• Title/Summary/Keyword: $CO_2$ loading

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Characteristics Analysis of MCM41 Impregnated with Ethylenediamine for CO2 Adsorption (CO2 흡착을 위한 Ethylenediamine 함침 MCM41의 특성 분석)

  • Lee, Chul-Kyu;Choi, Sung-Woo
    • Journal of Environmental Science International
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    • v.21 no.6
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    • pp.705-711
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    • 2012
  • Adsorption experiment of carbon dioxide was performed on MCM41 silica with a 30 wt.% EDA(ethylenediamine) loading at different $CO_2$ inlet concentration and various adsorption temperature. The surface characteristics of $CO_2$ capturing agent were carried out using BET analysis, X-ray diffraction and FT-IR. The results of BET showed 781 $m^2/g$ for MCM41 and 464 $m^2/g$ for EDA/MCM41. X-ray diffraction results reveled typical hexagonal pore system. The higher sorption capacity of EDA/MCM41 was about 80 $mg_{CO2}/g_{sorbent}$ with 50% $CO_2$ inlet concentration and 303 K adsorption temperature. The isosteric heat of adsorption in 303-353 K ranged from -25.47 to -28.24 KJ/mole for EDA/MCM41, which indicates $CO_2$-EDA/MCM41 interaction with exothermic adsorption process. Finally, the performance of EDA/MCM41 in 10 consecutive sorption-desorption runs was a stable with only a minor drop in its sorption capacity.

Potentiometric Determination of L-Malate Using Ion-Selective Electrode in Flow Injection Analysis Syste

  • Kwun, In-Sook;Lee, Hye-Sung;Kim, Meera
    • Preventive Nutrition and Food Science
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    • v.4 no.1
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    • pp.79-83
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    • 1999
  • A potentiometric biosensor employing a CO3-2 ion-selective electrode(ISE) and malic enzyme immobilization in al flow injection analysis (FIA) system was constructed. Analytical parameters were optimized for L-malate determination . The CO3-2 -ISE-FIA system was composed of a pump, an injector, a malic enzyme (EC1.1.1.40) reactor, a CO3-2 ion-selective electrode, a pH/mV meter and a recorder. Cofactor NADP was also injected with substrate for theenzyme reaction into the system. Optimized analytical parameters for L-malate determination in the CO3-2 ISE-FIA system were as follows ; flow rate, 14.5ml/hr ; sample injection volume, 100ul; enzyme loading in the reactor, 20 units ; length of the enzyme reactor , 7 cm ; tubing length form the enzyme reactor to the detector as a geometric factor in FIA, 15 cm . The response time for measuring the entire L-malate concentration range (10-2 ~10-5 mol/L ; 4 injections )was <15minutes . In this CO3-2 -ISE-FIA system, the potential differences due to th eformation of CO3-2 by the reaction of malic enzyme on L-malate were correlated to L-malate concentration in the range of 10-2 ~10-5mol/L ; the detection limit was 10-5 mol/L. This potentionmetric CO3-2 ISE--FIA system was found to be useful for L-malate measurement.

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COMPARISON OF RIGIDITY AND CASTABILITY IN DIFFERENT DESIGNS OF MAXILLARY MAJOR TITANIUM FRAMEWORK (타이타늄 상악 주연결장치에 디자인에 따른 주조성 및 견고성 비교)

