• Journal of Energy Engineering
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• v.20 no.3
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• pp.191-199
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• 2011

The char burn-out and NOx emissions from sub-bituminous coal were investigated in drop tube furnace under $O_2/N_2$ and $O_2/CO_2$ environments with different $O_2$ concentrations of 12, 21 and 31%. Results show that the char burn-out rate is faster as $O_2$ concentration increases higher and char burn-out rate under $O_2/CO_2$ decreases due to the lower oxygen diffusion into coal surface through the $CO_2$ rich boundary layer. NO concentration increases with increasing $O_2$ concentration, but declines at $O_2$ concentration of 31%. Meanwhile, NO emission indexes decreases monotonically with increasing $O_2$ concentration, which indicates that more NO reduction occurs with higher $O_2$ concentration probably due to greater HCN formation. For all conditions of $O_2$ concentration, the NO concentration under $O_2/N_2$ maintains higher than those of $O_2/CO_2$ due to presence of thermal NO.

• Journal of Korean Society of Transportation
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• v.33 no.4
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• pp.357-367
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• 2015

This study aims to propose integrated management strategies based on the relationship between co-benefits and total benefits of greenhouse gases and air pollutant emissions for establishing a transport and environmental policy. The results show that the integrated management of the following policies: 'Car Free Day' and 'Early Scrapping of Decrepit Diesel Vehicle', which are used for reducing reduce gasoline and diesel, can together reduce both PM and $CO_2$ emissions and increase total benefits. In addition, the integrated management of 'Car Free Day' with environment policies and 'Congestion Charge' with environment policies simultaneously controls the three factors which influence emissions, including travel volume, travel speed and emissions factor, and was found to be effective in terms of co-benefits. This study reduces both air pollutants, which are harmful to health, and greenhouse gas emissions, which influence climate change, and improves the efficiency of policy through the integrated management of policies.

• Journal of Industrial Convergence
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• v.22 no.6
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• pp.13-23
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• 2024

In this study, the optimal level of CER issuance price in the energy industry was estimated using a real options considering the uncertainty of emission price. As a result of the analysis, the break-even point for CDM projects in the energy industry registered by UNFCCC from December 2012 to the end of 2021 was 0.64-36.69 euros per ton of CO2 for each individual project. More closely, the emission permit price that reaches the break-even point when NPVw/o CER+ NPVCER ≥ 0 is estimated to be 12.10 euros on average, and the emission permit price that reaches the break-even point when NPVw/o CER + NPVCER ≥ option value is estimated to be 12.63 euros on average. Meanwhile, the option value using real options to reduce business uncertainty is about 19% at the 1-5 euro per ton level, about 11% at the 5-10 euro per ton level, and about 5% at the 10-15 euro per ton level. It was analyzed that there was an effect of increasing emissions prices due to uncertainty reduction. The results of this study may be useful to greenhouse gas reduction project entities, including investors, project operators, and companies with potential mandatory reductions.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.57 no.1
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• pp.89-97
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• 2012

Reduction of greenhouse gas (GHG) emissions from upland crop field as well as paddy field is being required, but little information on GHG emissions according to cultivation practices in upland field is available. Soil GHG emissions during the growing season were investigated in the field of three decades rotation and tillage treatments which were consisted of plow, chiesl tillage and no tillage in west central Indiana, USA in 2006. Seasonal cumulative $CO_2$ emissions were not different among treatments. $CH_4$ emission increased a little in plow tillage during early soybean growing season. Most of $N_2O$ emission occurred during early corn growing season after N-fertilizer application from mid June to mid July, and was significantly affected by tillage practices in which seasonal cumulative $N_2O$ emission was significantly higher under chisel tillage. $N_2O$ emission under no-tillage was lower about 64% and 39% than that under chisel tillage and plow tillage, respectively. No-tillage practice with rotation of corn and soybean seems to be promising in point of less GHG emission and less labor for cultivation without grain yield reduction.

• Environmental and Resource Economics Review
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• v.23 no.2
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• pp.157-185
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• 2014

The Kyoto Protocol has extended its life until 2020 by the decision at COP18 in Doha, Qatar in 2012. So has the Kyoto Mechanism of CDM, JI, and ETS. Nonetheless, the sustainability of CDM projects is jeopardized by the recent rule changes in the international emissions trade market such as EU ETS and the price decrease in emission credits. In particular, the domestic CDM projects reducing non-$CO_2$ GHG emissions are being directly affected. This study examines the trend of carbon credit price change in the international market. It also examines how the rule changes in the international emissions trade market have affected domestic non-$CO_2$ CDM projects through which mechanisms. The policy implications drawn from this study is two-fold: it suggests how the government can assist the project developers in utilizing GHG emission reduction technologies and the market in promoting investment environment before the domestic ETS enters into effect in 2015; apart from possible measures within ETS, an additional measures such as bilateral carbon offset system is suggested to help the private sector reduce uncertainty in investment and increase options to choose.

