• 제목/요약/키워드: $CaAl_2Si_2O_8$

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Effects of Dietary Yellow Loess on Serum Constituents in Korean Rockfish, Sebastes schlegeli (황토 첨가 사료가 조피볼락의 혈청성분에 미치는 영향)

  • 강동수;조영철;최옥수;이영재;김해섭;배태진
    • Journal of Life Science
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    • v.10 no.3
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    • pp.286-291
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    • 2000
  • This study was performed to define the effects of various levels (0∼15%) of dietary yellow loess on serum constituents in Korean rockfish (Sebastes schlegeli). After seven weeks of feeding trial, hemoglobin, protein, albumin, triglyceride, cholesterol and bilirubin in serum were investigated. Chemical composition of yellow loess were composed of SiO2 49.80%, Al2O3 27.50%, FeO3 8.33%, CaO 0.09%, MgO 0.64%, K2O 1.62%, Na2O 0.12%, P2O5 0.20% and MnO 0.03%. Serum levels of total protein and albumin showed higher values the yellow loess addition groups than the control group, and the values of protein and albumin were increased with dietary yellow loess level. Serum levels of triglyceride and cholesterol in the groups fed yellow loess were lower than those in the group fed control diet. And these values decreased with dietary yellow loess level up 10%, then increased with 15% yellow loess diet. The values of bilirubin in serum significantly decreased with dietary yellow loess level up 10%, then increased with 15% yellow loess diet. Hemoglobin level from rockfish fed 7.5% and 10% yellow loess diet were significantly higher than those from fed the control diet.

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Electrical Properties of $(Sr_{0.85}Ca_{0.15})TiO_3$ Thin Films with Top Electrodes (상부전극에 따른 $(Sr_{0.85}Ca_{0.15})TiO_3$ 박막의 전기적 특성)

  • Jo, Chun-Nam;Kim, Jin-Sa;Sin, Cheol-Gi;O, Jae-Han;Choe, Un-Sik;Kim, Chung-Hyeok;Lee, Jun-Ung
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.49 no.2
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    • pp.107-112
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    • 2000
  • $(Sr_{0.85}Ca_{0.15})TiO_3$(SCT) thin films were deposited on Pt-coated $TiO_2/SiO_2/Si$ wafer by the rf sputtering method. Experiments were conducted to investigate the electrical properties of SCT thin films with various top electrodes. Various top electrodes as Pt, Al, Ag, Cu were deposited on SCT thin films by sputter and thermal evaporator. The characteristics of C-F and C-V of SCT thin films were not obviously varied with various top electrodes, SCT thin films annealed at $600^{\circ}C$ represents as favorable capacitance characteristics than SCT thin films not annealed, and Pt top electrode have the most high capacitance. The characteristic of I-V of SCT thin films showed that Pt top electrode revealed more less leakage current density than other electrodes, had a leakage current density below 10-8$[A/cm^2]$ until 25[V] applied voltage.

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Development of Mineral Admixture for Concrete Using Spent Coffee Grounds (커피찌꺼기를 활용한 콘크리트 혼화재의 개발)

  • Kim, Sung-Bae;Lee, Jae-Won;Choi, Yoon-Suk
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.3
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    • pp.185-194
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    • 2022
  • Coffee is one of the most consumed beverages in the world and is the second largest traded commodity after petroleum. Due to the great demand of this product, large amounts of waste is generated in the coffee industry, which are toxic and represent serious environmental problems. This study aims to study the possibility of recycling spent coffee grounds (SCG) as a mineral admixture by replacing the cement in the manufacturing of concrete. To recycle the coffee g rounds, the SCG was dried to remove moisture and fired in a kiln at 850 ℃ for 8 hours. Carbonized coffee grounds are produced as coffee grounds ash (CGA) through ball mill grinding. The chemical composition of the prepared coffee grounds ash was investigated using X-ray fluorescence (XFR). According to the chemical composition analysis, the major elements of coffee grounds ash are K2O(51.74 %), CaO(15.92 %), P2O5(14.39 %), MgO(7.74 %) and SO3(6.89 %), with small amounts of F2O3(0.66 %), SiO2(0.59 %) and Al2O3(0.31 %) content. To evaluate quality and mechanical properties, substitutions of 5, 10, and 15 wt.% of coffee grounds ash (CGA) were tested. From the quality test results, the 28-day activity index of CGA5 reached 80 %, and the flow value ratio reached 96 %, which is comparable to the minimum requirement for second-grade FA. From the test results of the mortar, the optimal results have been found in specimens with 5 wt-% coffee grounds ash, showing good mechanical and physical properties.

