• Title/Summary/Keyword: $CO_2$capture

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A Study on the Optimal Process Design of Cryogenic Air Separation Unit for Oxy-Fuel Combustion (순산소 연소를 위한 초저온 공기분리장치의 최적공정 설계 연구)

  • Choi, Hyeung-Chul;Moon, Hung-Man;Cho, Jung-ho
    • Korean Chemical Engineering Research
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    • v.56 no.5
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    • pp.647-654
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    • 2018
  • In order to solve the global warming and reduce greenhouse gas emissions, it has been developed the $CO_2$ capture technology by oxy-fuel combustion. But there is a problem that the economic efficiency is low because the oxygen production cost is high. ASU (Air Separation Unit) is known to be most suitable method for producing large capacity of oxygen (>2,000 tpd). But most of them are optimized for high purity (>99.5%) oxygen production. If the ASU process is optimized for low purity(90~97%) oxygen producing, it is possible to reduce the production cost of oxygen by improving the process efficiency. In this study, the process analysis and comparative evaluation was conducted for developing large capacity ASU for oxy-fuel combustion. The process efficiency was evaluated by calculating the recovery rate and power consumption according to the oxygen purity using the AspenHysys. As a result, it confirmed that the optimal purity of oxygen for oxyfuel combustion is 95%, and the power consumption can be reduced by process optimization to 12~18%.

An Experimental Study on Mode Switching from Air-firing to Oxy-firing in Pilot-scale Combustion Systems (미분탄 순산소 연소 운전 모드 전환 과정에 대한 Pilot 규모 설비에서의 실험적 연구)

  • Choi, Chong-Gun;Na, Ik-Hwan;Lee, Jae-Wook;Chae, Tae-Young;Yang, Won;Kim, Young-Ju;Kim, Jong-An;Seo, Sang-Il
    • Journal of the Korean Society of Combustion
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    • v.16 no.3
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    • pp.12-20
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    • 2011
  • Oxy-coal combustion for $CO_2$ capture in coal power plants entails a mode switching from air-firing to oxyfiring. In this study, procedure of the mode switching was investigated and discussed through experiments in pilot scale facilities: (1) a 0.3 $MW_{th}$ furnace with a vertical single burner and a FGR(Flue Gas Recirculation) system (2) a 1 $MW_{th}$ furnace with horizontal 4 burners and a FGR system. Principle of the mode switching was established and performed with control of FD fan, FGR fan, ID fan and oxygen flow rates. We have found that equivalence ratio in the oxy-firing mode should be increased more than that in the air-firing to achieve stable mode switching. Control of FD, ID and FGR fans should be performed carefully in the mode switching, in the sense of complete combustion and flame attachment. Moisture contents in the ash and the flue gas recycled to the primary oxidizer stream should be removed to prevent condensation, corrosion and duct clogging.

Ecologically Sustainable Management of Short-necked Clam, Ruditapes philippinarum, on the Coast of Yeongi at Tongyeong, Korea (통영 연기해역의 바지락자원 적정관리에 관한 연구)

  • Cho, Sang-Man;Jeong, Woo-Geon;Lee, Sang-Jun
    • The Korean Journal of Malacology
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    • v.24 no.3
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    • pp.189-197
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    • 2008
  • In order to develop the sustainable ecological management, short-necked clams, Ruditapes philippinarum, were collected from Yoengi coast in Tongyoeng, Korea. The growth of the clam was estimated as: $L_f=68.08{\cdot}(1-e^{-0.145(t+0.324)})$ from ring radius composition of shell. Instantaneous co-efficiency of total mortality and natural mortality were calculated as: 0.991/year and 0.494/year, respectively. The age of the clams from the first capture was estimated to be 3.28. The total biomass was estimated to be 212 MT in the fisheries area (6.4 ha). Applied by these parameters, the annual recruit biomass and the current yield per recruit were calculated to be 649.5 individual/$m^2$ and $0.7\;g/m^2$, respectively. The current fishing intensity was much lower for maximum sustainable yield and acceptable biological catch. Although higher yield per recruit could be achieved by increasing fishing intensity, it is favorable to retain the current fishing intensity because of the unique fishing attitude on Yeongi coast in Tongyoeng, Korea.

