• Journal of Climate Change Research
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• v.5 no.3
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• pp.209-218
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• 2014

In this study, the researchers have developed the greenhouse gas emission coefficients targeted at sewage sludge incineration plants that treat sewage sludge by incineration. Among the gases emitted from the sewage sludge incineration plants, the greenhouse gases showed concentrations of 6.84% for $CO_2$, 4.51 ppm for $CH_4$, and 86.34 ppm for $N_2O$; calculated into greenhouse gas emission coefficients, these gave $276.06kg\;CO_2/ton$, $0.0066kg\;CH_4/ton$, and $0.35kg\;N_2O/ton$. As the result of calculating the greenhouse gas emission quantity in sewage sludge incineration plants using the greenhouse gas emission coefficients, the gross greenhouse gas emission was $84.63ton\;CO_2\;eq./day$, and the net emission was $23.90ton\;CO_2\;eq./day$; this was $37.52ton\;CO_2\;eq./day$ less than the net greenhouse gas emission that was calculated using the standard values of IPCC, which was $61.42ton\;CO_2\;eq./day$. This difference is probably because unlike the standard values of IPCC, the greenhouse gas emission coefficients of this study reflected the special properties of subject facilities. Thus, it is thought that emission coefficient research on the facilities that deviated from the standard values of IPCC should continue to achieve the development of national greenhouse gas coefficient that reflects the special properties of Korea.

• Journal of Sensor Science and Technology
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• v.25 no.2
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• pp.124-130
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• 2016

NDIR $CO_2$ gas sensor was built with ASIC implemented thermopile sensor which included temperature sensor and unique elliptical waveguide structures in this paper. The temperature dependency of dual infrared sensor module ($CO_2$ and reference IR sensors) has been characterized and its output voltage characteristics according to the temperature and gas concentration were proposed for the first time. NDIR $CO_2$ gas and reference IR sensors showed linear output voltages according to the variation of ambient temperatures from 243 K to 333 K and their slopes were 14.2 mV/K and 8.8 mV/K, respectively. The output voltages of temperature sensor also presented a linear dependency according to the ambient temperature and could be described with V(T)=-3.191+0.0148T(V). The output voltage ratio between $CO_2$ and reference IR sensors revealed irrelevant to the changes of ambient temperatures and gave a constant value around 1.6255 with standard deviation 0.008 at 0 ppm. The output voltage of $CO_2$ gas sensor at zero ppm $CO_2$ gas consisted of two components; one is caused by the HPB (half pass-band) of IR filter and the other is attributed to the part of $CO_2$ absorption wavelength. The characteristics of output voltages of $CO_2$ gas sensor could be accurately modeled with three parameters which are dependent upon the ambient temperatures and represented small average error less than 1.5% with 5% standard deviation.

• Transactions of the Korean Society of Automotive Engineers
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• v.15 no.6
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• pp.102-107
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• 2007

A fast response $CO_2$ ($fCO_2$) analyzer for real-time measurement of carbon dioxide concentration during transient states of internal combustion engines has been developed. This analyzer uses non-dispersive infrared absorption (NDIR) technique for measuring $CO_2$ concentration and Kalman filter for removing noise components from output signals. The analyzer has good linearity, repeatability and drift with a response time of 11 ms; it is sufficiently fast to detect $CO_2$ concentration during transient states of internal combustion engines. The $fCO_2$ analyzer was used to measure transient $CO_2$ concentration of exhaust gas of the SI engine with a standard gas analyzer, and the signal of the $fCO_2$ analyzer was compared to that of the standard gas analyzer. The two concentrations were well matched during the steady state, and the $fCO_2$ analyzer could measure the variations of $CO_2$ concentration during the transient state.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.18 no.1
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• pp.40-46
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• 2013

