• 한국표면공학회지
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• 제43권6호
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• pp.278-282
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• 2010

In this research, the friction and wear characteristic behaviors of coating materials of TiAlN and CrAlN were investigated. The wear test was conducted in air and un-lubricated state using the reciprocating friction wear tester. Temperature were 50 and $120^{\circ}C$, and load were 3, 7, and 11 kgf for tests. By comparing the coefficient of friction and observing the wear microstructure, the friction and wear characteristic behaviors of TiAlN and CrAlN coating layers on SKD61 were investigated. The coefficient of friction of CrAlN coating was lower than that of TiAlN at all conditions. Therefore, CrAlN was suggested to be more advantageous coating than TiAlN for the extrusion mold of aluminum.

• Current Applied Physics
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• 제18권11호
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• pp.1320-1326
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• 2018

High crystalline quality CrN thin films have been grown on $La_{0.67}Sr_{0.33}MnO_3$ (LSMO) templates by molecular beam epitaxy. The structure and magnetic properties of CrN/LSMO heterojunctions are investigated combining with the experiments and the first-principles simulation. The N?el temperature of the CrN/LSMO samples is found to be 281 K and the saturation magnetization of CrN/LSMO increases compared to that of LSMO templates. The magnetic property of CrN/LSMO heterostructures mainly comes from Cr atoms of (001) CrN and Mn atoms of (001) LSMO. The (001) LSMO induces and couples the spin of the CrN sublattice at CrN/LSMO interface.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2011년도 춘계학술대회 및 Fine pattern PCB 표면 처리 기술 워크샵
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• pp.189-189
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• 2011

CrZrN 박막은 CrN 박막에 비해서 향상된 기계적 특성과 우수한 표면 조도특성을 가지고 있다. 그러나 $500^{\circ}C$ 이상에서 기계적 특성이 급격히 감소하는 현상이 알려져 있다. 본 연구에서는 CrZrN 박막에 Si를 첨가하여 Si 함량에 따른 고온에서의 기계적 특성을 CrZrN 박막과 비교하였다. $500^{\circ}C$에서 마모 실험한 결과 CrZrN 박막에 비하여 소량의 Si의 첨가만으로 고온에서의 마모 특성이 향상되는 것을 확인하였다. 이것은 Si 첨가에 따라 고온에서 안정한 비정질상의 형성 영향으로 판단된다.

• 한국재료학회지
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• 제17권5호
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• pp.256-262
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• 2007

Effects of interlayer and the combination of different coating methods on the mechanical and corrosion behaviors of TiN and CrN coated on 420 stainless steel have been studied. STS 420 specimen were tempered at $300^{\circ}C$ for 1 hr in vacuum furnace. The TiN and CrN thin film with 2 ${\mu}m$ thickness were coated by arc ion plating and DC magnetron sputtering following the formation of interlayer for pure titanium and chromium with 0.2 ${\mu}m$ thickness. The microstructure and surface analysis of the specimen were conducted by using SEM, XRD and roughness tester. Mechanical properties such as hardness and adhesion also were examined. XRD patterns of TiN thin films showed that preferred TiN (111) orientation was observed. The peaks of CrN (111) and $Cr_2N$ (300) were only observed in CrN thin films deposited by arc ion plating. Both TiN and CrN deposited by arc ion plating had the higher adhesion and hardness compared to those formed by magnetron sputtering. The specimen of TiN and CrN on which interlayer deposited by magnetron sputtering and thin film deposited by arc ion plating had the highest adhesion with 22.2 N and 19.2 N. respectively. TiN and CrN samples shown the most noble corrosion potentials when the interlayers were deposited by using magnetron sputtering and the metal nitrides were deposited by using arc ion plating. The most noble corrosion potentials of TiN and CrN were found to be approximately -170 and -70 mV， respectively.

• Korean Journal of Mathematics
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• 제6권2호
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• pp.243-257
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• 1998

The purpose of this paper is to give some characterizations of $n$-dimensional CR-submanifolds with ($n-1$) CR-dimension immersed in a complex projective space $CP^{\frac{n+2}{2}}$, in terms of the Riemannian curvature tensor R.

• 대한수학회지
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• 제39권1호
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• pp.91-102
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• 2002

Let M and N be CR manifolds with nondegenerate Levi forms of hypersurface type of dimension 2m ＋ 1 and 2n ＋ 1, respectively, where 1 $\leq$ m $\leq$ n. Let f : M longrightarrow N be a CR mapping. Under a generic assumption we construct a complete system of finite order for the infinitesimal deformations of f. In particular, we prove the space of infinitesimal deformations of f forms a finite dimensional Lie algebra.