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Performance Evaluation of an Oxy-coal-fired Power Generation System - Thermodynamic Evaluation of Power Cycle (순산소 석탄 연소 발전 시스템의 성능 평가 - 동력 사이클의 열역학적 해석)

  • Lee, Kwang-Jin;Choi, Sang-Min;Kim, Tae-Hyung;Seo, Sang-Il
    • Journal of the Korean Society of Combustion
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    • v.15 no.2
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    • pp.1-11
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    • 2010
  • Power generation systems based on the oxy-coal combustion with carbon dioxide capture and storage (CCS) capability are being proposed and discussed lately. Although a large number of lab scale studies for oxy-coal power plant have been made, studies of pilot scale or commercial scale power plant are not enough. Only a few demonstration projects for oxy-coal power plant are publicized recently. The proposed systems are evolving and various alternatives are to be comparatively evaluated. This paper presents a proposed approach for performance evaluation of a commercial 100 MWe class power plant, which is currently being considered for 'retrofitting' for the demonstration of the concept. The system is configurated based on design and operating conditions with proper assumptions. System components to be included in the discussion are listed. Evaluation criteria in terms of performance are summarized based on the system heat and mass balance and simple performance parameters, such as the fuel to power efficiency and brief introduction of the second law analysis. Also, gas composition is identified for additional analysis to impurities in the system including the purity of oxygen and unwanted gaseous components of nitrogen, argon and oxygen in air separation unit and $CO_2$ processing unit.

PHOSPHATE-DEFICIENCY REDUCES THE ELECTRON TRANSPORT CAPACITIES OF THYLAKOID MEMBRANES THROUGH LIMITING PHOTOSYSTEM II IN LEAVES OF CHINESE CABBAGE

  • Park, Youn-Il;Hong, Young-Nam
    • Journal of Photoscience
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    • v.1 no.2
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    • pp.95-105
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    • 1994
  • Experiments were carried out to investigate whether P, deficiency in detached 25 mM mannose-feeding led to a decline of the photosynthetic electron transport rates through acidification of the thylakoid lumen. With increasing mannose-feeding time, the maximal CO2 exchange rates and the maximal quantum yields of photosynthesis decreased rapidly up to 6 h by 73% then with little decrease up to 12 h. The ATP/ADP ratio declined by 54% 6 h after the treatment and then recovered to the control level at 12 h. However, the NADPH/NADP~ ratio was not significantly altered by mannose treatment. Electron transport rates of thylakoid membranes isolated from 6 h treated leaves did not change, but they decreased by 30% in 12 h treated leaves. The quenching analysis of Chl fluorescence in mannose-treated leaves revealed that both the fraction of reduced plastoquinone and the degree of acidification of thylakoid lumen remained higher than those of the control. The reduction of PSI in mannose fed leaves was inhibited due to acidification of thylakoid lumen (high qE). The reduction of primary quinone acceptor of PSII was inhibited by mannose feeding. Mannose treatment decreased the efficiency of excitation energy capture by PSII. Fo quenching was induced when treated with mannose more than 6 h, and had a reverse linear correlation with (Fv)m/Fm ratio. These results suggest that Pi deficiency in Chinese cabbage leaves reduce photosynthetic electron transport rates by diminishing both PSII function and electron transfer from PSII to PSI through acidification ofthylakoid lumen, which in turn induce the modification of photosynthetic apparatus probably through protein (de)phosphorylation.

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Study on Resistance Component of Container Ship According to Trim Conditions (트림 변화에 따른 컨테이너선의 저항성분별 특성 연구)

  • Han, Ki-Min;Park, Hyun-Suk;Seo, Dae-Won
    • Journal of Ocean Engineering and Technology
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    • v.29 no.6
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    • pp.411-417
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    • 2015
  • The shipping and shipbuilding industries have had business difficulties since the implementation of regulations on the CO2 emissions from ships by IMO and the occurrence of the global financial crisis in 2008. Under this global recession, most shipping firms have started to operate their fleets at slow steaming rates with the goal of improving the profit ratio per transported unit. This study analyzed the resistance performance of a 6,800 TEU container ship corresponding to its trim variation with slow steaming, compared with that at its original design speed. Two different grid systems were used for the numerical calculation, one that considered the free surface allowing the capture of the dynamic trim and one that did not. This made it possible to clearly classify each resistance component to provide useful information to hull-form designers. In addition, a form factor assumption method using CFD was used for a reasonable effective power prediction in compliance with the 1978 ITTC performance prediction method. It was found that the total resistance of a 6,800 TEU container ship was reduced by 2.6% in the case of a 1-m trim at the bow at 18 kn.

Work Posture Analysis Using Digital Ergonomic Simulation (디지털 인간공학 시뮬레이션 기법을 이용한 작업자세 분석)

  • Kim, Nam-Du;Yim, Hyun-June;Park, Hee-Sok;Cha, Tae-In
    • Journal of the Ergonomics Society of Korea
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    • v.26 no.2
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    • pp.81-88
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    • 2007
  • The objective of this study was to investigate the validity of the digital ergonomic simulation (DES) method as a prospective alternative to the ergonomic analyses conducted by experts. The DES method utilizes commercial digital manufacturing software, and can compute the RULA scores continuously throughout the simulated work cycle. It was shown in a case study that the accuracy and objectivity of the DES method are superior to those obtained by experts. Also, it was demonstrated that the DES method has a distinct capability to simulate and validate a proposed work plan. Major limitations of the current DES method lie in the extensive time and efforts required for accurate digital simulation, which may be overcome through an automatic module for RULA data acquisition and a motion capture system.

