution contained $HCO_3^-$ with various concentrations and controlled to $100mg{\cdot}L^{-1}$ in nitrogen concentration. The pH in soil solution of root media 10 weeks after transplant of blue lettuces were 7.04 and 7.10 in the treatments of 30 and $70mg{\cdot}L^{-1}$ of $HCO_3^-$, respectively. But those rose gradually after week 3 and finally reached 7.39, 7.48 and 7.56 at week 10 in the treatments of 110, 150 and $180mg{\cdot}L^{-1}\;HCO_3^-$, respectively. The pH in the treatments of 30 and $70mg{\cdot}L^{-1}\;HCO_3^-$ in cultivation of red leaf lettuce were around 6.65 during week 4 to week 8, but this rose abruptly and reached 6.92 and 7.01 at week 10, respectively. Those in the treatments of 110, 150, and $180mg{\cdot}L^{-1}\;HCO_3^-$ rose gradually and finally reached to 7.49, 7.53, and 7.58, respectively. The EC rose gradually after week 2 in all treatments of blue and red leaf lettuces. The change of macro ion concentrations in both blue and red leaf lettuces showed similar trends. The concentrations of $PO_4-P$, $Ca^{2+}$ and $Mg^{2+}$ increased gradually in all treatments of $HCO_3^-$ during cultivation of blue and red leaf lettuces. As the concentrations of $HCO_3^-$ in irrigation solution were elevated, the concentrations of $PO_4-P$, $Ca^{2+}$ and $Mg^{2+}$ became higher and that of ${SO_4}^{-2}$ became lower in soil solution of root media. The main reason of concentration changes were that $HCO_3^-$ influenced pH and the pH changes also affect the activities of the ions in soil solution of root media.

Studies on ammonium adsorption by and desorption from various soils (I) -Langmuir adsorption isotherm of ammonium (토양별(土壤別) 암모늄의 흡착(吸着) 및 탈착(脫着)에 관(關)한 연구(硏究) (I) -암모늄의 Langmuir 등온흡착(等溫吸着))

  • Shim, Sang-Chil;Kim, Kwang-Rai;Kim, Moo-Sung;Park, Hoon
    • Korean Journal of Soil Science and Fertilizer
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    • v.10 no.1
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    • pp.1-6
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    • 1977
  • Fifteen soils including volcanic ash, acid sulfate and degraded saline soils were investigated for Languir adsorption isotherm of ammonium using $NH_4H_2PO_4$. The results are as follows. Languir adsorption maxima of ammonium (LAMA) ranged from 2.4me/100g soil to 12.3 and the average was 5.3. Initial concentration of 30 to 60 or 40 to 80 ppm(as N) appears to be suitable for LAMA measurement. There were two LAMA in some soils. Difference between adsorption constants (bonding energy) was mostly greater than that between LAMA. LAMA ranged from 9.4% to 72% of cation exchange capacity and average was 47%. It did not show any clear tendency with CEC, pH, organic matter content, base saturation percent, P, K, Ca, Mg, Na and Si. Except volcanic ash soils which were grouped into two groups according to ammonium adsorption LAMA was significantly (r=0.951 at 1%) correlated with adsorption at 200ppm. This single concentration seems suitable for LAMA measurement. Probable mechanism of ammonium adsorption was discussed, in which the associated anions were combined with iron and aluminum and then ammonium was bound to phosphorus. Applicability of Langmuir adsorption isotherm model to the soils under field condition was also discussed.

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Optimal Culture Conditions for Production of Environment-Friendly Biosurfactant by Pseudomonas sp. EL-G527 (Pseudomonas sp. EL-G527에 의한 환경친화성 생물계면활성제의 생산최적조건)

  • 차미선;임은경;이근희;조순자;손홍주;이상준
    • Journal of Environmental Science International
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    • v.11 no.3
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    • pp.177-182
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    • 2002
  • A biosurfactant-producing microorganism was isolated from activated sludge by enrichment culture when grown on a minimal salt medium containing n-hexadecane as a sole carbon source. This microorganism was identified as Pseudomonas sp. and it was named Pseudomonas sp. EL-G527. It's optimal culture condition is 2% n-hexadecane, 0.2% NH$_4$NO$_3$, 0.3% KH$_2$PO$_4$, 0.3% $K_2$HPO$_4$, 0.02% MgSO$_4$ㆍ7$H_2O$, 0.0025% CaCk$_2$ㆍ6$H_2O$, 0.0015% FeSO$_4$ㆍ7$H_2O$ in 1$\ell$ distilled water and initial pH 7.0. Cultivation was initiated with a 2% inoculum obtained from starter cultures grown in 30 $m\ell$ of the same medium in 250 $m\ell$ flask. They were cultivated at 3$0^{\circ}C$ in reciprocal shaking incubator and the highest biosurfactant production was observed after 4 days.

