• Transactions of the Korean hydrogen and new energy society
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• v.27 no.5
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• pp.554-561
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• 2016

Depending on the Bio-gas sources, main component gases of $CH_4$ and $CO_2$ are shown to be variously present in amounts. For the anaerobic digester, The concentration of $CH_4$ and $CO_2$ in the gases are 60~70 and 30~35 vol%. For the landfill gas, $CH_4$ and $CO_2$ are 40~60 and 40~60 vol%. For the food wastes, $CH_4$ and $CO_2$ are 60~80 and 20~40 vol%, respectively. In this study, maximum conversion rates of $CO_2$ were obtained from the variety of concentrations of $CH_4$ and $CO_2$ by the catalysts of reforming reactions. Moreover, in order to get maximum producing amount of synthetic gas, experimental studies were performed to optimize the reaction variables. On the basis of $CH_4$, 243 ml, R [$CH_4/(O2+CO_2)$] value were varied from 0.8 to 1.35, in the study of $CH_4$ and $CO_2$ reforming reactions. It was shown that the optimal results were obtained for 1.35 of R value. And also, at $850^{\circ}C$ and 1 atm, the production rate of synthetic gas was 90% and the conversion rates of $CH_4$ and $CO_2$ were higher than 99% and 90%, respectively.

• Membrane Journal
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• v.25 no.2
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• pp.99-106
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• 2015

Polysulfone (PSF) hollow fiber membrane was prepared to separate $CO_2$ from the flaring gas. Fabricated PSF membrane system was fulfilled under 1 stage, 2 stage membrane process and simulation in order to confirm the operating condition for 99% of $CH_4$ and 1% of $CO_2$ concentration. Also, $25Nm^3/h$ bench scale $CO_2$ separation membrane system was operated under 1% of $CO_2$ concentration during 100 hr, and $CH_4$ recovery ratio was 98%.

• Journal of Microbiology and Biotechnology
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• v.11 no.5
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• pp.772-775
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• 2001

A highly $CO_2$ tolerant microalga, Chlorella KR-1, has been isolated and used to fix $CO_2$ from actual flue gas. Growth of Chlorella KR-1 with the supply of flue gas from a liquified natural gas boiler was comparable to that obtained with 10% $CO_2$. Chlorella KR-1 produced from $CO_2$ fixation using the flue has about 50% crude protein with balanced amino acid profiles. Toxicity was not detected when the microalga was used as a feedstuff for chicks. These results indicate that the KR-1 cells could be a favorable protein source for poultry.

• The Transactions of the Korean Institute of Electrical Engineers C
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• v.54 no.5
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• pp.232-237
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• 2005

In this paper, we fabricated $CO_2$ gas sensor based on the MEMS infrared sensor and characterized its electrical and $CO_2$-sensing properties. The fabricated $CO_2$ gas sensor by MEMS technique has many advanges over NDIR(nondispersive) $CO_2$ sensor such as monolithic fabrication, very high selectivity on $CO_2$, low power consumption and compact system. Microbolometer by surface micromachining was fabricated for gas detector and $CO_2$ filter chip by bulk micromachining was fabricated for signal referencing. By using the proposed and fabricated gas sensor, we are expected to measure $CO_2$ concentration more accurately with high reliability.

• Journal of Advanced Marine Engineering and Technology
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• v.34 no.2
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• pp.259-266
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• 2010

The heat flowrate and pressure dorp of $CO_2$ in a multi-tube-in-tube helical coil type gas cooler were predicted using LMTD method and compared with the experimental data. The mass flowrate of $CO_2$ and coolant were varied from 0.06 to 0.075 [kg/s], and the cooling pressure of gas cooler were from 8 to 10 [MPa], respectively. The LMTD method is used to predict the heat flowrate and pressure drop of supercritical $CO_2$ during in-tube cooling. The equations used by LMTD method were Gnielinski correlation for $CO_2$ and Dittus-Boelter correlation for coolant, respectively. The equation used to predict the pressure drop of $CO_2$ and coolant is Blasius correlation. In comparison of heat flowrate and pressure drop of $CO_2$ measured by experiment to that predicted by LMTD method, the experimental heat flowrate and pressure drop of $CO_2$ in the multi-tube-in-tube helical coil type gas cooler shows a relatively good agreement with that predicted by LMTD method.