The isotope ratios of $^{13}C/^{12}C$ and $^{18}O/^{16}O$ for a sample in a mass spectrometer are measured relative to those of a pure $CO_2$ reference gas (i.e., laboratory working standard). Thus, the calibration of a laboratory working standard gas to the international isotope scales (Pee Dee Belemnite (PDB) for ${\delta}^{13}C$ and Vienna Standard Mean Ocean Water (V-SMOW) for ${\delta}^{18}O$) is essential for comparisons between data sets obtained by other groups on other mass spectrometers. However, one often finds difficulties in getting well-calibrated standard gases, because of their production time and high price. Additional difficulty is that fractionation processes can occur inside the gas cylinder most likely due to pressure drop in long-term use. Therefore, studies on laboratory production of pure $CO_2$ isotope standard gas from stable solid calcium carbonate standard materials, have been performed. For this study, we propose a method to extract pure $CO_2$ gas without isotope fractionation from a solid calcium carbonate material. The method is similar to that suggested by Coplen et al., (1983), but is better optimized particularly to make a large amount of pure $CO_2$ gas from calcium carbonate material. The $CaCO_3$ releases $CO_2$ in reaction with 100% pure phosphoric acid at $25^{\circ}C$ in a custom designed, evacuated reaction vessel. Here we introduce optimal procedure, reaction conditions, and samples/reactants size for calcium carbonate-phosphoric acid reaction and also provide the details for extracting, purifying and collecting $CO_2$ gas out of the reaction vessel. The measurements for ${\delta}^{18}O$ and ${\delta}^{13}C$ of $CO_2$ were performed at Seoul National University using a stable isotope ratio mass spectrometer (VG Isotech, SIRA Series II) operated in dual-inlet mode. The entire analysis precisions for ${\delta}^{18}O$ and ${\delta}^{13}C$ were evaluated based on the standard deviations of multiple measurements on 15 separate samples of purified $CO_2$. The pure $CO_2$ samples were taken from 100-mg aliquots of a solid calcium carbonate (Solenhofen-ori $CaCO_3$) during 8-day experimental period. The multiple measurements yielded the $1{\sigma}$ precisions of ${\pm}0.01$‰ for ${\delta}^{13}C$ and ${\pm}0.05$‰ for ${\delta}^{18}O$, comparable to the internal instrumental precisions of SIRA. Therefore, we conclude the method proposed in this study can serve as a way to produce an accurate secondary and/or laboratory $CO_2$ standard gas. We hope this study helps resolve difficulties in placing a laboratory working standard onto the international isotope scales and does make accurate comparisons with other data sets from other groups.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.33 no.2
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• pp.133-140
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• 2009

A fast-response $CO_2$ analyzer has been developed for measuring the $CO_2$ concentration during transient condition of a SI engine. The analyzer consists of the non-dispersive infrared absorption method, electrical chopping system and water cooling system. The analyzer has good repeatability, linearity and permissible drift characteristic. Besides, it showed 18ms of a response to measure the $CO_2$ concentration. The fast-response $CO_2$ analyzer was applied to a single cylinder SI engine and the $CO_2$ emission was examined during engine start. Simultaneously, the standard exhaust gas analyzer, which has slow response time, was used for confirming the accuracy of the exhaust gas analysis using the fast-response $CO_2$ analyzer. The developed analyzer showed much faster responsive characteristic than that of a standard analyzer and made cycle by cycle exhaust gas analysis possible. The transient engine operating characteristics will be estimated from the $CO_2$ concentration of engine-out emissions and engine operating variables.