Crystallographic analysis of dehydrated fully Tl+-exchanged zeolite Y

  • Lim, Woo Taik;Kwon, Ji Hye;Choi, Sik Young;Kim, Young Hun;Heo, Nam Ho
    • Analytical Science and Technology
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    • v.18 no.4
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    • pp.278-286
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    • 2005
  • The crystal structure of ($Tl_{71}$-Y ($Tl_{71}Si_{121}Al_{71}O_{384}$), ${\alpha}=24.706(3){\AA}$, dehydrated at 653 K and $8{\times}10^{-6}$ torr, has been determined by single-crystal X-ray diffraction techniques in the cubic space group $Fd\bar{3}m$ at 294(1) K. The structure was refined using all intensities to the final error indices (using only the 302 reflection for which $F_{\circ}$ > $4{\sigma}(F_0)$) $R_1=0.0602$ (based on F) and $R_w=0.1744$ (based on $F_2$). The 71 $Tl^+$ ions per unit cell are found at four crystallographically distinct positions. Site I' position in the sodalite cavity opposite D6Rs are each occupied by eighteen $Tl^+$ ions per unit cell; these $Tl^+$ ions are recessed ca. $1.45{\AA}$ into the sodalite cavity from their O(3) plane (Tl-O=2.701(15), $3.163(16){\AA}$ and O-Tl-O=$92.1(4)^{\circ}$). The 23 $T1^+$ ions fill site II in the supercage; these $T1^+$ ions are recessed ca. $1.58{\AA}$ into the supercage from their O(2) plane (Tl-O = 2.850(16), $3.156(16){\AA}$ and O-T1-O = $85.1(5)^{\circ}$). The 19 $Tl^+$ ions lie at site III' in the supercage near a triple 4-ring (Tl-O = 3.10(7), $3.39(5){\AA}$ and O-Tl-O = 47.8(9), $95.3(18)^{\circ}$) and the remaining II ions occupy another site III' near a triple 4-ring in the supercage (Tl-O = 2.81(4), $2.71(4){\AA}$ and O-Tl-O = $57.3(8)^{\circ}$).

A Study on the Application of a Turbidity Reduction System for the Utilization of Thermal Wastewater in High Turbidity Zones (고탁도 해역의 온배수 활용을 위한 탁도저감시스템 적용에 대한 연구)

  • Ha, Shin-Young;Oh, Cheol;Gug, Seung-Gi
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.24 no.7
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    • pp.916-922
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    • 2018
  • Recently, power plant effluent condensers received a Renewable Energy Certificate as components of hydrothermal energy (weighted 1.5 times) as one target item of the Renewable Portfolio Standard (RPS) policy. Accordingly, more attention is being paid to the value of thermal wastewater as a heat source. However, for utilization of thermal wastewater from power plants in high-turbidity areas like the West Sea of Korea, a turbidity reducing system is required to reduce system contamination. In this study, an experimental test was performed over a month on thermal wastewater from power plants located in the West Sea of Korea. It was found that water turbidity was reduced by more than 80 % and that the concentration of organic materials and nutrient salts was partially reduced due to the reduction of floating/drifting materials. To conduct a comparative analysis of the level of contamination of the heat exchanger when thermal wastewater flows in through a turbidity reducing system versus when the condenser effluent flows in directly without passing through the turbidity system, we disassembled and analyzed heat exchangers operated for 30 days. As a result, it was found that the heat exchanger without a turbidity reducing system had a higher level of contamination. Main contaminants (scale) that flowed in to the heat exchanger included minerals such as $SiO_2$, $Na(Si_3Al)O_8$, $CaCO_3$ and NaCl. It was estimated that marine sediment soil flowed in to the heat exchanger because of the high level of turbidity in the water-intake areas.