Reliability Evaluation of Accelerated Carbonation Results According to Carbon Dioxide Concentration (이산화탄소 농도에 따른 촉진 탄산화 결과의 신뢰도 평가)

  • Park, Dong-Cheon
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.04a
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    • pp.166-167
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    • 2022
  • The International Energy Agency(IEA) recommends that intergovernmental agreements reduce CO2 emissions by 2050 to about 50% in 2005 in its report. To realize these demands, it is suggested to actively utilize energy efficiency improvement technology, renewable energy, nuclear power, carbon dioxide capture & storage technology (CCS). In the field of building materials and cement, mineral carbonization technology is widely used. Inorganic by-products applicable to greenhouse gas storage include waste concrete, slag, coal ash, and gypsum. If the Mineral Carbonation Act is used, it is expected that about 12 million tons of greenhouse gases can be immobilized every year. Greenhouse gas immobilization using cement hydrate can be immobilized by injecting carbon dioxide into the hydrated products C-S-H, and Ca(OH)2. In the case of immobilization through concrete carbonization, a carbon dioxide promotion test is used, which is often different from the actual carbon dioxide carbonization reaction. If the external carbon dioxide concentration is abnormally higher than the reality, it is thought that it will be different from the actual reaction. In this study, the carbonation phenomenon according to the concentration and identification of the carbon dioxide reaction mechanism of cement hydrate was to be considered.

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Single-trait GWAS of Leaf Rolling Index with the Korean Rice Germplasm

  • ByeongYong Jeong;Muhyun Kim;Tae-Ho Ham;Seong-Gyu Jang;Ah-Rim Lee;Min young Song;Soon-Wook Kwon;Joohyun Lee
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2022.10a
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    • pp.17-17
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    • 2022
  • Leaves are an important organism for photosynthesis and transpiration. The shape of leaf is crucial factor affecting plant architecture. V-shape leaf rolling is enhancing canopy photosynthesis by increasing the CO2 penetration and the light capture by reducing the shadow between the leaves. Therefore, moderate leaf rolling is thought to more high grain yield per area than flat leaf. We investigated 278 KRICE_CORE accession's Adaxial Leaf Rolling Index (LRI) in first heading using the following equation. For each accession, genomic DNA was used for sequencing. We sequenced the genomics with ~8 X coverage to detect SNPS. Raw reads were aligned against the rice reference (IRGSP 1.0) for SNP identification and genotype calling. To generate genotype data for GWAS, SNPs were filtered with minor allele frequency 0.05. Finally, 841,134 high-quality SNPs were used for our GWAS. The significant threshold was -log10(P)>7.23. From the results, 2 significance SNP were detected. Considering the LD block of 250kbp, 60 candidate gene were selected including Hypothetical gene and Conserved gene. In this poster, we analyzed candidate gene affecting adaxial Leaf Rolling through single-trait GWAS.

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Single-trait GWAS of Leaf Rolling Index with the Korean Rice Germplasm

  • ByeongYong Jeong;Muhyun Kim;Tae-Ho Ham;Seong-Gyu Jang;Ah-Rim Lee;Min young Song;Soon-Wook Kwon;Joohyun Lee
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2022.10a
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    • pp.243-243
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    • 2022
  • Leaves are an important organism for photosynthesis and transpiration. The shape of leaf is crucial factor affecting plant architecture. V-shape leaf rolling is enhancing canopy photosynthesis by increasing the CO2 penetration and the light capture by reducing the shadow between the leaves. Therefore, moderate leaf rolling is thought to more high grain yield per area than flat leaf. We investigated 278 KRICE CORE accession's Adaxial Leaf Rolling Index (LRI) in first heading using the following equation. For each accession, genomic DNA was used for sequencing. We sequenced the genomics with ~8 X coverage to detect SNPS. Raw reads were aligned against the rice reference (IRGSP 1.0) for SNP identification and genotype calling. To generate genotype data for GWAS, SNPs were filtered with minor allele frequency 0.05. Finally, 841,134 high-quality SNPs were used for our GWAS. The significant threshold was -log10(P) >7.23. From the results, 2 significance SNP were detected. Considering the LD block of 250kbp, 60 candidate gene were selected including Hypothetical gene and Conserved gene. In this poster, we analyzed candidate gene affecting adaxial Leaf Rolling through single-trait GWAS.

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