• Journal of Sensor Science and Technology
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• v.21 no.6
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• pp.456-460
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• 2012

Au/$SnO_2$ core-shell structure nanoparticles (NPs) were synthesized by microwave hydrothermal method, and the effect of working temperature on sensitivity of Au/$SnO_2$ core-shell NPs for CO gas was investigated. The $SnO_2$ shell layer was consisted of $SnO_2$ primary particles with 4.5 nm diameter. The response of Au/$SnO_2$ core-shell NPs for CO gas was maximized at the working temperature of $350^{\circ}C$ while the sensitivity increased with decreasing the working temperature due to the low grain size effect of $SnO_2$ NPs on the response of CO gas.

• Transactions of the Korean hydrogen and new energy society
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• v.15 no.4
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• pp.301-308
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• 2004

The methane reforming with $CO_2$ and steam for manufacture of synthesis gas over $Ni/ZrO_2$ catalyst was investigated. Mixed reforming carried out $CO_2$ dry reforming with $O_2$ and steam for development of DME process in pilot plant. To improve a catalyst deactivation by coke formation, the mixed reforming added carbon dioxide and steam as a oxidizer of the methane reforming was suggested. The result of experiments over commercial catalyst in $CO_2$ dry reforming has shown that the catalyst activity decrease rapidly after 20 hours. In case of $NiO-MgO/Al_2O_3$ catalyst, the deactivation of 20 percent after 30 hours was occurred. The activity of Ni/C catalyst still was not decreased dramatically after 100 hours. The effect of $H_2$ reforming with steam over $Ni/CO_2$ catalyst obtained the optimal conversion of methane and carbon dioxide, and could be produced synthesis gas at ratio of $H_2/CO$ under 1.5.

• Journal of the Korean Institute of Gas
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• v.7 no.3 s.20
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• pp.7-12
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• 2003

A sour natural gas feed containing 1.37 and 1.70 mole percent $CO_2$ and $H_2S$ respectively is to be sweetened. Our research is to design an amine treating facility to bring the concentration of the acid gases in 100 MMSCFD of natural gas down to less than 5 ppm. The K-values for $CO_2,\;H_2S,\;H_2O$ and amine components contained in natural gas is obtained by using Kent-Eisenberg model. The new gas sweetening process designed by Ball and Veldman is modeled and optimized with the commercial simulator. Results of simulations led to further economic improvements over the present operating process.

• Journal of Welding and Joining
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• v.12 no.1
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• pp.51-58
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• 1994

Amount of spatter, welding conditions and welding costs were investigated for MAG welding. $CO_2$, Ar+18%;$CO_2$ and Ar+8%$O_2$ were used for shielding gases. As results, arc characteristics and appropriate range for welding were obtained. Amount of spatter in Ar+18%$CO_2$ gas welding was 20% of that of $CO_2$ welding, and Ar+8%$O_2$ was 10% of that of $CO_2$ welding. Therefore by using Ar+18%$CO_2$and Ar+8%$O_2$ gases, welding costs could be reduced compared with $CO_2$ welding due to avoiding spatter.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.4
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• pp.465-473
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• 2011

To find the optimum mixing ratio of WGS catalyst with $CO_2$ absorbent for SEWGS process, water gas shift reaction tests were carried out in a fluidized bed reactor using commercial WGS catalyst and sand (as a substitute for $CO_2$ absorbent). WGS catalyst content, gas velocity, and steam/CO ratio were considered as experimental variables. CO conversion increased as the catalyst content increased during water gas shift reaction. Variations of the CO conversion with the catalyst content were small at low gas velocity. However, those variations increased at higher gas velocity. Within experimental range of this study, the optimum operating condition(steam/CO ratio=3, gas velocity = 0.03 m/s, catalyst content=10 wt.%) to get high CO conversion and $CO_2$ capture efficiency was confirmed. Moreover, long time water gas shift reaction tests up to 20 hours were carried out for two cases (catalyst content = 10 and 20 wt.%) and we could conclude that the WGS reactivity at those conditions was maintained up to 20 hours.