Surface Morphology of PEO-treated Ti-6Al-4V Alloy after Anodic Titanium Oxide Treatment (ATO 처리후, 플라즈마 전해 산화 처리된 Ti-6Al-4V 합금의 표면 형태)

  • Kim, Seung-Pyo;Choe, Han-Cheol
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.75-75
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    • 2018
  • Commercially pure titanium (CP-Ti) and Ti-6Al-4V alloys have been widely used in implant materials such as dental and orthopedic implants due to their corrosion resistance, biocompatibility, and good mechanical properties. However, surface modification of titanium and titanium alloys is necessary to improve osseointegration between implant surface and bone. Especially, when titanium oxide nanotubes are formed on the surface of titanium alloy, cell adhesion is greatly improved. In addition, plasma electrolytic oxide (PEO) coatings have a good safety for osseointegration and can easily and quickly form coatings of uniform thickness with various pore sizes. Recently, the effects of bone element such as magnesium, zinc, strontium, silicon, and manganese for bone regeneration are researching in dental implant field. The purpose of this study was researched on the surface morphology of PEO-treated Ti-6Al-4V alloy after anodic titanium oxide treatmentusing various instruments. Ti-6Al-4V ELI disks were used as specimens for nanotube formation and PEO-treatment. The solution for the nanotube formation experiment was 1 M $H_3PO_4$ + 0.8 wt. % NaF electrolyte was used. The applied potential was 30V for 1 hours. The PEO treatment was performed after removing the nanotubes by ultrasonics for 10 minutes. The PEO treatment after removal of the nanotubes was carried out in the $Ca(CH_3)_2{\cdot}H_2O+(CH_3COO)_2Mg{\cdot}4H_2O+Mn(CH_3COO)_2{\cdot}4H_2O+Zn(CH_3CO_2)_2Zn{\cdot}2H_2O+Sr(CH_2COO)_2{\cdot}0.5H_2O+C_3H_7CaO_6P$ and $Na_2SiO_3{\cdot}9H_2O$ electrolytes. And the PEO-treatment time and potential were 3 minutes at 280V. The morphology changes of the coatings on Ti-6Al-4V alloy surface were observed using FE-SEM, EDS, XRD, AFM, and scratch tester. The morphology of PEO-treated surface in 5 ion coating solution after nanotube removal showed formation or nano-sized mesh and micro-sized pores.

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Studies on the Fusibility of Fly Ash-Flux Mixtures (융제 첨가 비산회의 융융성 연구)

  • Yang, Hyun S.;Lee, Kyu C.;Park, Chu S.
    • Applied Chemistry for Engineering
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    • v.8 no.6
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    • pp.985-993
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    • 1997
  • The effects of CaO and MgO fluxes on the fusibility of fly-ashes were investigated for two different fly-ashes. A fusion temperature of mixtures of selected fly-ashes and fluxes were measured by the ASTM test method(D1857) and the differential thermal analysis. IDT of these samples added CaO and MgO as a fluxing agent dropped in the range of 114 to $294^{\circ}C$ and 80 to $224^{\circ}C$, respectively. Compared with ash fusion temperature to Base/Acid ratio, the lowest ash fusion temperature were measured in the range of 0.7 to 0.8 for CaO-fly ash mixtures and 0.3 to 0.4 for MgO-fly ash mixtures. As a result, MgO in small addition acted as a more effective flux than CaO. A conventional Base/Acid ratio and liquidus point of ternary diagram did not show a good correlation with ash fusion temperature for these samples. In pure fusion temperature of fly ash-mixtures, DTA was better method than ASTM test method.