  • Lee, Young-Jae;Vang, Mong-Sook;Yang, Hong-So;Park, Sang-Won;Park, Ha-Ok;Lim, Hyun-Pil
    • The Journal of Korean Academy of Prosthodontics
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    • v.45 no.4
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    • pp.431-443
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    • 2007
  • Statement of problem: Injuries along with discomfort may result on the oral mucosa when non-rigid material is used as the major connector in construction of RPD, since nonrigid major connectors transmit unstable forces throughout the appliance. Titanium which recently draws attention as a substitute of Co-Cr had a difficulty in fabricating due to high melting temperature but the development of casting technique makes it possible to apply to the clinical case. Purpose: The purpose of this study was to investigate the rigidity and the castability of titanium upper major connector by design and make a comparison with Co-Cr major connectors which are widely used in clinical cases now. Material and methods: Casting was done using CP-Ti(Grage 2) (Kobe still Co., Japan) for the experimental groups, and 4 various designs namely palatal strap, U-shaped bar, A-P strap, and complete palatal plate were casted and 5 of each designs were included in each group. For the experimental group, Universal testing machine (Model 4502; Instron, Canton, Mass) was used to apply vertical torsional force vertically to the horizontal plane of major connector. In the second experiment, Vertical compressive force was applied to the horizontal plane of major connector. As a comparative group, Co-Cr major connector was equally manufactured and underwent the same experimental procedures Strain rate was measured after constant loading for one minute duration, and statistical analysis was done with SPSS ver.10.0 for WIN(SPSS. Inc. USA). From the one-way ANOVA and variance analysis (P=0.05), Scheffe's multiple comparison test implemented. Results: 1. Least amount of strain was observed with complete palatal plate followed by A-P bar, palatal bar, and the U-shaped bar having most amount of strain. 2. In all designs of titanium major connector, less strain rate was observed under compressive loading than under torsional loading showing more resistance to lateral force. 3. For titanium major connector, less strain rate was observed when the force is applied to the first premolar area rather than to the second molar area indicating more strength with shorter length of lever. 4. In Comparison of Co-Cr major connector with titanium major connector, palatal strap and U-shaped bar designs showed higher strength under torsional force that is statically significant, and under compressive force, no significant difference was observed expert for U-shaped bar. 5. In titanium major connector, complete palatal plate showed lowest success rate in casting when compared with the Co-Cr major connector. Conclusion: Above results prove that when using titanium for major connector, only with designs capable of generating rigidity can the major connector have almost equal amount of rigidity as Co-Cr major connector and show lower success rate in casting when compared with the Co-Cr major connector.

Case Studies of Mass Concentration Variation in the Central-Southern Korean Peninsula Caused by Synoptic Scale Transport of Dust Storms

  • Kim, Hak-Sung;Cho, Jae-Hee
    • Journal of the Korean earth science society
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    • v.40 no.4
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    • pp.414-427
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    • 2019
  • In East Asia, the long-range transport of dust storms originating from Mongolia and northern China affects airborne dust loadings over downwind areas in the southern Korean Peninsula. Since 1997, dust loading cases caused by dust storms have been observed using the thresholds of total suspended particles (TSP, ${\geq}250{\mu}g\;m^{-3}\;hr^{-1}$) and particulate matter less than $10{\mu}g$ ($PM_{10}$, ${\geq}190{\mu}g\;m^{-3}\;hr^{-1}$) in the central-southern Korean Peninsula. There were two dust loading cases that exceeded these thresholds in 2016 and three in 2017, which reflects the downward trend of the last twenty-one years in the central-southern Korean Peninsula. Furthermore, five other dust loading cases with mass concentrations lower than the thresholds were observed from 2016 to 2017. In the moderate dust loading cases exceeding the thresholds, a descending motion of cut-off lows below $45^{\circ}N$ and a southward trough at 500 hPa gpm isopleths intensified at the western ridge, and largely extended the surface high-pressure system over southeast China. Airborne dust loadings following pronounced north-westerlies in the forward side of the high-pressure system were transported to the surface of the central-southern Korean Peninsula. However, in slight dust loading cases lower than the thresholds, the restricted descending motion of cut-off lows over $45^{\circ}N$ and the southwestward trough at 500 hPa gpm isopleths intensified the zonal flow over the Korean Peninsula. Surface high- and low-pressure systems moved eastward from the source compared to moderate dust loading cases. Due to the zonal movement of dust storms traversing eastern China, slight dust loading cases were observed with relatively higher ratios of $PM_{2.5}/TSP$ and carbon monoxide (CO) in the central-southern Korean Peninsula.