• Analytical Science and Technology
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• v.19 no.5
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• pp.369-375
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• 2006

Calibration gas mixtures were prepared using dynamic volumetric method according to ISO 6145-5 and the uncertainty was evaluated. Ten identical capillaries with 0.25 mm in inner diameter and 50 cm in length were applied in this system. Dilution ratio of parent gas was determined by the number of capillaries that passes parent gas and that passes balance gas through. Capillaries were made of Teflon which had good chemical stability against adsorption of gaseous substances. Mechanical valves were introduced in this system in order to minimize the thermal effect of solenoid valves. Concentration of prepared gases were compared with master grade standard gases in cylinders made by RiGAS Co. and calibration of the instrument were completed using comparison method according to ISO 6143. Experimental results showed that the coefficient of variance of diluted oxygen standard gases showed less then 0.2% in most dilution range, that of diluted hydrogen sulfide standard gases showed less then 1.0%. Therefore, it is proven that the standard gases prepared by this system are appropriate to be used as a calibration standards in ambient monitoring, etc.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2008.04a
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• pp.41-60
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• 2008

This paper analyses the main cause of pollution in Beijing city-the limiting of the pollution caused by coal burning has seen important progress, and natural gas is assuming an important role in China's energy strategy as the country actively seeks new and cleaner sources of energy, since 1997 to 2007, the gas supply for Beijing was given, compared with the air quality standard above II which set up by WHO(World Healthy Organization), as a result the important relationship between the environment and gas using was found, then the percent of $SO_2$, $NO_2$, PM10, CO, $O_3$ of air was shown from August $8^{th}-24^{th}$ 2006, Which it was verified that the quality of air will be perfect within the standard of WHO during the Olympic Game 2008 China.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.5 no.1
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• pp.83-86
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• 2004

A high temperature tolerant microelectronic-based carbon monioxde(CO) gas sensor has been developed. The gas sensing performance has been studied over a wide temperature range$(100-300^\circ{C)}$. The gas sensitivity of the sensor is high, its initial sensing behavior is very fast, and the sensor is reproducible. Pt-SiC and $Pt-SnO_2-SiC$ diodes are fabricated using standard semiconductor processes and their CO gas-sensing behaviors are analyzed as a function of CO gas concentration and temperature by I-V and $\Delta{I-t}$ methods under steady-state and transient conditions. The sensitivity of the device with $Pt-SnO_2$ catalytic gate is higher than that of the Pt gate. The experimental results indicate that $SnO_2$ layer improves the catalytic reaction of the Pt layer.

• Journal of the Korean Society for Marine Environment & Energy
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• v.6 no.3
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• pp.16-25
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• 2003

In this paper, the reduction of green house effect gas CO₂ emission and NOx gas emission by using the RORO ship coastal transport of import-export container cargo was investigated. At first, the domestic CO₂ gas emission and the transportation of import-export container cargo were Investigated. Next, the characteristic of a RORO ship and CO₂ emission standard and NOx emission standard were investigated. And also, the reduction of CO₂ emission and NOx emission by the shift of coastal transport from land transport for the transportation of import-export container cargo between Kyongin area and Pusan Port were calculated. Finally, the change of CO2 and NOx gas emission due to the change of the share of coastal transportation and the load efficiency of RORO ship are investigated. The research results show that the shift of RORO ship coastal transport from land transport was very effective to reduce the CO₂ emission but it was no good to reduce the NOx emission.

• Proceedings of the KSME Conference
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• 2008.11b
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• pp.3079-3084
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• 2008

A fast response $CO_2$ analyzer has been developed for measuring the $CO_2$ concentration during transient condition of SI engine. The analyzer is based on the non-dispersive infrared absorption technique, electrical chopping system and water cooling system. The analyzer has good repeatability, linearity and permissible drift characteristic. Besides, it has 18ms with a response to measure the $CO_2$ concentration. The fast response $CO_2$ analyzer was applied to single cylinder SI engine and the $CO_2$ emission was examined during engine start. Simultaneously, the standard exhaust gas analyzer, which has slow response time, was used for considering the engine-out $CO_2$ characteristic. The developed analyzer showed much faster responsive characteristic than that of a standard analyzer and made cycle by cycle exhaust gas analysis possible. The transient engine operating characteristics will be estimated and the transient behaviors on engine-out emission and performance will be improved.