Effect of Incorporation Rate of Polyacrylamide Hydrogel on Changes in Chemical Properties of Root Media (Polyacrylamide 고흡수성 수지의 혼합 비율이 상토의 화학성에 미치는 영향)

  • Wang, Hyun-Jin;Choi, Jong-Myung;Lee, Jong-Suk
    • Journal of Bio-Environment Control
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    • v.14 no.3
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    • pp.190-195
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    • 2005
  • This research was conducted to investigate the changes in soil chemical properties of root media as influenced by incorporation rate of a polyacryl amide hydrogel, Stocksorb C. The pH at 5 weeks after treatment in four root media such as peatmoss + vermiculite (1:1, v/v; PV), peatmoss + composted rice hull (1:1; PR), peatmoss + composted saw dust (1:1; PD) and peatmoss + composted pine bark (1:1; PB) containing STSB were in the range from 7.04 to 7.30, which was too high. Elevated incorporation rate of STSB resulted in increase of EC in soil solution of four root media with linear and quadratic response. The concentrations of $NH_4^+-N,\;NO_3^--N,\;PO_4-P^{3-},\;K^+,\;Ca^{2+}and\;Mg^{2+}$ in four kinds of root media increased as incorporation rates of STSB were elevated. But the $NO_3^-$-N concentrations in PS media were lower than those in other there root media tested. The Fe concentrations in PV, PR and PS media increased as incorporation rates of STSB were elevated, but those in PB medium did not show significant different. The concentrations of $Fe^{2+},\;Mn^{2+},\;Zn^{2+}and\;Cu^{2+}$ in PS media were higher than those in other three root media.

Effect of Storage Duration, Temperature and Priming Treatment on Seed Germination of Polygonatum odoratum var. pluriflorum (둥굴레의 종자발아에 관여하는 저장기간, 온도 및 프라이밍의 영향)

  • Chang, Young-Deug;Lee, Cheol-Hee
    • Korean Journal of Plant Resources
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    • v.20 no.5
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    • pp.481-489
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    • 2007
  • Present experiments are conducted to study the seed viability and optimum germination temperature of Polygonatum odoratum var. pluriflorum that is known to have low germination ability and long germination duration. To enhance germination rate, various growth regulators and inorganic salts were employed. Low germination rate was obtained with 4 year old seeds, but not with $1{\sim}2$ year old seeds. The seeds germinated very well under $22{\sim}25^{\circ}C$ and germinated speed was rapid. Especially, $1{\sim}2$ year old seeds germinated at $25^{\circ}C$ showed $70{\sim}71.2%$ germination rate. Priming treatments using $GA_3$, IAA, NAA, kinetin, $KNO_3$, $KH_2PO_4$, $Ca(NO_3)_2$ were effective compared to control except BA. 1 year old seeds treated with $GA_3$ 0.5 mM and IAA 1 mM showed 96% and 93% germination rate, respectively.

Effect of pre-planting liming fertilization in peatmoss based substrates on plug seeding growth of 'Red Madness' petunia and changes in soil chemical properties (피트모스 혼합상토에 기비로 혼합된 석회질 비료가 'Red Madness' 페튜니아 플러그 묘 생장과 상토화학성에 미치는 영향)

  • Lee, Poong-Ok;Lee, Jong-Suk;Choi, Jong-Myung
    • Korean Journal of Agricultural Science
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    • v.38 no.1
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    • pp.17-23
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    • 2011
  • This research was conducted to investigate the influence of application rate of liming fertilizers on changes in soil chemical properties and growth of 'Red Madness' petunia in plug production. To achieve this, dolomite (DO) with 0, 1.0, 3.5, 8.0 or 13.0 $g{\cdot}L^{-1}$ and calcium carbonate (CC) with 0, 2.0, 2.5, 3.0, 3.5, or 4.0 $g{\cdot}L^{-1}$ were incorporated into peatmoss + vermiculite (1:1, v/v) during the root substrates formulation. The treatments of 3.5 $g{\cdot}L^{-1}$ of DO and 2.5 or 3.0 $gL^{-1}$ of CC had acceptable ranges of pH and EC in soil solution such as 5.6~6.2 and 0.7~1.0 $dS{\cdot}m^{-1}$, respectively. The faster rising of pH was observed in root media containing CC rather than those of DO. This indicates that the solubility of CC is higher than DO. The soil Ca concentrations in all treatments of CC were 1.8 times as high as those of DO. The treatments of 3.5 or 8.0 $g{\cdot}L^{-1}$ of DO had the highest soil Mg concentrations, but all treatments of CC had lower soil Mg concentrations than control treatment indicating that additional application of Mg fertilizers are required. The elevated application rate of DO or CC resulted in the increase of fresh and dry weight. But plant heights were not influenced by application of liming fertilizers. The results of tissue analysis showed that application of DO or CC influenced the $PO_4{^-}P$, Ca and Mg contents, but not influenced the contents of other nutrients such as N, P, Fe, Mn, Zn and Cu.