• 대한수학회지
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• 제46권5호
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• pp.895-905
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• 2009

Let $B^{n+1}$ be the unit ball in the complex vector space $\mathbb{C}^{n+1}$ with the standard Hermitian metric. Let ${\Sigma}^n={\partial}B^{n+1}=S^{2n+1}$ be the boundary sphere with the induced CR structure. Let f : ${\Sigma}^n{\hookrightarrow}{\Sigma}^N$ be a local CR immersion. If N < 3n - 1, the asymptotic vectors of the CR second fundamental form of f at each point form a subspace of the CR(horizontal) tangent space of ${\Sigma}^n$ of codimension at most 1. We study the higher order derivatives of this relation, and we show that a linearly full local CR immersion f : ${\Sigma}^n{\hookrightarrow}{\Sigma}^N$, N $\leq$ 3n-2, can only occur when N = n, 2n, or 2n + 1. As a consequence, it gives an extension of the classification of the rational proper holomorphic maps from $B^{n+1}$ to $B^{2n+2}$ by Hamada to the classification of the rational proper holomorphic maps from $B^{n+1}$ to $B^{3n+1}$.

• Corrosion Science and Technology
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• 제22권4호
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• pp.232-241
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• 2023

The mechanical properties of the hydrogen valve responsible for supplying and blocking hydrogen gas in a hydrogen fuel cell electric vehicle (FCEV) were researched. Mechanical properties by hydrogen embrittlement were investigated by coating chromium nitride (CrN) and titanium nitride (TiN) on aluminum alloy by arc ion plating method. The coating layer was deposited to a thickness of about 2 ㎛, and a slow strain rate test (SSRT) was conducted after hydrogen embrittlement to determine the hydrogen embrittlement resistance of the CrN and TiN coating layers. The CrN-coated specimen presented little decrease in mechanical properties until 12 hours of hydrogen charging due to its excellent resistance to hydrogen permeation. However, both the CrN and TiN-coated specimens exhibited deterioration in mechanical properties due to the peeling of the coating layer after 24 hours of hydrogen charging. The specimens coated at 350 ℃ presented a significant decrease in ultimate tensile strength due to abnormal grain growth.

• 한국표면공학회지
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• 제50권5호
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• pp.339-344
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• 2017

Highly corrosion resistance performance of CrAlSiN coatings were obtained by applying ultrathin $Al_2O_3$ thin films using atomic layer deposition (ALD) method. CrAlSiN coatings were prepared on Cr adhesion layer/SUS304 substrates by a hybrid coating system of arc ion plating and high power impulse magnetron sputtering (HiPIMS) method. And, ultrathin $Al_2O_3$ passivation layer was deposited on the CrAlSiN/Cr adhesion layer/SUS304 sample to protect CrAlSiN coatings by encapsulating the whole surface defects of coating using ALD. Here, the high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) and energy dispersive X-ray spectrometry (EDX) analysis revealed that the ALD $Al_2O_3$ thin films uniformly covered the inner and outer surface of CrAlSiN coatings. Also, the potentiodynamic and potentiostatic polarization test revealed that the corrosion protection properties of CrAlSiN coatings/Cr/SUS304 sample was greatly improved by ALD encapsulation with 50 nm-thick $Al_2O_3$ thin films, which implies that ALD-$Al_2O_3$ passivation layer can be used as an effect barrier layer of corrosion.

• Bulletin of the Korean Chemical Society
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• 제26권7호
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• pp.1044-1050
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• 2005

The reaction of cis-[Cr([14]-decane)($OH_2)_2]^+$ ([14]-decane = rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-teraazacyclotetradecane) with auxiliary ligands {$L_a$ = isothiocyanate ($NCS^-$), azide ($N3^-$) or chloroacetate(caa)} leads to a new cis-[Cr([14]-decane)($NCS)_2]ClO_4{\cdot}H_2O$ (1), cis-[Cr([14]-decane)($N_3)_2]ClO_4$ (2) or cis-[Cr([14]-decane)($caa)_2]ClO_4$ (3). These complexes have been characterized by a combination of elemental analysis, conductivity, IR and Vis spectroscopy, mass spectrometry, and X-ray crystallography. Analysis of the crystal structure of cis-[Cr([14]-decane)($NCS)_2]ClO_4{\cdot}H_2O$ reveals that central chromium(III) has a distorted octahedral coordination environment and two $NCS^-$anions are bonded to the chromium(III) ion via the Ndonor atom in the cis positions. The angle $N_{axial}-Cr-N_{axial}$ deviates by 13$^{\circ}$ from the ideal value of 180$^{\circ}$ for a perfect octahedron. The bond angle N-Cr-N between the Cr(III) ion and the two nitrogen atoms of the isothiocyanate ligands is close to 90$^{\circ}$. The bond lengths of Cr-N between the chromium and $NCS^-$groups are 1.964(5) and 2.000(5) $\AA$. They are shorter than those between chromium and nitrogen atoms of the macrocycle. The IR spectra of 1, 2 and 3 display bands at 2073, 1344 and 1684 $cm^{-1}$ attributed to the $NCS^-$, ${N_3}^-$ and caa groups stretching vibrations, respectively.