Cell Wall Micropore Loading of Pulp Fibers (펄프 섬유의 세포벽 미세공극 충전)

  • Lee, Jong-Man;Jo, Byoung-Muk
    • Journal of the Korean Wood Science and Technology
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    • v.20 no.4
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    • pp.57-64
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    • 1992
  • The unique cell wall micropores of pulp fiber can be utilized as loading site in variety of important practical application which could be the basis of new papermaking technologies. One of these includes the manufature of paper containing higher levels of in situ filler precipitated. Hardwood pulp fiber were first impregnated with the solution of sodium carbonate($Na_2CO_3$). The micropores in cell wall of pulp fibers were filled with the liquid salt solution. The second calcium nitrate($Ca(NO_3)_2$) solution formed an insoluble calcium carbonate($CaCO_3$) precipitate within the cell wall micropores by interacting with the first sodium carbonate solution. The effects of chemical concentration and dryness of pulp fibers on the retention of cell wall micropore loaded filler were investigated. The paper properties of cell wall micropore loaded pulp fibers were compared with those of conventionally loaded and lumen loaded pulp fibers. Also the presense of the fillers within the cell wall micropore was observed by SEM. Increasing the chemical concentration to generate the calcium carbonate increased the retention of filler in cell wall micropore loaded pulp fibers. The particle size distribution of precipitated calcium carbonate ranged from $0.1{\mu}m$ to $80{\mu}m$. But, the average particle size of cell wall micropore loaded calcium carbonate was $4{\mu}m$. The paper made from never dried pulp fibers, the cell wall micropores which were filled with calcium carbonate, had better mechanical and optical properties than those of conventionally loaded or lumen loaded pulp fibers.

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A study of the effect on variable generation cost by the variation of $CO_2$ emission trading price ($CO_2$ 거래비용 변화에 따른 발전원가(변동비) 영향 분석)

  • Jung, Young-Beom;Lee, Young-Eal;Yoon, Yong-Beum
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.822-823
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    • 2007
  • It is easily can be expected that Korea cannot be free under the regulation, because Korea is one of the major $CO_2$ emitter in the world. Even though Korea currently doesn't have any obligation to mitigate the carbon emission, power industry needs to study the effect of that. this paper aims to analyze the change of economic loading order for generation dispatch by various carbon price, looking at each plant's or generator's variable generation cost per unit electricity(kWh) that consists of basic generation price calculated by automatic generation system planning model, WASP 4.0, and $CO_2$ price per unit electricity generation.

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Effect of Organic Loading Rate and Hydralic Retention Time on the Volatile Fatty Acid Production in 2- Step Anaerobic Fermentation System of Swine Wastes (돈분의 2단계 혐기발효시 산생성 단계에서의 유기물 부하율과 체류시간에 따른 휘발성지방산의 생산량)

  • 김범석;이상락;맹원재
    • Journal of Animal Environmental Science
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    • v.4 no.2
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    • pp.167-174
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    • 1998
  • It is known that the anaerobic fermentation of organic matter (OM) is divided into 2 phases, acidogenic phase in which OM is digested into volatile fatty acid (VFA), and methanogenic phase where the produced VFA is converted to CH4 and CO2. In a natural fermenting procedure, these 2 phases occur at the same time. However the total production of end products (methane) may be limited if these 2 phases occur at the same time. This is believed to be due to the difference in growth rate, substrate-utilizing efficiency and favorable environment for each microbes (acidogens and methanogens), involved in each phase. It is therefore suggested for the maximum recycling of organic waste (such as animal waste) through providing 2 different steps in fermenting procedure, acidogenic phase and methanogenic phase, in each case the activity of involved microbes can be maintained at the maximum level. The results obtained from these experiments are summarized as follows : The loading rates of swine waste were made through 2.5, 5 and 10 gVS / l / d to identify its acidogenic fermenting character in this study. The VFA yield was maximized at 10 gVS / l / d of loading rate. On the basis of this study was executed to identify the optimum HRT of 1, 2 and 4 days at 10 gVS / l / d of loading rate in acidogenic phase. The maximum VFA yield was obtained at 1 days of HRT.

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The CO2 Absorption of Synthetic Amine using the Ethylene Oxide-Ammonia Reaction (에폭사이드와 암모니아의 반응을 이용한 합성아민의 이산화탄소 흡수연구)

  • CHOI, JEONGHO;YOON, YEOIL;PARK, SUNGYOUL;BAEK, ILHYUN;NAM, SUNGCHAN
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.5
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    • pp.561-569
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    • 2017
  • In this study, a synthetic amine made using the ethylene oxide-ammonia reaction was used as an absorbent to remove carbon dioxide. Existing absorbents were used in a mix in order to improve performance; however, because the ethylene oxide-ammonia reaction generates primary, secondary, and tertiary amines simultaneously, it has the merit that separate mixing of the absorbents was not needed. The performance of carbon dioxide absorption with the synthetic amine was compared to that of MEA. As a result of an experiment, it was determined that the $CO_2$ loading was 1.15 times better than that of MEA (a commonly used amine), while the cyclic capacity was 2.28 times higher. Because the heat of reaction was 1.10 times lower than for MEA, the synthetic amine showed superior performance in terms of absorption and regeneration.