• Journal of the Korean Society of Combustion
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• v.20 no.2
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• pp.28-35
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• 2015

In this study, the CH4/air lean-rich combustion system with exhaust gas recirculation (EGR) was investigated to explore the potential for lowering pollutant emissions. To achieve this purpose, experiments of lean-rich combustion system with EGR were conducted to measure the changes in the characteristics of the pollutant emission and flame shape with various equivalence ratios and EGR rates. Here, this study was applied to the fuel distribution ratio of 3:1 for the formation of the lean and rich flames. Additionally, the results were compared with $CH_4$/air lean premixed combustion system. The results show that flame shape of lean-rich combustion system was determined by lean and rich equivalence ratios (${\Phi}_L$ and ${\Phi}_R$) and stratified flame was formed with increasing ${\Phi}_R$. According to the pollutant emission characteristics based on experimental results, the NOx and CO emission index (EINOx and EICO) decreased with increasing EGR rate. Especially, in the range needed to form a stable flame, the reduction rates of EINOx and EICO were approximately 47% and 48% for an EGR rate of 25%, global equivalence ratio of 0.85 and ${\Phi}_L$ of 0.80 compared with lean premixed combustion system (${\Phi}$ = 0.78).

• Applied Chemistry for Engineering
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• v.28 no.1
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• pp.112-117
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• 2017

This study demonstrated the emission of combustion gases of medium density fibreboard (MDF)s coated with piperazinomethyl-bis-phosphonic acid (PIPEABP), methylpiperazinomethyl-bis-phosphonic acid (MPIPEABP), N,N-dimethylethylenediaminomethyl-bis-phosphonic acid (MDEDAP), or bis-(dimethylaminomethyl) phosphinic acid (DMDAP). Each MDFs were coated in three times with a brush with 15 wt% aqueous solution of the phosphorus-nitrogen acid additives. After the specimens were dried at room temperature, the emission of combustion gases was tested using a cone calorimeter (ISO 5660-1, 2). The peak smoke production rate ($SPR_{peak}$) of the specimens coated with phosphorus-nitrogen acids was 18.5 to 41.5%, which is lower than that of using the virgin plate. However, the production of peak carbon monoxide ($CO_{peak}$) was 6.7 to 24.2% higher than that of using the virgin plate. Also, the peak carbon dioxide ($CO_{2peak}$) was 4.2 to 24.4% lower than that of using virgin plate. While the peak oxygen depletion rate was much higher than the level of 15%, which can be fatal to humans and the resulting risk could thus be eliminated. Overall, the combustibility of coated specimens was partially suppressed, but showed a negative effect on the reduction of carbon monoxide.

• Transactions of the Korean hydrogen and new energy society
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• v.23 no.1
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• pp.100-109
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• 2012

In this paper, some ideas are proposed to establish the infrastructure of all-electric houses which are able to reduce primary energy consumption and $CO_2$ emission by adopting heat pump systems and induction heating cookers excluding the use of fossil fuel energy. This electrification concept is based on the consumption of only one type of energy which means electricity as secondary energy and the conventional fossil fuel energy is just consumed to generate electricity as primary energy. All-electric house is laid on the extension of the hydrogen economy in a long-term viewpoint so that the effectiveness of this new conceptual house is estimated analyzing the reduction of $CO_2$ emission. In this analysis, the balance of electricity supply and demand is considered including the construction of new power plants by renewable energy such as nuclear, IGCC and fuel cell because decarbonization is an essential element of hydrogen technology and economy and this action is accomplished in both supply and demand side of electricity. The results are able to contribute to develop various useful hydrogen policies and strategies and some detail researches are required previously to make the best application of this new conceptual house.

• Clean Technology
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• v.25 no.1
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• pp.14-18
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• 2019

In general after the etching process, waste etching solution contains metals. (ex. Nickel (Ni), Chromium (Cr), Zinc (Zn), etc.) In this work, we proposed a recycling process for waste etching solution and refining from waste liquid contained nickel to make nickel metal nano powder. At first, the neutralization agent was experimentally selected through the hydrolysis of impurities such as iron by adjusting the pH. We selected sodium hydroxide solution as a neutralizing agent, and removed impurities such as iron by pH = 4. And then, metal ions (ex. Manganese (Mn) and Zinc (Zn), etc.) remain as impurities were refined by D2EHPA (Di-(2-ethylhexyl) phosphoric acid). The nickel powders were synthesized by liquid phase reduction method with hydrazine ($N_2H_4$) and sodium hydroxide (NaOH). The resulting nickel chloride solution and nickel metal powder has high purity ( > 99%). The purity of nickel chloride solution and nickel nano powders were measured by EDTA (ethylenediaminetetraacetic) titration method with ICP-OES (inductively coupled plasma optical emission spectrometer). FE-SEM (field emission scanning electron microscopy) was used to investigate the morphology, particle size and crystal structure of the nickel metal nano powder. The structural properties of the nickel nano powder were characterized by XRD (X-ray diffraction) and TEM (transmission electron microscopy).

• Transactions of the Korean Society of Mechanical Engineers B
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• v.26 no.6
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• pp.833-841
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• 2002

The present study examined the possibility of NOx reduction in the high temperature industrial furnaces, duct burner of gas turbine cogeneration and two-stage gas turbine combustor. The experimental study was carried out for the non-premixed flame of second stage combustor with the variations of oxygen concentration in the hot exhaust gas of first stage combustor. It also examined the flammability range, temperature and NOx, $CO_2$, $O_2$formation in the combustor with respect to oxygen concentration in which the fuel(natural gas) is supplying into the hot exhaust gas. The results show that the inner temperature of flame reaches 1,20$0^{\circ}C$ at EGR $O_2$23% and that 15ppm of NOx at EGR $O_2$15.5% increases up to 60ppm at EGR $O_2$23%. It is believed that Fenimore＇s prompt NOx mechanism is more influential on the NOx formation than Zeldovich＇s thermal NOx mechanism does.