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Low k Materials for High Frequency High Integration Modules

  • Na, Yoon-Soo;Lim, Tae-Young;Kim, Jin-Ho;Shin, Hyo-Soon;Hwang, Jong-Hee;Cho, Yong-Soo
    • Journal of the Korean Ceramic Society
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    • v.46 no.4
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    • pp.413-418
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    • 2009
  • Glass systems based on Ca, Sr, Ba, and Zn modified alumino-boro silicates were investigated in order to improve the dielectric and mechanical properties of a typical LTCC (low temperature co-fired ceramic) which was developed for high frequency highly-integrated modules. The glass was prepared by a typical melting procedure and then mixed with cordierite fillers to fabricate glass/ceramic composite-type LTCC materials. The amount of cordierite filler was fixed at 50 volumetric%. For an optimal glass composition of 7.5% CaO, 7.5% BaO, 5% ZnO, 10% $Al_2O_3$, 30% $B_2O_3$, and 40% $SiO_2$ in mole ratio, the resultant LTCC composite showed a dielectric constant of 5.8 and a dielectric loss ($tan{\delta}$) of 0.0009 after firing at $900^{\circ}C$. An average bending strength of 160MPa was obtained for the optimal composition.

Mineralogical Characteristics of Lime Mortars Used in Pointing of Namhansanseong Yeojang in Joseon Dynasty (남한산성 여장의 사춤으로 사용된 조선시대 석회 모르타르의 광물학적 특성 연구)

  • Kim, Eunkyung;Ahn, Sunah;Mun, Seongwoo;Kang, Soyeong
    • Journal of the Mineralogical Society of Korea
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    • v.30 no.4
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    • pp.179-186
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    • 2017
  • This study investigated the mineralogical characteristics of lime mortars used in pointing of Namhansanseon Yeojang from Joseon dynasty. Polarization microscopy revealed quartz, feldspar, mica, pyroxene and opaque minerals in the lime mortars. XRD analysis also confirmed clay minerals chlorite and kaolin. As a result of particle size analysis of lime mortars, the particle size distribution was wide and size was not uniform. 60% of samples were corresponded to the sand area. The chemical components detected from XRF analysis, 8.71-11.18 % of Ca as the main component of lime and $SiO_2$, $Al_2O_3$, and $Fe_2O_3$ in soil minerals were main components. The lime mortars showed an endothermic peak due to decarbonization reaction of $CaCO_3$ at $750^{\circ}C$ and weight reduction rate of 10%. The microstructures were agglomerated amorphous and observed rhombohedral calcite crystals by scanning electron microscope. It is considered that the pointing of Yeojang is a mortar mixed with lime and soil. In addition the Hanbongseong Yeojang was constructed using the same materials and construction technique because the minerals composition is not different according to the Yeojang location and use.

Characterization and Distribution of Clay Minerals in Corn Field Soils in Korea

  • Jang, Jeonghun;Park, Nayun;Lee, Donghoon;Choi, Seyeong;Park, Junhong;Park, Man
    • Korean Journal of Soil Science and Fertilizer
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    • v.49 no.6
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    • pp.813-818
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    • 2016
  • Distribution of clay minerals separated from clay fraction of corn fields in Korea has been investigated along with their characterization. Crystalline phases of the clay minerals were identified by powder X-ray diffraction (XRD) pattern, and their relative chemical compositions were analyzed by X-ray fluorescence spectrometry (XRF). The soils were found to have pH 6.4, organic matter $37.2g\;kg^{-1}$, available $P_2O_5$ $599mg\;kg^{-1}$, respectively, and exchangeable K, Ca and Mg were 1.2, 7.3 and $1.8cmol_c\;kg^{-1}$, respectively. Major primary minerals consisted mainly of quartz and mica, and kaolinite and chlorite were identified as major secondary clay minerals. For most of soils, mica phase was identified to be muscovite rather than biotite. The average contents of $SiO_2$, $Al_2O_3$ and $Fe_2O_3$ were 43.7, 23.6 and 8.8%, respectively, although they were different with the locations.