Integrated System of RBC-lime Precipiatation for Simultaneous Removal of Organics and Nutrients (회전원판공정과 화학침전공정 조합을 이용한 유기물과 질소*인의 동시제거)

  • 박종안;허준무;손부순
    • Journal of Environmental Health Sciences
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    • v.24 no.1
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    • pp.132-140
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    • 1998
  • Laboratory-scale experiments were conducted using a three-stage rotating biological contactor unit followed by lime precipitation and sedimentation with effluent recycle to the first stage. The purpose of this study was to evaluate the effects of hydraulic loadings of 0.031-0.076 $m^3/m^2/d and recycle ratio of 1 to 3 on the simultaneous removal of organics and nutrients from domestic wastewater. Lime was added to maintain pH of 10.4-11.0 in the coagulation-flocculation reactor. Results showed that the highest nitrogen removal rate of 70.5% occurred at the lower hydraulic loading of 0.031 $m^3/m^2/d at a recirculation rate of 300%, and similarly, highest nitrification occurred at the same hydraulic loading and recycle ratio. Concentration of ammonia nitrogen in the effluent was less than 1 mg/l at the same operating conditions for higher nitrogen removal. Whereas, high BOD and COD removal was observed at hydraulic loading rate of 0.054 $m^3/m^2/d, and high removal of organic matter was evident from the consistent low COD and BOD value. Results obtained from the operating condition of higher loading rate, 300% of recycle rate showed the highest removals. Increasing in recycle rate and hydraulic loading rate increased the volatile solids fraction of the sludges generated to the extent of 47% at 0.076 $m^3/m^2/d hydraulic loading and 300% recirculation rate. Since pH in the flocculator was maintained at the pH of 10.4-11.0, above 90% removal of phosphorus was obtained. Average concentration of suspended solids was always maintained over 40 mg/l in the effluent. Therefore an RBC unit operating at a hydraulic loading near 0.031 $m^3/m^2/d with a recycle rate of 300% is a viable and feasible alternate conditions to produce an effluent with relative low organic matter and phosphorus, provided that there is a neutralization unit to control the pH and SS of the effluent.

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Results of immediate loading for implant restoration in partially edentulous patients: a 6-month preliminary prospective study using SinusQuickTM EB implant system

  • Kim, Jong-Hwa;Kim, Young-Kyun;Yi, Yang-Jin;Yun, Pil-Young;Lee, Hyo-Jung;Kim, Myung-Jin;Yeo, In-Sung
    • The Journal of Advanced Prosthodontics
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    • v.1 no.3
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    • pp.136-139
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    • 2009
  • STATEMENT OF PROBLEM. Many dental clinicians are concerned about immediate loading of inserted implants. However, there have been few clinical studies surveying the success rates of immediate loading, based on Korean implant systems. PURPOSE. The aim of this study was to evaluate the outcome of immediate functional loading of the implant ($SinusQuick^{TM}$EB, Neobiotech Co., Seoul, Korea) in partially edentulous maxilla or mandible. MATERIAL AND METHODS. Total 15 implants were placed. Within 2 weeks after implant insertion, provisional implant-supported fixed partial dentures were delivered to the patients. Quantitatively, marginal bone loss was measured at the time of immediate loading, after 3-months of continued loading and at the last follow-up. The mean follow-up period was 4.8 months. RESULTS. Mean marginal bone loss from implant surgery to early loading, 3-months follow-up and last follow-up was $0.03\pm0.07$ mm, $0.16\pm0.17$ mm and $0.29\pm0.19$ mm. No implant failed up to 6 months after insertion, resulting in a 100% survival rate. CONCLUSION. Immediate loading exhibited high success rate in partial edentulism for up to 6 months. Well-controlled long term clinical studies with large sample size are necessary to confirm this finding.